Made available in DSpace on 2014-12-17T14:55:19Z (GMT). No. of bitstreams: 1 MarinaldoPSN_TESE.pdf: 2731148 bytes, checksum: 7c2caa3355d4d42f0702baf0d147bf97 (MD5) Previous issue date: 2014-04-25 / Universidade Federal do Rio Grande do Norte / Metamaterials have attracted a great attention in recent years mostly due to their electromagnetic properties not found in nature. Since metamaterials began to be synthesized by the insertion of artificially manufactured inclusions in a medium specified host , it provides the researcher a broad collection of independent parameters such as the electromagnetic properties of the material host. In this work was presents an investigation of the unique properties of Split Ring Resonators and compounds metamaterials was performed. We presents a theoretical and numerical analysis , using the full-wave formalism by applying the Transverse Transmission Line - LTT method for the radiation characteristics of a rectangular microstrip antenna using metamaterial substrate, as is successfully demonstrated the practical use of these structures in antennas. We experimentally confirmed that composite metamaterial can improved the performance of the structures considered in this thesis / Os metamateriais tem atra?do uma grande aten??o nas ?ltimas d?cadas, principalmente devido as suas propriedades eletromagn?ticas n?o encontradas na natureza. Desde que os metamateriais passaram a ser sintetizados atrav?s da inser??o de inclus?es artificialmente fabricadas num meio hospedeiro especificado, isto propicia ao pesquisador uma larga cole??o de par?metros independentes, tais como as propriedades eletromagn?ticas do material hospedeiro. Neste trabalho foi realizada uma investiga??o das propriedades ?nicas dos Ressoadores em Anel Partido (Split Ring Ressonators - SRR) e dos metamateriais compostos. Apresentou-se uma an?lise te?rica e num?rico-computacional, utilizando o formalismo de onda completa atrav?s da aplica??o do m?todo da Linha de Transmiss?o Transversa LTT, para as caracter?sticas ressonantes de uma antena de microfita com patch retangular utilizando substrato metamaterial, assim como ? demonstrado com sucesso ? utiliza??o pr?tica dessas estruturas em antenas. Esta utiliza??o pr?tica ? confirmada experimentalmente

Orientadores: Roy Edward Bruns, Isabel Cristina S. F. Jardim / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Quimica / Made available in DSpace on 2018-08-09T16:30:39Z (GMT). No. of bitstreams: 1 Breitkreitz_MarciaCristina_M.pdf: 914312 bytes, checksum: 69f8afa4f7adf7b6e40961bef5aed1ee (MD5) Previous issue date: 2007 / Resumo: Este trabalho teve como objetivo o desenvolvimento de modelos combinados considerando simultaneamente o tipo de Fase Estacionária (FE) como variável de processo e diferentes composições de Fase Móvel (FM) como variáveis de mistura para descrever a influência de cada uma destas variáveis, bem como a interação entre elas, na separação de diversos compostos presentes em duas amostras: uma mistura de compostos neutros e uma mistura de agrotóxicos. Os experimentos necessários para a determinação dos coeficientes dos modelos foram realizados de acordo com um planejamento split-plot, no qual os tipos de FE, C 8 e C 18 foram considerados main-plots e as composições de FM, sub-plots. Os resultados foram tratados de duas maneiras: de acordo com a estrutura split-plot do planejamento e supondo completa aleatorização na realização dos experimentos. Para descrever a qualidade da separação, foi utilizada uma função objetiva e o procedimento de otimização simultânea de várias respostas, descrito por Derringer e Suich, empregando, neste caso, critérios elementares como fator de retenção, resolução e fator de separação como respostas. Os modelos foram avaliados empregando-se Análise da Variância quanto à significância dos tratamentos e falta de ajuste. Na descrição da qualidade da separação dos compostos nas duas misturas, o procedimento de Derringer e Suich se mostrou superior às funções objetivas, pois permitiu a construção de modelos tendo como respostas parâmetros cromatográficos, os quais são, de fato, funções da composição da FM e da FE. Estes modelos, quando combinados através da desejabilidade global, permitiram que as condições para a melhor separação de todos os compostos em cada mistura fossem alcançadas, sem perda de informações sobre a separação individual dos pares de picos. Todos os modelos apresentaram capacidade preditiva para as respostas avaliadas ¿ fatores de retenção/resolução/fatores de retenção relativos - nas duas misturas, sem ou com pequena falta de ajuste. Embora todos os planejamentos tenham sido realizados de acordo com um procedimento split-plot, não foram verificadas diferenças nos valores dos erros dos coeficientes dos modelos matemáticos nos cálculos split-plot e supondo completa aleatorização e isto se deveu ao fato do erro main-plot ter sido muito menor que o erro sub-plot / Abstract: The aim of this work was to develop combined statistical models including the stationary phase (SP) as process variables and different compositions of the mobile phase (MP) as mixture variables in order to describe the influence of each type of variable as well as their interactions for the separation of compounds in two samples sets: one containing ten neutral compounds and another containing eleven pesticides. The experiments required to determine the coefficients of the models were carried out according to a split-plot approach, in which the stationary phases, C 8 or C 18 were considered as main-plots and the mobile phase compositions as sub-plots. The results were treated according to the split-plot approach and also supposing a completely random setup. The results provided by an objective function were compared to those obtained by Derringer¿s desirability functions constructed with simple chromatographic criteria such as resolution and relative retention factors as responses. The models were evaluated by means of Analysis of Variance, regarding regression significance and lack of fit. In order to describe the quality of the separation of the compounds in the two mixtures, the desirability procedure was preferred over the objective functions because the responses used in the latter were, in fact, functions of the stationary and mobile phases. The models combined into a global desirability function allowed the best conditions to the separation of all compounds to be found, without loss of information on the individual peak separation. All models presented predictive capabilities for the responses evaluated with none or little lack of fit. Although the experiments were carried out according to a split-plot approach, no significant differences were found in coefficient errors comparing to the complete random approach, which can be explained based on the low main-plot error / Mestrado / Quimica Analitica / Mestre em Química

