Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / As cerâmicas piesoelétricas estudadas neste trabalho (Pb1,03Zr0,53Ti0,47O3, Pb1,03Zr0,525Nb0,05Ti0,465Fe0,005O3, Pb1,03Zr0,515Nb0,015Ti0,465Fe0,005O3, Pb1,03Zr0,525Nb0,005Ti0,455Fe0,015O3 e Pb1,03Zr0,515Nb0,015Ti0,455Fe0,015O3) foram sinterizadas a 1200oC e 1250oC por 3,5 h a fim de que suas propriedades piesoelétricas fossem investigadas. Nas composições dos PZT obtidas, a matriz e os dopantes empregaram óxidos como matérias primas. As misturas dos óxidos precursores foram calcinadas a 850oC por 3,5 h para obtenção da fase PZT. Os precursores, os pós e os corpos de prova de PZT foram caracterizados quanto às microestruturas, densidades e propriedades físicas. Após a conformação dos pós e a sinterização, os materiais cerâmicos foram polarizados para caracterização de suas propriedades piesoelétricas através de um impedancímetro na faixa de freqüência de 100 KHz a 200 KHz. Os resultados de dispersão de laser dos precursores revelaram aglomeração do óxido de chumbo e óxido de zircônio. As composições calcinadas apresentaram tamanho de partícula na faixa de 0,44 μm a 0,63 μm. As análises de densidade por método de Arquimedes indicaram uma boa densificação dos corpos de prova sinterizados e pouca influência da temperatura de sinterização com uma escala de valores de 95,73 a 97,65% da densidade teórica. As análises de microscopia eletrônica de varredura revelaram que os sinterizados contendo concentrações diferentes de dopantes exibem uma correlação do tipo e teor de dopante com a natureza da fratura, sendo transgranular, quando dopante ferro for predominante e intergranular, quando o dopante Nb for predominante. Também, o aumento da temperatura de sinterização resultou em fratura transgranular independente do tipo e da concentração de dopante, exceto para baixo teor de dopante da composição equimolar, cujos resultados não foram consistentes com a literatura sobre o material. No que diz respeito às propriedades piesoelétricas, revelou-se que a combinação da variação da composição com a temperatura foi favorável para o aumento dos valores da constante dielétrica da formulação equimolar com maior percentual de dopantes. Já o efeito da temperatura com a composição surtiu um efeito muito negativo para os valores de fator de qualidade mecânica da formulação dopada com mais ferro. Para os valores de constante de freqüência da formulação com maior percentagem de nióbio, o efeito da temperatura com a composição gerou um efeito positivo. / The piezoelectric ceramics studied in this work, Pb1.03Zr0.53Ti0.47O3, Pb1.03Zr0.525Nb0.05Ti0.465Fe0.005O3, Pb1.03Zr0.515Nb0.015Ti0.465Fe0.005O3, Pb1.03Zr0.525Nb0.005Ti0.455Fe0.015O3 and Pb1.03Zr0.515Nb0.015Ti0.455Fe0.015O3, were all of them sintered between 1200oC and 1250oC for 3.5h. After that, their piezoelectric properties were investigated. In the present work, oxides were used as raw material in both, matrices and dopants. The mixture of the precursor oxides were calcinaned at 850oC during 3.5h for obtaining the PZT phase. The precursor oxides, the powders and the PZT samples went through characterization tests in order to have their microstructures, densities and physical properties correctly determined. After the powders had been conformed and performed the sinterization process, the PZT ceramics were polarized and their piezoelectric properties determined by using an impedancemeter working in the frequency from 100 KHz to 200 KHz. The obtained results from laser dispersion had revealed agglomeration of lead and zirconium oxide. The calcined samples presented particle sizes from 0.44 μm to 0.63 μm. The density analyses using the Archimedes method indicated a good densification of the sintered samples and a weak influence of the sintering temperature on the obtained density values, whose values ranged from 95.73 to 97.65 % of the theoretical density value. Analysis performed using the scanning electron microscopy technique (MEV) revealed that the sintered samples had showed a correlation between the type and concentration of the dopant with their fracture mode, which were transgranular when Fe prevails over the Nb as dopant, and intergranular, when is the Nb that prevails over the Fe as dopant. By the other side, from increasing the sintering temperature resulted transgranular fractures, independently of which type and content of dopant had been used, except for the equimolar case with relatively low content of dopant, whose results were not consistent with the literature related to this material. About the piezoelectric properties, the results had showed that the combination of the dopant composition with the sintering temperature had brought better values of dielectric constant for the equimolar formulation with more content of dopant. Relating to the mechanical quality factor, from the combination of the dopant composition with the sintering temperature had decreased the factor when Fe prevails over Nb and increased the frequency factor when is the Nb that prevails over the Fe.

