<p>Algae is regarded as a good potential substrate for biogas production, due to high cells productivity, low cellulose and zero lignin content. Two parts were included in this study: first, cultivations of micro-algae (<em>Chlorella sorokiniana</em> and <em>Tetraselmis suecica</em>) at two different nitrate concentrations, also the effect of addition of CO₂ on algae grow was investigated in this first part. Second, batch fermentations of the cultivated micro-algae as well as a powder <em>Chlorella</em> (obtained from Raw Food Shop) and a dry mix filamentous algae (collected in the pounds in the park at the back of the Tema-building and then dried) were performed. In this part also effects of thermo-lime pretreatment (room temperature, 80^oC, 105^oC and 120^oC) on the algae biogas potentials was investigated.</p><p> </p><p>Both strains of micro-algae cultured at low nitrate gave more CH₄ yield: 319 (±26) mL and 258 (±12) mL CH₄per added gVS was obtained during the degradation of <em>Chlorella sorokiniana </em>grown at 0.4mM-N and 2mM-N level, respectively. For<em> Tetraselmis suecica</em> 337 (±37) mL and 236 (±20) mL CH₄ per added gVS was obtained at 2.4mM-N and 12mM-N level, respectively. Powder <em>Chlorella</em> gave the highest biogas production (719 ±53 mL/added gVS) and CH₄ yields (392 ±14 mL/added gVS), followed by the dry filamentou<em>s</em> algae (661 ±20 mL biogas and 295 ±9 mL CH₄ per added gVS) and <em>Tetraselmis suecica</em> (12 mM-N; 584 ±7 mL biogas and 295 ±9 mL CH₄ per added gVS).</p><p> </p><p>A negative effect of lime treatment at room temperature on CH₄ yield of algal biomass was obtained. Lime treatment at 120^oC showed the fastest degradation rate for <em>Tetraselmis</em> <em>suecica </em>and powder <em>Chlorella</em> during the initial 5 days of incubation.  </p><p> </p><p><em>Chlorella sorokiniana</em> and <em>Tetraselmis suecica</em> cultures flushed with biogas containing 70% and also CO₂ enriched air (5% CO₂) did not increase cells growth (measured as OD₆₀₀) if compared to references grown under air. On the contrary, a clearly inhibition effect on the algal cells growth was observed in some cultures.</p>

This dissertation presents the synthesis of a series of thermo- and pH-sensitive hydrophilic block copolymers and the study of their solution behavior in water. By incorporating a small amount of weak acid or base groups into the thermosensitive block(s) of a hydrophilic block copolymer, the LCST of the thermosensitive block(s) can be modified by changing the solution pH. Accordingly, the critical micellization temperature (CMT) and the sol-gel transition temperature (Tsol-gel) of the block copolymer in water can be tuned. Chapter 1 describes the synthesis of thermo- and pH-sensitive poly(methoxydi(ethylene glycol) methacrylate-co-methacrylic acid)-b-PEO-bpoly( methoxydi(ethylene glycol) methacrylate co-methacrylic acid) and the study of sol-gel transitions of its aqueous solutions at various pH values. The CMT of the 0.2 wt% solution and the Tsol-gel of the 12.0 wt% solution of this copolymer can be varied over a large temperature range. By judiciously controlling temperature and pH, multiple sol-gel-sol transitions were realized. Chapter 2 presents a systematic study of pH effect on rheological properties of micellar gels formed from 10.0 wt% aqueous solutions of thermo- and pH-sensitive poly(ethoxydi(ethylene glycol) acrylate-co-acrylic acid)-b-PEO-b-poly(ethoxydi(ethylene glycol) acrylate-co-acrylic acid). With the increase of pH, the sol-gel transition became broader. The plateau moduli (GN) evaluated from frequency sweeps at T/Tsol-gel of 1.025, 1.032, and 1.039 decreased with the increase of pH from 3.00 to 5.40 with the largest drop observed at pH = ~ 4.7. The decrease in GN reflects the reduction of the number of bridging chains. The ionization of carboxylic acid introduced charges onto the thermosensitive blocks and made the polymer more hydrophilic, facilitating the formation of loops and dangling chains. Chapter 3 presents the synthesis of PEO-b-poly(methoxydi(ethylene glycol)methacrylate-co-2-(N-methyl-N-(4-pyridyl)amino)ethyl methacrylate) with the thermosensitive block containing a catalytic 4-N,N-dialkylaminopyridine and the study of the effect of thermo-induced micellization on its activity in the hydrolysis of pnitrophenyl acetate. The CMTs of this copolymer at pH of 7.06 and 7.56 were 40 and 37 °C, respectively. Below CMT, the logarithm of initial hydrolysis rate changed linearly with 1/T. Above CMT, the reaction rate leveled off, which is presumably because it was controlled by mass transport to the core of micelles above CMT.

