Laser Powder Bed Fusion (LPBF) is a metal additive manufacturing (AM) technique that creates objects layer by layer from a bed of loose powder, using a laser beam as the heat source. This layer-wise approach allows for the fabrication of highly complex structures and intricate geometries with high accuracy, including solid, porous, and lattice structures. LPBF offers significant potential for use in industries such as aerospace, biomedical, and automotive due to its ability to fabricate unique and sophisticated designs. This technology has recently attracted significant attention for the fabrication of multimaterial parts with improved properties and applicability in different fields. However, challenges persist in understanding the relationship between process parameters and the properties of resulting multimaterial parts and interfaces. Additionally, limitations exist in design and interface selection for multimaterial fabrication using this technique. Negative thermal expansion (NTE) metamaterials, discussed in this research, are mechanical structures that show negative expansion properties by contracting with increase in temperature, while expanding with a decrease in temperature. These metamaterials are typically multimaterial systems where constituents with positive coefficients of thermal expansion (CTE) are strategically integrated, resulting in an overall NTE effect in one or more directions This research focuses on the design, simulation, and fabrication of negative thermal expansion (NTE) metamaterials using Laser Powder Bed Fusion (LPBF) with Grade 304L Stainless Steel (SS304L), Grade 300 Maraging Steel (MS300), and Invar 36 (Invar) alloys. Bimaterial combinations of SS304L-MS300 and SS304L-Invar were explored. After determining the optimal processing parameters, results showed that a robust, defect-free interface could be achieved in both combinations. Various lattice structures were designed based on these alloy pairs and analyzed using finite element analysis. The designs with the high NTE potential were successfully fabricated through LPBF, using optimal interface parameters. Thermal expansion testing of the fabricated structures demonstrated NTE behavior in line with FEA analysis predictions. / Thesis / Master of Applied Science (MASc)

Phased microphone arrays are valuable tools for aeroacoustic measurements that can measure the directivity of multiple acoustic sources. However, when deployed in closed test-section wind tunnels, the acoustics suffer due to intense pressure fluctuations contained in the wall-bound turbulent boundary layer. Furthermore, phased microphone arrays require many sensors distributed over a large aperture to ensure good spatial resolution over a wide frequency range. Microphone arrays of such large count are not always feasible due to constraints in space and cost. This thesis describes an alternative approach for measuring single broadband acoustic sources that uses an acoustic metasurface. The metasurface is comprised of a meandering channel of quarter-wave cavities and an array of equally spaced half-wave open through-cavities. A series of tests were conducted in Virginia Tech's Anechoic Wall-Jet Tunnel where combinations of a wall-bound turbulent jet-flow and a single broadband acoustic source were used to excite the metasurface and produce acoustic surface waves. Measurements of the acoustic surface waves were performed using two methods: a pair of traversing microphones scanning the pressure field along the length of the metasurface 0.25 mm beneath its bottom face, and an array of unequally spaced microphones embedded inside the metasurface. Spectral analysis on the measurements revealed that the inclusion of multiple through-cavities leads to constructive reinforcement of select acoustic surface waves as a function of the acoustic source location. In the case of the embedded microphones, acoustic beamforming was applied in order to extract spatial information. This reinforcement was observed during measurements made with both flow and acoustic excitation, up to Wall-Jet Tunnel nozzle exit speeds of 40 m/s beyond which it was no longer seen. A series of quiescent measurements made with a range of speaker locations constituted a calibration for the metasurface which was used to locate an unknown broadband acoustic source within an The Root-Mean-Square (RMS) error of 1.06 degrees. / Master of Science / Phased microphone arrays are valuable tools for aeroacoustic measurements that can measure the directivity of multiple acoustic sources within a sound field. When used in conjunction with signal processing techniques, such as delay-and-sum beamforming, a researcher or engineer can obtain an intuitive view of the sound field and distinguish between multiple sources over a wide frequency range. However, these microphone arrays often utilize dozens of microphones which raises the array's complexity and cost. Furthermore, when a phased microphone array is mounted flush to the wall of a wind tunnel test section, it is submerged under a turbulent boundary layer which imposes intense pressure fluctuations on the microphones making it difficult to identify acoustic sources. Boundary layers form at the interface between a fluid and solid interface. This thesis describes experimentation performed in the Virginia Tech Anechoic Wall-Jet Tunnel on a new type of pressure sensing microphone array that leverage acoustic metamaterial technology. The acoustic metamaterial shields the microphones from the flow, lessening the influence of the turbulent boundary layer on the measurement. The focus in this thesis is on the novel array's ability to locate a single broadband acoustic source using as few as six microphones. The metasurface was installed in the Wall-Jet Tunnel test plate such that an array of evenly spaced through-cavities are flush to the surface. The through-cavities communicate the pressure field on top of the test surface to a meandering channel of interconnected closed cavities below. Near the resonant depth frequencies of the closed cavities, acoustic surface waves form which are evanescent pressure waves that are bound to the surface or structure that support them. The interference between the acoustic surface waves generated at each through-cavity leads to reinforced acoustic surface waves which are sensitive to the direction of a broadband source. In all, an acoustic metamaterial was tested under a variety of conditions such as: Wall-Jet Tunnel flow speed, speaker location, and the number of through-cavities open. The performance of the novel array and future plans are discussed.

