Single-mode fiber transmission can no longer satisfy exponentially growing capacity demand. Space-division multiplexing (SDM) appears to be the only way able to dramatically improve the transmission capacity, for which, novel optical fiber is one of the key technologies. Such fibers must possess the following characteristics: 1) high mode density per cross-sectional area and 2) low crosstalk or low modal differential group delay (DMGD) to reduce complexity of digital signal processing. In this dissertation, we explore the design and characterization of three kinds of fibers for SDM: few-mode fiber (FMF), few-mode multi-core fiber (FM-MCF) and coupled multi-core fiber (CMCF) as well as their applications in transmission and networking. For the ultra-high density need of SDM, we have proposed the FMMCF. It combines advantages of both the FMF and MCF. The challenge is the inter-core crosstalk of the high-order modes. By applying a hole-assisted structure and careful fiber design, the LP11 crosstalk has been suppressed down to -40dB per km. This allows separate transmission on LP01 and LP11 modes without penalty. In fact, a robust SDM transmission up to 200Tb/s has been achieved using this fiber. To overcome distributed modal crosstalk in conjunction with DMGD, supermodes in CMCFs have been proposed. The properties of supermodes were investigated using the coupled-mode theory. The immediate benefits include high mode density and large effective area. In supermode structures, core-to-core coupling is exploited to reduce modal crosstalk or minimize DMGD. In addition, higher-order supermodes have been discovered in CMCFs with few-mode cores. We show that higher-order supermodes in different waveguide array configurations can be strongly affected by angle-dependent couplings, leading to different modal fields. Analytical solutions are provided for linear, rectangular and ring arrays. Higher-order modes have been observed for the first time using S2 imaging method. Finally, we introduce FMF to gigabit-capable passive optical networks (GPON). By replacing the conventional splitter with a photonic lantern, upstream combining loss can be eliminated. Low crosstalk has been achieved by a customized mode-selective photonic lantern carefully coupled to the FMF. We have demonstrated the first few-mode GPON system with error-free performance over 20-km 3-mode transmission using a commercial GPON system carrying live Ethernet traffic. We then scale the 3-mode GPON system to 5-mode, which resulted in a 4dB net gain in power budget in comparison with current commercial single-mode GPON systems.

Up-conversion (UC) in rare-earth co-doped fluorides to convert diode laser light in the near infrared to red, green and blue visible light is applied to make possible high performance emissive displays. The infrared-to-visible UC in the materials we study is a sequential form of non-linear two photon absorption in which a strong absorbing constituent absorbs two low energy photons and transfers this energy to another constituent which emits visible light. Some of the UC emitters' most appealing characteristics for displays are: a wide color gamut with very saturated colors, very high brightness operation without damage to the emitters, long lifetimes and efficiencies comparable to those of existing technologies. Other advantages include simplicity of fabrication, versatility of operating modes, and the potential for greatly reduced display weight and depth. Thanks to recent advances in material science and diode laser technology at the excitation wavelength, UC selected materials can be very efficient visible emitters. However, optimal UC efficiencies strongly depend on chosing proper operating conditions. In this thesis, we studied the conditions required for optimization. We demonstrated that high efficiency UC depends on high pump irradiance, low temperature and low scattering. With this understanding we can predict how to optimally use UC emitters in a wide range of applications. In particular, we showed how our very efficient UC emitters can be applied to make full color displays and very efficient white light sources.

Extreme ultraviolet lithography(EUVL) is being developed worldwide as the next generation technology to be inserted in ~ 2009 for the mass production of IC chips with feature sizes <35 nm. One major challenge to its implementation is the development of a 13.5 nm EUV source of radiation that meets the requirements of current roadmap designs of the source of illumination in commercial EUVL scanners. The light source must be debris-free, in a free-space environment with the imaging EUV optics that must provide sufficient, narrow spectral band EUV power to print 100 wafers/hr. To meet this need, extensive studies on emission from a laser plasma source utilizing tin-doped droplet target was conducted. Presented in this work, are the many optical techniques such as spectroscopy, radiometry, and imaging, that were employed to characterize and optimize emission from the laser plasma source State of the art EUV spectrographs were employed to observe the source's spectrum under various laser irradiation conditions. Comparing the experimental spectra to those from theory, has allowed the determination of the Sn ion stages responsible for emitting into the useful EUV bandwidth. Experimental results were compared to spectral simulations obtained using Collisional-Radiative Equilibrium (CRE) model, as well. Moreover, extensive measurements surveying source emission from 2 nm to 30 nm, which is the region of the electromagnetic spectrum defined as EUV, was accomplished. Absolutely calibrated metrology was employed with the Flying Circus instrument from which the source's conversion efficiency (CE)--from laser to the useful EUV energy--was characterized under various laser irradiation conditions. Hydrodynamic simulations of the plasma expansion together with the CRE model predicted the condition at which optimum conversion could be attained. The condition was demonstrated experimentally, with the highest CE to be slightly above 2%, which is the highest value among all EUV source contenders. In addition to laser intensity, the CE was found to depend on the laser wavelength. For better understanding, this observation is compared to results from simulations. Through a novel approach in imaging, the size of the plasma was characterized by recording images of the plasma within a narrow band, around 13.5 nm. The size, approximately 100 ìm, is safely within the etendue limit set by the optical elements in the EUV scanner. Finally, the notion of irradiating the target with multiple laser beams was explored for the possibility of improving the source's conversion efficiency.

