Humic substances are macromolecules that naturally occur in all environments in which vegetation matter are present. In general, humic acid is part of humic substances which form the major fraction of the dissolved organic matters in surface water and represents 90% of dissolved organic carbon. Humic acid plays a fundamental role in many ecosystems since it interacts with toxic metal ions present in the system, resulting in a decrease in the bio-availability of such ions. Moreover, the availability of humic acid in water can react with other chemical compounds, such as chlorine to form trihalomethanes (including chloroform) and causes an increasing risk of cancer and may be linked to heart, lung, kidney, liver, and central nervous system damage. Therefore, humic acid removal in water treatment processes is very important in order to achieve the drinking water standards. Heavy metals are significant contaminants in aqueous system. All heavy metals can produce toxicity when ingested in sufficient quantities, but there are several important ones such as lead, mercury, copper, cadmium, arsenic, nickel and silver. These heavy metals are so pervasive and produce toxicity at low concentrations. Moreover, they may build up in biological systems and become a significant health hazard. / Adsorption is approved as an effective and simple method for water and wastewater treatment process. Many adsorbents then are developed for use in adsorption process such as montmorillonite, peat, activated carbon, etc. In this research, humic acid and heavy metals were mainly selected for adsorption study. In the sorption experiment, several adsorbents such as synthesised zeolite (SZ), natural zeolite (NZ), powdered activated carbon (PAC) and fly ash (FA), were selected to examine the application of HA and heavy metals both in individual and simultaneous adsorption, The characteristics and interactions of the adsorbents with HA and heavy metals were systematically studied by batch laboratory experiments. In the beginning, the adsorption of HA onto SZ, NZ, PAC and FA was investigated and their adsorption capacity was compared. The equilibrium adsorption of HA on SZ, NZ, PAC and FA was found to be 84.1, 67.8, 81.2 and 34.1 mg/g, respectively, at 30 oC and pH 5.0. Dynamic adsorption data show that these adsorbents could reach their adsorption equilibrium after 50 hours. From pH analysis, HA adsorption is favoured at low pH and an increase in pH will lead to the reduction of HA adsorption. SZ and NZ adsorption capacity were affected by the changing of solution temperature; however, in PAC and FA sorption study, there was no significant effect observed. Two heavy metal ions (Cu, Pb) removal by the adsorbents was then conducted. The results showed that the equilibrium sorption capacity of Cu and Pb ions on SZ, NZ, PAC and FA were 43.5, 24.2, 19.7, 28.6 and 190.7, 129.0, 76.8 mg/g, respectively at 30 oC and a pH value of 5. The appropriate pH for Cu and Pb removal was found to be 5 and 6. In most dynamic cases, these adsorbents needed at least 50 hours to reach the adsorption equilibrium. Only adsorption on FA required more than 150 hours to reach the equilibrium. / In simultaneous adsorption experiments, the influences of HA and heavy metal concentration (in the range of 10 to 50 mg/L for HA and 10 to 30 mg/l for heavy metals) on the HA-heavy metal complexation were investigated. The results demonstrated that increasing HA concentration mostly affected Cu adsorbed on SZ, FA and PAC and Pb adsorbed on SZ, NZ and PAC. For HA adsorption, the adsorption rate decreased rapidly with increased initial metal ion concentration. Moreover, the adsorption of heavy metals increased with increased heavy metals concentration in the presence of HA. In the presence of heavy metal ions, the order of HA adsorption followed PAC > FA > SZ > NZ. According to the results, the individual and simultaneous adsorption of HA and heavy metals on each adsorbent achieved a different trend. It mainly depended on the adsorption property of both adsorbates (HA and heavy metals) and adsorbents (SZ, NZ, PAC and FA) and also the operation factors such as pH, concentration, temperature and operation time. Even though this experiment could not obtain high adsorption performance, especially in coadsorption, as compared with other adsorbents, the adsorbents in this study represented a higher adsorption capacity and provide the potential for further development.

