- About
-
The Global ETD Search service is a free service for researchers
to find electronic theses and dissertations. This service is
provided by the
Networked Digital Library of Theses and Dissertations.
Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
Search results
Showing 1 to 10 of 11 (0.016 seconds)| 1 |
Engineering water dissociation sites in MoS2 nanosheets for accelerated electrocatalytic hydrogen productionFeng, Xinliang, Zhang, Jian, Wang, Tao, Liu, Pan, Liu, Shaohua, Dong, Renhao, Zhuang, Xiaodong, Chen, Mingwei 21 July 2017 (has links) (PDF)
Earth-abundant MoS2 is widely reported as a promising HER electrocatalyst in acidic solutions, but it exhibits extremely poor HER activities in alkaline media due to the slow water dissociation process. Here we present a combined theoretical and experimental approach to improve the sluggish HER kinetics of MoS2 electrocatalysts through engineering the water dissociation sites by doping Ni atoms into MoS2 nanosheets. The Ni sites thus introduced can effectively reduce the kinetic energy barrier of the initial water-dissociation step and facilitate the desorption of the −OH that are formed. As a result, the developed Ni-doped MoS2 nanosheets (Ni-MoS2) show an extremely low HER overpotential of ∼98 mV at 10 mA cm−2 in 1 M KOH aqueous solution, which is superior to those (>220 mV at 10 mA cm−2) of reported MoS2 electrocatalysts.
|
| 2 |
Zinc(II) Adsorption by Low-Carbon Shungite: The Effect of pHFischer, Axel R., Sgolik, Luisa, Kreller, André, Dornack, Christina 11 June 2018 (has links) (PDF)
Shungite is a carbonaceous rock which is abundant in Karelia (Russian Federation). Large deposits of shungite with low levels of carbon (approx. 10% C) are also found in Kazakhstan, where it is mined under the trade name Taurit (Koksu Mining Company). Although Taurit has been reported to be used as an adsorbent for hazardous compounds in water treatment, there is very little precise data about its adsorption capacity or the compounds adsorbed. In this study, the ability of Taurit to adsorb Zn(II) was investigated and Freundlich isotherms were determined for both distilled water and tap water. Taurit was found to have a high buffer capacity leading to pH values > 7.0 in aqueous solution. Because dissolved zinc precipitates as Zn(OH)2 under alkaline conditions, the pH must be carefully controlled and kept ≤7.0. Despite the small inner surface area (BET) of Taurit (13.4 m2 g−1), Freundlich coefficients for distilled water (Kf = 2.4, n = 4.0) and tap water (Kf = 1.5, n = 2.5) were similar to other adsorbents. Our results indicate that Taurit could provide a cheap alternative to activated carbon since both substances have a similar adsorption capacity (at least for Zn(II)).
|
| 3 |
Combining Partial Least Squares and the Gradient-Boosting Method for Soil Property Retrieval Using Visible Near-Infrared Shortwave Infrared SpectraLiu, Lanfa, Ji, Min, Buchroithner, Manfred F. 06 June 2018 (has links) (PDF)
Soil spectroscopy has experienced a tremendous increase in soil property characterisation, and can be used not only in the laboratory but also from the space (imaging spectroscopy). Partial least squares (PLS) regression is one of the most common approaches for the calibration of soil properties using soil spectra. Besides functioning as a calibration method, PLS can also be used as a dimension reduction tool, which has scarcely been studied in soil spectroscopy. PLS components retained from high-dimensional spectral data can further be explored with the gradient-boosted decision tree (GBDT) method. Three soil sample categories were extracted from the Land Use/Land Cover Area Frame Survey (LUCAS) soil library according to the type of land cover (woodland, grassland, and cropland). First, PLS regression and GBDT were separately applied to build the spectroscopic models for soil organic carbon (OC), total nitrogen content (N), and clay for each soil category. Then, PLS-derived components were used as input variables for the GBDT model. The results demonstrate that the combined PLS-GBDT approach has better performance than PLS or GBDT alone. The relative important variables for soil property estimation revealed by the proposed method demonstrated that the PLS method is a useful dimension reduction tool for soil spectra to retain target-related information.
