Slurry is the fluid within a drilled excavation that is introduced when an excavation is deeper than the water table or where additional stability is needed for loose sandy dry soils. Although construction practices vary greatly throughout the country and the world, slurry levels should be maintained above the existing ground water level by a suitable margin. The most widely used slurry type is mineral slurry formed by mixing dry clay powder with water; either bentonite or attapulgite powder may be used (attapulgite being used in saline water conditions). Regardless of whether the slurry material is mineral, polymer or natural, the construction practice must address the slurry properties to ensure the stability of the excavation is never compromised. Proper performance of slurries used to stabilize drilled shaft excavations is maintained by assuring the density, viscosity, pH, and sand content stay within specified limits. These limits have been set either by past experience, research findings and/or by manufacturer recommended values. However, field slurry testing is time consuming as all measurements are manually performed. With the overwhelming advances in digital down-hole devices, it is not unreasonable to assume that slurry property tests are equally applicable to this trend. This formed the basis of this project. The most commonly used test to indicate slurry viscosity is the Marsh Funnel Test which is essentially a timed flow for a fixed volume of slurry to exit a falling head funnel. Using a library of unique pressure versus flow rate responses for a wide range of slurry viscosities, an automated downhole device was designed and tested that incorporated this information to estimate viscosity in the excavation without the need to remove slurry in order to test. Direct measurement of slurry density was also incorporated into the device and the sand content was computed from density and the viscosity where the suspended solids that make up the density stems from both the slurry products and the soil cuttings.

In South African estuaries the anomuran mud prawn, Upogebia africana (Ortmann), is the main organism exploited as bait by recreational and subsistence anglers. In the Knysna estuary, three groups of bait collectors were identified on the basis of their source of income: subsistence fishermen who rely on bait-collecting and fishing for their income, supplementary anglers who catch fish to supplement their income and leisure anglers who draw no income from fishing. Two groups were identified based on the methods used: lelsure anglers who collect bait using a prawn pusher or pump and fish using a fishing rod and tackle, and non-leisure anglers who collect mud prawns using tin cans and fish with handlines. The hypothesis was erected that bait-collecting does not affect the U africana populations in the Knysna estuary. The approach adopted was to assess the distribution, density, population structure and reproductive patterns of the bait stock and to estimate the intensity of bait collection, to test the validity of the hypothesis. U africana has an extensive distribution, occupying 62 % of the available intertidal area of the Knysna estuary. Mud prawns have a broad intertidal distribution from the high water level (Spartina zone) to the shallow subtidal. The density, biomass and population structure of the mud prawns vary significantly with distance up the estuary and with tidal height on each shore. The Invertebrate Reserve supports very low densities of U africana (x = 11.7 m⁻²), whereas a relatively inaccessible centre bank in the middle reaches of the estuary appears to be a very effective natural mud prawn reserve as it supports the highest densities (x = 176.5m⁻²). The mud prawn stock of the estuary is estimated to be 2.19 x 108 prawns (82.7 tonnes dry mass). The numbers of bait collectors present per mudbank is highest on public holidays (x = 34) and higher during the summer holidays (x = 16) than during the winter (x = 4). A total of 1.858 x 106 U africana or 700.53 kg (dry mass) are removed by bait collectors annually from the 6 popular bait-collecting sites studied. This represents 8.49 % of the mud prawn stocks at these sites and 0.85 % of the entire estuary stock. 85 % of the U africana taken as bait annually, is removed by the 77.12 % of bait collectors who are non-leisure anglers. Recreational or leisure anglers are responsible for removing 14.2 %. The reproduction of female U africana in the Knysna estuary is seasonal and occurs from late July to April. There is evidence that this breeding season consists of two merging breeding cycles. The largest percentage (63 %) of ovigerous females is found in the middle reaches of the Knysna estuary at the Oyster Bank where the highest numbers of stage 1 larvae (165 m⁻³) are released. Larvae were exported from the estuary on the crepuscular ebb tide with peaks in abundance of nearly 1500 m⁻³ in November 1995 and January 1996. Although numbers caught are not significantly higher, larvae are nearly twice as abundant on crepuscular neap tides following a new moon (waxing quarter) than on those following a full moon (waning quarter). Recruitment of juvenile U africana to populations in the estuary was highest in December (45 m⁻²) and decreased over the summer. The highest numbers of recruits (31 m⁻²) were found at those sites closest to the mouth or on the main channel. Recruitment to the Leisure Isle and Thesens sites which are intensively exploited by bait collectors is high (20 - 32 m⁻²). The number of juveniles recruiting to U africana populations is estimated to be four times as high as the numbers of mud prawns taken by bait collectors. Legal methods of bait collection used in the Knysna estuary by the majority of anglers appear to cause minimal sediment disturbance and are not likely to affect the associated infauna. Illegal bait-collecting methods are however highly destructive and must be prohibited. It is concluded that the null hypothesis is acceptable, as mud prawn stocks of the Knysna estuary are not over-exploited and appear to be naturally regulated. The recruitment rate of juvenile U africana is estimated to be sufficiently high to sustain the present levels of exploitation.