Pollutants follow various subsurface and surface water pathways from sources within a catchment to its outlet and may cause detrimental effects on downstream water quality and ecosystems. Along their different transport pathways through a catchment, pollutants may be attenuated subject to different physical and biogeochemical processes. In this thesis, physical process effects on such catchment-scale pollutant transport and attenuation, resulting coastal pollutant loading and its efficient abatement are investigated. For this purpose, pollutant transport-attenuation is modeled both generically using a Lagrangian Stochastic Advective-Reactive (LaSAR) approach and site specifically for the Swedish Norrström basin using the GIS-based dynamic nitrogen transport-attenuation model POLFLOW. Furthermore, the role of such modeling for catchment-scale pollutant abatement is also investigated by use of economic optimization modeling. Results indicate that appropriate characterization of catchment-scale solute transport and attenuation processes requires accurate quantification of the specific solute pathways from different sources in a catchment, through the subsurface and surface water systems of the catchment, to the catchment outlet. The various physical processes that act on solute transported along these pathways may be quantified appropriately by use of relevant solute travel time distributions for each water subsystem that the pathways cross through the catchment. Such distributions capture the physical solute travel time variability from source to catchment outlet and its effects on reactive pollutant transport. Results of this thesis show specifically that neglect of such physical solute travel time variability in large-scale models of nitrogen transport and attenuation in catchments may yield misleading model estimates of nitrogen attenuation rates. Results for nitrogen abatement optimization in catchments further indicate that inefficient solutions for coastal nitrogen load reduction may result from simplifying physical transport assumptions made in different catchment-scale nitrogen transport-attenuation models. Modeling of possible future nitrogen management scenarios show also that slow nitrogen transport and reversible mass transfer processes in the subsurface water systems of catchments may greatly delay and temporally redistribute coastal nitrogen load effects of inland nitrogen source abatement over decades or much longer. Achievement of the national Swedish environmental objective to reduce the anthropogenic coastal nitrogen loading by 30% may therefore require up to a 40% reduction of both point sources, for achieving a fast coastal load response, and diffuse sources, for maintaining the coastal load reduction also in the long term. / QC 20100908

Early 1990s to late 2000s freshening (ΔS ≈ -0.001–0.002) and warming (Δθ ≈ 0.02°C–0.035°C) of bottom waters was detected in the southern Pacific Ocean, and Ross Sea source waters progressively freshened during the past four decades. This study investigates potential freshwater anomaly sources and quantifies their effect. Glacial melt water inputs to the GCT increased by 1.3 km^3 per decade (1976– 2007), more rapidly so after 2000 (6.8 km^3 per decade), freshening local Shelf Water by 0.0004 per decade. Lighter basal melt inputs to the LAT started in 1994 and also picked up after 2000 to 14.9 km^3 per decade, lowering the local Antarctic Surface Water salinity by -0.017 per decade. Upstream in the Amundsen Sea surface water freshened by -0.03 per decade (1994–2007) mostly (50%) from larger melt water inputs from the Pine Island (17.7 km^3 per decade) and Dotson (14.8 km^3 per decade) glaciers. Two decades of steady (1978-2000) strengthening of sea ice productivity (200 km^3 per decade) within the Ross Sea Polynya suddenly reversed to weakening (-98.6 km^3 per decade) and resulted in Shelf Water freshening (-0.02 per decade) thereafter. To fully account for the observed variability in Ross Sea waters, the progressive (1992- 2011) adjustment of the density field and induced advective contributions are estimated based on a simplified three-layer stratification. Eastern (western) inflow (outflow) of light surface (dense shelf) water increased by 28% (15%) to 1.11 Sv (1.01 Sv) by 2011; whereas a sluggish intermediate inflow (0.02 Sv) of Modified Circumpolar Deep Water turned into outflow after 2007, thus contributing 0.09 Sv by 2011 to the ventilation of deep waters farther offshore. The estimated evolution of overturning and advective salt fluxes in the Ross Sea yield overall freshening of water masses similar to those derived from observations. Volumetric mean salinities declined at -0.07 per decade for Antarctic Surface Water, -0.05 per decade for Modified Circumpolar Water, and -0.03 per decade for Shelf Water. Outflow intensification of Shelf Water mixtures is also consistent with bottom water property changes (freshening and warming) measured farther downstream in the southern Pacific Ocean.