|
| 4 |
Tuning the Sensitivity of the PDR5 Promoter-Based Detection of Diclofenac in Yeast BiosensorsSchuller, Astrid, Rödel, Gerhard, Ostermann, Kai 15 November 2017 (has links) (PDF)
The commonly used drug diclofenac is an important environmental anthropogenic pollutant. Currently, detection of diclofenac is mainly based on chemical and physical methods. Here we describe a yeast biosensor that drives the diclofenac-dependent expression of a recombinant fluorescent protein from the authentic promoter of the PDR5 gene. This key component of the pleiotropic drug response encodes a multidrug transporter that is involved in cellular detoxification. We analyse the effects on diclofenac sensitivity of artificial PDR5 promoter derivatives in wild-type and various yeast mutant strains. This approach enabled us to generate sensor strains with elevated drug sensitivity.
|
| 5 |
Quantitative Retrieval of Organic Soil Properties from Visible Near-Infrared Shortwave Infrared (Vis-NIR-SWIR) Spectroscopy Using Fractal-Based Feature Extraction.Liu, Lanfa, Buchroithner, Manfred, Ji, Min, Dong, Yunyun, Zhang, Rongchung 27 March 2017 (has links) (PDF)
Visible and near-infrared diffuse reflectance spectroscopy has been demonstrated to be a fast and cheap tool for estimating a large number of chemical and physical soil properties, and effective features extracted from spectra are crucial to correlating with these properties. We adopt a novel methodology for feature extraction of soil spectroscopy based on fractal geometry. The spectrum can be divided into multiple segments with different step–window pairs. For each segmented spectral curve, the fractal dimension value was calculated using variation estimators with power indices 0.5, 1.0 and 2.0. Thus, the fractal feature can be generated by multiplying the fractal dimension value with spectral energy. To assess and compare the performance of new generated features, we took advantage of organic soil samples from the large-scale European Land Use/Land Cover Area Frame Survey (LUCAS). Gradient-boosting regression models built using XGBoost library with soil spectral library were developed to estimate N, pH and soil organic carbon (SOC) contents. Features generated by a variogram estimator performed better than two other estimators and the principal component analysis (PCA). The estimation results for SOC were coefficient of determination (R2) = 0.85, root mean square error (RMSE) = 56.7 g/kg, the ratio of percent deviation (RPD) = 2.59; for pH: R2 = 0.82, RMSE = 0.49 g/kg, RPD = 2.31; and for N: R2 = 0.77, RMSE = 3.01 g/kg, RPD = 2.09. Even better results could be achieved when fractal features were combined with PCA components. Fractal features generated by the proposed method can improve estimation accuracies of soil properties and simultaneously maintain the original spectral curve shape.
|
| 6 |
Assessment of Managed Aquifer Recharge through Modeling—A ReviewRingleb, Jana, Stefan, Catalin, Sallwey, Jana 28 March 2017 (has links) (PDF)
Managed aquifer recharge (MAR) is the purposeful recharge of an aquifer for later recovery or environmental benefits and represents a valuable method for sustainable water resources management. Models can be helpful tools for the assessment of MAR systems. This review encompasses a survey and an analysis of case studies which apply flow and transport models to evaluate MAR. The observed modeling objectives include the planning or optimization of MAR schemes as well as the identification and quantification of geochemical processes during injection, storage and recovery. The water recovery efficiency and the impact of the injected water on the ambient groundwater are further objectives investigated in the reviewed studies. These objectives are mainly solved by using groundwater flow models. Unsaturated flow models, solute transport models, reactive geochemical models as well as water balance models are also frequently applied and often coupled. As each planning step to setup a new MAR facility requires cost and time investment, modeling is used to minimize hazard risks and assess possible constraints of the system such as low recovery efficiency, clogging and geochemical processes.
|
| 7 |
Soil Chemical and Microbial Properties in a Mixed Stand of Spruce and Birch in the Ore Mountains (Germany) - A Case StudySchua, Karoline, Wende, Stefan, Wagner, Sven, Feger, Karl-Heinz 27 July 2015 (has links) (PDF)
A major argument for incorporating deciduous tree species in coniferous forest stands is their role in the amelioration and stabilisation of biogeochemical cycles. Current forest management strategies in central Europe aim to increase the area of mixed stands. In order to formulate statements about the ecological effects of mixtures, studies at the stand level are necessary. In a mixed stand of Norway spruce (Picea abies (L.) Karst.) and silver birch (Betula pendula Roth) in the Ore Mountains (Saxony, Germany), the effects of these two tree species on chemical and microbial parameters in the topsoil were studied at one site in the form of a case study. Samples were taken from the O layer and A horizon in areas of the stand influenced by either birch, spruce or a mixture of birch and spruce. The microbial biomass, basal respiration, metabolic quotient, pH-value and the C and N contents and stocks were analysed in the horizons Of, Oh and A. Significantly higher contents of microbial N were observed in the Of and Oh horizons in the birch and in the spruce-birch strata than in the stratum containing only spruce. The same was found with respect to pH-values in the Of horizon and basal respiration in the Oh horizon. Compared to the spruce stratum, in the birch and spruce-birch strata, significantly lower values were found for the contents of organic C and total N in the A horizon. The findings of the case study indicated that single birch trees have significant effects on the chemical and microbial topsoil properties in spruce-dominated stands. Therefore, the admixture of birch in spruce stands may distinctly affect nutrient cycling and may also be relevant for soil carbon sequestration. Further studies of these functional aspects are recommended.