A split-phase induction motor (SPIM) is obtained by splitting each of the three-phase stator windings of an induction motor into two equal halves. This results in two sets of three-phase windings with a spatial angle difference of 30◦ (electrical) between them. The two sets of windings are fed from two different voltage-source inverters for speed control of the split-phase motor drive. Low dc bus voltage requirement and improved torque profile are some of the advantages of the split-phase motor, compared to the normal three-phase induction motor. A pulse width modulation (PWM) technique is used to produce the gating signals for the power semiconductor devices in the two inverters. The PWM technique can either be a carrier comparison (CC) based method or a space-vector (SV) based scheme. The carrier based PWM methods employ six modulating waves, which are compared against a common triangular carrier to generate the gating pulses. In space-vector based PWM schemes, the voltage reference is specified in terms of a rotating reference vector. In each subcycle, a set of voltage vectors are applied for appropriate durations of time to produce an average vector equal to the reference vector. Unlike three-phase induction motor drives, where the voltage vectors are two dimensional, the voltage vectors in the case of SPIM drive are four dimensional. This thesis presents a detailed survey on carrier-comparison based and space-vector based PWM techniques for the SPIM drive. In this thesis, sine-triangle PWM (STPWM) is analyzed from a space-vector perspective. The set of voltage vectors applied and the sequence of application of the voltage vectors in each half-carrier cycle are studied. The analysis shows that the set of voltage vectors and the switching sequence employed by STPWM are different from those used by the well known SVPWM tech-niques. Two other CC based PWM techniques, based on common mode injection, are considered for the SPIM drive. In one method, the common-mode signal is derived from all the six modulating signals, and is the same for both the inverters. In the second method, the common-mode signal is different for the two inverters; each common-mode signal is derived from the three-phase sinusoidal signals of the respective inverter. The study shows that the latter method has the highest dc bus utilization and results in the lowest total harmonic distortion (THD) among the CC PWM techniques. An experimental comparison of the three carrier-comparison techniques with three well known space-vector PWM techniques is presented. Total harmonic distortion (THD) of the line current is measured at different modulation indices for all six techniques. The experimental results are obtained from a 6kW, 200V, 50Hz split-phase induction motor drive, with constant V /F ratio. The PWM techniques are implemented using an ALTERA cyclone II field programmable gate array (FPGA) digital controller. One of the SV techniques, termed here as 4-dimensional 24-sector (4D24SEC) PWM is found to be the best in terms of line current THD among all the CC and SV based PWM techniques considered. However, compared to any carrier-based technique, implementation of the 4D24SEC PWM based on the space vector approach is found to be resource intensive. Hence, an equivalent carrier-based implementation of 4D24SEC PWM is proposed in this thesis. The feasibility of the proposed approach is verified experimentally, and is found to be consuming much less logical resources than the space-vector implementation (i.e. 4102 logical elements for the CC approach as against 33,655 logical elements for the SV approach). A new space-vector PWM technique is also proposed in the thesis. This technique utilizes a new set of voltage vectors and a new switching sequence, which are motivated by the analyses of the carrier-based methods, presented earlier. The proposed technique is implemented, and is compared with other space-vector and carrier-based methods at different modulation indices and switching frequencies. The proposed PWM technique is found to have the same dc-bus utilization as the existing 4-dimensional SV based PWM techniques. The performance of the proposed method is found to be not better than existing 4-dimensional SV PWM methods. The possibilities for new switching sequence is being explored here.

