The necessity of using extremely high sensitivity biosensors in certain research areas has remarkably increased during the last two decades. Optical structures, where light is used to transduce biochemical interactions into optical signals, are a very interesting approach for the development of this type of biosensors. Within optical sensors, photonic integrated architectures are probably the most promising platform to develop novel lab-on-a-chip devices. Such planar structures exhibit an extremely high sensitivity, a significantly reduced footprint and a high multiplexing potential for sensing applications. Furthermore, their compatibility with CMOS processes and materials, such as silicon, opens the route to mass production, thus reducing drastically the cost of the final devices. Optical sensors achieve their specificity and label-free operation by means of a proper chemical functionalization of their surfaces. The selective attachment of the receptors allows the detection of the target analytes within a complex matrix. This PhD Thesis is focused on the development of label-free photonic integrated sensors in which the detection is based on the interaction of the target analytes with the evanescent field that travels along the structures. Herein, we studied several photonic structures for sensing purposes, such as photonic crystals and ring resonators. Photonic crystals, where their periodicity provokes the appearance of multiple back and forth reflections, exhibits the so-called slow-light phenomenon that allows an increase of the interaction between the light and the target matter. On the other hand, the circulating nature of the resonant modes in a ring resonator offers a multiple interaction with the matter near the structure, providing a longer effective length. We have also proposed a novel approach for the interrogation of photonic bandgap sensing structures where simply the output power needs to measured, contrary to current approaches based on the spectral interrogation of the photonic structures. This novel technique consists on measuring the overlap between a broadband source and the band edge from a SOI-based corrugated waveguide, so that we can determine indirectly its spectral position in real-time. Since there is no need to employ tunable equipment, we obtain a lighter, simpler and a cost-effective platform, as well as a real-time observation of the molecular interactions. The experimental demonstration with antibody detection measurements has shown the potential of this technique for sensing purposes / García Castelló, J. (2014). A Novel Approach to Label-Free Biosensors Based on Photonic Bandgap Structures [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/35398

Ce mémoire présente la modélisation, la simulation, l’expérimentation et la conception d’une structure composite intelligente pour des mesures de haute température (jusqu’à 300 °C). Pour ce faire, une fibre à revêtement métallique, particulièrement résistante pour de tels niveaux thermiques, a été considérée et intégrée au sein d’un revêtement d'alumine. La structure composite intelligente se compose alors du substrat, du dépôt et d’un capteur à fibre optique à modulation d’intensité. Pour mener cette étude, une estimation des flux thermiques basée sur le thermogramme expérimental s’est révélée nécessaire afin d’alimenter un modèle numérique. Différents modèles ont ensuite été construits afin d’évaluer les niveaux de températures atteints en surface ainsi que les niveaux de contraintes au sein même du composite. La simulation a montré que le dépôt pouvait thermiquement être considéré comme une couche mince et que la diffusion de la chaleur au sein du dépôt et du substrat était rapide et pouvait être estimée à l'échelle de la milliseconde. La répartition des contraintes est comme on pouvait s'y attendre dépendante du flux incident mais aussi de la géométrie globale du composite. Les contraintes restent relativement uniformes lors de l'échauffement et durant leur propagation mais s’intensifient après le refroidissement. Il s'avère également que les contraintes résultantes ne sont pas symétriques dans la fibre et sont dépendantes de la position de la fibre par rapport au substrat. Après une phase de modélisation des niveaux thermiques et des contraintes susceptibles d’être atteints au sein du matériau, une phase expérimentale consistant à intégrer une fibre optique non fonctionnalisée dans un dépôt d’alumine a donc été réalisée. Les observations microscopiques en surface et en coupe ont été effectuées afin de vérifier l’intégrité de la fibre intégrée. L’adhérence mécanique des fibres a ensuite été mesurée ainsi que l’atténuation optique pendant le processus d’intégration et le comportement thermique de l’ensemble durant des cyclages thermiques. Enfin, un capteur à fibre optique à modulation d’intensité a été conçu par intégration dans un dépôt céramique réalisé par projection thermique. Un système de mesure de la température a donc été construit et les premiers essais de réponse thermique ainsi que le cyclage thermique du capteur de température ont été effectués et analysés. En concluision, cette