|
| 8 |
Contribution of Small-Scale Gum and Resin Commercialization to Local Livelihood and Rural Economic Development in the Drylands of Eastern AfricaAbtew, Asmamaw Alemu, Pretzsch, Jürgen, Secco, Laura, Mohamod, Tarig Elshikh 21 July 2014 (has links) (PDF)
This paper examines the extent to which the economic gains derived from gum and resin commercialization impact rural livelihood improvement under different resource management regimes in the drylands of Ethiopia and Sudan. Primary data were collected through semi-structured interviews with 240 randomly selected small-scale producers in four regions with gradients of resource management regimes. The survey was supplemented by secondary data, group discussions and key informant interviews. In the four regions, gum and resin income contributes to 14%–23% of the small-scale producers’ household income. Absolute income was positively correlated with resource management regime and commercialization level. It was higher from cultivated resources on private lands, followed by regulated access to wild resources. In open-access resources, the producers’ income was the lowest, although accessed by the poor and women. However, dependence on gum and resin was higher in open-access resource areas. Households’ socioeconomic characteristics, resource access, production and marketing variables determining income from gum and resin were identified and their variation across the cases is discussed. Overall, gum and resin commercialization in the study areas play a potential poverty alleviation role as a source of regular income, a safety net, and a means of helping producers move out of poverty.
|
| 9 |
Temporal Stability of GPS Transmitter Group Delay VariationsBeer, Susanne, Wanninger, Lambert 12 June 2018 (has links) (PDF)
The code observable of global navigation satellite systems (GNSS) is influenced by group delay variations (GDV) of transmitter and receiver antennas. For the Global Positioning System (GPS), the variations can sum up to 1 m in the ionosphere-free linear combination and thus can significantly affect precise code applications. The contribution of the GPS transmitters can amount to 0.8 m peak-to-peak over the entire nadir angle range. To verify the assumption of their time-invariance, we determined daily individual satellite GDV for GPS transmitter antennas over a period of more than two years. Dual-frequency observations of globally distributed reference stations and their multipath combination form the basis for our analysis. The resulting GPS GDV are stable on the level of a few centimeters for C1, P2, and for the ionosphere-free linear combination. Our study reveals that the inconsistencies of the GDV of space vehicle number (SVN) 55 with respect to earlier studies are not caused by temporal instabilities, but are rather related to receiver properties.
|
| 10 |
Relative contribution of land use change and climate variability on discharge of upper Mara River, KenyaMwangi, Hosea M., Julich, Stefan, Patil, Sopan D., McDonald, Morag A., Feger, Karl-Heinz 27 July 2017 (has links) (PDF)
Study region
Nyangores River watershed, headwater catchment of Mara River basin in Kenya.
Study focus
Climate variability and human activities are the main drivers of change of watershed hydrology. The contribution of climate variability and land use change to change in streamflow of Nyangores River, was investigated. Mann Kendall and sequential Mann Kendall tests were used to investigate the presence and breakpoint of a trend in discharge data (1965–2007) respectively. The Budyko framework was used to separate the respective contribution of drivers to change in discharge. Future response of the watershed to climate change was predicted using the runoff sensitivity equation developed.
New hydrological insights for the region
There was a significant increasing trend in the discharge with a breakpoint in 1977. Land use change was found to be the main driver of change in discharge accounting for 97.5% of the change. Climate variability only caused a net increase of the remaining 2.5% of the change; which was caused by counter impacts on discharge of increase in rainfall (increased discharge by 24%) and increase in potential evapotranspiration (decreased discharge by 21.5%). Climate change was predicted to cause a moderate 16% and 15% increase in streamflow in the next 20 and 50 years respectively. Change in discharge was specifically attributed to deforestation at the headwaters of the watershed.
|
Page generated in 0.4072 seconds