This thesis explores the natural forces controlling variability of the tropospheric oxidants on interannual to glacial-interglacial time scales. The oxidants (primarily OH and ozone) determine the lifetime of many trace gases of human interest, including air pollutants and long-lived greenhouse gases such as methane. The oxidants respond to meteorological conditions, precursor emissions (natural and anthropogenic), and surface and overhead stratospheric boundary conditions, all of which have changed since the Last Glacial Maximum (LGM; ~21ka). This dissertation first examines in mechanistic detail the effect of variability in the lightning source of nitrogen oxides \((NO_x)\) precursors on interannual variability (IAV) of the oxidants in the recent past. An optimized technique is presented to constrain the lightning \(NO_x\) source in the GEOS-Chem global chemical transport model (CTM) to time-varying satellite data from the Lightning Imaging Sensor. This constraint improves the ability of the CTM to reproduce observed IAV in 9-year (1998-2006) hindcasts of tropical ozone and OH. IAV in ozone and OH is more sensitive to lightning than to biomass burning, despite greater IAV in \(NO_x\) from the latter source. The sensitivity of OH to lightning reflects positive chemical feedbacks on ozone production, \(HO_x\) recycling, and loss frequencies. This dissertation next introduces an offline-coupled climate-biosphere-chemistry framework for determining oxidant levels at and since the LGM. Detailed simulations of tropospheric composition are performed by GEOS-Chem driven by meteorological fields from the GISS ModelE general circulation model, land cover from the BIOME4-TG global terrestrial equilibrium vegetation model, and fire emissions from the LMfire model. Time slice simulations are presented for the present day, preindustrial, and two different possible representations of the LGM climate. Sensitivity of the results to uncertainty in lightning and biomass burning emissions is tested. Though well-buffered, all simulations find net reduced oxidative capacities relative to the present day. The most important parameters for controlling tropospheric oxidants over glacial-interglacial periods are changes in overhead ozone, tropospheric \(H_2O\), and lightning. The results are discussed in the context of the ice-core record, particularly for methane. / Engineering and Applied Sciences

Communication security is a very important part of modern life. A crucial aspect of security is the ability to identify with near 100% certainty who is on the other side of a connection. This problem can be overcome through the use of random number generators, which create unique identities for each person in a network. The effectiveness of an identity is directly proportional to how random a generator is. The speed at which a random number can be delivered is a critical factor in the design of a random number generator. This thesis covers the design and fabrication of three ring oscillator based truly random number generators, the first two of which were fabricated in 0.13µ m CMOS technology. The randomness from this type of random number generator originates from phase noise in a ring oscillator. The second and third ring oscillators were designed to have a low slew rate at the inverter switching threshold. The outputs of these designs showed vast increases in timing jitter compared to the first design. The third design exhibited improved randomness with respect to the second design.

The goal of the present study is to examine the way in which Samuel Beckett, an artist whose work contributes also to philosophy, presents his metaphysical vision of the world through drama, where different plays represent different philosophical interpretations of the world. Using Paul Ricœur’s Memory, History, Forgetting as a theoretical platform, this thesis will concentrate on the manner in which Krapp’s Last Tape presents identity as a phenomenological construction based on cumulative past experiences inserted into and spread throughout time. Based on this assumption, to tamper with one’s conceptions of a memory-time continuum is to alter the identity which is a result of this dynamic. The Beckettian vision of the world does not see identity – the ever-elusive self, as many authors would say – simply as a unique and separate phenomenon that, by staying constant through time, serves as the basis for one’s phenomenological experience ; rather, in Krapp’s Last Tape the self is the sum of mnemonic experiences lived through time, which in turn impacts the identity of the individual. This philosophical perception of identity is further complicated by other phenomenological questions which must come into play if we are to study the way in which this identity is perceived not only by the reader-spectator, but also by the subject himself. For example, how does the ideal image that Krapp constructs of himself impact his identity ? Does he modify memory so as to conform to the idealistic vision he has created of himself, and does this image, perceived as the desired Other, foment in him a feeling of alterity when faced with himself as he is, as opposed to the fulfillment of the desired Other by which he measures his success ? / Thesis (Master, French) -- Queen's University, 2008-09-26 09:07:19.995