<p dir="ltr">Hybrid metamaterials have garnered significant attention in recent years owing to their unique properties not found in natural materials. These materials are engineered by integrating two or more distinct materials at the nanoscale, forming various microstructures such as particle-in-matrix, pillar-in-matrix, and multilayers. The recent development of vertically aligned nanocomposites (VANs) offers a platform in forming pillar-in-matrix metamaterials in a self-assembled fashion. Transition metal nitrides, such as titanium nitride (TiN), are interesting materials for VAN designs due to their outstanding plasmonic properties, chemical stability, and compatibility with various functional materials. However, the current range of material selection and morphological demonstrations in two-phase nitride-based nanocomposites is limited. There is a growing need for a deeper understanding of the self-assembly growth mechanism and greater freedom in structural and property tunability of nitride-based VANs to develop the next generation of integrated photonic and electronic devices.</p><p dir="ltr">This dissertation investigates the design, growth mechanisms, and tunability of nitride-based VANs for advanced metamaterial applications. The first chapter focuses on integrating ferromagnetic CoFe₂ into a plasmonic TiN matrix to achieve anisotropic optical and magnetic properties, as well as coupling effects between the two phases. In the second chapter, a third phase, gold (Au), is introduced into TiN-CoFe₂ VANs in a core-shell configuration, demonstrating enhanced tunability in microstructure and resultant properties, such as distinct hyperbolic behavior and switchable magnetic easy axis. The third chapter extends the exploration into three-dimensional (3D) nanostructured films by combining different VAN films (e.g., TiN-CoFe₂, TaN-CoFe₂) in multilayer configurations, demonstrating highly tunable optical properties along with ferromagnetic response. This 3D nanocomposite approach highlights the potential for advanced tunability in metamaterials beyond traditional two-phase VAN designs. The fourth chapter explores the control of stoichiometry and phase composition in TiN-CuO systems. By systematically adjusting oxygen partial pressure during deposition, a gradual transition from metallic to dielectric behavior in these nanocomposite films has been observed. This investigation provides valuable insights into the comprehensive understanding of the interaction processes within hybrid nanocomposites during self-assembly. Overall, this thesis presents diverse methodologies for tuning microstructures and functionalities within nitride-based VAN systems, showing potentials for advanced applications in optics, magnetics, and beyond in metamaterial research.</p>

4D printing is a rapidly emerging field in which 3D printed stimuli-responsive materials produce morphing and multifunctional structures, with time being the fourth dimension. This approach enables the 3D printing of pre-programmed responsive sheets, which transition into complex curved shapes upon exposure to external stimuli, resulting in a substantial reduction in material consumption and printing time (70 - 90 %). Commonly used materials for 4D printing are polymer composites, such as hydrogels, polydimethylsiloxane (PDMS), liquid crystal elastomers (LCEs), and shape memory polymers (SMPs). However, the low elastic modulus (E) that these materials exhibit during shape change (E range of 10-4 – 10 MPa) limits their scalability, actuation stress, and load bearing. Moreover, these materials exhibit low ultimate stresses, leading to correspondingly low toughness (K) values in the range of 0.08 to 5 MJ m-3. Consequently, this results in structures with low damage tolerance. Therefore, an existing challenge for the field of 4D printing is to develop materials that can maintain their large and predictable morphing mechanism for complex shape transformation, while improving the E and K for high performance applications. Furthermore, many existing approaches rely on passive structures that necessitate the control of global conditions of the surrounding environment (e.g., hot plates, ovens, external magnets, water baths) to provide the stimulus for actuation. In this work, we tackle these challenges by introducing novel materials, ink formulations, and innovative printing techniques for multi-material Direct Ink Writing (DIW). We aim to create electrically controllable 4D printed structures that exhibit exceptional stiffness and toughness, all while preserving a large and predictable morphing mechanism for intricate shape transformations. First, we introduce multiscale heterogeneous polymer composites as a novel category of stiff, electrically controllable thermally responsive 4D printed materials. These