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Les feldspaths comme support pour la datation par luminescence de gisements archéologiques et de séquences quaternaires d'Aquitaine / Feldspars as support for the luminescence dating of archaeological deposits and quaternary sequences of AquitaineFrouin, Marine 12 December 2014 (has links)
Les données chronologiques disponibles pour les gisements du Paléolithique moyen du Sud-Ouest de la France font état d’un manque de jalons chronologiques fiables. Pour ces périodes anciennes, l’établissement d’un cadre chronologique nécessite un investissement méthodologique important dans le domaine de la datation numérique. Les résultats obtenus dans cette étude reposent essentiellement sur la datation par luminescence optique de grains de feldspaths et de quartz contenus dans les sédiments. En particulier, l’étude des signaux de luminescence classiquement exploités (IRSL, pIR-IRSL), nous permet de mieux évaluer la fiabilité des datations à partir des feldspaths potassiques. Un protocole de datation fondé sur l’exploitation du signal de radioluminescence (IR-RF) de ces minéraux a aussi été développé. Ainsi, la luminescence optique a été appliquée à des échantillons provenant de six gisements de référence : Les Pradelles (Marillac, Charente), Combe Brune 2 (Creysse, Dordogne), Roc de Marsal (Campagne, Dordogne), Artenac (Saint-Mary, Charente), La Quina (Gardes-le-Pontaroux, Charente) et La Ferrassie (Savignac-de-Miremont, Dordogne). La combinaison des résultats obtenus nous a permis, au sein de chaque niveau archéologique, d’évaluer la pertinence des datations et de proposer pour chaque gisement un scénario chronologique qui nous semble fiable. À l’issue de cette étude, les occupations humaines, caractérisées selon leurs industries, ont pu être replacées sur une échelle des temps en regard des variations paléoclimatiques et paléoenvironnementales régionales. Plusieurs constats ont été dressés enrichissant le registre de nos connaissances sur les cultures néandertaliennes. / Currently available chronological information for Middle Palaeolithic sites in southwestern France precludes the establishment of a robust chronological framework. For these early periods, developing such a framework relies upon important methodological advancements in numerical dating techniques. The results of this study are essentially based on the optical luminescence dating of sedimentary feldspars and quartz. Focusing on the most commonly employed luminescence signals (IRSL, pIR-IRSL), it was possible to more clearly evaluate the reliability of dates obtained on K-feldspars. A dating protocol for these materials based on their radioluminescence signal (IR-RF) was also developed. Optical luminescence dates were produced for six major archaeological sites: (Marillac, Charente), Combe Brune 2 (Creysse, Dordogne), Roc de Marsal (Campagne, Dordogne), Artenac (Saint-Mary, Charente), La Quina (Gardes-le-Pontaroux, Charente) et La Ferrassie (Savignac-de-Miremont, Dordogne). Collating the results for each archaeological level allowed the coherence of the dates to be tested and a reliable chronological sequence to be proposed for each site. The different human occupations, characterised by their industrial attribution, could be placed within a chronological framework that incorporates regional palaeoenvironmental and palaeoclimatic variations. Finally, several observations provide new insights for our understanding of Neandertal cultures.