Ion traps used in mass spectrometers are of two classes. One class consists of traps having three electrode geometries which have rotational symmetry about central axis. They are called axially symmetric ion traps. Paul trap, Cylindrical Ion Trap(CIT) are examples in this class. Other class of traps contain 2D electric field inside them which has same profile along the central axis due to translational symmetry. Linear Ion Trap(LIT) and Rectilinear Ion Trap(RIT) are examples in this class. In the ideal hyperbolic geometries of Paul trap and LIT, electric field is a perfectly linear function of distance from the center of the trap. But when these ideal geometries are simplified in to simpler geometries of the CIT and the RIT for ease in machining, linearity of field, which is a specialty of Paul trap and LIT is lost. In this thesis, an effort is made to optimize the field within the traps by using split electrodes. The ring electrode of the CIT and both pairs of electrodes in the RIT are divided into more number of parts. Suitable voltages are applied on these parts to improve the linearity of the field. This thesis contains six chapters. Chapter 1 contains a background information about mass spectrometry. Chapter 2 discusses the Boundary Element Method (BEM) used to calculate charge distribution and Nelder-Mead method used for optimization. It also shows the calculation of multipoles. In Chapter 3, two new geometries namely split-electrode RIT and split-electrode CIT are considered with the objective of improving the linearity of electric field inside them. It is shown here that by applying certain external potential on various parts of split electrodes of these geometries, it is possible to improve the linearity of electric field inside them. In Chapter 4, capacitor models of new geometries proposed in chapter 3 are discussed. The use of external capacitors as a replacement to external power supply is also discussed in this chapter. InChapter5, study similar to that ofChapter3is carried out by splitting the geometries in more number of parts. The possibility of improved field profile is investigated by applying full potential to some of these parts and keeping other parts at ground potential. In Chapter 6, concluding remarks are discussed.

The thesis considers a representation of a discrete multidimensional probability distribution using an apparatus of compositional models, and focuses on the theoretical background and structure of search space for structure learning algorithms in the framework of such models and particularly focuses on the subclass of decomposable models. Based on the theoretical results, proposals of basic learning techniques are introduced and compared.

The diploma thesis is consisting of two parts. Forepart is a theoretic survey. It construes basic office of the air conditioning and deal with used air conditioner arrangements. More deeply it deals with air conditioner systems with refrigerant and the air conditioning for electronic equipments. Project of split system for air conditioning lecture rooms and schoolrooms, and units for air conditioning rooms with cluster and server is processed in the second part. Project is derives from calculation thermal stress of air conditioned space. There is calculated price of air conditioner system and made comparison offers of several accessible suppliers. Elaboration drawing documentation of project is part of the diploma thesis.

