Trigger core 07, is a 53 cm long sediment core that was collected during the Danish-Swedish expedition “Lomonosov Ridge off Greenland 2012” on the slope of the Lomonosov Ridge in the Arctic Ocean at a depth of 2522 m. This part of the world has experienced critical environmental changes during the Quaternary. Ice-sheets have advanced and retreated, and deposited sediments through all the Arctic Ocean. Glacial sediments contain coarser material and are gray, whereas interglacial sediments are brown, because of high amounts of manganese, and consist of fine-grained material.  The aim of this project is to make grain size analysis on TC 07 with the purpose to make an interpretation of the grain size data in relation to glaciation history and paleo-oceanography. For that, a correlation with piston core 07 has been made, and also a correlation between piston core 07 and the Arctic Coring Expedition, ACEX. The results showed that fine-grained material is more abundant in the top brown unit down to 32 cm, suggesting an interglacial period. This is followed by a gray-beige unit that goes down to 49 cm, and consist of coarser material, indicating glacial deposits. This unit can be linked to the Marine Isotope Stage 2, MIS 2, which began approximately 29000 years ago and ended about 14000 years ago / ”Trigger core 07” är en 53 cm lång sedimentkärna som togs upp på ett djup av 2522 m från Lomonosovryggen i Arktisk under en dansk-svensk expedition kallad ”Lomonosov Ridge off Greenland 2012”. Den här delen av världen har genomgått kraftiga klimatförändringar under kvartär. Istäcken har vuxit fram och dragit sig tillbaka och avsatt sediment över hela Arktis. Sediment avsatta under istider, kännetecknas av att vara gråa med mycket grovt material, medan sediment avsatta under mellanistider är bruna, vilket är på grund av de höga halterna av mangan och består av finkornigt material. Målet med denna uppsats är att göra en kornstorleksanalys på sedimentkärnan, med syfte i åtanke på att göra en tolkning av informationen i förhållande till istidshistorik och paleo-oceanografi. För att kunna gå tillväga med det, har en korrelation gjorts mellan kärnan och ”piston core 07”, samt en korrelation mellan ”piston core 07” och ”Arctic Coring Expedition, ACEX”. Resultaten visar en brun enhet rik på finkornigt material ned till 32 cm, vilket är typiskt för mellanistider. Den följs av en grå-beige enhet som sträcker sig ned till 49 cm och består av grovkornigt material vilket tyder på istid. Den här enheten kan kopplas till ”Marine Isotope Stage 2, MIS ”, som varade mellan 14000 och 29000 år sedan.

High levels of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in edible fish in the Baltic Sea have raised health concerns in the Baltic region and the rest of Europe. Thus, there are urgent needs to characterize sources in order to formulate effective mitigation strategies. The aim of this thesis is to contribute to a better understanding of past and present sources of PCDD/Fs in the Baltic Sea environment by exploring chemical fingerprints in sediments, air, and biota. The spatial and temporal patterns of PCDD/F distributions in the Baltic Sea during the 20th century were studied in Swedish coastal and offshore sediment cores. The results showed that PCDD/F levels peaked in 1975 (± 7 years) in coastal and 1991 (± 5 years) in offshore areas. The time trends of PCDD/Fs in the sediment cores also showed that environmental half-lives of these pollutants have been shorter in coastal than in offshore areas (15 ± 5 and 29 ± 14 years, respectively). Consequently, there have been remarkable recoveries in coastal areas, but slower recovery in offshore areas with 81 ± 12% and 38 ± 11% reductions from peak levels, respectively. Source-to-receptor multivariate modeling by Positive Matrix Factorization (PMF) showed that six types of PCDD/F sources are and have been important for the Baltic Sea environment: PCDD/Fs related to i) atmospheric background, ii) thermal processes, iii) manufacture and use of tetra-chlorophenol (TCP) and iv) penta-chlorophenol (PCP), v) industrial use of elementary chlo- rine and the chloralkali-process (Chl), and vi) hexa-CDD sources. The results showed that diffuse sources (i and ii) have consistently contributed >80% of the total amounts in the Southern Baltic Sea. In the Northern Baltic Sea, where the biota is most heavily contaminated, impacts of local sources (TCP, PCP and Chl) have been higher, contributing ca. 50% of total amounts. Among the six sources, only Thermal and chlorophenols (ii-iv) have had major impacts on biota. The impact of thermal sources has, however, been declining as shown from source apportioned time-trend data of PCDD/Fs in Baltic herring. In contrast, impacts of chlorophenol-associated sources generally increased, remained at steady-state or slowly decreased during 1990-2010, suggesting that these sources have substantially contributed to the persistently high levels of PCDD/Fs in Baltic biota. Atmospheric sources of PCDD/Fs for the Baltic region (Northern Europe) were also investigated, and specifically whether the inclusion of parallel measurements of metals in the analysis of air would help back-tracking sources. PCDD/Fs and metals in high-volume air samples from a rural field station near the shore of the central Baltic Sea were measured. The study focused on the winter season and air from the S and E sectors, as these samples showed elevated levels of PCDD/Fs, particularly PCDFs. Several metals were found to correlate significantly with the PCDFs. The wide range of candidate metals as source markers for PCDD/F emissions, and the lack of an up-to-date extensive compilation of source characteristics for metal emission from vari- ous sources, limited the use of the metals as source markers. The study was not able to pin-point primary PCDD/F sources for Baltic air, but it demonstrated a new promising approach for source tracing of air emissions. The best leads for back-tracking primary sources of atmospheric PCDD/Fs in Baltic air were seasonal trends and PCDD/F congener patterns, pointing at non-industrial related thermal sources related to heating. The non-localized natures of the sources raise challenges for managing the emissions and thus societal efforts are required to better control atmospheric emissions of PCDD/Fs. / EcoChange / BalticPOPs