composites consist of an epoxy matrix with an adjustable cross-link density and a plurality of isotropic and anisotropic nanoscale and microscale fillers. Leveraging this platform, we generate a set of 37 inks covering a broad range of negative and positive linear coefficients of thermal expansion. This set of inks exhibits an elastic modulus range that is four orders of magnitude greater than that of existing 4D printed materials and offers tunable electrical conductivities for simultaneous Joule heating actuation and self-sensing capabilities. Utilizing electrically controllable bilayers as building blocks, we design and print a flat geometry that changes shape into a 3D self-standing lifting robot, displaying record actuation stress and specific force when compared to other 3D printed actuators. We integrate this lifting robot with a closed-loop control system, achieving autoregulated actuation exhibiting a 4.8 % overshoot and 0.8 % undershoot, while effectively rejecting disturbances of up to 170 times the robot's weight. Furthermore, we employ our ink palette to create and 3D print planar lattice structures that transform into various self-supporting complex 3D surfaces. Ultimately, we achieve a 4D printed electrically controlled crawling robotic lattice structure, highlighting its capacity to transport loads up to 144 times its own weight. Finally, we introduced a printable PDMS adhesive that serves as synthetic fascia to hold our epoxy-based synthetic muscle together, enhancing the K of our 4D printed structures, all while maintaining high stiffness, large, predictable, and addressable actuation mechanism. Through the integration of these soft adhesive materials with high-stiffness thermally responsive epoxies via DIW, we achieved an improvement of about two orders of magnitude in the K of the resulting synthetic muscle composite, all while maintaining high stiffness and morphing mechanism. Utilizing this fabrication method, we printed an electrically controllable bilayer exhibiting damage detection and tolerance, enduring up to 7 fractures while continuing to function effectively. Furthermore, we integrated the synthetic muscle composite into our lifting robot design, setting yet again new records in specific force and actuation stress when compared to other 3D printed actuators. Notably, even after failure, the actuator maintained its operational integrity and high performance. Ultimately, we present a 4D printed lattice structure featuring the incorporation the synthetic muscle composite, showcasing a sensitive electrically responsive surface with fracture detection capabilities. To emphasize this, we subjected one of these 4D printed lattices to extreme conditions, driving a car over it. Notably, the lattice structure detected fractures and exhibited high resilience, enduring external compressive damage equivalent to 331,060 times its own weight. / 2026-05-23T00:00:00Z

Les métamatériaux sont des composites artificiels présentant des propriétés électromagnétiques qu’on ne trouve pas dans la nature. Malgré des développements spectaculaires durant la dernière décennie, le potentiel de ces structures aux longueurs d’ondes optique n’est pas encore clairement défini en raison de problèmes technologiques et de contraintes physiques telles que les pertes dans les métaux entrant dans la composition des métamatériaux. Dans notre thèse, nous montrons que les métamatériaux ont des propriétés très favorables dans le contexte de l’optique intégrée dans le proche infrarouge. Nous avons développé une stratégie pour incorporer des métamatériaux dans des circuits photoniques qui n’absorbent que très peu d’énergie. Pour cela, nous ne faisons pas directement agir l’ensemble du mode guidé avec les métamatériaux, mais seulement une composante évanescente à l’extérieur du guide. Pour réaliser un tel adaptateur ou d’autres fonctionnalités, il importe de déterminer quelle géométrie de métamatériaux est la plus favorable aux applications infrarouges. Nous proposons d’utiliser des structures à base de fils d’or empilés couche sur couche. A l’aide de simulations numériques et d’expériences en espace libre, nous montrons qu’il est possible d’obtenir toute une gamme de réponses optiques en contrôlant le couplage entre les différents niveaux de fils, c'est-à-dire en ajustant la distance entre les fils ainsi que leur alignement. En particulier, nous avons réussi à contrôler séparément la réponse électrique et magnétique de nos structures, ce qui offre une flexibilité de conception qui ne se rencontre pas dans les métamatériaux proposés jusqu’à présent. / Metamaterials are artificial composites with electromagnetic properties not found in nature. Although the development of metamaterials has experienced a tremendous growth over the past few years, their potential at