This thesis introduces three different algorithmical and statistical strategies for the analysis of high-throughput sequencing data. First, we introduce a heuristic method based on enhanced suffix arrays to map short sequences to larger reference genomes. The algorithm builds on the idea of an error-tolerant traversal of the suffix array for the reference genome in conjunction with the concept of matching statistics introduced by Chang and a bitvector based alignment algorithm proposed by Myers. The algorithm supports paired-end and mate-pair alignments and the implementation offers methods for primer detection, primer and poly-A trimming. In our own benchmarks as well as independent bench- marks this tool outcompetes other currently available tools with respect to sensitivity and specificity in simulated and real data sets for a large number of sequencing protocols. Second, we introduce a novel dynamic programming algorithm for the spliced alignment problem. The advantage of this algorithm is its capability to not only detect co-linear splice events, i.e. local splice events on the same genomic strand, but also circular and other non-collinear splice events. This succinct and simple algorithm handles all these cases at the same time with a high accuracy. While it is at par with other state- of-the-art methods for collinear splice events, it outcompetes other tools for many non-collinear splice events. The application of this method to publically available sequencing data led to the identification of a novel isoform of the tumor suppressor gene p53. Since this gene is one of the best studied genes in the human genome, this finding is quite remarkable and suggests that the application of our algorithm could help to identify a plethora of novel isoforms and genes. Third, we present a data adaptive method to call single nucleotide variations (SNVs) from aligned high-throughput sequencing reads. We demonstrate that our method based on empirical log-likelihoods automatically adjusts to the quality of a sequencing experiment and thus renders a \"decision\" on when to call an SNV. In our simulations this method is at par with current state-of-the-art tools. Finally, we present biological results that have been obtained using the special features of the presented alignment algorithm. / Diese Arbeit stellt drei verschiedene algorithmische und statistische Strategien für die Analyse von Hochdurchsatz-Sequenzierungsdaten vor. Zuerst führen wir eine auf enhanced Suffixarrays basierende heuristische Methode ein, die kurze Sequenzen mit grossen Genomen aligniert. Die Methode basiert auf der Idee einer fehlertoleranten Traversierung eines Suffixarrays für Referenzgenome in Verbindung mit dem Konzept der Matching-Statistik von Chang und einem auf Bitvektoren basierenden Alignmentalgorithmus von Myers. Die vorgestellte Methode unterstützt Paired-End und Mate-Pair Alignments, bietet Methoden zur Erkennung von Primersequenzen und zum trimmen von Poly-A-Signalen an. Auch in unabhängigen Benchmarks zeichnet sich das Verfahren durch hohe Sensitivität und Spezifität in simulierten und realen Datensätzen aus. Für eine große Anzahl von Sequenzierungsprotokollen erzielt es bessere Ergebnisse als andere bekannte Short-Read Alignmentprogramme. Zweitens stellen wir einen auf dynamischer Programmierung basierenden Algorithmus für das spliced alignment problem vor. Der Vorteil dieses Algorithmus ist seine Fähigkeit, nicht nur kollineare Spleiß- Ereignisse, d.h. Spleiß-Ereignisse auf dem gleichen genomischen Strang, sondern auch zirkuläre und andere nicht-kollineare Spleiß-Ereignisse zu identifizieren. Das Verfahren zeichnet sich durch eine hohe Genauigkeit aus: während es bei der Erkennung kollinearer Spleiß-Varianten vergleichbare Ergebnisse mit anderen Methoden erzielt, schlägt es die Wettbewerber mit Blick auf Sensitivität und Spezifität bei der Vorhersage nicht-kollinearer Spleißvarianten. Die Anwendung dieses Algorithmus führte zur Identifikation neuer Isoformen. In unserer Publikation berichten wir über eine neue Isoform des Tumorsuppressorgens p53. Da dieses Gen eines der am besten untersuchten Gene des menschlichen Genoms ist, könnte die Anwendung unseres Algorithmus helfen, eine Vielzahl weiterer Isoformen bei weniger prominenten Genen zu identifizieren. Drittens stellen wir ein datenadaptives Modell zur Identifikation von Single Nucleotide Variations (SNVs) vor. In unserer Arbeit zeigen wir, dass sich unser auf empirischen log-likelihoods basierendes Modell automatisch an die Qualität der Sequenzierungsexperimente anpasst und eine \"Entscheidung\" darüber trifft, welche potentiellen Variationen als SNVs zu klassifizieren sind. In unseren Simulationen ist diese Methode auf Augenhöhe mit aktuell eingesetzten Verfahren. Schließlich stellen wir eine Auswahl biologischer Ergebnisse vor, die mit den Besonderheiten der präsentierten Alignmentverfahren in Zusammenhang stehen.

