Results are presented for towing tank experiments of a surface-piercing flat plate with superimposed Stokes wave in order to examine free surface and wave effects on the boundary layer and wake. Measurements with servo wave gauges are made to characterize the Stokes-wave wave field in terms of its two-dimensionality, amplitude, and wavelength. Flow field measurements using stereo particle image velocimetry are used to identify the boundary layer and wake velocities. Particular attention is drawn to the juncture region to resolve the complex and poorly understood secondary flow patterns. Four test cases are presented (1) flat free surface without plate, (2) Stokes-wave without plate, (3) flat free surface with plate, and (4) Stokes-wave with plate; the cases were chosen in order to isolate and identify the performance of the velocimeter system, Stokes-wave flow field, free-surface effects, and combined Stokes-wave and free surface effects, respectively. All cases are conducted at Froude numbers of Fn = 0.4, length-based Reynolds number of Re = 1.64×106, and momentum thickness-based Reynolds number of about Re = 4000. Results show, as expected, that the free surface effects penetrate to a depth slightly greater than the boundary layer thickness and wave effects diminish at roughly one half the wavelength. The juncture region flow was resolved to levels that far exceed previous towing tank experiments, but leave more to be desired. The data and analysis are important, not only from a scientific perspective, but have a practical application with regard to development of turbulence models for computational fluid dynamic techniques.

The methods for solving domain optimization problems depends on the case of study. There are methods that have been developed for the discretized problem, but not much is done in the infinite dimensional case. We analyze the theoretical aspects of the infinite dimensional case for a particular domain optimization problem where a portion of the boundary is parametrized, these results involve the existence of the solution to our problem and the calculation of the derivative of the shape functional. Shape optimization problems have a long history of mathematical study and a wide range of applications. In recent decades there has been an interest in solving these problems with partial differential equation (PDE) constraints. We consider a special class of PDE-constrained shape optimization problems where different boundary condition types (Dirichlet and Neumann) are imposed on the same boundary segment. We also consider the case where the interface between these different boundary condition types may also be parameter dependent. This study also includes special cases where the shape of the region where the PDE is imposed does not change, but the domain of the partial differential operator is parameter dependent, due to the change in boundary condition type. Our treatment centers on the infinite dimensional formulation of the optimization problem. We consider existence of solutions as well as the calculation of derivatives of the associated shape functionals via adjoint solutions. These derivative formulations serve as a starting point for practical numerical approximations. / Ph. D. / Optimization problems arise in a number of areas and are usually posed as finding values of design parameters that minimize a given cost function. Examples include finding the shape of a car or airplane wing to reduce drag and improve fuel economy which maintaining a desired level of performance. This is an example of a constrained optimization problem where the constraint is described by a physical model known as a partial differential equation (PDE). For shape optimization problems, we want to find the best shape to minimizes a certain cost function, and the cost depends on the shape through the solution to the PDE. The strategy for solving a shape optimization problem depends on the particular problem at hand. In many cases, one assumes that the solution of an optimization problem exists, so the development of methods to find or approximate possible solutions is the first step. In this dissertation, we study some theoretical aspects of the problem that can be used to guarantee the existence of an optimal (or locally optimal) solution to the problem. We focus our attention on a special class of PDE constraints where the cost function is calculated over a domain with an unknown portion that needs to be determined. We further consider a special case of boundary conditions for the PDE constraints known as mixed boundary conditions. In this work, we study the theoretical aspects to guarantee the existence of a solution, and then we provide formulations of the derivatives that permit algorithms to search for the shape of the domain that minimizes a given cost function. These formulations are important to develop efficient numerical approximations.