The work presented in this thesis investigates novel transducer implementations that take advantage of directional sensing and generation of acoustic waves. These transducers are conceived by exploiting a Fourier-based design methodology. The proposed devices find application in the broad field of Structural Health Monitoring (SHM), which is a very active research area devoted to the assessment of the structural integrity of critical components in aerospace, civil and mechanical systems. Among SHM schemes, Guided Waves (GWs) testing has emerged as a prominent option for inspection of plate-like structures using permanently attached piezoelectric transducers. GWs-based methods rely on the generation and sensing of elastic waves to evaluate structural integrity. They offer an effective method to estimate location, severity and type of damage. It is widely acknowledged among the GWs-SHM community that effective monitoring of structural health is facilitated by sensors and actuators designed with ad hoc engineered capabilities. The objective of this research is to design innovative piezoelectric transducers by specifying their electrode patterns in the Fourier domain. Taking advantage of the Fourier framework, transducer design procedures are outlined and tailored to relevant SHM applications, such as (i) directional actuation and sensing of GWs, (ii) simultaneous sensing of multiple strain components with a single device, and (iii) estimation of the location of impact sites on structural components. The proposed devices enable significant reductions in cost, hardware, and power requirements for advanced SHM schemes when compared to current technologies.

Novel technology which can provide new solutions and enable augmented capabilities to CMOS based technology is highly desired. Piezotronic nanodevices and integrated systems exhibit potential in achieving these application goals. By combining laser interference lithography and low temperature hydrothermal method, an effective approach for ordered growth of vertically aligned ZnO NWs array with high-throughput and low-cost at wafer-scale has been developed, without using catalyst and with a superior control over orientation, location/density and morphology of as-synthesized ZnO NWs. Beyond the materials synthesis, by utilizing the gating effect produced by the piezopotential in a ZnO NW under externally applied deformation, strain-gated transistors (SGTs) and universal logic operations such as NAND, NOR, XOR gates have been demonstrated for performing piezotronic logic operations for the first time. In addition, the first piezoelectrically-modulated resistive switching device based on piezotronic ZnO NWs has also been presented, through which the write/read access of the memory cell is programmed via electromechanical modulation and the logic levels of the strain applied on the memory cell can be recorded and read out for the first time. Furthermore, the first and by far the largest 3D array integration of vertical NW piezotronic transistors circuitry as active pixel-addressable pressure-sensor matrix for tactile imaging has been demonstrated, paving innovative routes towards industrial-scale integration of NW piezotronic devices for sensing, micro/nano-systems and human-electronics interfacing. The presented concepts and results in this thesis exhibit the potential for implementing novel nanoelectromechanical devices and integrating with MEMS/NEMS technology to achieve augmented functionalities to state-of-the-art CMOS technology such as active interfacing between machines and human/ambient as well as micro/nano-systems capable of intelligent and self-sufficient multi-dimensional operations.