The need for more bandwidth in communications has stimulated the search for new fiberizable materials with properties superior to fused silica which is the current state-of-the-art. One of the key properties is Raman gain by which a pump beam amplifies a signal beam of longer wavelength. An apparatus capable of directly measuring the spectral dependence and absolute magnitude of the material Raman gain coefficient using nonlinear optics techniques has been built. Using radiation from a 1064 nm Nd:YAG laser as the pump and from a tunable Optical Parametric Generator and Amplifier as the signal, the Raman gain spectrum was measured for different families of glass samples with millimeter thickness. A number of glass families were investigated. Tellurites with added oxides of tungsten, niobium, and thallium produced the largest Raman gain coefficients of any oxide family reported to date, typically 30-50 times higher than that of fused silica. On the other hand, phosphate families were found with spectrally broad Raman gain response, 5 times broader than fused silica and flat to [plus or minus] dB over the full spectral range in some compositions. Although the chalcogenides were found to photodamage easily, coefficients 50 - 80 times that of fused silica were measured. Finally, a numerical study was undertaken to predict the theoretical performance and noise properties of tellurite fibers for communications. Included in the computer modeling were linear loss; the interaction among multiple pumps and signals; forward and/or backward propagating pump beams; forward, backward and double Rayleigh scattering; noise properties of amplifiers; excess noise, etc. This led to a comparison of the optical signal-to-noise characteristics for Raman gain in a tellurite versus a silica fiber.

A new fully integrated wavelength stabilization scheme based on grating-coupled surface-emitting lasers is explored. This wavelength stabilization scheme relies on two gratings. The first grating is fabricated on the p-side of the semiconductor laser in close proximity to the laser waveguide such that it couples light out of the guided mode of the waveguide into a propagating mode in the substrate; this grating is known as the grating coupler. The second grating is fabricated on the n-side of the substrate such that for the stabilization wavelength, this second grating operates in the Littrow condition and is known as the feedback grating. Furthermore with the proper design of the two gratings, the feedback grating will operate under total internal reflection conditions allowing a near unity retro-reflection of the light of the stabilization wavelength. The grating coupler and feedback grating together comprise a dual grating reflector (DGR). The DGR wavelength stabilization scheme is investigated both theoretically by means of numerical modeling and experimentally by integration of a DGR as a wavelength selective reflector into a single quantum well semiconductor laser with a gain peak centered at 975nm. Numerical modeling predicts a peak reflection of approximately 70% including losses and a spectral width of 0.3nm. The integration of a DGR into a semiconductor laser proved both the efficacy of the scheme and also allowed us to experimentally determine the effective reflectivity to be on the order of 62%; the spectral width of light output from these devices is typically on the order of 0.2nm. Furthermore, these devices had light-current characteristic slopes greater than 0.84W/A operating under continuous wave conditions. The DGR was then modified to provide a reflection with two spectral peaks. A semiconductor device incorporating this dual wavelength DGR was fabricated and tested. These devices showed a peak optical power of in excess of 5.5W and a light-current characteristic slope of 0.86W/A in quasi continuous wave operation; these devices also exhibit a large operating current range in which both wavelengths have comparable output powers. Another modified DGR design was investigated for the purpose of providing an even narrower spectral reflection. Devices incorporating this modified design provided an output with a spectral width as narrow as 0.06nm. DGRs were also integrated into an extremely broad area device of an unorthodox geometry; square devices that lase in two orthogonal directions were fabricated and tested. The last idea investigated was combining a DGR wavelength stabilized laser with a tapered semiconductor optical amplifier into a master oscillator power amplifier device, with the optical coupling between the two components provided by identical grating couplers disposed on the p-side surfaces of each of the devices. These master oscillator power amplifiers provide a peak power of 32W when operating under quasi continuous wave operation.