In this thesis, we prove the existence and uniqueness of the solution to a Neumann boundary problem for an elliptic differential operator with singular coefficients, and reveal the relationship between the solution to the partial differential equation (PDE in abbreviation) and the solution to a kind of backward stochastic differential equations (BSDE in abbreviation).This study is motivated by the research on the Dirichlet problem for an elliptic operator (\cite{Z}). But it turns out that different methods are needed to deal with the reflecting diffusion on a bounded domain. For example, the integral with respect to the boundary local time, which is a nondecreasing process associated with the reflecting diffusion, needs to be estimated. This leads us to a detailed study of the reflecting diffusion. As a result, two-sided estimates on the heat kernels are established. We introduce a new type of backward differential equations with infinity horizon and prove the existence and uniqueness of both L2 and L1 solutions of the BSDEs. In this thesis, we use the BSDE to solve the semilinear Neumann boundary problem. However, this research on the BSDEs has its independent interest. Under certain conditions on both the "singular" coefficient of the elliptic operator and the "semilinear coefficient" in the deterministic differential equation, we find an explicit probabilistic solution to the Neumann problem, which supplies a L2 solution of a BSDE with infinite horizon. We also show that, less restrictive conditions on the coefficients are needed if the solution to the Neumann boundary problem only provides a L1 solution to the BSDE.

Many boundary value problems of mathematical physics are modelled by elliptic differential operators L in a given domain Ω . An effective method for treating such problems is the method of layer potentials, whose essence resides in reducing matters to solving a boundary integral equation. This, in turn, requires inverting a singular integral operator, naturally associated with L and Ω, on appropriate function spaces on ƌΩ. When the operator L is of second order and the domain Ω is Lipschitz (i.e., Ω is locally the upper-graph of a Lipschitz function) the fundamental work of B. Dahlberg, C. Kenig, D. Jerison, E. Fabes, N. Rivière, G. Verchota, R. Brown, and many others, has opened the door for the development of a far-reaching theory in this setting, even though several very difficult questions still remain unanswered. In this dissertation, the goal is to solve a number of open questions regarding spectral properties of singular integral operators associated with second and higher-order elliptic boundary value problems in non-smooth domains. Among other spectral results, we establish symmetry properties of harmonic classical double layer potentials associated with the Laplacian in the class of Lipschitz domains in R2. An array of useful tools and techniques from Harmonic Analysis, Partial Differential Equations play a key role in our approach, and these are discussed as preliminary material in the thesis: --Mellin Transforms and Fourier Analysis; --Calderón-Zygmund Theory in Uniformly Rectifiable Domains; -- Boundary Integral Methods. Chapter four deals with proving invertibility properties of singular integral operators naturally associated with the mixed (Zaremba) problem for the Laplacian and the Lamé system in infinite sectors in two dimensions, when considering their action on the Lebesgue scale of p integrable functions, for 1 < p < ∞. Concretely, we consider the case in which a Dirichlet boundary condition is imposed on one ray of the sector, and a Neumann boundary condition is imposed on the other ray. In this geometric context, using Mellin transform techniques, we identify the set of critical integrability indexes p for which the invertibility of these operators fails. Furthermore, for the case of the Laplacian we establish an explicit characterization of the Lp spectrum of these operators for each p є (1,∞), as well as well-posedness results for the mixed problem. In chapter five, we study spectral properties of layer potentials associated with the biharmonic equation in infinite quadrants in two dimensions. A number of difficulties have to be dealt with, the most significant being the more complex nature of the singular integrals arising in this 4-th order setting (manifesting itself on the Mellin side by integral kernels exhibiting Mellin symbols involving hyper-geometric functions). Finally, chapter six, deals with spectral issues in Lipschitz domains in two dimensions. Here we are able to prove the symmetry of the spectra of the double layer potentials associated with the Laplacian. This is in essence a two-dimensional phenomenon, as known examples show the failure of symmetry in higher dimensions. / Mathematics

Reaction-diffusion equations have been used to study various phenomena across different fields. These equations can be posed on the whole real line, or on a subinterval, depending on the situation being studied. For finite intervals, we also impose diverse boundary conditions on the system. In the present thesis, we solely focus on the bistable reaction-diffusion equation while working on a bounded interval of the form $[0,L]$ ($L>0$). Furthermore, we consider both mixed and no-flux boundary conditions, where we extend the former to Dirichlet boundary conditions once our analysis of that system is complete. We first use phase-plane analysis to set up our initial investigation of both systems. This gives us an integral describing the transit time of orbits within the phase-plane. This allows us to determine the bifurcation diagram of both systems. We then transform the integral to ease numerical calculations. Finally, we determine the stability of the steady states of each system.