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Hybrid energy harvesting is a concept applied for improving the performance of the conventional stand-alone energy harvesters. The thesis presents the analytical formulations and characterization of a hybrid energy harvester that incorporates photovoltaic, piezoelectric, electromagnetic, and electrostatic mechanisms. The initial voltage required for electrostatic mechanism is obtained by the photovoltaic technique. Other mechanisms are embedded into a bimorph piezoelectric cantilever beam having a tip magnet and two sets of comb electrodes on two sides of its substructure. All the segments are interconnected by an electric circuit to generate combined output when subjected to vibration and solar illumination. Results for power output have been obtained at resonance frequency using an optimum load resistance. As the power transduced by each of the mechanisms is combined, more power is generated than those obtained by stand-alone mechanisms. The synergistic feature of this research is further promoted by adding fatigue analysis using finite element method.

Le coefficient de couplage électromécanique (CCEM) est un paramètre essentiel pour la description des matériaux piézoélectriques, il traduit la conversion d’énergie électrique en énergie mécanique et vice versa. Ce coefficient de couplage est étudié et déterminé dans le cadre de cette thèse pour des céramiques piézoélectriques. Ces dernières sont utilisées pour trois structures différentes ; la première structure étudiée est constituée d’une poutre longue et mince avec des petits patchs collés symétriquement sur les deux faces de la poutre en Aluminium, la seconde structure se compose d’une poutre courte et épaisse avec deux grands patchs. La dernière structure étudiée est une plaque composite multicouche du type aéronautique avec un seul grand patch. Ces trois structures ont été étudiées afin de déterminer le coefficient de couplage électromécanique effectif qui est considéré comme un indicateur de performance de l’amortissement passif shunté. Ce coefficient de couplage a été évalué de différentes manières en utilisant différents paramètres dont les conditions limites électriques, les propriétés élastiques des patchs, les propriétés modales de la poutre seule ainsi que les facteurs de couplages piézoélectriques. Une première étude expérimentale a été menée sur la poutre longue pour deux types de configurations en court circuit et circuit ouvert pour identifier ses propriétés modales. La poutre longue a été simulée pour deux types de polarisations, identiques et opposées, et simulée dans les deux codes Ansys® et Abaqus®. L’influence de la condition d’équipotentielle sur le coefficient de couplage a été étudiée. Une seconde campagne expérimentale et numérique sur une autre structure a été nécessaire pour valider les résultats obtenus. Pour pouvoir atteindre cet objectif, il était nécessaire de travailler sur une structure plus courte et plus rigide. Ainsi, la poutre courte a été simulée dans Ansys® et les résultats obtenus ont confirmé la nécessité de prendre en compte l’équipotentialité sur les faces des patchs. Cette condition a pour effet de réduire le couplage électromécanique et parfois de découpler certains modes. L’écart résultant de la corrélation expérimentale / numérique des deux poutres instrumentées a incité à recaler les modèles numériques. Ce recalage peut se présenter sous trois formes : mécanique en remplaçant l’encastrement par des ressorts linéaires, électrique en remplaçant les capacités fournies par le fabricant par les valeurs mesurées expérimentalement et électromécanique en utilisant les deux recalages précédents simultanément. Les deux poutres ont ensuite été simulées en déformations planes et contraintes planes et recalées afin d’approcher les résultats expérimentaux. L’étude de ces deux structures a permis de confronter les différentes méthodes d’évaluation du CCEM effectif, d’évaluer l’influence de l’équipotentialité sur les faces des électrodes et de comparer les simulations bidimensionnelles aux tridimensionnelles. Une plaque composite multicouche du type aéronautique a été ensuite étudiée pour généraliser la méthode d’évaluation du CCEM effectif pour les structures minces composites. La plaque seule a d’abord été simulée dans Ansys® pour valider le modèle numérique. Des tests sur la structure adaptative ont ensuite été menés pour l’évaluation du CCEM expérimental. La position choisie du patch a été déterminée par une analyse de l’énergie de déformation de la plaque seule pour les modes d’intérêt. Cette méthode de placement du patch s’est avérée efficace dans le sens où elle a conduit à des CCEM effectifs élevés pour certains modes de la bande de fréquence retenue. / The electromechanical coupling coefficient (EMCC) is an important parameter for the description of piezoelectric materials; it measures the conversion of electrical energy into mechanical one and vice versa. The coupling coefficient is studied and determined in this