In spread spectrum systems employing parity bit selected spreading sequences, parity bits generated from a linear block encoder are used to select a spreading code from a set of mutually orthogonal spreading sequences. In this thesis, turbo receivers for SS-PB systems are proposed and investigated. In the transmitter, data bits are rst convolutionally encoded before being fed into SS-PB modulator. In fact, the parity bit spreading code selection technique acts as an inner encoder in this system without allocating any transmit energy to the additional redundancy provided by this technique. The receiver implements a turbo processing by iteratively exchanging the soft information on coded bits between a SISO detector and a SISO decoder. In this system, detection is performed by incorporating the extrinsic information provided by the decoder in the last iteration into the received signal to calculate the likelihood of each detected bit in terms of LLR which is used as the input for a SISO decoder. In addition, SISO detectors are proposed for MC-CDMA and MIMO-CDMA systems that employ parity bit selected and permutation spreading. In the case of multiuser scenario, a turbo SISO multiuser detector is introduced for SS-PB systems for both synchronous and asynchronous channels. In such systems, MAI is estimated from the extrinsic information provided by the SISO channel decoder in the previous iteration. SISO multiuser detectors are also proposed for the case of multiple users in MC-CDMA and MIMO-CDMA systems when parity bit selected and permutation spreading are used. Simulations performed for all the proposed turbo receivers show a signi cant reduction in BER in AWGN and fading channels over multiple iterations.