Liquid crystal (LC) devices can be operated as amplitude modulators and phase modulators. LC amplitude modulation is commonly used in liquid crystal display (LCD) while phase-only modulation is useful for laser beam steering, tunable grating, prism, lens, and other photonic devices. Most LC devices are polarization dependent and require at least one polarizer. As a result, the optical efficiency is low. To enhance display brightness, a power hungry backlight has to be used leading to a high power consumption and short battery life. In a LC phase modulator, the polarization dependent property complicates the laser beam steering system. It is highly desirable to develop new operating mechanisms that are independent of the incident light polarization. In this dissertation, we have developed eight polarization-independent liquid crystal operation principles: three of them are aimed for displays and the other five are for phase modulators. For amplitude modulations, a new polymer-dispersed liquid crystal (PDLC) and two new dye-doped LC gels are polarizer-free by combining light scattering with dye-absorption effects. In phase modulation, we explore five device concepts: PDLC and Polymer-Stabilized Cholesteric Texture (PSCT), homeotropic LC gels, thin polymer film separated double-layered structure, and double-layered LC gels. In the low voltage regime, both PDLC and PSCT have a strong light scattering. However, as the voltage exceeds a certain level, the phase modulation is scattering-free and is independent of polarization. The homeotropic LC gels do not require any biased voltage and the response time is still fast. Although the remaining phase in these devices is small, they are still useful for micro-photonic device applications. To increase the phase change, thin polymer film separated double-layered structure is a solution. The orthogonal arrangement of top and bottom LC directors results in polarization independence. However, the response time is slow. Similarly, double-layered LC gels are not only polarization independent but also fast response due to the established polymer network.

All-optical synchronization and its application in advanced optical communications have been investigated in this dissertation. Dynamics of all-optical timing synchronization (clock recovery) using multi-section gain-coupled distributed-feedback (MS-GC DFB) lasers are discussed. A record speed of 180-GHz timing synchronization has been demonstrated using this device. An all-optical carrier synchronization (phase and polarization recovery) scheme from PSK (phase shift keying) data is proposed and demonstrated for the first time. As an application of all-optical synchronization, the characterization of advanced modulation formats using a linear optical sampling technique was studied. The full characterization of 10-Gb/s RZ-BPSK (return-to-zero binary PSK) data has been demonstrated. Fast lockup and walk-off of the all-optical timing synchronization process on the order of nanoseconds were measured in both simulation and experiment. Phase stability of the recovered clock from a pseudo-random bit sequence signal can be achieved by limiting the detuning between the frequency of free-running self-pulsation and the input bit rate. The simulation results show that all-optical clock recovery using TS-DFB lasers can maintain a better than 5 % clock phase stability for large variations in power, bit rate and optical carrier frequency of the input data and therefore is suitable for applications in ultrafast optical packet switching. All-optical timing synchronization of 180-Gb/s data streams has been demonstrated using a MS-GC DFB laser. The recovered clock has a jitter of less than 410 fs over a dynamic range of 7 dB. All-optical carrier synchronization from phase modulated data utilizes a phase sensitive oscillator (PSO), which used a phase sensitive amplifier (PSA) as a gain block. Furthermore, all-optical carrier synchronization from 10-Gb/s BPSK data was demonstrated in experiment. The PSA is configured as a nonlinear optical loop mirror (NOLM). A discrete linear system analysis was carried out to understand the stability of the PSO. Complex envelope measurement using coherent linear optical sampling with mode-locked sources is investigated. It is shown that reliable measurement of the phase requires that one of the optical modes of the sampling pulses be locked to the optical carrier of the data signal to be measured. Carrier-envelope offset (CEO) is found to have a negligible effect on the measurement. Measurement errors of the intensity profile and phase depend on the pulsewidth and chirp of the sampling pulses as well as the detuning between the carrier frequencies of the data signal and the center frequency of the sampling source. Characterization of the 10-Gb/s RZ-BPSK signal was demonstrated using the coherent detection technique. Measurements of the optical intensity profile, chirp and constellation diagram were demonstrated. A CW local oscillator was used and electrical sampling was performed using a sampling scope. A novel feedback scheme was used to stabilize homodyne detection.