This thesis is an analysis of Salman Rushdie's Midnight's Children, The Satanic Verses and The Moor's Last Sigh. The approach is twofold: (a) it seeks to establish an interplay between the concept of exile-in-narration (theme) and narrators-in-exile (form) as a reflection upon questions of rootlessness; and (b) it seeks to underscore this interplay as a recurring 'double bind' within each novel, such that the novels form a loosely bound trilogy that functions as a developing discourse on individual and national identity from a decentred perspective. The aim is similarly twofold: (a) it proposes that the metaphor of exile as a polarized state manifests itself as either an unreflecting pull of opposites or as a thoughtful acceptance of the inter-connectedness between ideas, people, places and things; and (b) it argues that once this polarization becomes evident, it disturbs all static narratives of selfhood and community to the point at which they can be reconceptualized, and yet remain open-ended.

The South Westland Continental Margin (SWCM) is incised by two major active canyon channels, the Hokitika and Cook canyons, which export large volumes of terrigenous sediment from the active New Zealand landmass to the deep ocean basins. This thesis examines modern sediment textures and compositions of shelf and canyon heads, to interpret depositional and transport processes in shelf-canyon interactions and the dispersal and provenance of SWCM surface sediments. This is the first detailed study of modern sediments south of the Whataroa River which focuses on both shelf and canyon head sediments. Submarine canyons that incise active continental shelves are major conduits for sediment transfer. The frequency and magnitude of this transfer has important implications for ocean nutrient cycling (i.e. organic carbon), the stratigraphy and morphology of continental shelves, and the development of economic mineral deposits. Grain size analysis, petrology, geochemistry, detrital magnetite analysis (microprobe), swath bathymetry, and wave hindcast data are used to interpret the spatial distribution, dispersal, and provenance of surface grab samples, canyon cores, and beach and river samples on the SWCM. Four main surficial facies are defined from textural and compositional results, primarily reflecting the supply and storm dominated nature of the SWCM. Facies 1 is comprised of inner shelf very fine to medium sand sized quartz, metamorphic lithics, and feldspar. This facies occurs above the mean Hsig wave base (48 m) where silts, clays, and sand sized micas are bypassed further offshore. Facies 2 is a transitional sand to mud facies between 40 -70 m depth where increasing clay, silt, and mica reflect a decrease in the frequency and magnitude of wave orbital remobilisation. Facies 3 is a mud dominated (80-90%), clay rich (7-9%) facies with the highest mica and Al₂O₃ content of all the SWCM facies. The shelves south of the Hokitika canyon are blanketed beyond the inner shelf in facies 3 towards the shelf break. Facies 4 is restricted to the canyon head north rims and is characterised by mixed relict and modern terrigenous sediments and glaucony. Net transport on the SWCM shelf is to the north, particularly during south-westerly storms where wind drift and storm swells may stir and transport the deeper Facies 2 and 3 sediments. The SWCM has an energetic wave climate and numerous high yield mountainous rivers. As a result the shelf has an extensive coverage of silts and clays with sediment transport most likely dominated by nepheloid layers and fluid mud flows during wet storms. North of the Hokitika canyon, shelf width increases as fluvial supply falls, resulting in a more storm dominated shelf as the prevailing hydraulic conditions prevent modern silts and clays from blanketing the outer shelf. Narrower shelf widths and higher fluvial supply between the Hokitika canyon and the Haast region results in more fluvial dominated shelves. Contrasting canyon rim textures and compositions reflect the major influence the Hokitika and Cook canyon heads impose on the SWCM by intercepting modern net northward shelf transport paths. This interception creates a leeward sediment deficit on