Bedrock islands add variation to the estuarine system that results in deviations from typical unconfined estuarine sediment transport patterns. Limited literature exists regarding the dynamics of seabed morphology, delta formation, sediment divergence patterns, and sedimentary facies classifications of non-fjordic bedrock confined systems. Such knowledge is critical to address coastal management concerns adequately. This research presents insights from the Skeena Estuary, a macrotidal estuary in northwestern Canada with a high fluvial sediment input (21.2-25.5 Mtyr-1). Descriptions on sub-environments, stratification, and sediment accumulation within the Skeena Estuary utilize HydroTrend model outputs of riverine sediment and discharge, Natural Resources Canada radiocarbon-dated sediment cores and grain size samples, and acoustic Doppler current profiler and conductivity-temperature-depth measurements from three field campaigns. Research findings delineate a fragmented delta structure with elongated mudflats and select areas of slope instability. Variations from well-mixed water circulation to lateral stratification, govern the slack tide flow transition and sediment transport pathways within seaward and landward passages of the estuary. Fostering a comprehensive understanding of bedrock confined estuary and delta systems has implications for the assessment of coastal management strategies, the productivity of ecological habitats, and the impacts of climate change within coastal areas. / Graduate

Since 1750, human emissions of greenhouse gases have created a temperature increase, affecting the whole world. Diatoms, single-celled microscopic algae that lives in waters all over the world, have different environmental preferences such as the water depth at which the thrive, salinity, nutrients, pH-values and more. Diatoms also responds quickly to changing circumstances, which makes the suitable as environmental indicators. The purpose of the study is to investigate how the abundance and composition of diatoms has changed during the last 200 years in lake Ensjön, located just south of Norrköping, and to relate those changes both to climate change and known events and environmental factors in the area.  The survey is conducted by subsampling sediment cores from which each diatom sample was prepared in accordance with the scheme of Battarbee (1984). The diatoms in the samples were counted under a microscope and the results were analyzed and related to the Cyclotella-Aulacoseira-Fragilaria-theory (CAF) and documented historical events in the local environment. The result of the analysis shows that the composition and abundance of diatoms has changed during the last 200 years, and that this change is due to both climate change (temperature and precipitation increase) and the land-use history of Ensjön. The cahnges in composition of Aulacoseira spp. and Cyclotella spp., where Aulacoseira spp. is expected to decrease, and Cyclotella spp. is expected to increase with a rising temperature, match the CAF-theory for the most part. The change in composition also coincides with several documented environmental factors in the area, especially the change in use of fertilizers and herbicides in agriculture. / Människans utsläpp av växthusgaser har sedan år 1750 skapat en temperaturökning som går allt snabbare, och påverkar hela världen. Kiselalger, encelliga mikroskopiska alger som lever i vatten över hela världen, har olika miljöpreferenser såsom bland annat på vilket vattendjup de trivs, optimal halt av salt, näringsvärden, pH-värden, samt reagerar snabbt på förändrade omständigheter, vilket gör dem lämpliga som miljöindikatorer. Syftet med studien är att studera förändringar i kiselalgernas sammansättning under de senaste 200 åren i den lilla sjön Ensjön belägen något söder om Norrköping och att relatera dessa förändringar till dokumenterade händelser och miljöfaktorer i sjöns avrinningsområde samt till de pågående klimatförändringarna.  Undersökningen är utförd genom provtagning av sedimentkärnor från vilka prover preparerades enligt Battarbees (1984) flödesschema. Proverna av kiselalger räknades under mikroskop och sammansättningen analyserades utifrån teorin Cyclotella-Aulacoseira-Fragilaria (CAF) och kända historiska händelser i närmiljön. Analysresultatet visade att kiselalgssammansättningen har förändrats under de senaste 200 åren, och att denna förändring sannolikt kan kopplas både till klimatförändringar (en ökad temperatur) och Ensjöns markanvändningshistoria. Förändringen hos Aulacoseira spp. och Cyclotella spp. följer till stor del CAF-teorin om att det första släktet skulle minska och det andra skulle öka vid en temperaturökning. Vid flera tillfällen sammanfaller förändringar i kiselalgssammansättningen med kända miljöfaktorer i närmiljön, främst i samband med utvecklingen i användningen av mineralgödsel och växtskyddsmedel.