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Heterometallic coordination polymers : toward luminescence modulation / Polymères de coordination hetherometallique : vers la modélisation de la luminescenceFan, Xiao 13 March 2015 (has links)
Les polymères de coordination décrits dans cette thèse ont été préparés en accord avec les concepts de la chimie verte par réactions dans l’eau entre les sels de sodium des ligands et les ions lanthanides compris entre La et Lu (sauf Pm) plus Y. Deux types d’échantillons ont été préparés : des monocristaux et des poudres microcristallines. Les structures cristallines ont été résolues sur la base des monocristaux et les poudres microcristallines ont été utilisées pour étudier les propriétés physicochimiques des composés : stabilité thermique, propriétés de luminescence et de magnétisme. Dans nos travaux, quatre systèmes de polymères de coordination ont été étudiés. Ils ont été obtenus à partir de quatre acides : acide chelidonique (H2cda), acide 5-hydroxy-isophthalique (H2hip), acide 5-nitroisophthalique (H2nip) et acide 4-carboxyphenylboronique (Hcpb). Dix nouveaux monocristaux ont été obtenus par diffusions lentes en tubes en U à travers des gels physique (Agar) ou chimiques (TMOS ou TEOS), par diffusion lente en tubes en H à travers de l’eau distillée ou par évaporation lente du filtrat obtenu après la synthèse des poudres microcristallines. Les poudres microcristallines ont été classées sur la base de leurs diagrammes de diffraction des rayons-X. Leurs propriétés de luminescence ou de magnétisme ont été étudiées à l’état solide. Les transferts d’énergie intermétalliques ont été discutés, en particulier pour les ligands H2hip et Hcpb. Les composés hétéro-nucléaires (Gd / Tb et Eu / Tb) ont été préparés pour moduler les propriétés luminescentes de ces composés en variant les proportions relatives en ions lanthanides. Les polymères de coordination à base de terres rares synthétisés et étudiés dans ce manuscrit fournissent des informations intéressantes pour la conception future de matériaux multifonctionnels. / According to the concepts of Green Chemistry, the coordination polymers based on lanthanide ions were prepared by reactions in water between the sodium salts of ligands and lanthanide ions comprised between La and Lu (except Pm) plus Y. Two kinds of samples were prepared : single crystals and microcrystalline powders. The former ones are used to determine the single crystal structure, and the later ones are used to measure the physical-chemical properties : thermal stability, luminescence and magnetism properties. In our work, four ligands were explored: chelidonic acid (H2cda), 5-hydroxy-isophthalic acid (H2hip), 5-nitroisophthalic acid (H2nip) and 4-carboxyphenylboronic acid (Hcpb). As a result, 10 new single crystals were obtained by slow diffusion in U-shape tubes through physical gel (agar) or chemical gels (TMOS or TEOS), by slow diffusion in H-shape tubes through distilled water or by evaporation of the filtrate obtained after the synthesis of the microcrystalline powders. Microcrystalline powders were classified on the basis of their X-ray powder diffraction patterns. Their luminescent properties and magnetic properties were studied in the solid state. Intermetallic energy transfers were also discussed. Especially, for ligands H2hip and H2cpb. Hetero-nuclear compounds (Gd/Tb and Eu/Tb) were also prepared to tune luminescent properties by changing the relative ratios of the lanthanide ions. Lanthanide coordination polymers described in this thesis provide information that could be useful as far as multifunctional materials are targeted.
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Детаљна луминесцентна хронологија последња два глацијално-интерглацијална циклуса Тителског лесног платоа / Detaljna luminescentna hronologija poslednja dva glacijalno-interglacijalna ciklusa Titelskog lesnog platoa / Detailed luminescence chronology of the lasttwo glacial-interglacial cycles from the Titelloess corePerić Zoran 14 February 2018 (has links)
<p>Еолски седименти представљају идеалан материјал за примену методе луминесцентног датирања. Један од главних разлога је њихов минеролошки састав који углавном чине кварц и фелдспат. Ови минерали поседују читав низ луминесцентних карактеристика који их чине погодним за луминесцентно датирање а поред тога, могуће је релативно једноставно извршити њихову екстракцију и сепарацију од других неминералних састојака. У случају лесних платоа (еолски транспортованих седимената), може се претпоставити да су индивидуална минерална зрна била потпуно изложена сунчевој светлости и да су у довољној мери ресетована пре депозиције. Истраживана секција Велики сурдук на Тителском лесном платоу, изабрана је за датирање, на основу своје моћности, високе стопе седиментације и комплетности које овај локалитет чине најдетаљнијим палеоклиматским архивом последња два глацијално- интерглацијална циклуса у овом делу Европе.