The main goal of this dissertation is to introduce and demonstrate a new method for the rapid determination of the nonlinear absorption spectra and the dispersion of the nonlinear refraction of optical materials in the visible and near IR spectral regions. However, conventional methods like, white-light continuum pump-probe and Z-scan techniques were used to measure the peak 2PA cross-sections for a number of commercially available photoinitiators. In the new method mentioned above, a high energy, broadband femtosecond white-light continuum is used to replace the single wavelength source conventionally used in a Z-scan experiment. In a Z-scan experiment, the transmittance of a focused beam through a sample is monitored as the sample travels through the focus, in the Z direction, along the focused beam. Providing the sample exhibits nonlinear absorption and/or refraction, the detector monitors a change in transmittance and/or a change in the beam divergence (if the energy is partially collected through an aperture in front of the detector). Replacing the single wavelength source with a white-light continuum allows for a much faster way of measuring nonlinear absorption/refraction spectra. This could eliminate the need for using other tunable sources (e.g. Optical Parameter Generators/Amplifiers) for nonlinear measurements. These sources made nonlinear spectroscopy using Z-scan experiments a time consuming task. This new source/method allows for rapid and simultaneous measurement of the nonlinear absorption spectrum and the dispersion of the nonlinear refraction. We have confirmed the functionality of the continuum as a source for nonlinear optical characterization of materials by using it to perform Z-scans on the well characterized semiconductors ZnSe and ZnS and on solutions of organic dyes.

Multi-photon absorption processes have received significant attention from the scientific community during the last decade, mainly because of their potential applications in optical limiting, data storage and biomedical fields. Perhaps, one of the most investigated processes studied so far has been two-photon absorption (2PA). These investigations have resulted in successful applications in all the fields mentioned above. However, 2PA present some limitations in the biomedical field when pumping at typical 2PA wavelengths. In order to overcome these limitations, three-photon absorption (3PA) process has been proposed. However, 3PA in organic molecules has a disadvantage, typical values of σ3' are small (10-81 cm6s2/photon2), therefore, 3PA excitation requires high irradiances to induce the promotion of electrons from the ground state to the final excited state. To overcome this obstacle, specific molecules that exhibit large 3PA cross-section must be designed. Thus far, there is a lack of systematic studies that correlate 3PA processes with the molecular structure of organic compounds. In order to fill the existent gap in 3PA molecular engineering, in this dissertation we have investigated the structure/property relationship for a new family of fluorene derivatives with very high three-photon absorption cross-sections. We demonstrated that the symmetric intramolecular charge transfer as well as the -electron conjugation length enhances the 3PA cross-section of fluorene derivatives. In addition, we showed that the withdrawing electron character of the attractor groups in a pull-pull geometry proved greater 3PA cross-section. After looking for alternative ways to enhance the effective σ3' of organic molecules, we investigated the enhancement of two- and three-photon absorption processes by means of Surface Plasmon. We demonstrated an enhancement of the effective two- and three-photon absorption cross-section of an organic compound of 480 and 30 folds, respectively. We proved that the enhancement is a direct consequence of the electric field enhancement at a metal/buffer interface. Next, motivated by the demands for new materials with enhanced nonlinear optical properties, we studied the 3PA of Hematoporphyrin IX and J-aggregate supramolecular systems. As a result, we were able to propose the use of 3PA in photodynamic therapy using Photofrin, the only drug approved by the FDA for PDT.

This dissertation explores various aspects and potential of optical pulse generation based on active, passive, and hybrid mode-locked quantum dot semiconductor lasers with target applications such as optical interconnect and high speed signal processing. Design guidelines are developed for the single mode operation with suppressed reflection from waveguide discontinuities. The device fabrication procedure is explained, followed by characteristics of FP laser, SOA, and monolithic two-section devices. Short pulse generation from an external cavity mode-locked QD two-section diode laser is studied. High quality, sub-picosecond (960 fs), high peak power (1.2 W) pulse trains are obtained. The sign and magnitude of pulse chirp were measured for the first time. The role of the self-phase modulation and the linewidth enhancement factor in QD mode-locked lasers is addressed. The noise performance of two-section mode-locked lasers and a SOA-based ring laser was investigated. Significant reduction of the timing jitter under hybrid mode-locked operation was achieved owing to more than one order of magnitude reduction of the linewidth in QD gain media. Ultralow phase noise performance (integrated timing jitter of a few fs at a 10 GHz repetition rate) was demonstrated from an actively mode-locked unidirectional ring laser. These results show that quantum dot mode-locked lasers are strong competitors to conventional semiconductor lasers in noise performance. Finally we demonstrated an opto-electronic oscillator (OEO) and coupled opto-electronic oscillators (COEO) which have the potential for both high purity microwave and low noise optical pulse generation. The phase noise of the COEO is measured by the photonic delay line frequency discriminator method. Based on this study we discuss the prospects of the COEO as a low noise optical pulse source.