étude démontre la faisabilité d’une structure composite intelligente par intégration d'un capteur à modulation d’intensité à fibre optique dans un dépôt céramique élaboré par projection thermique susceptible de pouvoir travailler jusqu’à des températures de 300 °C. / This paper presents the modeling, simulation, experimentation and design of a smart composite structrure for high temperature measurements (up to 300 °C). In order to achieve this goal, a high temperature resistant metal coated optical fiber was considered and integrated into alumina coating. The smart composite structure consists of a substrate, a coating and an intensity modulated optical fiber temperature sensor. Firstly, an estimation of heat flux based on a experimental thermogram was firstly carried out in order to feed a numerical modeling. Then, different modelings were built to evaluate the surface temperature levels as well as the composite stress levels. The simulation showed that the composite (substrate and coating) could be considered as a thermally thin medium, the heat propagation within the composite was fast and could be estimated at a scale of millisecond. The stresses remained relatively uniform during the heating process but intensified during the cooling process. The modeling also showed that the stresses are not symmetrical in the fiber and depend on the position of the fiber relative to the substrate. After a modeling evaluation of the thermal levels as well as the stresses that may be achieved in the composite, an experimental step integrating a optical fiber into a thermal coating was carried out. Microscopic observation of surface and cross section were conducted in order to analyze the characteristics of the integrated fiber. The mechanical strength of the integrated fiber was then measured and the optical attenuation during the integration process as well as the thermal behavior of the integrated fiber during the thermal cycling were evaluated. Finally, an intensity modulated optical fiber temperature sensor was designed and integrated into ceramic coating by thermal spraying. A temperature measuring system was designed and the first tests of the thermal response as well as thermal cycling of temperature sensor were carried out. This study demonstrates the feasibility of designing a high temperature resistant smart composite structure by integrating an intensity modulated optical fiber temperature sensor in a ceramic coating elaborated by thermal spraying.

[EN] Microwave photonics (MWP) is a well-established research field that investigates the use of photonic technologies to generate, distribute, process and analyze RF waveforms in the optical domain. Despite its great potential to solve long-standing problems faced by both the microwave and electronics industries, MWP systems are bulky, expensive and consume a lot of power. Integrated microwave photonics (IMWP) is an emerging area of research that promises to alleviate most of these drawbacks through the use of photonic integrated circuits (PIC). In this work, we have aimed at further closing the gap between the worlds of MWP and integrated optics. In particular, we have focused on the design and experimental characterization of PICs with reconfigurable, ring-assisted Mach-Zehnder interferometer filters (RAMZI), and demonstrated its potential use in different IMWP applications. These filters consist of a symmetric MZI loaded with ring resonators, which are coupled to the MZI branches by different optical couplers. The contributions of this thesis can be split into two sections. In the first one, we demonstrate integrated optical couplers and reflectors with variable power splitting and reflections ratios. These exploit the well-known properties of tapered multimode interference couplers (MMI), and their inherent robustness makes them highly suitable for the implementation of both RAMZI and reflective filters. Besides, we study in detail the impact of manufacturing deviations in the performance of a 4x4 MMI-based 90º hybrid, which is a fundamental building block in coherent optical communication systems. In the second section, we demonstrate the use of integrated RAMZI filters for three different IMWP applications, including instantaneous frequency measurement (IFM), direct detection of frequency-modulated signals in a MWP link, as well as in tunable, coherent MWP filters. A theoretical analysis of the limits and trade-offs that exist in photonics-based IFM systems is also provided. Even though these are early proof-of-concept experiments, we hope that further technological developments in the field will finally turn MWP into a commercial reality. / [ES] La fotónica de microondas (MWP) es un campo de investigación que estudia el uso de tecnologías ópticas para generar, distribuir, procesar y analizar señales de RF. A pesar de su gran potencial para resolver algunos de los problemas a los que se enfrentan las industrias electrónica y de microondas, estos sistemas son voluminosos, caros y consumen mucha potencia. La fotónica de microondas integrada (IMWP) es un área emergente que promete solucionar todos estos inconvenientes a través