optical wavelengths is not clearly established due to technological and physical constraints such as high material losses in this spectral range. Here we show that metamaterials have a great potential in the context of integrated optics in the near infrared. We developed a strategy to incorporate metamaterials in photonic circuits with minimal absorption losses. Our approach relies on making the guided modes interact with the metamaterials only through the evanescent tail outside the waveguide. To achieve such an adaptor and other functionalities, it is important to know what is the best geometry for near-infrared applications. We propose to use metamaterials based on multi-layers of Au cut wires. With numerical simulations and experiments, we show that it is possible to create a wide range of optical properties by controlling the interaction between the wires, i.e. by adjusting the distance between the wires and their alignment. In particular we were able to demonstrate

<p dir="ltr">Metamaterials are artificially engineered nanoscale systems with a three-dimensional repetitive arrangement of certain components, and present exceptional optical properties for applications in nanophotonics, solar cells, plasmonic devices, and more. Self-assembled oxide-metal vertically aligned nanocomposites (VANs), with metallic phase as nanopillars embedded in the matrix oxide, have been recently proposed as a promising candidate for metamaterial applications. However, precise microstructural control and the structure-property relationships in VANs are still in high demand. Thus, by employing multiple approaches for structural design, this dissertation attempts to investigate the mechanisms of nanostructure evolutions and the corresponding optical responses.</p><p dir="ltr">In this dissertation, the precise control over the nanostructures has been demonstrated through morphology tuning, nanopillar orderings, and strain engineering. Firstly, Au, a well-known plasmonic mediator, has been selected as the metallic phase that forms nanopillars. Based on the previously proposed strain compensation model which describes the basic formation mechanism of VAN morphology, two oxides were then considered: La_0.7Sr_0.3MnO₃(LSMO) and CeO₂. In the first two chapters of this dissertation, LSMO was considered due to its similar lattice (a_LSMO= 3.87 Å, a_Au= 4.08 Å) and its enormous potential in nanoelectronics and spintronics. Deposited on SrTiO₃ (001) substrate through pulsed laser deposition (PLD), LSMO-Au nanocomposites exhibit ideal VAN morphology as well as promising hyperbolic dispersions in response to the incident illuminations. By substrate surface treatment of annealing at 1000°C, and variation of STO substate orientations from (001), to (111) and (110), the improved and tunable in-plan orderings of Au nanopillars have been successfully achieved. In the third chapter, a new oxide-metal VAN system of <a href="" target="_blank">CeO₂</a>-Au (a_CeO2= 5.411 Å, and a_CeO2/= 3.83 Å) has been deposited. The intriguing 45° rotated in-plan epitaxy presents an unexpected update to the strain compensation model, and tuning of Au morphology from nanopillars, nanoantennas, to nanoparticles also shows an effective modulation of the LSPR responses. COMSOL simulations have been exploited to reveal the relationships between Au morphologies and optical responses. In the last chapter, the two VAN systems of LSMO-Au and CeO₂-Au have been combined to form a complex layered VAN thin film. Investigations into the strain states, the nature of complex interfaces, and the according hybrid properties, show dramatic possibilities for further strain engineering. In summary, this dissertation has provided multiple routes for highly tailorable oxide-metal nanocomposite designs. And the two proposed material systems present great potential in optical metamaterial applications including biosensors, photovoltaics, super lenses, and more.</p>

Metamaterials are typically described as materials with ’unusual’ wave propagation properties. Originally developed for electromagnetic waves, these materials have also spread into the field of acoustic wave guiding and cloaking, with the most relevant of these ’unusual’ properties, being the so called band-gap phenomenon. A band-gap signifies a frequency region where elastic waves cannot propagate through the material, which in principle, could be used to protect buildings from earthquakes. Based on this, two relevant concepts have been proposed in the field of seismic engineering, namely: metabarriers, and metamaterial-based foundations. This thesis deals with the development of the Metafoundation, a metamaterial-based foundation system for the seismic protection of fuel storage tanks against excessive base shear and pipeline rupture. Note that storage tanks have proven