<br />Употребом класичног SAR протокола за датирање утврђено је да кварцна зрна са<br />Тителског лесног платоа представљају прецизне дозиметре до ~120 Gy, после чега долази до очигледног засићења сигнала. Највиша утврђена доза фелдспата измерена модификованим SAR пост-IRIR<sup>200,290</sup> протоколом је била 854,0±24 Gy. Пост-IRIR<sup>200,290</sup> протокол није утврдио сатурацију код минералних зрна фелдспата, што је умногомо подигло поуздану старосну границу за датирање на секцији Велики сурдук, а највероватније и на осталим лесним профилима у Србији. Примена различитих протокола и мерења аплицираних на различите групе минерала и њихове фракције дају овим истраживањима далекосежан методолошки значај. На овај начин је доказано да у поменутом временском опсегу OSL датирање грубог кварца даје поуздане старосне процене до 35,8±3,7 ka док су зрна фелдспата датирана до чак 237,7±12,8 ka. Кварц има апсолутно највећу подударност са очекиваним геолошким временом до MIS 2 за разлику од фелдспата који показује бoљу подударност са претпостављеном геолошком хронологијом до MIS 7.</p> / <p>Eolski sedimenti predstavljaju idealan materijal za primenu metode luminescentnog datiranja. Jedan od glavnih razloga je njihov minerološki sastav koji uglavnom čine kvarc i feldspat. Ovi minerali poseduju čitav niz luminescentnih karakteristika koji ih čine pogodnim za luminescentno datiranje a pored toga, moguće je relativno jednostavno izvršiti njihovu ekstrakciju i separaciju od drugih nemineralnih sastojaka. U slučaju lesnih platoa (eolski transportovanih sedimenata), može se pretpostaviti da su individualna mineralna zrna bila potpuno izložena sunčevoj svetlosti i da su u dovoljnoj meri resetovana pre depozicije. Istraživana sekcija Veliki surduk na Titelskom lesnom platou, izabrana je za datiranje, na osnovu svoje moćnosti, visoke stope sedimentacije i kompletnosti koje ovaj lokalitet čine najdetaljnijim paleoklimatskim arhivom poslednja dva glacijalno- interglacijalna ciklusa u ovom delu Evrope.<br />Upotrebom klasičnog SAR protokola za datiranje utvrđeno je da kvarcna zrna sa<br />Titelskog lesnog platoa predstavljaju precizne dozimetre do ~120 Gy, posle čega dolazi do očiglednog zasićenja signala. Najviša utvrđena doza feldspata izmerena modifikovanim SAR post-IRIR<sup>200,290</sup> protokolom je bila 854,0±24 Gy. Post-IRIR<sup>200,290</sup> protokol nije utvrdio saturaciju kod mineralnih zrna feldspata, što je umnogomo podiglo pouzdanu starosnu granicu za datiranje na sekciji Veliki surduk, a najverovatnije i na ostalim lesnim profilima u Srbiji. Primena različitih protokola i merenja apliciranih na različite grupe minerala i njihove frakcije daju ovim istraživanjima dalekosežan metodološki značaj. Na ovaj način je dokazano da u pomenutom vremenskom opsegu OSL datiranje grubog kvarca daje pouzdane starosne procene do 35,8±3,7 ka dok su zrna feldspata datirana do čak 237,7±12,8 ka. Kvarc ima apsolutno najveću podudarnost sa očekivanim geološkim vremenom do MIS 2 za razliku od feldspata koji pokazuje bolju podudarnost sa pretpostavljenom geološkom hronologijom do MIS 7.</p> / <p>Aeolian sediments represent an ideal material for the application of the luminescence dating method. One of the main reasons is their mineralogical composition which consists mainly of quartz and feldspars. These minerals possess a whole range of luminescence characteristics that make them suitable for luminescence dating, and in addition, it is relatively easy to extract and separate them from other non-mineral ingredients. In the case of loess plateaus (eolically transported sediments), it can be assumed that individual mineral grains were completely exposed to sunlight and were sufficiently bleached before deposition. The investigated section Veliki surduk on the Titel loess plateau was chosen for dating, based on its thicknes, the high rate of sedimentation and completeness which makes this site one of the most detailed paleoclimatic archives of the last two glacial and interglacial cycles in this part of Europe.<br />Using the classic SAR protocol for dating, it has been found that the quartz grains from the Titel loess plateau are precise dosimeters up to ~120 Gy, followed by an apparent saturation of the signal. The highest established dose of feldspars measured by the modified SAR postIRIR<sup>200,290</sup> protocol was 854.0±24 Gy. The post-IRIR<sup>200,290</sup> protocol did not determine the saturation of feldspar minerals, which has largely raised the age limit for luminescence dating at the Veliki surduk section, and most probably, also on other loess profiles in Serbia. The application of various protocols and measurements applied to different groups of minerals and their fractions give these research a far-reaching methodological significance. In this way, it has been proven that in the mentioned time range, OSL dating of coarse grain quartz yields reliable age estimates up to 35.8±3.7 k while the feldspar grains are dated to as high as 237.7±12.8 ka. Quartz has the highest match with the expected geological age to MIS 2 as opposed to feldspar, which shows better correspondance with the assumed geological chronology to MIS 7.</p>
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Spectroscopie de luminescence et Raman de complexes des métaux du bloc d à température et pression variable : transitions de phase et changement de l'état émissifBlanc, Pierre-François 08 1900 (has links)
Ce mémoire se penche sur les propriétés photophysiques de différents complexes métalliques,
particulièrement leur changement de structure moléculaire, leur état fondamental ainsi que leur
état émissif par spectroscopie Raman et de luminescence. Ces techniques spectroscopiques
peuvent être utilisées pour détecter et suivre des changements, comme des transitions de phase
structurales.