For developing the available hydrocarbon reserves and for exploring new reservoirs, deeper and more complex wells are drilled. Drilling such deeper and complex wells requires a constant monitoring and controlling of the well paths. Therefore, the bottom hole assembly, the lower section of the drill string above the drill bit, is equipped with numerous measuring sensors for collecting geological and directional data while drilling. The collected data have to be transmitted to the surface in real time. Prior to transmit the data measured downhole to the surface, they are processed and translated into a binary code. Accordingly, the data will be represented as a series of zeroes and ones. The most common method for data transmission in boreholes is the so called mud pulse telemetry which sends the information through the drilling mud inside the drill string by means of coded pressure pulses. There are two types of devices available for downhole pressure pulses generation. The first type is the (positive or negative) pressure pulser which transmits the data by quasi-static variations of the pressure level inside the drill string. The second type is the (rotating or oscillating) mud siren which transmits the data by generating continuous pressure waves at specific frequencies. The main disadvantage of the mud pulse telemetry is its low data transmission rate which is about 10 bps. This data rate is very low compared to the measured amount of raw data. Therefore, the efficiency of the mud pulse telemetry must be improved, so that the data could be transmitted at higher rates. The present research work presents different developed and tested concepts for increasing the efficiency and the data transmission rate of the mud pulse telemetry. Both, the transmitter and the receiver end, were taken into consideration by developing the new concepts. Different hardware and software tools were used for performing the present research work. The available flow loop test facility and the experimental prototypes of the mud siren and positive pulser were used. The test facility was extended in order to enable the investigation of the new concepts. The available 3D numerical model (ANSYS CFX) was modified and extended in order to study the new concepts. At the transmitter end, a novel concept for a hybrid mud pulse telemetry system was developed and successfully tested. Here, two different types of mud pulse telemetry could be used in a combination, such as a mud siren and a pressure pulser. The developed concept was registered at the German Patent and Trade Mark Office for a patent in 2018. Two concepts for a multi-frequency mud siren were developed for simultaneous generation of two frequencies. In the first approach, two sets of stator/rotor were installed in a row connection, while they were installed in a parallel connection in the second approach. The two concepts were registered at the German Patent and Trade Mark Office for patents in 2015. An experimental multi-frequency generator was built and used for testing of several new ideas, such as transmitting the data using several carrier frequencies at the same time, transmitting the data with different wave forms (sine, sawtooth, triangle and rectangle), or transmitting the data using the chirp modulation. The innovative design of the experimental multi-frequency generator was registered at the German Patent and Trade Mark Office for patents in 2016. At the receiver end, two different methods for processing and analyzing the received multi-frequency signals using the Wavelet and Fourier analysis were drafted and tested. A novel concept for the use of a multi-sensor receiver was developed and successfully tested. The use of a multi-sensor receiver could strongly improve the detection of the received signals.:Table of Contents Declaration ii Abstract iii Acknowledgements v Table of Contents vi List of Abbreviations x List of Symbols xii CHAPTER 1 Introduction 1 CHAPTER 2 Modern Drilling Technology and Low Data Transmission Rate as a Limitation 5 2.1 Introduction to the modern drilling technology 5 2.1.1 Directional drilling technology 5 2.1.2 Steering technology 6 2.1.3 Measuring technology 8 2.1.4 Technology of data transmission in boreholes 9 2.2 Low data transmission rate as a problem with respect to the whole drilling process 13 CHAPTER 3 Fundamentals of Communication Technology 16 3.1 Modulation techniques for data transmission in baseband 16 3.2 Modulation techniques for data transmission in passband 17 3.3 Multiple frequency and chirp spread spectrum modulation techniques 19 3.4 Digital signal processing 21 3.4.1 Fourier transformation 21 3.4.2 Continuous wavelet transformation 23 3.4.3 Filtering 24 CHAPTER 4 State of the Art for Mud Pulse Telemetry Systems 26 4.1 Historical development of mud pulse telemetry including latest improvements applied for increasing its data transmission rate 26 4.2 Available types of mud pulse telemetry devices 30 4.2.1 Negative pulser 31 4.2.2 Positive pulser 32 4.2.3 Mud siren 32 4.2.4 Oscillating shear valve 33 4.3 Limitations of data transmission via mud pulse telemetry 34 4.3.1 Effect of noise sources in the mud channel on the transmission signal 34 4.3.2 Effect of attenuation in the mud channel on the transmission signal 36 4.3.3 Effect of reflections and their interference with the main transmission signal 37 4.3.4 Pass and stop bands 38 4.4.5 Minimum transmission time slot 38 CHAPTER 5 Novel Concepts and Tools for Increased Data Transmission Rates of Mud Pulse Telemetry 40 5.1 Transmitter end 41 5.1.1 Hybrid mud pulse telemetry (HMPT) 41 5.1.2 Multi-frequency generator 43 5.2 Receiver end 45 5.2.1 Investigation of the Wavelet analysis suitability for multi-frequency signal detection 45 5.2.2 Flexible placement of multi-sensor receiver 46 CHAPTER 6 Laboratory Test Facility and Used Hard and Soft Tools 49 6.1 Laboratory test facility for hydraulic data transmission in boreholes 49 6.2 Experimental prototypes of the pressure pulsers and mud siren 53 6.3 3D numerical simulation model for the test facility and mud siren 55 6.4 MATLAB software 58 CHAPTER 7 Hybrid Mud Pulse Telemetry (HMPT) System 59 7.1 Combination of mud siren and negative pressure pulser 60 7.2 Combination of mud siren and positive pressure pulser 63 7.3 Evaluating the laboratory investigations of the hybrid mud pulse telemetry (HMPT) system 66 CHAPTER 8 Mathematical and Numerical Investigation of the Concept of the Multi-Frequency Mud Siren 68 8.1 Preliminary considerations for the concept of the multi-frequency mud siren 69 8.2 Mathematical model investigation of different approaches for the multi-frequency mud siren concept 71 8.2.1 Multi-frequency mud siren with stators and rotors in a row 72 8.2.2 Multi-frequency mud siren with parallel connection of stators and rotors 74 8.3 Numerical model investigation of multi-frequency mud siren with two sets of stator/rotor in a row 77 8.3.1 Numerical simulations for data transmission with a multi-frequency mud siren using two carrier frequencies 79 8.3.2 Evaluation of the simulation results 81 8.3.3 Increasing the transmission reach of the mud siren for deep drilling operations 83 CHAPTER 9 Laboratory Investigations of Multi-Carrier Hydraulic Data Transmission Using an Experimental Multi-Frequency Generator 85 9.1 Laboratory multi-carrier frequency transmission tests 87 9.2 Investigation of the Wavelet analysis suitability for the detection of multi-frequency signal transmitted in boreholes 95 9.3 Initial investigations of hydraulic data transmission using chirp modulation and different pressure wave forms 100 9.3.1 Data transmission using chirp modulation (Chirp Spread Spectrum, CSS) 100 9.3.2 Data transmission using different wave forms 101 CHAPTER 10 Investigation of the Use of a Multi-Sensor Receiver for Improving the Hydraulic Data Transmission in Boreholes 104 10.1 Numerical model investigation of the use of a multi-sensor receiver 104 10.1.1 Data transmission using single-input and multiple-output (SIMO) 104 10.1.2 Data transmission using multiple-input and multiple-output (MIMO) 107 10.2 Laboratory investigations of the use of a multi-sensor receiver 108 10.3 Evaluating the use of a multi-sensor receiver for improving the hydraulic data transmission in boreholes 112 CHAPTER 11 Conclusion and Outlook 116 11.1 Conclusion 116 11.2 Outlook 120 References 122 List of Figures 129 List of Tables 136 List of Publications 137 List of Patents 138 Appendix- Chapter 7 139 Appendix- Chapter 8 141 Appendix- Chapter 9 142 Appendix- Chapter 10 146