to be highly sensitive to earthquakes, can trigger sever economic and environmental consequences in case of failure and were therefore chosen as a superstructure for this study. Furthermore, when tanks are protected with traditional base isolation systems, the resulting horizontal displacements, during seismic action, may become excessively large and subsequently damage connected pipelines. A novel system to protect both, tank and pipeline, could significantly augment the overall safety of industrial plants. With the tank as the primary structure of interest in mind, the Metafoundation was conceived as a locally resonant metamaterial with a band gap encompassing the tanks critical eigenfrequency. The initial design comprised a continuous concrete matrix with embedded resonators and rubber inclusions, which was later reinvented to be a column based structure with steel springs for resonator suspension. After investigating the band-gap phenomenon, a parametric study of the system specifications showed that the horizontal stiffness of the overall foundation is crucial to its functionality, while the superstructure turned out to be non-negligible when tuning the resonators. Furthermore, storage tanks are commonly connected to pipeline system, which can be damaged by the interaction between tank and pipeline during seismic events. Due to the complex and nonlinear response of pipeline systems, the coupled tank-pipeline behaviour becomes increasingly difficult to represent through numerical models, which lead to the experimental study of a foundation-tank-pipeline setup. Under the aid of a hybrid simulation, only the pipeline needed to be represented via a physical substructure, while both tank and Metafoundation were modelled as numerical substrucutres and coupled to the pipeline. The results showed that the foundation can effectively reduce the stresses in the tank and, at the same time, limit the displacements imposed on the pipeline. Leading up on this, an optimization algorithm was developed in the frequency domain, under the consideration of superstructure and ground motion spectrum. The advantages of optimizing in the frequency domain were on the one hand the reduction of computational effort, and on the other hand the consideration of the stochastic nature of the earthquake. Based on this, two different performance indices, investigating interstory drifts and energy dissipation, revealed that neither superstructure nor ground motion can be disregarded when designing a metamaterial-based foundation. Moreover, a 4 m tall optimized foundation, designed to remain elastic when verified with a response spectrum analysis at a return period of 2475 years (according to NTC 2018), reduced the tanks base shear on average by 30%. These results indicated that the foundation was feasible and functional in terms of construction practices and dynamic response, yet unpractical from an economic point of view. In order to tackle the issue of reducing the uneconomic system size, a negative stiffness mechanism was invented and implemented into the foundation as a periodic structure. This mechanism, based on a local instability, amplified the metamaterial like properties and thereby enhanced the overall system performance. Note that due to the considered instability, the device exerted a nonlinear force-displacement relationship, which had the interesting effect of reducing the band-gap instead of increasing it. Furthermore, time history analyses demonstrated that with 50% of the maximum admissible negative stiffness, the foundation could be reduced to 1/3 of its original size, while maintaining its performance. Last but not least, a study on wire ropes as resonator suspension was conducted. Their nonlinear behaviour was approximated with the Bouc Wen model, subsequently linearized by means of stochastic techniques and finally optimized with the algorithm developed earlier. The conclusion was that wire ropes could be used as a more realistic suspension mechanism, while maintaining the high damping values required by the optimized foundation layouts. In sum, a metamaterial-based foundation system is developed and studied herein, with the main findings being: (i) a structure of this type is feasible under common construction practices; (ii) the shear stiffness of the system has a fundamental impact on its functionality; (iii) the superstructure cannot be neglected when studying metamaterial-based foundations; (iv) the complete coupled system can be tuned with an optimization algorithm based on calculations in the frequency domain; (v) an experimental study suggests that the system could be advantageous to connected pipelines; (vi) wire ropes may serve as resonator suspension; and (vii) a novel negative stiffness mechanism can effectively improve the system performance.

