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Improving methane production using hydrodynamic cavitation as pre-treatment / Förbättrad methanproduktion med hydrodynamisk kavitation som förbehandlingAbrahamsson, Louise January 2016 (has links)
To develop anaerobic digestion (AD), innovative solutions to increase methane yields in existing AD processes are needed. In particular, the adoption of low energy pre-treatments to enhance biomass biodegradability is needed to provide efficient digestion processes increasing profitability. To obtain these features, hydrodynamic cavitation has been evaluated as an innovative solutions for AD of waste activated sludge (WAS), food waste (FW), macro algae and grass, in comparison with steam explosion (high energy pre-treatment). The effect of these two pre-treatments on the substrates, e.g. particle size distribution, soluble chemical oxygen demand (sCOD), biochemical methane potential (BMP) and biodegradability rate, have been evaluated. After two minutes of hydrodynamic cavitation (8 bar), the mean fine particle size decreased from 489- 1344 nm to 277- 381 nm (≤77% reduction) depending of the biomasses. Similar impacts were observed after ten minutes of steam explosion (210 °C, 30 bar) with a reduction in particle size between 40% and 70% for all the substrates treated. In terms of BMP value, hydrodynamic cavitation caused significant increment only within the A. nodosum showing a post treatment increment of 44% compared to the untreated value, while similar values were obtained before and after treatment within the other tested substrates. In contrast, steam explosion allowed an increment for all treated samples, A. nodosum (+86%), grass (14%) and S. latissima (4%). However, greater impacts where observed with hydrodynamic cavitation than steam explosion when comparing the kinetic constant K. Overall, hydrodynamic cavitation appeared an efficient pre-treatment for AD capable to compete with the traditional steam explosion in terms om kinetics and providing a more efficient energy balance (+14%) as well as methane yield for A. nodosum. / Det behövs innovativa lösningar för att utveckla anaerob rötning i syfte att öka metangasutbytet från biogassubstrat. Beroende på substratets egenskaper, kan förbehandling möjliggöra sönderdelning av bakterieflockar, uppbrytning av cellväggar, elimination av inhiberande ämnen och frigörelse av intracellulära organiska ämnen, som alla kan leda till en förbättring av den biologiska nedbrytningen i rötningen. För att uppnå detta har den lågenergikrävande förebehandlingsmetoden hydrodynamisk kavitation prövats på biologiskt slam, matavfall, makroalger respektive gräs, i jämförelse med ångexplosion. Effekten på substraten av dessa två förbehandlingar har uppmäts genom att undersöka distribution av partikelstorlek, löst organiskt kol (sCOD), biometan potential (BMP) och nedbrytningshastigheten. Efter 2 minuters hydrodynamisk kavitation (8 bar) minskade partikelstorleken från 489- 1344 nm till 277- 281 nm (≤77 % reduktion) för de olika biomassorna. Liknande påverkan observerades efter tio minuters ångexplosion (210 °C, 30 bar) med en partikelstorlekreducering mellan 40 och 70 % för alla behandlade substrat. Efter behandling med hydrodynamisk kavitation, i jämförelse med obehandlad biomassa, ökade metanproduktionens hastighetskonstant (K) för matavfall (+65%), makroalgen S. latissima (+3%), gräs (+16 %) samtidigt som den minskade för A. nodosum (-17 %). Förbehandlingen med ångexplosion ökade hastighetskonstanten för S. latissima (+50 %) och A. nodosum (+65 %) medan den minskade för gräs (-37 %), i jämförelse med obehandlad biomassa. Vad gäller BMP värden, orsakade hydrodynamisk kavitation små variationer där endast A. nodosum visade en ökning efter behandling (+44 %) i jämförelse med obehandlad biomassa. Biomassa förbehandlade med ångexplosion visade en ökning för A .nodosum (+86 %), gräs (14 %) och S. latissima (4 %). Sammantaget visar hydrodynamisk kavitation potential som en effektiv behandling före rötning och kapabel att konkurrera med den traditionella ångexplosionen gällande kinetik och energibalans (+14%) samt metanutbytet för A. nodosum.
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Methane and Carbon Dioxide Emissions From Three Smallscale Hydropower Stations in South of Sweden / Metan- och Koldioxidutsläpp Från Tre Småskaliga Vattenkraftverk i Södra SverigeDanielsen, Edevardt Johan, Jonsson Valderrama, Alexandra January 2022 (has links)
Over the past decades, evidence show that the anthropogenetic greenhouse gases (GHG) emissions of carbon dioxide (CO₂) and methane (CH₄) are the main drivers behind global warming and are becoming stronger. Globally, hydropower is among the main sources of renewable energy and the popular notion that hydropower electricity is carbon neutral has been under debate as evidence from measurements in different regions of the globe show significant and highly variable carbon emissions from hydropower reservoirs. But these global estimates are still highly uncertain since they are restricted to a few locations in the south of Europe, North America, and South America, and lack both the temporal and spatial variability in addition to some of the flux pathways (often downstream emission and degassing). This study assesses the CH4 and CO₂ emissions from reservoirs associated to three small hydropower stations in the south of Sweden and aims to understand potential spatial and temporal variability in the temperate region. The study performed flux measurements of CH4 and CO₂, an analysis of CH4 and DIC concentration in the water, and a depth profile of temperature, DO, CH4 and DIC at the hydropower station’s reservoirs. In summation this study finds significant CH4 and DIC concentrations, as well as CH4 and CO₂emissions from the studied reservoirs. The findings of this study underline the notion that hydropower might be a `blind spot` in the Swedish GHG budget report, and if so, the carbon emissions from hydropower electricity need to be re-evaluated.
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