Catalytic hydrodeoxygenation (HDO), is an effective process to convert oxygenated compounds to hydrocarbons. This process is widely used for improving the negative properties of biomass-derived pyrolysis oils (bio-oils) such as high acidity, poor stability, and low heating value. During this process oxygen is removed from the bio-oil in the form of water, thus the liquid product of HDO process consists of aqueous phase and hydrocarbon phase that can be easily separated. Synthesis of efficient HDO catalyst has been a major challenge in the field of bio-oil upgrading. Red mud, which is an alkaline waste from alumina industry was used to develop a new red mud-supported nickel catalyst (Ni/RM) for the HDO of pinyon-juniper catalytic pyrolysis oil. The new catalyst was more effective than the commercial Ni/silica-alumina catalyst for the HDO of organic phase pyrolysis oil, the aqueous phase pyrolysis oil, and bio-oil model compounds. Less hydrogen was consumed in the case of Ni/RM and more liquid hydrocarbon yield was obtained compared to the commercial catalyst. In addition to HDO reactions, the Ni/RM catalyst catalyzed ketonization and carbonyl alkylation reactions that was important to produce liquid hydrocarbon from low molecular weight oxygenated compounds. Unlike the commercial catalyst, Ni/RM was regenerable by burning off the deposited coke and activation by reduction using hydrogen.

Drilling is crucial to many industries, including hydrocarbon extraction, CO2 sequestration, geothermal energy, and others. During penetrating the subsurface rocks, drilling fluid (mud) is used for drilling bit cooling, lubrication, removing rock cuttings, and providing wellbore mechanical stability. Significant mud loss from the wellbore into the surrounding formation causes fluid lost-circulation incidents. This phenomenon leads to cost overrun, environmental pollution, delays project time and causes safety issues. Although lost-circulation exacerbates wellbore conditions, prediction of the characteristics of subsurface formations can be obtained. Generally, four formation types cause lost-circulation: natural fractures, and induced fractures, vugs and caves, and porous/permeable medium. The focus in this work is on naturally fractured formations, which is the most common cause of lost circulation. In this work, a novel prediction tool is developed based on analytical solutions and type-curves (TC). Type-curves are derived from the Cauchy equation of motion and mass conservation for non-Newtonian fluid model, corresponding to Herschel-Bulkley model (HB). Experimental setup from literature mimicking a deformed fracture supports the establishment of the tool. Upscaling the model of a natural fracture at subsurface conditions is implemented into the equations to achieve a group of mud type-curves (MTC) alongside another set of derivative-based mud type-curves (DMTC). The developed approach is verified with numerical simulations. Further, verification is performed with other analytical solutions. This proposed tool serves various functionalities; It predicts the volume loss as a function of time, based on wellbore operating conditions. The time-dependent fluid loss penetration from the wellbore into the surrounding formation can be computed. Additionally, the hydraulic aperture of the fracture in the surrounding formation can be estimated. Due to the non-Newtonian behavior of the drilling mud, the tool can be used to assess the fluid loss stopping time. Validation of the tool is performed by using actual field datasets and published experimental measurements. Machine-Learning is finally investigated as a complementary approach to determine the flow behavior of mud loss and the corresponding fracture properties.