Pour ce mémoire, quatre composés seront étudiés par spectroscopie. Le premier est un composé
de nickel(II) ayant un ligand azoture pontant, dont l’agencement spatial change avec une
diminution de la température, cette dernière causant un changement dans la susceptibilité
magnétique du composé. Les spectres obtenus montrent bel et bien un changement abrupt dans
le pic du cisaillement du ligand azoture aux environs de 210 K. Les mesures à pression variable
montrent également un changement soudain, entre 1 bar et 1,1 kbar.
Le deuxième composé contient deux centres de manganèse(II) ayant chacun une coordination
inhabituelle de sept, ce qui n’est pas souvent observé. Il s’avère que la spectroscopie Raman n’est
pas assez précise pour mesurer un changement dans ce composé. Tous les déplacements de
maxima des bandes mesurés se retrouvaient dans un intervalle de 1 cm-1
; la résolution de
l’appareil limite la confirmation s’il y a bel et bien une transition de phase. Les spectres de
luminescence ne montrent pas de changement évident non plus.
Le troisième composé est un complexe de platine plan carré qui possède des interactions
platine(II)-platine(II), et qui montre un spectre de luminescence. Des complexes similaires ont
déjà été étudiés par d’autres membres du groupe de recherche; il s’agit donc de compléter la
banque de résultats et de comparer avec les données connues. Les résultats ne montrent aucun
déplacement dans la transition, mais un amincissement du pic, ce qui est comparable aux
données antérieures.
Le quatrième composé est également un complexe de platine(II) plan carré, qui montre un
spectre de luminescence. Un composé similaire a déjà été étudié par un étudiant de notre groupe
de recherche, en rapportant un changement soudain dans le pic de luminescence. Les spectres
mesurés montrent un changement de structure, qui se fait de manière graduelle plutôt que
soudainement.
Ce mémoire est donc axé sur la spectroscopie Raman et de luminescence à températures et
pression variables. Les spectres mesurés, notamment les déplacements des maxima, donnent de
l’information sur des changements de structure, de l’état fondamental et de l’état émissif. / This master’s thesis is focused on the vibrational spectroscopy of coordination compounds
displaying or undergoes spatial or structural changes as well as variations in their ground state
and their emitting state, studied via Raman and luminescence spectroscopy. These spectroscopic
techniques can be used to detect and observe various changes, such as phase transitions. In this
thesis, four compounds will be studied.
The first one is a nickel(II) compound featuring azide bridging ligand, whose spatial arrangement
changes by lowering the temperature, causing also a change in the magnetic susceptibility of the
compound. The spectra we measured show clearly a sudden change in the scissoring vibration for
the azide, at temperatures around 210 K. The variable pressure data we collected also show a
sudden change between 1 bar and 1,1 kbar.
The second compound contains two manganese(II) centers, both having a coordination number
of seven, which is rarely seen for this metal center. Raman spectroscopy isn’t accurate enough to
detect any structural changes. Any changes of band maxima were under 1 cm-1, at the limits of
the instrument’s resolution. Luminescence graphs do not show anything in particular.
The third compound is a square planar platinum(II) complex showing platinum(II)-platinum(II)
interactions, influencing its luminescence spectrum. Similar complexes have already been studied
by other members of this research group; this research will therefore add results to those we
already have, and will be compared to these results. The results don’t show any transition, but
the peaks are narrowing at low temperature, a behaviour similar to other systems.
The fourth compound is also a square planar platinum(II) complex showing a luminescence
spectrum. A similar complex has already been studied by a student in this research group,
reporting a sudden shift in the luminescence peak. The spectrum shows indeed a structural
change, but this change is gradual instead of sudden.