de la utilización de circuitos ópticos integrados (PIC). En esta tesis, hemos pretendido avanzar un poco más en el acercamiento entre estas dos disciplinas. En concreto, nos hemos centrado en el diseño y caracterización experimental de PICs con filtros reconfigurables basados en interferómetros Mach-Zehnder cargados con anillos (RAMZI), y demostrado su potencial uso en diferentes aplicaciones de IMWP. Los filtros RAMZI están hecho básicamente de un MZI simétrico cargado con anillos, los cuales a su vez se acoplan a las ramas del interferómetro a través de distintos acopladores ópticos. Las contribuciones de este trabajo se pueden dividir en dos partes. En la primera, hemos demostrado acopladores y reflectores ópticos integrados con coeficientes de acoplo y reflexión variables. Éstos explotan las propiedades de los acopladores por interferencia multimodal (MMI), y su robustez les hace muy atractivos para la implementación de filtros RAMZI y de tipo reflectivo. Además, hemos analizado el impacto que las tolerancias de fabricación tienen en el rendimiento de un híbrido óptico de 90º basado en un MMI 4x4, el cual es un elemento fundamental en los sistemas de comunicaciones ópticas coherentes. En la segunda parte, hemos demostrado el uso de filtros RAMZI en tres aplicaciones distintas de IMWP. En concreto, hemos utilizado dichos filtros para implementar sistemas de medida de frecuencia instantánea (IFM), detección directa de señales moduladas en frecuencia para enlaces fotónicos, así como en filtros coherentes y sintonizables de MWP. También hemos desarrollado un análisis teórico de las limitaciones y problemas que existen en los sistemas IFM. A pesar de que todos los experimentos realizados han consistido en prototipos para una prueba de concepto, esperamos que futuros avances tecnológicos permitan que la fotónica de microondas se convierta algún día en una realidad comercial. / [CA] La fotònica de microones (MWP) és un camp d'investigació que estudia l'ús de tecnologies òptiques per a generar, distribuir, processar y analitzar senyals de radiofreqüència. A pesar del seu gran potencial per a resoldre alguns dels problemes als que s'enfronten les indústries electrònica i de microones, estos sistemes son voluminosos, cars i consumixen molta potència. La fotònica de microones integrada (IMWP) és un àrea emergent que promet solucionar tots estos inconvenients a través de la utilització de circuits òptics integrats (PIC). En esta tesi, hem pretés avançar un poc més en l'acostament entre estes dos disciplines. En concret, ens hem centrat en el disseny i caracterització experimental de PICs amb filtres reconfigurables basats en interferòmetres Mach-Zehnder carregats amb anells (RAMZI), i demostrat el seu potencial en diferents aplicacions d' IMWP. Els filtres RAMZI estan fets bàsicament d'un MZI simètric carregat amb anells, els quals, al seu torn, s'acoblen a les branques del interferòmetre a través de distints acobladors òptics. Les contribucions d'este treball es poden dividir en dos parts. En la primera, hem demostrat acobladors i reflectors òptics integrats amb coeficients de transmissió i reflexió variables. Estos exploten les propietats dels acobladors per interferència multimodal (MMI), i la seua robustesa els fa molt atractius per a la implementació de filtres RAMZI i de tipo reflectiu. A més a més, hem analitzat l'impacte que les toleràncies de fabricació tenen en el rendiment d'un híbrid òptic de 90 graus basat en un MMI 4x4, el qual és un element fonamental en els sistemes de comunicacions òptiques coherents. En la segona part, hem demostrat l'ús de filtres RAMZI en tres aplicacions diferents de IMWP. En concret, hem utilitzat estos filtres per a implementar sistemes de mesura de freqüència instantània (IFM), detecció directa de senyals modulades en freqüència per a enllaços fotònics, així com en filtres coherents i sintonitzables de MWP. També hem desenvolupat una anàlisi teòrica de les limitacions i problemes que existixen en els sistemes IFM. A pesar de que tots els experiments realitzats han consistit en prototips per a una prova de concepte, esperem que futurs avanços tecnològics permeten que la fotònica de microones es convertisca algun dia en una realitat comercial. / Sánchez Fandiño, JA. (2016). Integrated Optical Filters for Microwave Photonic Applications [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/67690