Östby waterworks in the community of Kramfors has since 2003 had problems of fast clogging of the slow sand filters. As the clogging appears more often, they must be cleaned more frequently which has made the drinking water preparation difficult. Wintertime it has sometimes been impossible to clean the filters which has led to their closing and this has influenced the water quality negatively. The waterworks is a surface waterworks which takes its raw water from the lake Sjöbysjön. The water is flocculated and filtered in a contact filter with the flocculent EKOFLOCK 91. Thereafter it is alkalinized before it reaches the outdoors placed slow sand filters. After the filters the water is alkalinized and disinfected before it reaches the customers. This thesis work has looked into which factors influence the clogging and trials have been made in order to optimize the waterworks and thereby reduce the clogging. The raw water has been studied with aspect to biology and chemistry, the filtered water has been studied with aspect to chemistry and also the pressures in the slow sand filters have been studied. The colour of the raw water from Sjöbysjön and its catchment area has increased since the beginning of the 90-ies and also the bio volume has increased in the lake. The contents of aluminium before the slow sand filters are far higher than the contents after, which leads to the conclusion that aluminium is accumulated in the filters. The differential pressure over the sand bed increases with time after a cleaning. This indicates an accumulation of particles which increases with the load. Observations of the filter surface before cleaning showed that it was covered by a brown, jelly-like film. The internal resistance in the filter beds increases successively after a cleaning and one month after cleaning it is highest in the upper part of the sand bed. All this points to that flocculated aluminium is gathered in the slow sand filters, on the surface, causing clogging. While the thesis work has been going on a process of alkalinizing before the contact filters has been reengaged and this has influenced the flocking of organic materials. When raising the pH the dose of flocculent was increased and this combined increased the amount of flocculated material. The contact filters could not bear this increased amount of flock load but showed instead a breakthrough. In a few lab scale trials the flocking pH was varied as well as the dose flocculent to the raw water and after this the water was filtrated. A tendency was seen that the separation of aluminium, colour and turbidity increased with increasing pH and dose flocculent. At the pH 6.2 and the chemical dose of 60 g/m3 the content of aluminium, the colour and the turbidity showed the lowest values in the filtrate. / Vattenverket i Östby, Kramfors kommun, har sedan 2003 haft problem med för snabba igensättningar i långsamfiltren. Ju oftare de sätter igen desto mer frekvent måste de rensas vilket har försvårat dricksvattenberedningen. Vintertid har rensningar ibland inte kunnat utföras och långsamfiltren har därför stängts av vilket har påverkat vattenkvaliteten negativt. Verket är ett ytvattenverk som tar sitt råvatten från Sjöbysjön. Vattnet flockas och filtreras i kontaktfilter med fällningskemikalien EKOFLOCK 91. Därefter mellanalkaliniseras det innan det går till de utomhus placerade långsamfiltren. Efter långsamfiltren efteralkaliniseras och desinficeras det innan det når konsumenterna. I detta examensarbete har faktorer som påverkar igensättningarna undersökts och försök har också gjorts för att optimera driften och därmed minska igensättningarna. Råvattnet har undersökts avseende dess biologi och kemi, filtraten i verken har undersökts med avseende på deras kemi och tryckbildningar i långsamfiltren har studerats. Färgtalet i råvattentäkten Sjöbysjön och dess tillrinningsområde har ökat sedan början av 90- talet och dessutom har biovolymen i sjön ökat. Halterna aluminium före långsamfiltren är mycket högre än halterna efter, vilket antyder att aluminium ansamlas i filtren. Differentialtrycket över sandbädden ökar med tiden efter en rensning. Detta tyder på en ansamling av partiklar som ökar med belastningen. Observationer av filterytan innan rensning visade att den täcktes av en brun geléaktig hinna. Motståndet i filtren ökar successivt efter en rensning och är en månad efter rensning störst i den övre delen av sandbädden. Allt detta pekar på att aluminiumflock ansamlas i långsamfiltren, på ytan, och orsakar igensättningarna. Under examensarbetets gång har en föralkalinisering återinförts i vattenverkets process och den har påverkat fällningen av det organiska materialet. Då pH höjts har också dosen fällningskemikalie ökats vilket har ökat mängden flock. Denna ökade flockmängd har kontaktfiltren inte kunnat bära utan istället släppt igenom. I några försök i labbskala varierades fällnings-pH och dos fällningskemikalie till råvatten med en efterföljande filtrering. Tendenser som kunde ses var att avskiljningen av aluminium, färg och turbiditet ökade med ökat pH och ökad dos fällningskemikalie. Vid pH 6,2 och kemikaliedos på 60 g/m3 var aluminiumhalterna, färgen och turbiditeten som minst i filtratet.