This thesis is focusing on variable temperature and pressure Raman and luminescence
spectroscopy. The experimental spectra show information about structural change, fundamental
state and emissive state.
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Hot-carrier luminescence in grapheneAlexeev, Evgeny January 2015 (has links)
In this thesis, the effect of the sample properties on the characteristics of the hot carrier luminescence in graphene is investigated. The present work focuses on the two main issues described below. The first issue is the modification effects of near-infrared pulsed laser excitation on graphene. For excitation fluences several orders of magnitude lower than the optical damage threshold, the interaction with ultrafast laser pulses is found to cause a stable change in the properties of graphene. This photomodification also results in a decrease of the hot photoluminescence intensity. The detailed analysis shows that ultrafast photoexcitation leads to an increase in the local level of hole doping, as well as a change in the mechanical strain. The variation of doping and strain are linked with the enhanced adsorption of atmospheric oxygen caused by the distortion of the graphene surface. These findings demonstrate that ultrashort pulsed excitation can be invasive even if a relatively low laser power is used. Secondly, the variation of the hot photoluminescence intensity with the increasing charge carrier density in graphene is investigated. The electro-optical measurements performed using graphene field-effect transistors show a strong dependence of the photoluminescence intensity on the intrinsic carrier concentration. The emission intensity has a maximum value in undoped graphene and decreases with the increasing doping level. The theoretical calculations performed using a refined two-temperature model suggest that the reduction of the photoluminescence intensity is caused by an increase in the hot carrier relaxation rate. The modification of the carrier relaxation dynamics caused by photoinduced doping is probed directly using the two-pulse correlation measurements. The discovered sensitivity of the hot photoluminescence to the intrinsic carrier concentration can be utilised for spatially-resolved measurements of the Fermi level position in graphene samples, offering an advantage in resolution and speed.
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Fabrication of Radially Symmetric Graded Porous Silicon using a Novel Cell DesignZhao, Mingrui, Keswani, Manish 22 April 2016 (has links)
A contactless method using a novel design of the experimental cell for formation of porous silicon with morphological gradient is reported. Fabricated porous silicon layers show a large distribution in porosity, pore size and depth along the radius of the samples. Symmetrical arrangements of morphology gradient were successfully formulated radially on porous films and the formation was attributed to decreasing current density radially inward on the silicon surface exposed to Triton (R) X-100 containing HF based etchant solution. Increasing the surfactant concentration increases the pore depth gradient but has a reverse effect on the pore size distribution. Interestingly, when dimethyl sulfoxide was used instead of Triton (R) X-100 in the etchant solution, no such morphological gradients were observed and a homogeneous porous film was formed.
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The retention testing of sterilising grade membranes with Pseudomonas diminutaWaterhouse, Sara January 1994 (has links)
Membranes with a pore size rating of 0.2μm are recommended for the sterilisation of liquids by filtration and are validated for this purpose by a retention test with Pseudomonas diminuta. Practices for retention testing were found to vary among the membrane manufacturers and only one type of commercial 0.2μm rated membrane was found to reliably retain P. diminuta. The retention for P. diminuta given by experimental grafted membranes was studied and was sometimes higher than that given by non-grafted membranes due to obstruction of the pores by graft material. The dimensions for individual cells of P. diminuta was studied by scanning electron microscopy and a rapid electronic method. Bacteria of larger dimensions than the pore size rating of experimental membranes were found in test permeates. It was shown that cells from an aerated P. diminuta culture were larger than cells from a similar but stationary culture. A retention test procedure for 0.2 μm rated membranes using cross-flow filtration was developed. The procedure simulated process conditions and enabled tubular ceramic monolithic membranes and flat-sheet membranes to be retention tested with P. diminuta. It is feasible that a standard retention test using cross-flow filtration can be developed. The time needed for results from current retention test procedures to become available is a consequence of using traditional cultural techniques for permeate analysis. Test procedure were developed using three popular methods for the rapid detection and enumeration of bacteria (ATP luminescence, impedance microbiology and the DEFT) for the detection and enumeration of P. diminuta in retention test permeates. The method using ATP luminescence was found to be the most applicable. The development of a bioluminescent strain of P. diminuta through genetic engineering will enable the rapid, sensitive and straightforward retention testing of 0.2 μm rated membranes. Retention tests using a bioluminescent strain of Escherichia coli containing the structural genes for bacterial luciferase indicated that the proposed test is feasible. Developments were made towards cloning the same genes into P. diminuta. The use of all bioluminescent micro-organisms for membrane retention testing is the subject of a patent application and a proposal for a three year SERC research grant.
