2-Dodecyl benzotriazole and 9,9-dioctylfluorene containing alternating copolymers poly((9,9-dioctylfluorene)-2,7-diyl-(2-dodecyl-benzo[1,2,3]triazole)) (P1), poly((9,9-dioc-tylfluorene)-2,7-diyl-(4,7-bis(thien-2-yl) 2-dodecyl benzo[1,2,3]triazole)) (P2), poly((9,9 dioctylfluorene)-2,7-diyl-(4,7-bis(3-hexylthien-5-yl) 2-dodecyl-benzo[1,2,3]triazole)) (P3) were synthesized via Suzuki polycondensation. Synthesized monomers and copolymers were characterized by Nuclear Magnetic Resonance (1H-NMR, 13C-NMR). Optical and electronic properties of resulting alternating copolymers were investigated by means of Cyclic Voltammetry (CV), Ultraviolet&ndash / Visible Spectroscopy and spectroelectrochemistry. All three polymers showed both p and n doping behaviors and multicolored electrochromic states. In order to learn switchingtimes and percent transmittance changes kinetic studies were also performed. Thermal properties of the polymers were investigated via Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Due to the convenient HOMO and LUMO levels, band gaps, strong absorptions in the visible region and thermal stability, polymers were tested in Organic Solar Cell (OSC) device applications. The preliminary investigation indicated that polymers had promising power conversion efficiencies.

Two subjects are included in this thesis; one is to construct the Coffin-Manson equation of the unleaded SnAgCu solder according to the experimental results provided by the Metal Research Laboratory (MRL) of Industrial Technologies Research Institute (ITRI). The results of CSP thermal cycle fatigue and SOJ pull tests and the corresponding stress and strain distributions solved from FEM analyses have been used to derive the Coffin-Manson equation for the SnAgCu solder. The other subject is to investigate the effect of CTE mismatch on the fatigue life of solder balls in the opto-electronic packaging. The solidified shapes of the different solder balls after undergoing the re-flow process are predicted by employing the Surface Evolver package program. The FEA meshes of the solidified solder balls in opto-electronic packaging are built according to the output results of the Surface Evolver program. The maximum equivalent plastic shear strain range of the solder after under one thermal cycle process is calculated by employing the MARC finite element package. The fatigue lives of solder balls under different arrangements are estimated according to the proposed Coffin-Manson equation. The effect of solder ball parameters, i.e. solder volume, solder offset distance, solder DNP and solder material on the reliability of different solder balls has also been explored in this thesis.

We study the characteristics of the dual frequency liquid-crystal (LC) optoelectronic devices in this literary. We fabricate the LC lens with the dual frequency liquid crystal in our experiment. In this study, we first prepare a parabolic polymer structure on the glass substrate to form a polymeric lens glass, then, fill the dual-frequency LC into the empty cell which consists of one ITO glass and the polymeric lens glass to fabricate a frequency modulation LC lens. Additionally, a hybrid surface alignment is also used for our LC lens. For the dual-frequency LC, a hybrid surface alignment is necessary to obtain a frequency modulation LC lens. Because of the polymeric lens, the electric fields are inhomogeneous distributions in the LC lens when a voltage is applied to the electrodes. In this situation, an inhomogeneous electric field is applied to the cell to create GRIN lens-like distribution of the gradient refractive index. Thus, the focusing effects occur when the light passes through the LC lens. Moreover, by changing the amplitude and frequency of the applied voltage, the focal length of the LC lens can be changed. We mainly discuss the optical property and the response time of the LC lens based on the voltage modulation and the frequency modulation. The experimental results reveal that the frequency modulation has more advantages, such as widen range of controlled focal length and faster response time, comparing with the voltage modulation.

The focus of this study is the optoelectronic integration of a micro-optical displacement detection architecture with a biomimetic MEMS microphone membrane based on the directional hearing mechanism of the parasitic fly Ormia Ochracea. The micromachined microphones feature optical interferometric displacement detection achieved using a commercially available Vertical Cavity Surface Emitting Laser (VCSEL) coupled with a custom designed silicon photodiode array. This design is shown to have significant advantages over conventional hearing aid microphones, which employ capacitive detection. A Multi-Chip Module (MCM) optoelectronic package is designed to integrate the biomimetic membrane with the optical displacement detection electronics in order to produce a fully integrated acoustic sensor. The modular package components, which are fabricated using high resolution stereolithography apparatus (SLA) equipment, provide accurate optical alignment of the optoelectronic components and allow complete device integration in a package with a total volume under 0.5cc. Characterization of the integrated microphones is described in detail, including measurements of sensitivity, noise floor and directivity. A displacement resolution of 3.5x10⁻¹³ m/√Hz was measured between 4kHz and 16kHz in an anechoic test chamber, corresponding to a dynamic range of 115dB for the optical detection architecture. The total noise SPL of the device is 35.9dBA. Unlike capacitive microphones with similar noise levels, the device developed in this work exhibits first order dipole directivity patterns between 250Hz-1kHz, with an ideal Directivity Index of 4.8dB @ 1kHz and directional attenuation exceeding 25dB. With these results the optoelectronic package presented in this work demonstrates the viability of the integrated optical biomimetic microphones in compact, low power applications, specifically directional hearing aids.

Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 126-147). Available also in a digital version from Dissertation Abstracts.

published_or_final_version / abstract / Electrical and Electronic Engineering / Doctoral / Doctor of Philosophy

Broadband light emitters operation, which covers multiple wavelengths of the electromagnetic spectrum, has been established as an indispensable element to the human kind, continuously advancing the living standard by serving as sources in important multi-disciplinary field applications such as biomedical imaging and sensing, general lighting and internet and mobile phone connectivity. In general, most commercial broadband light sources relies on complex systems for broadband light generation which are bulky, and energy hungry. Recent demonstration of ultra-broadband emission from semiconductor light sources in the form of superluminescent light emitting diodes (SLDs) has paved way in realization of broadband emitters on a completely novel platform, which offered compactness, cost effectiveness, and comparatively energy efficient, and are already serving as a key component in medical imaging systems. The low power-bandwidth product is inherent in SLDs operating in the amplified spontaneous emission regime. A quantum leap in the advancement of broadband emitters, in which high power and large bandwidth (in tens of nm) are in demand. Recently, the birth of a new class of broadband semiconductor laser diode (LDs) producing multiple wavelength light in stimulated emission regime was demonstrated. This very recent manifestation of a high power-bandwidth-product semiconductor broadband LDs relies on interband optical transitions via quantum confined dot/dash nanostructures and exploiting the natural inhomogeneity of the self-assembled growth technology. This concept is highly interesting and extending the broad spectrum of stimulated emission by novel device design forms the central focus of this dissertation. In this work, a simple rate equation numerical technique for modeling InAs/InP quantum dash laser incorporating the properties of inhomogeneous broadening effect on lasing spectra was developed and discussed, followed by a comprehensive experimental analysis of a novel epitaxial structure design. The layered structure is based on chirping the barrier layer thickness of the over grown quantum dash layer, in a multi-stack quantum dash/barrier active region, with the aim of inducing additional inhomogeneity. Based on material-structure and device characterization, enhanced lasing-emission bandwidth is achieved from the narrow (2 u m)ridge-waveguide LDs as a result of the formation of multiple ensembles of quantum dashes that are electronically different, in addition to improved device performance. Moreover, realization of SLDs from this device structure demonstrated extra-ordinary emission bandwidth covering the entire international telecommunication union (O- to U-) bands. This accomplishment is a collective emission from quantum wells and quantum dashes of the device active region. All these results lead to a step forward in the eventual realization of more than 150 nm lasing bandwidth from a single semiconductor laser diode.

Numerical analysis of the electromagnetic fields in large, complex structures is very challenging due to the high computational overhead. Recently, it has been shown that a new method called Trefftz-FLAME ( Flexible Local Approximation MEthod) is suitable for problems where there exist a large number of similar structures. / This thesis develops Trefftz-FLAME in two areas. First, a novel 2D Trefftz-FLAME method incorporates the modal analysis and port boundary condition that are essential to an accurate calculation of reflection and transmission coefficients for photonic crystal devices. The new technique outperforms existing methods in both accuracy and computational cost. / The second area pertains to the 3D, vector problem of electromagnetic wave scattering by aggregates of identical dielectric particles. A methodology for the development of local basis functions is introduced, applicable to particles of any shape and composition. Boundary conditions on the surface of the finite FLAME domain are described, capable of representing the incident wave and absorbing the outgoing radiation. A series of problems involving dielectric spheres is solved to validate the new method. Comparison with exact solutions is possible in some cases and shows that the method is able to produce accurate near-field results even when the computational grid spacing is equal to the radius of the spheres.

No description available.

The evolving needs of network carriers are changing the design of optical networks. In order to reduce cost, latency, and power consumption, electrical switches are being replaced with optical switching fabrics at the core of the networks. An example of such a network is an Agile All-Photonic Network (AAPN). / This thesis presents a novel device that was designed to operate as an optical switch within the context of an AAPN network. The device is a Reprogrammable Optical Phase Array (ROPA), and the design consists of applying multiple electric fields of different magnitudes across an electro-optic material in order to create a diffractive optical element. The configuration of the electric fields can change to modify the properties of the diffractive device. / Such a device has a wide range of potential applications, and two different ROPA designs are presented. Both designs are optimized to function as 1xN optical switches. The switches are wavelength tunable and have switching times on the order of microseconds. The ROPA devices consist of two parts: a bulk electro-optic crystal, and a high-voltage CMOS chip for the electrical control of the device. The design, simulation, fabrication and testing of both the electrical and optical components of the devices are presented.