Stainless steels are high-alloyed, usually with multiple components and often also dual matrix phases, as for duplex stainless steels. This make predictions and calculations of alloying effects on equilibria and transformations complicated. Computational thermodynamics has emerged as an indispensable tool for calculations within these complex systems with predictions of equilibria and precipitation of phases. This thesis offers examples illustrating how computational methods can be applied both to thermodynamics, kinetics and coarsening of stainless steels in order to predict microstructure and, to some extent, also properties. The performance of a current state-of-the-art commercial thermodynamic database was also explored and strengths and weaknesses highlighted. / <p>QC 20130429</p>

Warm forming of aluminum alloys of has shown promising results for increasing the formability of aluminum alloy sheet. Warm forming is a term that is generally used to describe a sheet metal forming process, where part or all of the blank is formed at an elevated temperature of less than one half of the material’s melting temperature. The focus of this work is to study the effects of warm forming on Novelis X926 clad aluminum brazing sheet. Warm forming of clad aluminum brazing sheet, which is commonly used in automotive heat exchangers has not been studied. This work can be split into three main goals: i) to characterize the material behavior and develop a constitutive model, ii) to experimentally determine the effects of warm forming on deep drawing; and, iii) to create and validate a finite element model for warm forming of Novelis X926. For an accurate warm forming material model to be created, a temperature and rate dependant hardening law as well as an anisotropic yield function are required. Uniaxial isothermal tensile tests were performed on 0.5mm thick Novelis X926at 25°C (room temperature), 100°C, 150°C, 200°C, and 250°C. At each temperature, tests were performed with various strain rates between 7.0 E -4 /sec and 7.0 E -2 /sec to determine the strain rate sensitivity. Tensile tests were also performed at 0° (longitudinal), 45° (diagonal), and 90° (transverse) with respect to the material rolling direction in order to assess the anisotropy of the material. It was found that increasing forming temperature increases elongation to failure by 200%, decreases flow stress by 35%, and increases strain rate sensitivity. Barlat’s Yield 2000 yield function (Barlat et al., 2003a) and the Bergström work hardening law (van den Boogaard and Huétink , 2006) were found to accurately method model the material behavior. Warm deep drawing of 101.6 mm (4”) diameter cylindrical cups was performed using specially designed tooling with heated dies and a cooled punch. Deep drawing was performed on 228.6 mm (9“) and 203.2 mm (8”) diameter blanks of 0.5 mm thick Novelis X926. Deep drawing was performed with die temperatures ranging from 25°C to 300°C with a cooled punch. Teflon sheet and Dasco Cast 1200 lubricants were used in experiments. Different punch velocities were also investigated. 228.6 mm diameter blanks, which could not be drawn successfully at room temperature, were drawn successfully using 200°C dies. Increasing the die temperature further to 250°C and 300°C provided additional improvement in formability and reduced tooling loads. Increasing the punch velocity, increases the punch load when forming at elevated temperatures, reflecting the strong material rate sensitivity at elevated temperatures. A coupled thermal mechanical finite element model was developed using the Bergström hardening rule and the Yield 2000 yield surface using LS-DYNA. The model was found to accurately predict punch force for warm deep drawing using Teflon sheet as a lubricant. Results for Dasco Cast 1200 were not as accurate, due to the difficulties in modeling the lubricant’s behavior. Finite element simulations demonstrated that warm forming can be used to reduce thinning at critical locations, compared to parts formed at room temperature.