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Solvothermal chemistry of luminescent lanthanide fluoridesJayasundera, Anil January 2009 (has links)
Exploration of novel lanthanide fluoride framework materials in inorganic-organic hybrid systems under solvothermal conditions towards development of new luminescent materials is discussed. X-ray single crystal and powder diffraction methods have been used as crystallographic characterisation techniques. Determination and study of luminescence properties for selected hybrid materials has also been carried out. The first organically templated luminescent lanthanide fluoride framework, [C₂N₂H₁₀]₀.₅ [Ln₂F₇] (Ln= Nd, Tb, Dy, Ho, Er, Yb and Lu), has been synthesised and characterised. This structure type consists of a three-dimensional yttrium fluoride framework incorporating two similar, but crystallographically distinct, yttrium sites. Photoluminescence studies of [C₂N₂H₁₀]₀.₅ [Y₂F₇]: Ln³⁺ (Ln³⁺ = Gd³⁺, Eu³⁺ and Tb³⁺) have been explored and characteristic luminescence emissions are reported. An inorganic-organic hybrid indium fluoride and its scandium fluoride analogue, [C₄H₁₄N₂][MF₅](M=In and Sc) is reported. The structure consists of infinite trans vertex sharing (InF₅)[subscript(∞)] chains, which are linked via H-bonded organic moieties. The scandium and fluorine local environments of [C₄H₁₄N₂][ScF₅] are characterised by ¹⁹F, and ⁴⁵Sc solid-state MAS NMR spectroscopies. A single scandium site has been confirmed by ⁴⁵Sc MAS NMR. ¹⁹F MAS NMR clearly differentiates between bridging and terminal fluorine. The photoluminescence properties of these complexes, [C₄H₁₄N₂][In[subscript(1-x)] Ln[subscript(x)]F₅] (Ln=Tb and/or Eu), have been explored. The optimum composition for Eu³⁺ doped samples occurs at x = 0.05 Eu³⁺ and the “asymmetry ratio” of R = I₅₉₀/I₆₁₅ ( ⁵D₀ → ⁷F₂ and ⁵D₀ → ⁷F₁) gives a clear picture of the sensitivity for crystal field of the compound. For x = 0.08 Tb³⁺, a strong down-conversion fluorescence corresponding to ⁵D₄ → ⁷F₅ (green at 543.5 nm) occurs. In addition, a Tb³⁺/Eu³⁺ co-doped sample exhibits a combination of green (Tb³⁺) and orange (Eu³⁺) luminescence, with Tb³⁺ enhancing the emission of Eu³⁺ in this host. Exploration of novel indium, aluminium, and zirconium fluoride crystal structures with potential luminescent properties has also been undertaken. A chiolite-like phase K₅In₃F₁₄ (space group P4/mnc) has been synthesised. No phase transition occurs over the temperature range 113K< T< 293 K, as has been seen in other chiolite-like structures. An organically templated indium fluoride, [NH₄]₃[C₆H₂₁N₄]₂[In₄F₂₁] has been prepared; this features the trimeric unit [In₃F₁₅]³⁻ which appears to be the first of its type in a metal fluoride. A new hybrid fluoride, Sr[N₂C₂H₁₀]₂[Al₂F₁₂].H₂O has been synthesised. Because the ionic radius of Eu²⁺ is similar to that of Sr ²⁺ this may be a potential host for blue luminescent Eu²⁺. The new material KZrF₅.H₂O shows pentagonal-bipyramidal geometry of Zr⁴⁺ with a polar space group, Pb2₁m, which may potentially have ferroelectric properties.
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Synthesis and luminescence studies of homo- and heteronuclear complexes of gold and copper陳翠玲, Chan, Chui-ling. January 1998 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Holocene evolution of a hypersaline lake: Lagkor Tso, western TibetLee, Ting, Jennifer, 李婷 January 2008 (has links)
published_or_final_version / abstract / Earth Sciences / Master / Master of Philosophy
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