dissertation for piezoelectric ceramics. The latter are used for different structures: the first studied one is a long and thin Aluminium beam with small patches bonded symmetrically on its faces, the second one is a short and thick Aluminium beam with symmetrically bonded two large patches, and the third structure is considered more complex because it is an aeronautic-type multilayer composite plate with a single large patch. These three structures were studied to determine the electromechanical coupling coefficient which is considered as a performance indicator for passive shunted damping. The coupling coefficient was evaluated in different ways using different parameters, including the electrical boundary conditions, the elastic properties of the patches, the modal properties of the base beam and the piezoelectric coupling factor. A first experimental study was conducted on the long beam for two configurations, short circuit and open circuit, to identify its modal properties. The long beam was simulated for two configurations of polarization, same and opposite, in Ansys® and Abaqus® commercial codes. The equipotential condition influence on the coupling coefficient has been studied. A second experimental and numerical campaign for a different structure was necessary to validate the obtained results. For this purpose, it was necessary to work on a shorter and more stiff structure. Thus, the short beam was simulated in Ansys® which results have confirmed the necessity to consider the equipotentiality of the patches faces. This condition was found to reduce the electromechanical coupling and to uncouple some modes. The difference between experimental and numerical results of both adaptive structures was reduced by updating the numerical models. This updating is made in three ways: mechanically, by replacing the theoretical clamp conditions by linear springs, electrically, by replacing the capacities provided by the supplier by the experimental measured values, and electromechanically by considering previous updatings simultaneously. Both beams were simulated in 2D plane-strain and plane-stress and updated in order to approximate the experimental results. The study of these two structures allowed to assess different methods for the evaluation of the EMCC, to evaluate the influence of the equipotentiality constraints on the electroded faces, and to compare two-dimensional simulations to three-dimensional ones. Finally, an aeronautic-type multilayer plate composite has been studied in order to generalize the evaluation method of the EMCC for thin composite structures. The base plate was first simulated in Ansys® in order to validate the numerical model, then tests of the adaptive plate were conducted in order to evaluate the experimental EMCC. The selected position of the patch results from a strain energy analysis of the base plate for the mode of interest. The patch placement method was efficient in the sense that it provided high EMCC for some modes in the retained frequency range.

För att nå utsatta klimatmål i Sverige och på EU-nivå är begränsningen av fossil fordonstrafik en hörnsten. Lösningen kan vara eldrift, men dilemmat vid långa transporter är påfyllnad av drivmedel. Utmaningen blir att tillgodose den ökade efterfrågan på energi – både gällande distribution och produktion – på ett miljömässigt försvarbart sätt. En litteraturstudie samt en intervju utförs för att undersöka om vägar kan göras smartare för att främja en grönare, eldriven fordonstrafik och ge möjlighet för energiutvinning i vägområdet samt elektrisk energidistribution till fordon under färd. Teknologin till energidistribution och energiutvinningssystem finns, men den kan alltid utvecklas för billigare tillverkning och effektivare produkter. Studerade energidistribueringssystem är induktion och konduktion. Energiutvinningssystemen som har behandlats är solenergi, piezoelektricitet och vindkraft. Pilotprojekt inom de bägge områdena existerar och fler projekt är under utveckling. / Sweden and the EU has a lot of climate goals, to achieve these goals the use of fossil fuels must be reduced. One solution can be electric powered vehicles, when travelling long distances there is a problem to replenish fuel. The challenge is to meet the increased demand for energy - both in terms of production and distribution - in an environmentally sound manner. A literature study as well as an interview is carried out to investigate whether roads can be made smarter to promote a greener, electric vehicle traffic and the possibility of energy harvesting systems and energy distribution in the road area. The technology for energy harvesting systems and energy distribution is available, but it can always be further developed for cheaper manufacturing and more efficient products. Energy distribution systems studied are induction and conduction. The energy harvesting systems in this report are solar energy, piezoelectricity and wind power. Pilot projects in both areas exists and more projects are under development.