the canyon north rims where low sedimentation rates prevail and relict sediments are partially exposed. The south and east rims of both canyons are characterised by modern fine grained terrigenous textures and compositions similar to the SWCM middle to outer shelf facies 3. The build-up and storage of these unconsolidated sediments at the south and east rims provides favourable environments for sediment gravity flows that feed into the canyon systems. Wave orbitals can resuspend fine sands up to 50 m below the canyon rims during large storms. This resuspension will be a main driver of canyon head sedimentation in the form of fluid mud flows. Gully networks along the south and east rims of the Hokitika and Cook canyons indicate active submarine erosion, unconfined fluid flow, and sediment gravity flows operate here. ii In contrast, the north canyon rims are characterised by gravels and coarse sands out of equilibrium with the prevailing modern hydraulic regime. Relict gravels are particularly prevalent on the Hokitika canyon north rim between 90 – 150 m depth. A lack of active gully networks and the presence of relict terraces and cuspate channels provide further evidence for a relict origin of HCH north rim sediments and little influx of modern fine sediments. North rim sediments on the Hokitika canyon between 90 – 125 m have features characteristic of relict beach and littoral environments. These features include pebble and coarse sand sized siliciclastics, high heavy mineral percentages (i.e. garnet), high Zr and Y levels, elevated SiO₂/Al₂O₃ ratios, and relict shell fragments. Mature glaucony is common on the north rims of both canyons, especially between 180 -200 m depth providing further evidence for extended periods of little to no modern sediment deposition in the canyon lee. Glaucony grains have experienced limited transport and are probably parautochthonous. The bulk composition of SWCM shelf, canyon, river, and beach sediments is controlled mainly by the hydrodynamic sorting of Alpine Schist derived material. Regional changes in catchment geology are identified in modern SWCM shelf sediments. Ultramafic signals (i.e. enriched trace element patterns and Cr/V and Ni/Y ratios) from the Pounamu Ultramafics and Dun Mountain Ultramafics were identified on the North and Cascade shelves respectively. The contribution of other lithologies to the bulk composition of SWCM sediments is localised due to rapid dilution with Alpine Schist detritus. The low carbonate and skeletal content on the SWCM is due to the energetic wave climate and high fluvial supply on the shelves. A variety of Cr-rich spinels and magnetites are supplied to the SWCM shelves and vary with regional changes in catchment geology. The Cascade shelf is rich in chromites (containing up to 215,000 ppm Cr) and Cr – rich magnetites sourced from the Dun Mountain Ultramafics via the Cascade River. Shelf, beach, and river samples between the Haast River and Waitaha River are dominated by low-Cr magnetite grains which represent the ‘background’ magnetite composition sourced from rivers draining the Alpine Schist dominated catchments. The dispersal of Cr-rich spinels is limited due to the dilution with low Cr-magnetites from rivers and littoral sediments. Glacio-eustatic lowstands such as the Last Glacial Cold Period (LGCP), represented periods of robust connection of local rivers with the Hokitika and Cook canyon heads, increased interception of littoral transport paths, and compartmentalisation of inter-canyon shelves. Hokitika canyon cores reflect these changes with textural and compositional ‘spikes’ indicating higher terrigenous input during the LGCP. The geochemistry of the terrigenous fraction in the Hokitika canyon provides evidence for enrichment in ferromagnesian and Cr-rich minerals during the LGCP. This is due to the increased connectivity of the Cr-spinel bearing Hokitika River to the canyon head. The Cr/V ratio in particular demonstrates its effectiveness as a proxy for interglacial – glacial change in submarine canyon stratigraphy. Increases and decreases in the connectivity of Cr-bearing fluvial systems during lowstands and highstands respectively can be observed with this ratio.