Surface water and groundwater systems consist of interconnected reservoirs, rivers, and confined and unconfined aquifers. The integrated management of such resources faces several challenges: High dimensionality refers to the requirement of the large number of variables that need to be considered in the description of surface water and groundwater systems. As the number of these variables increases, the computational requirements quickly saturate the capabilities of the existing management methods. Uncertainty relates to the imprecise nature of many system inputs and parameters, including reservoir and tributary inflows, precipitation, evaporation, aquifer parameters (e.g., hydraulic conductivity and storage coefficient), and various boundary and initial conditions. Uncertainty complicates very significantly the development and application of efficient management models. Nonlinearity is intrinsic to some physical processes and also enters through various facility and operational constraints on reservoir storages, releases, and aquifer drawdown and pumping. Nonlinearities compound the previous difficulties. Multiple objectives pertain to the process of optimizing the use of the integrated surface and groundwater resources to meet various water demands, generate sufficient energy, maintain adequate instream flows, and protect the environment and the ecosystems. Multi-objective decision models and processes continue to challenge professional practice. This research draws on several disciplines including groundwater flow modeling, hydrology and water resources systems, uncertainty analysis, estimation theory, stochastic optimization of dynamical systems, and policy assessment. A summary of the research contributions made in this work follows: 1.High dimensionality issues related to groundwater aquifers system have been mitigated by the use of transfer functions and their representation by state space approximations. 2.Aquifer response under uncertainty of inputs and aquifer parameters is addressed by a new statistical procedure that is applicable to regions of relatively few measurements and incorporates management reliability considerations. 3.The conjunctive management problem is formulated in a generally applicable way, taking into consideration all relevant uncertainties and system objectives. This problem is solved via an efficient stochastic optimization method that overcomes dimensionality limitations. 4.The methods developed in this Thesis are applied to the Jordanian water resources system, demonstrating their value for operational planning and management.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2009. / Härtill 4 uppsatser.

Reproducing moisture retention behavior of the upper and lower vadose zone in shallow water table settings provides unique challenges for integrated (combined surface and groundwater) hydrological models. Field studies indicate that moisture retention in shallow water table settings is highly variably affected by antecedent state and air entrapment. The theory and vertical behavior of a recently developed integrated surface and groundwater model (IHM) is examined through comparisons to collected field data in West-Central Florida. The objectives of this study were to (1) Identify important considerations and behavior of the vadose zone for reproducing runoff, ET and recharge in shallow water table settings; (2) Develop a conceptual model that describes vertical soil moisture behavior while allowing for field scale variability; (3) Test the model against observations of the vertical processes; (4) Investigate the sensitivity of model parameters on model vs. observed vertical behavior, and (5) offer recommendations for improvements and parameterization for regional model application. Rigorous testing was made to better understand the robustness and/or limitations of the methodology of the IHM for upper and lower vadose zone. The results are also generally applicable and useful to the upper zone and lower zone conceptualization and parameterization of stand alone HSPF and perhaps other surface water models. Simulation results indicate IHM is capable of providing reasonable predictions of infiltration, depth to water table response, ET distributions from the upper soil, lower soil and water table, and recharge while incorporating field scale variability of soil and land cover properties.