Our sample (Xit; Yit) consists of pairs of variables. The real variable Xit measures the creditworthiness of individual i in period t. The Bernoulli variable Yit is the default indicator of individual i in period t. The objective is to estimate a credit rating system, i.e. to particularly divide the range of the creditworthiness into several rating classes, each with a homogeneous default risk. The field of change point analysis provides a way to estimate the breakpoints between the rating classes. As yet, the literature only considers models without dependencies or with dependence only in cross section. This contribution proposes multi-period models including dependencies in cross section as well as in longitudinal section. Furthermore, estimators for the model parameters are suggested. The estimators are applied to a data set of a German credit bureau.

Im Rahmen der Untersuchungen wurde die N-Rhizodeposition verschiedener Futter- und Körnerleguminosen mittels Split-Root-Technik und kontinuierlicher 15N-Anreicherung quantifiziert. Anteilig an der gesamtpflanzlichen N-Menge unterschieden sich die durch Rhizodeposition abgegebenen N-Mengen zwischen den geprüften Leguminosenarten weder im Gewächshaus noch im Feld signifikant voneinander, so dass der Einflussfaktor Pflanzenart und –sorte auf die Höhe der spezifischen N-Rhizodeposition als eher gering einzuschätzen ist. Der Einfluss der Umwelt (Gewächshaus versus Freiland) auf die untersuchten Kenngrößen der Trockenmassen und N-Akkumulationen sowie der N-Rhizodeposition fiel hingegen sehr viel deutlicher aus. Die Untersuchungen zeigten zudem positive Zusammenhänge zwischen den N-Rhizodepositionsmengen und den Trockenmasseerträgen bzw. akkumulierten N-Mengen der Leguminosen.

Zur Beantwortung der Frage, wie sich die festigkeitssteigernden Effekte aus mehraxialer und dynamischer Druckbelastung in Beton überlagern wurde ein weltweit einzigartiger zweiaxialer Split-Hopkinson-Bar entwickelt. Es wurden umfangreiche Versuchsserien mit insgesamt mehr als 2500 Einzelversuchen durchgeführt. Ermittelt wurden dabei die ein- und zweiaxialen statischen und dynamischen Betondruckfestigkeiten zweier Betone der Druckfestigkeitsklassen C20/25 und C40/50. Die Versuchsergebnisse wurden hinsichtlich der Festigkeitsentwicklung in Abhängigkeit vom Spannungsverhältnis und der Dehnrate ausgewertet. Die Ergebnisse aus den zweiaxialen dynamischen Betondruckversuchen konnten als dreidimensionale Abhängigkeit der Spannungen in beiden Belastungsachsen von der Dehnrate für jede der beiden Betonsorten abgebildet werden. Aus den Ergebnissen wurde ein Ingenieurmodell für jede Betonsorte entwickelt, welches die Betondruckfestigkeitsentwicklung in Abhängigkeit vom Spannungsverhältnis und der Dehnrate beschreibt. Mit zunehmender Dehnrate wird die zweiaxiale Ergebniskurve um einen zusätzlichen, dynamischen Anteil der Festigkeitssteigerung vergrößert. Dabei kommt es aber nur zu einer teilweisen Überlagerung der beiden betrachteten festigkeitssteigernden Einflüsse. Eine Abschätzung der Größenordnung der jeweiligen Einflüsse aus Mehraxialität und hoher Belastungsgeschwindigkeit konnte durch eine entsprechend differenzierte Auswertung vorgenommen werden. Die Untersuchung der Bruchstücke der zerstörten Probekörper zeigte, dass die Verteilung der Partikelgröße stark von der Dehnrate abhängig ist. Im Gegensatz dazu hängt die Partikelgeometrie und die Form und Masse der entstehenden Kernbruchstücke vom Spannungsverhältnis ab.