O estudo das vibrações é importante para prevenir danos em equipamentos ou mesmo evitar catástrofes de grande natureza. Nesse sentido, aproveitar a energia que seria dissipada na vibração e contribuir no controle do sistema representa um grande avanço tecnológico. O termo Energy Harvesting (Colheita de Energia) está relacionado ao contexto do aproveitamento energético, utilizando sistema de conversão para transformação da energia em eletricidade. Através de um dispositivo com viga engastada e massa inercial na extremidade, é possível realizar o estudo de vibração e coleta de energia, ao se considerar uma estrutura piezelétrica acoplada na viga e conectada a um circuito elétrico com resistor. Estruturas inteligentes que atuam na conversão de energia mecânica em elétrica, ou vice-versa, são fundamentais para esse estudo, o que motiva a inclusão dos sensores piezelétricos no projeto de dispositivos estudados e sujeitos a vibrações. Por outro lado, otimizar parâmetros de projeto é fundamental para aumentar a amplitude de vibração e tornar o processo com maior desempenho, tendo em vista maior captação de energia. Ainda, parâmetros otimizados podem estar sujeitos a incertezas do projeto e variações, devido a flutuações ambientais, como temperatura, pressão, propriedades dos materiais, geometria, etc. Por isso, técnicas robustas que tornem os projetos menos sensíveis a variações são interessantes para serem abordadas. Embora métodos de projetos robustos sejam eficientes, poucas pesquisas têm sido feitas na área da dinâmica de vibrações e alguns processos podem demandar tempo computacional dependendo do estudo ou projeto. Este trabalho tem como propósito abordar um método específico de projeto robusto focado em uma metodologia com matrizes chamadas ortogonais. Além disso, o método determinístico via algoritmo de Programação Sequencial Quadrático (SQP) é utilizado. O trabalho consiste numa abordagem para coleta de energia em um modelo de viga engastada, otimizando parâmetros e inserindo incertezas no sistema para análise de robustez e verificação de comprimentos adequados de vigas para os dispositivos. Os resultados mostram um aumento da energia coletada, analisando funções de resposta em frequências para saída de potência, diante de uma entrada de deslocamento no engaste do dispositivo, projetado via otimização determinística, além de aumento de robustez de acordo com certos critérios considerando circuito elétrico com resistência corretamente selecionada. / The study of vibrations is important to prevent damage to equipment or even prevent major catastrophes. In this sense harvesting the energy that would otherwise be dissipated in vibration and contributing to the control of the system represents a great technological advance. The term Energy Harvesting is related to the context of energy use, using a conversion system to transform energy into electricity. Through a device with clamped beam and inertial mass at the end, it is possible to study the vibration and energy harvesting, considering a piezoelectric structure coupled to the beam and connected to a resistance electric circuit. Smart structures that act in the conversion of mechanical energy to electrical energy, or vice versa, are fundamental for this study, which motivates the inclusion of piezoelectric sensors in the design of studied devices and subject to vibrations. On the other hand, optimizing design parameters is fundamental to increase the amplitude of vibration and increase process performance, in view of greater power uptake. Furthermore, optimized parameters may be subject to design uncertainties and variations due to environmental fluctuations such as temperature, pressure, material properties, geometry, etc. Therefore, robust techniques that make designs less sensitive to variations are interesting to be addressed. Although robust design methods are efficient, few researches have been done in the area of vibration dynamics and some processes may require computational time depending on the study or project. This work aims to address a specific method of robust design focused on a methodology with matrices called orthogonal. In addition, the deterministic method using Sequential Quadratic Programming (SQP) algorithm is used. The work consists of an approach to harvest energy in a clamped beam model, optimizing parameters and inserting uncertainties in the system for robustness analysis and verification of adequate beam lengths for the devices. The results show an increase in the harvested energy, analyzing frequency response functions for power output, in the face of a displacement input in the device clamp, designed through deterministic optimization,besides increasing robustness according to certain criteria considering electric circuit with correctly selected resistance.