The objectives of this research are to measure the aquifer properties (S, T, and K) of selected watersheds delineated to the U.S. Geological Survey gauging stations using streamflow recession and baseflow data and to describe the relations among the properties of shallow aquifers and the physical properties of the basins, such as slope, regolith type and thickness, and land use type. Geographic Information System (GIS) techniques are utilized to investigate critical physiographic controls on transmissivity and storage coefficients on a regional basis. Moreover, the effect of evapotranspiration on recession index is illustrated. Finally, a detailed quantitative comparison of results for the Piedmont and the Blue Ridge Physiographic Provinces in southeast of the U.S. is provided. Recession index, annual groundwater recharge, and annual baseflow data were obtained from 44 USGS-gauging stations with drainage areas larger than 2 (mi2) and less than 400 (mi2). These gauging stations are located in Georgia and North Carolina. Analyses of data focused on GIS techniques to estimate watershed parameters such as total stream length, drainage density, groundwater slope, and aquifer half-width. The hydraulic diffusivity, transmissivity, and storage coefficient of watersheds were computed using hydrograph techniques and the Olmsted and Hely, and Rorabaugh mathematical models. Median recession index values for the Blue Ridge and Piedmont Provinces are 87.8 and 74.5 (d/log cycle), respectively. Median areal diffusivity values for the Blue Ridge and Piedmont are 35,000 and 44,200 (ft2/d), respectively. Median basin-specific estimates of transmissivity for basins in the Blue Ridge and Piedmont are 150 and 410 (ft2/d), respectively. The large values of transmissivity obtained for the Piedmont regolith may be attributed to the thick regolith, low values of basin relief, and voids that develop as a result of fracturing, foliation, weathering, and fractured quartz veins in the saprolite. Median basin-specific estimates of storage coefficient for basins in the Blue Ridge and Piedmont are 0.005 and 0.009, respectively. In general, the results from this study reveal great differences in basin-specific hydraulic parameters of the regolith material within the Piedmont compared to that of the Blue Ridge Physiographic Province.

Drinking water is a crucial provision for our survival and well-being. However, it is often taken for granted. The environmental objectives in Sweden appear insufficient to ensure drinking water with good quality, because the objectives lack clear protective descriptions, which allow municipalities to determine how to interpret and ensure drinking water. The purpose of this study is to investigate barriers and opportunities for sustainable management of drinking water sources in a tourist region. In order to fulfil the purpose, the study identifies vulnerabilities in the municipal drinking water system with the help from scenario analysis of climate change and tourism development. The study also presents relevant adaptation solutions. The DPSIR framework was used as a tool to categorize and describe the studied problem and was based on a literature study and a mapping of the study area. Åre ski resort was used as a case, and it is supplied with drinking water from two groundwater beds infiltrated by Åresjön (a lake, part of a river). Åresjön is included in an objective to keep drinking water quality standards.     The results show that climate change and tourism development reduces surface and groundwater quality, primarily by increasing microbiological particles. Increases in the number of tourists combined with insufficient monitoring of groundwater levels and infiltration capacity knowledge are unsustainable and are expected to reduce the amount of water in the large groundwater beds. The identified most vulnerable parts of the drinking water system are within the municipal planning process, water production and wastewater treatment. Therefore, the various adaptation solutions address these issues. Direct and indirect adaptations are necessary to ensure sufficient drinking water of good quality until 2100. Tourism development is the main driver for affecting drinking water (if no adaptation measures are implemented). / <p>20180623</p>

The aim of the diploma thesis was a statistical evaluation of the impact of farming methods and the land cover on hydrochemical parameters of surface waters. The area for the evaluation is located in Novohradsko and consist of lower and upper parts of the basin of Vackovy potok and a lower part of Pasecky potok. The area was chosen to include different landscape managements (arable soil, forest and meadows). Due to this fact, it is possible to compare the impact of the management on values of the chosen hydrochemical parameters, which were conductivity, N NO3-, TOC, NL105 and the outflow. Based on the results, it is possible to say that the surface waters from the intesively farmed part of the basin of Vackovy potok have the higher values of all chosen parameters compared to the forest basin or the meadow basin. There was a trend of the increase of the outflow and the values N NO3- in the surface waters always one day after a heavy rainfall. Overall, it is possible to claim that the arable soil has reduced abilities of the retention. This is supported by the large water drainage from the agricultural area.