From June to November 1967, a study on channel catfish, lctalurus punctatus (Rafinesque), in Mud Lake, Utah Co., Utah was undertaken. The objectives were (I) to estimate if channel catfish are increasing or decreasing in Mud Lake, (2) to estimate the mean size of adult channel catfish in Mud lake, (3) to determine which environmental factors effect the catch of channel catfish, and (4) to determine if the channel catfish in Mud lake are residents year round. A total of 310 mature channel catfish and 920 carp were collected with four hoop nets. Two fingerling were captured by seining. Ratios between carp and channel catfish over a 17 year period had been established which indicated a possible increase in the channel catfish population. With the exception of the fingerIings all channel catfish captured were at least 36.8 cm long with an average of 50.2 cm. A comparison between environmental factors (water temperture, turbidity, water level, and barometric pressure) and the catch showed that only water temperature changes had a statistically significant influence. Large catches during June, July, August, and September were recorded. In later months the numbers of fish captured decreased and no channel catfish could be seen when tho water cleared. It appears that channel catfish utiIize Mud Lake only during the summer.

No description available.

京都大学 / 新制・課程博士 / 博士(農学) / 甲第23938号 / 農博第2487号 / 新制||農||1089(附属図書館) / 学位論文||R4||N5373(農学部図書室) / 京都大学大学院農学研究科森林科学専攻 / (主査)教授 五十田 博, 教授 藤井 義久, 教授 梅村 研二 / 学位規則第4条第1項該当 / Doctor of Agricultural Science / Kyoto University / DGAM

Nuclear magnetic resonance (NMR) has become an effective borehole measurement option to assess petrophysical and fluid properties of porous and permeable rocks. In the case of fluid typing, two-dimensional (2D) NMR interpretation techniques have advantages over conventional one-dimensional (1D) interpretation as they provide additional discriminatory information about saturating fluids and their properties. However, often there is ambiguity as to whether fluids detected with NMR measurements are mobile or residual. In some instances, rapid vertical variations of rock properties (e.g. across thinly-bedded formations) can make it difficult to separate NMR fluid signatures from those due to pore-size distributions. There are also cases where conventional fluid identification methods based on resistivity and nuclear logs indicate dominant presence of water while NMR measurements indicate presence of water, hydrocarbon, and mud filtrate. In such cases, it is important to ascertain whether existing hydrocarbons are residual or mobile. The radial lengths of investigation of resistivity, nuclear, and NMR measurements are very different, with NMR measurements being the shallowest sensing. Even in the case of several radial zones of NMR response attributed to different acquisition frequencies and DC magnetic field gradients, the measured signal originates from a fairly shallow radial zone compared to that of nuclear and resistivity logs. Depending on drilling mud being used and the radial extent of mud-filtrate invasion, the NMR response of virgin reservoir fluids can be masked by mud filtrate because of fluid displacement and mixing. In order to separate those effects, it is important to reconcile NMR measurements with electrical and nuclear logs for improved assessment of porosity and mobile hydrocarbon saturation. Previously, Voss et al. (2009) and Gandhi et al. (2010) introduced the concept of Common Stratigraphic Framework (CSF) to construct and validate multi-layer static and dynamic petrophysical models based on the numerical simulation of well logs. In this thesis, the concept of CSF is implemented to reconcile 2D NMR interpretations with multi-layer static and dynamic petrophysical models. It is found that quantifying the exact radial zone of response and corresponding fluid saturations can only be accomplished with studies of mud-filtrate invasion that honor available resistivity and nuclear logs. This thesis indicates that the two interpretation methods complement each other and when applied in conjunction, improve and refine the overall petrophysical understanding of permeable rock formations. Examples of successful application include field data acquired in thinly-bedded gas formations invaded with water-base mud, where bed-boundary effects are significant and residual hydrocarbon saturation is relatively high. In such cases, numerical simulation of mud-filtrate invasion and well logs acquired after invasion enables reliable interpretations of petrophysical and fluid properties. The interpretation procedure introduced in this thesis also provides an explicit way to determine the uncertainty of petrophysical and fluid interpretations. / text