The current requirements in automotive lubrication impose complex formulation. Among all the additives present in oil, the presence of molybdenum dithiocarbamate and zinc dithiophosphate, both tribological additives containing sulfur and phosphorous is found. For environmental reasons, it is important to reduce or eliminate the presence of these two elements contained in oil. Organic molecules based on carbon, oxygen and hydrogen seems to be good candidate. The lubrication mechanism of fatty acids (e.g. stearic, oleic and linoleic acids) is revisited with a new approach combining experimental and computational chemistry studies. First, the adsorption mechanisms of fatty acids on iron-based surfaces are investigated by Ultra-Accelerated Quantum Chemistry Molecular Dynamics simulations. The adsorption of fatty acids on iron oxide surface occurred through the acid group. Depending on the nature of the substrate, on the density of the film and on the tilt angle between the molecule and the surface, different adsorption mechanisms (physisorption and chemisorption) can occur. Stearic acid molecules form a close-packed and well-arranged monolayer whereas unsaturation acids cannot because of steric effects induced by double carbon-carbon bonds. The friction process favors the formation of carboxylate function. Results are confirmed by surface analysis (XPS and PM-IRRAS). Tribological properties of pure fatty acids, blended in PAO 4 and mixture of saturated/unsaturated acids are studied by MD simulations and tribotests. Low friction coefficient with no visible wear is reported for pure stearic acid and single stearic acid blended in PAO 4 at 1%w at high temperature. This lubricating behavior is inhibited in the presence of unsaturated acids, especially at 150 °C. MD simulation results show a faster diffusion toward the surface for unsaturated fatty acids than for stearic acid at all studied temperature.

Title: Bifurcation of Ordinary Differential Equations from Points of Fučík Spectrum Author: Vendula Exnerová Department: Department of Mathematical Analysis Supervisor: doc. RNDr. Jana Stará, CSc., Department of Mathematical Analysis MFF UK, Prague Abstract: The main subject of the thesis is the Fučík spectrum of a system of two differential equations of the second order with mixed boundary conditions. In the first part of the thesis there are described Fučík spectra of problems of a differential equation with Dirichlet, mixed and Neumann boundary conditions. The other part deals with systems of two differential equations. It attends to basic properties of systems and their nontrivial solutions, to a possibility of a reduction of number of parameters and to a dependance of a problem with mixed boundary condition on one with Dirichlet boundary conditions. The thesis takes up the results of E. Massa and B. Ruff about the Dirichlet problem and improves some of their proofs. In the end the Fučík spectrum of a problem with mixed boundary conditions is described as the union of countably many continuously differentiable surfaces and there is proven that this spectrum is closed.

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For a bounded Lipschitz domain with Lipschitz interface we show the following compactness theorem: Any L2-bounded sequence of vector fields with L2-bounded rotations and L2-bounded divergences as well as L2-bounded tangential traces on one part of the boundary and L2-bounded normal traces on the other part of the boundary, contains a strongly L2-convergent subsequence. This generalises recent results for homogeneous mixed boundary conditions in Bauer et al. (SIAM J Math Anal 48(4):2912-2943, 2016) Bauer et al. (in: Maxwell’s Equations: Analysis and Numerics (Radon Series on Computational and Applied Mathematics 24), De Gruyter, pp. 77-104, 2019). As applications we present a related Friedrichs/Poincaré type estimate, a div-curl lemma, and show that the Maxwell operator with mixed tangential and impedance boundary conditions (Robin type boundary conditions) has compact resolvents.