Este trabalho tem por objetivo a extensão de métodos numéricos baseados em diferenças finitas no domínio do tempo (FDTD) e no domínio da freqüência (FD-BPM) para a simulação da propagação de ondas eletromagnéticas em materiais com propriedades ópticas diversas, por exemplo, isotrópicos, anisotrópicos, lineares, não-lineares, bem como a combinação destes em uma mesma estrutura. Inicialmente foram elaborados formalismos bidimensionais (FDTD e FD-BPM), dos quais foram investigados modos com polarização TM (Magnético Transversal) que se propagam em estruturas planares magnetoópticas/não-lineares/lineares. Esta polarização foi escolhida tendo em vista o campo magnetostático dc adotado, o qual possibilitou a observação do fenômeno não-recíproco associado ao não-linear simultaneamente. Por outro lado, é bem sabido que o método FDTD é computacionalmente muito intensivo. Portanto, um grande esforço foi dedicado aos formalismos no domínio da freqüência, os quais foram implementados em duas e três dimensões. Este último foi estendido para um formalismo totalmente vetorial, capaz de simular modos híbridos ou até mesmo a transferência de energia entre modos de polarizações ortogonais. Isto nos permitiu investigar geometrias ainda mais complexas, tais como um isolador óptico baseado em um guia de onda tip rib utilizando material magnetooptico. Adicionalmente, fenômenos de natureza complexa, tais como a dinâmica dos condensados de luz em materiais com não-lineares do tipo Kerr com saturação, também conhecidos como meios não-lineares cúbico-qüínticos, foram investigados pela primeira vez com um formalismo vetorial. Finalmente, métodos numéricos capazes de considerar qualquer combinação de materiais com propriedades ópticas distintas (linear e/ou não-linear e/ou magnetoóptico) são uma ferramenta extraordinária para a comunidade científica para o projeto de novos dispositivos ópticos, bem como a investigação de novos efeitos físicos com vistas à aplicações em computação óptica, que podem resultar em um menor e mais eficiente número de componentes para sistemas de comunicações ópticos. / This work introduces three improved formalisms for the analysis of electromagnetic wave propagation through materials with distinct optical properties, i.e., isotropic, anisotropic, linear, nonlinear, or any combination of them. Two finite difference approaches were extensively investigated in this work for this purpose, namely the finite difference in time domain (FDTD), and the finite difference beam propagation method (2D and 3D FD-BPM), these in frequency domain. Initially, a TM (transverse magnetic) mode propagating through a planar magnetooptic/nonlinear/linear waveguide was investigated by way of a two-dimensional formalism (FDTD and FD-BPM). This mode polarization was chosen based on the orientation of the external magnetostatic field adopted, which favored the observation of non-reciprocal and nonlinear effects simultaneously. On the other hand, it is well known that FDTD formalisms are computationally intensives. Therefore, a great effort was dedicated to its frequency domain counterpart (FD-BPM), which was implemented in two and three dimensions. The later was further extended to a fully vectorial formalism, which is capable of simulating hybrid modes or even the energy transfer between orthogonal modes. This enabled us to investigate more complex geometries, such as an optical isolator based on magnetooptic rib waveguide. Additionally, complex phenomena, such as the dynamic of light condensates in bulk nonlinear Kerr media with saturation, also known as cubic-quintic nonlinear media, were investigated for the first time with a 3D vectorial formalism. Finally, numerical methods capable of handling any combination of materials with distinct optical properties (linear and/or nonlinear and/or magnetooptic) are an extraordinary tool for the scientific community for the design of new optical devices, as well as the investigation of new physical effects aimed for optical computing, that may result in fewer and more efficient components for optical communication systems.

Este trabalho tem por objetivo a extensão de métodos numéricos baseados em diferenças finitas no domínio do tempo (FDTD) e no domínio da freqüência (FD-BPM) para a simulação da propagação de ondas eletromagnéticas em materiais com propriedades ópticas diversas, por exemplo, isotrópicos, anisotrópicos, lineares, não-lineares, bem como a combinação destes em uma mesma estrutura. Inicialmente foram elaborados formalismos bidimensionais (FDTD e FD-BPM), dos quais foram investigados modos com polarização TM (Magnético Transversal) que se propagam em estruturas planares magnetoópticas/não-lineares/lineares. Esta polarização foi escolhida tendo em vista o campo magnetostático dc adotado, o qual possibilitou a observação do fenômeno não-recíproco associado ao não-linear simultaneamente. Por outro lado, é bem sabido que o método FDTD é computacionalmente muito intensivo. Portanto, um grande esforço foi dedicado aos formalismos no domínio da freqüência, os quais foram implementados em duas e três dimensões. Este último foi estendido para um formalismo totalmente vetorial, capaz de simular modos híbridos ou até mesmo a transferência de energia entre modos de polarizações ortogonais. Isto nos permitiu investigar geometrias ainda mais complexas, tais como um isolador óptico baseado em um guia de onda tip rib utilizando material magnetooptico. Adicionalmente, fenômenos de natureza complexa, tais como a dinâmica dos condensados de luz em materiais com não-lineares do tipo Kerr com saturação, também conhecidos como meios não-lineares cúbico-qüínticos, foram investigados pela primeira vez com um formalismo vetorial. Finalmente, métodos numéricos capazes de considerar qualquer combinação de materiais com propriedades ópticas distintas (linear e/ou não-linear e/ou magnetoóptico) são uma ferramenta extraordinária