Re-entrant lines are widely used in many manufacturing systems, such as semiconductor, electronics, etc. However, the performance analysis of re-entrant lines is largely unexplored due to its complexity. In this thesis, we present iterative procedures to approximate the production rate of re-entrant lines with Bernoulli reliability of machines. The convergence of the algorithms, uniqueness of the solution, and structural properties, have been proved analytically. The accuracy of the procedures is investigated numerically. It is shown that the approaches developed can either provide a lower bound or a closed estimate of the system production rate. Finally, a case study of automotive ignition component line with re-entrant washing operations is introduced to illustrate the applicability of the method. The results of this study suggest a possible route for modeling and analysis of re-entrant systems.

The location of fronts has a direct influence on both the physical and biological processes in the Southern Ocean. However, until recently fronts have been poorly resolved by available data and climate models. In this thesis we utilise a combination of high resolution satellite data, model output and ARGO data to improve our basic understanding of fronts. A method is derived whereby fronts are identified as local maxima in sea surface height gradients. In this way fronts are defined locally as jets, rather than continuous-circumpolar water mass boundaries. A new climatology of Southern Ocean fronts is presented. This climatology reveals a new interpretation of the Subtropical Front. The currents associated with the Subtropical Front correspond to the western boundary current extensions from each basin, and we name these the Dynamical Subtropical Front. Previous studies have instead suggested that the Subtropical Front is a continuous feature across the Southern Ocean associated with the super gyre boundary. A comprehensive assessment of the relationship between front locations and wind stress is conducted. Firstly, the response of fronts to a southward shift in the westerly winds is tested using output from a 100 year climate change simulation on a high resolution coupled model. It is shown that there was no change in the location of fronts within the Antarctic Circumpolar Current as a result of a 1.3° southward shift in the westerly winds. Secondly, it is shown that the climatological position of the Subtropical Front is 5-10° north of the zero wind stress curl line, despite many studies assuming that the location of the Subtropical Front is determined by the zero wind stress curl. Finally, we show that the nutrient supply at ocean fronts is primarily due to horizontal advection and not upwelling. Nutrients from coastal regions are entrained into western boundary currents and advected into the Southern Ocean along the Dynamical Subtropical Front. / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Submitted.</p>

This thesis documents the construction of a performance project, At Last Sight, which was made with a group of undergraduates at University College Chester. The leader of that project is the same person as the writer of this thesis; this locates the act of writing as something embedded within the process of performance making. The writing forms an address to the unreliability of objective observational analysis. It does so through a resistance to those attempts at impartiality and detachment that might usually be expected in an academic investigation. In this case partiality and involvement are more than central to the investigative process, they form the very structure of enquiry. The body of this work was written at the same time as At Last Sight was being constructed, and the ideas encountered herein possess many of the rhythms of performance making. Space is both somewhere performance is made and an integral aspect of the made work. In a similar way the following chapters amount to more than the site where work has been recorded. In tracing the footprints that led to At Last Sight the thesis reveals itself as an element of that which is being traced. Where At Last Sight revealed the performers as the to-be-watched and also as the watchers, the study functions as the to-be-read and also as the reading. In this way the documentation becomes the documented. This notion of integration between the subject and its study runs through the thesis. Approaching performance analysis as something `other' creates a gap between it and its subject that can deny the best attempts to bring the two together. Approached in a less compartmentalised way the analysis is allowed to form an indivisible correspondence with the analysed. When the division between the act and the analysis is dissolved the documentation is able to exist as both fixed object and time-based event. Something of the fluidity of process is acknowledged and articulated in each of the sections presented.

The objective of this dissertation is to apply radiogenic isotopes extracted from marine sediments to investigate aspects of global climate change over the past 25 kyr, especially ocean and atmospheric circulation, continental aridity, and hydrology. By focusing on the geochemical records from marine sediments and authigenic precipitates preserved in these sediments, I aim to better understand climate forcing and feedback mechanisms, which are critical to models of climate change. Firstly, I have investigated the dynamics of the Intertropical Convergence Zone (ITCZ) over the past 25 kyr in the eastern equatorial Pacific by fingerprinting dust provenance using radiogenic isotopes (Nd, Sr, Pb) and trace elements (Fe, Si, Ba) in the detrital fraction of marine sediments along a transect across the equator at 110ºW. Results from this study suggest no glacial-Holocene difference in the mean position of the ITCZ, but a more northerly, possibly stronger, deglacial ITCZ. Secondly, I have applied Nd isotope ratios from authigenic precipitates extracted from marine sediments and those from fish debris to trace past intermediate water circulation changes on glacial-interglacial and millennial timescales. The authigenic Nd isotope record from the Florida Straits suggests a reduced circulation of Antarctic Intermediate Water (AAIW) into the tropical North Atlantic during the Younger Dryas (YD) and Heinrich 1 (H1) events, associated with a significant reduction in AMOC. However, in the Southern Caribbean, apparent deviations in the Nd isotopic compositions between the acid-reductive leachate and the fish debris suggest that the leachate method is not reliable at this location and that it needs to be tested in more detail in various oceanic settings. In the Southern Caribbean, the fish debris Nd isotope results suggest a two-step recovery of the upper North Atlantic Deep Water during the last deglaciation. Comparing our new fish debris Nd isotope data to authigenic Nd isotope data for sediments from the Florida Straits and the Demarara Rise, we propose that glacial and deglacial AAIW does not penetrate beyond the lower depth limit of modern AAIW in the tropical North Atlantic. Both studies suggest a tight connection between Atlantic intermediate water circulation variability and high-latitude North Atlantic climate change.

Thesis (M.A.)--University of St. Michael's College, 1982. / Description based on Print version record. Includes bibliographical references (leaves: 200-207).