The present research is concerned with developing analysis methods for analyzing and exploring finite-amplitude elastic wave propagation through periodic media. Periodic arrangements of materials with high acoustic impedance contrasts can be employed to control wave propagation. These systems are often termed phononic crystals or metamaterials, depending on the specific design and purpose. Design of these systems usually relies on computation and analysis of dispersion band structures which contain information about wave propagation speed and direction. The location and influence of complete (and partial) band gaps is a particularly interesting characteristic. Wave propagation is prohibited for frequencies that correspond to band gaps; thus, periodic systems behave as filters, wave guides, and lenses at certain frequencies. Controlling these behaviors has typically been limited to the manufacturing stage or the application of external stimuli to distort material configurations. The inclusion of nonlinear elements in periodic unit cells offers an option for passive tuning of the dispersion band structure through amplitude-dependence. Hence, dispersion analysis methods which may be utilized in the design of nonlinear phononic crystals and metamaterials are required. The approach taken herein utilizes Bloch wave-based perturbation analysis methods for obtaining closed-form expressions for dispersion amplitude-dependence. The influence of material and geometric nonlinearities on the dispersion relationship is investigated. It is shown that dispersion shifts result from both self-action (monochromatic excitation) and wave-interaction (multi-frequency excitation), the latter enabling dynamic anisotropy in periodic media. A particularly novel aspect of this work is the ease with which band structures of discretized systems may be analyzed. This connection enables topology optimization of unit cells with nonlinear elements. Several important periodic systems are considered including monoatomic lattices, multilayer materials, and plane stress matrix-inclusion configurations. The analysis methods are further developed into a procedure which can be implemented numerically with existing finite-element analysis software for analyzing geometrically-complex materials.

This thesis studies a new class of high gain planar resonant cavity antennas based on metamaterial surfaces. High-gain planar antennas are becoming increasing popular due to their significant advantages (e.g. low profile, small weight and low cost). Metamaterial surfaces have emerged over the last few years as artificial structures that provide properties and functionalities not readily available from existing materials. This project addresses novel applications of innovative metamaterial surfaces on the design of high-gain planar antennas. A ray analysis is initially employed in order to describe the beamfonning action of planar resonant cavity antennas. The phase equations of resonance predict the possibility of low-profile/subwavelength resonant cavity antennas and tilted beams. The reduction of the resonant cavity profile can be obtained by virtue of novel metamaterial ground planes. Furthermore, the EBG property of metamaterial ground planes would suppress the surface waves and obtain lower backlobes. By suppressing the TEM mode in a resonant cavity, a novel aperture-type EBG Partially Reflective Surface (PRS) is utilized to get low sidelobes in both planes (E-plane and H-plane) in a relatively finite structure. The periodicity optimization of PRS to obtain a higher maximum directivity is also investigated. Also it is shown that antennas with unique tilted beams are achieved without complex feeding mechanism. Rectangular patch antennas and dipole antennas are employed as excitations of resonant cavity antennas throughout the project. Three commercial electromagnetic simulation packages (Flomerics Microstripes ™ ver6.S, Ansoft HFSSTM ver9.2 and Designer ™ ver2.0) are utilized during the rigorous numerical computation. Related measurements are presented to validate the analysis and simulations.

<p>Metasurfaces are broadly defined as artificially engineered material interfaces that have the ability to determinately control the amplitude and phase signatures of an incident electromagnetic wave. Subwavelength sized optical scatterers employed at the planar interface of two media, introduce abrupt modifications to impinged light characteristics. Arbitrary engineering of the optical interactions and the arrangement of the scatterers on plane, enable ultra-compact, miniaturized optical systems with a wide array of applications (e.g. nanoscale and nonlinear optics, sensing, detection, energy harvesting, information processing and so on) realizable by the metasurfaces. However, maturation from the laboratory to industry scale realistic systems remain largely elusive despite the expanding reach and vast domains of functionalities demonstrated by researchers. A large part of this multi-faceted problem stems from the practical constraints posed by the commonly used plasmonic materials that limit their applicability in devices requiring high temperature stability, robustness in varying ambient, mechanical durability, stable growth into nanoscale films, CMOS process compatibility, stable bio-compatibility, and so on. </p> <p>Aiming to create a whole-some solution, my research has focused on developing novel, high-performance, functional plasmonic metasurface devices that utilize the inherent benefits of various emerging and alternative material platforms. Among these, the two-dimensional MXenes and the refractory transition metal nitrides are of particular importance. By exploiting the plasmonic response of thin films of the titanium carbide MXene (Ti₃C₂T_x) in the near infrared spectral window, a highly broadband metamaterial absorber has been designed, fabricated and experimentally demonstrated. In another work, high efficiency photonic spin Hall Effect has been experimentally realized in robust phase gradient metasurface devices based on two different refractory transition metal nitrides –titanium nitride (TiN) and zirconium nitride (ZrN). Further, taking advantage of the refractory nature of these plasmonic nitrides, a metasurface based temperature sensor has been developed that is capable of remote, optical sensing of very high temperatures ranging up to 1200^oC.</p>