para a comunidade científica para o projeto de novos dispositivos ópticos, bem como a investigação de novos efeitos físicos com vistas à aplicações em computação óptica, que podem resultar em um menor e mais eficiente número de componentes para sistemas de comunicações ópticos. / This work introduces three improved formalisms for the analysis of electromagnetic wave propagation through materials with distinct optical properties, i.e., isotropic, anisotropic, linear, nonlinear, or any combination of them. Two finite difference approaches were extensively investigated in this work for this purpose, namely the finite difference in time domain (FDTD), and the finite difference beam propagation method (2D and 3D FD-BPM), these in frequency domain. Initially, a TM (transverse magnetic) mode propagating through a planar magnetooptic/nonlinear/linear waveguide was investigated by way of a two-dimensional formalism (FDTD and FD-BPM). This mode polarization was chosen based on the orientation of the external magnetostatic field adopted, which favored the observation of non-reciprocal and nonlinear effects simultaneously. On the other hand, it is well known that FDTD formalisms are computationally intensives. Therefore, a great effort was dedicated to its frequency domain counterpart (FD-BPM), which was implemented in two and three dimensions. The later was further extended to a fully vectorial formalism, which is capable of simulating hybrid modes or even the energy transfer between orthogonal modes. This enabled us to investigate more complex geometries, such as an optical isolator based on magnetooptic rib waveguide. Additionally, complex phenomena, such as the dynamic of light condensates in bulk nonlinear Kerr media with saturation, also known as cubic-quintic nonlinear media, were investigated for the first time with a 3D vectorial formalism. Finally, numerical methods capable of handling any combination of materials with distinct optical properties (linear and/or nonlinear and/or magnetooptic) are an extraordinary tool for the scientific community for the design of new optical devices, as well as the investigation of new physical effects aimed for optical computing, that may result in fewer and more efficient components for optical communication systems.

Optofluidics is a new branch within photonics which attempts to unify concepts from optics and microfluidics. Unification of photonics and microfluidics enable us to carry out analysis of fluids through highly sensitive optical sensing device. These optical sensing devices are contained within a microchip, wherein light is made to pass through analyte (fluids of few nanoliters). The interaction between light and fluid gives rise to highly sensitive diagnostic systems. In this work the fabrication and performance characterization of a fluorescent green OLED for optofluidic applications is presented. The effect of thickness variation of hole injection (CuPc) and hole blocking (BCP) layers on the performance of fluorescent green organic light emitting diodes (OLEDs) have been studied. Even though these two organic layers have opposite functions, yet there is a particular combination of their thicknesses when they function in conjunction and luminous efficiency and power efficiency are maximized. The optimum thickness of CuPc layer, used as hole injection layer and BCP used as hole blocking layer were found to be 18 nm and 10 nm respectively. It is with this delicate adjustment of thicknesses, charge balancing was achieved and luminous efficiency and power efficiency were optimized. Such OLEDs with higher luminance can be monolithically integrated with other optical and fluidic components on a common substrate and can function as monolithically integrated internal source of light in optofluidic sensors. In this work the analysis of a fully integrated optofluidic lab-on-a-chip sensor for refractive index and absorbance based sensing using fluorescent green organic light emitting diode (OLED) as a light source is also presented. This device consists of collinear input and output waveguides which are separated by a microfluidic channel. When light is passed through the analyte contained in the fluidic gap an optical power loss due to absorption of light takes place. Apart from absorption a mode-mismatch between collinear input and output waveguide also occurs. The degree of mode-mismatch, quantum of optical power loss due to absorption of light by the fluid forms the basis of our analysis. Detection of minutest change in refractive index and changes in concentration of species contained in the analyte is indicative of sensitivity. Various parameters which influence the sensitivity of the sensor are mode spot size, refractive index of the fluid, molar concentration of the species contained in the analyte, width of the fluidic gap, waveguide geometry. By correlating various parameters, an optimal fluidic gap distance corresponding to a particular mode spot size to achieve the best sensitivity for refractive index based sensing and absorbance based sensing have been determined.

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