Dramatic advances are taking place in the microelectronic industry. The feature size continues to scale down and it is expected that the minimum feature size on the integrated circuit is expected to reach 9 nm by 2016, and there will be more than 8 billion transistors on a 310 cm² chip, according to various available roadmaps. Subsequently, this reduction in feature size would require the first-level input-output interconnects to decrease in pitch size to meet the increased number of transistors on the chip. Also, to minimize the on-chip interconnect delay, development of low-K dielectric/copper will become increasingly common in future devices. However, due to the low fracture strength of low-K dielectric, it is essential that the first-level interconnects exert minimal force on the die pads and therefore, do not crack or delaminate the low-K dielectric material. It is also preferable to have a wafer-level packaging approach to facilitate test-and-burn in and to produce known-good dies. Based on these growing demands from the microelectronics industry, there is a compelling need to develop innovative interconnect technologies. This thesis aims to develop one such innovative interconnect — G-Helix interconnect. G-Helix is a scalable lithography-based wafer-level electroplated compliant interconnect that has the potential to meet the fine-pitch first-level chip-to-substrate interconnect requirements. The three-mask fabrication of G-Helix is based on lithography, electroplating and molding (LIGA-like) technologies, and this fabrication can be easily integrated into large-area wafer-level fine-pitch batch processing. In this work, the fabrication, assembly, experimental reliability testing, and numerical physics-based modeling of the G-Helix interconnects will be presented. The fabrication of the interconnects will be demonstrated at 100μm pitch on a 20 x 20 mm die in a class 10/1000 cleanroom facility. The wafers with compliant interconnects will be singulated into individual dies and assembled on substrates using Pb/Sn eutectic solder. The assembly will then be subjected to air-to-air thermal cycling between 0℃and 100℃ and the reliability of the compliant interconnect will be assessed. In addition to the thermo-mechanical reliability testing, some of the dies with free-standing interconnects will also be used for measuring the compliance of the interconnects by compressing with a nanoindenter. In parallel to the experimental research, a numerical analysis study will also be carried out. The numerical model will use direction-, temperature, time-dependent, and time independent material constitutive properties as appropriate. The thermo-mechanical fatigue life of the compliant interconnect assembly will be determined and compared with the experimental data. Recommendations will be developed for further enhancement of reliability and reduction in pitch size.

Microalgae hold a great potential to serve as feedstocks for biodiesel production. Tropical and subtropical zones have more solar energy than temperate areas for microalgal culturing. However, outdoor high irradiance results in high temperature in the culturing medium, which is damaging if not lethal to most known microalgal species. New microalgae with heat tolerance, high growth rates and high lipid contents are desirable to establish this industry. Four new green microalgae were isolated in southern Taiwan, located in the subtropical zone. All four species are members of the genus Desmodesmus in the family Senedesmaceae. Two of the four species survived at 45¢Jfor 24 hours, with 5 to 13% mortality rates caused by the heat. Lipid contents of two species reached over 50% in dry biomass under nitrogen starvation. Oil accumulation in tion. Oil accumulation in tion. Oil accumulation in tion. Oil accumulation in the four species positively correlates with their photosystem efficiencies during stress treatments (R2=0.90).

Cette thèse porte sur le vieillissement thermo-oxydant de fibres géotextiles en polypropylène, l'objectif principal étant la prédiction de durée de vie à partir d'essais de vieillissement accéléré par une méthode non-empirique. Des essais ont été réalisés à des températures comprises entre 50 et 130°C et des pressions d'oxygène entre 0,02 et 5,0 MPa sur du PP non stabilisé et sur divers échantillons de PP contenant diverses concentrations de phosphite ou d'anti-oxydant phénolique. L'étude de l'effet d'un milieu aqueux sur le vieillissement a également été abordée. L'ensemble des données bibliographiques disponibles et des résultats expérimentaux acquis a permis de faire une proposition de schéma mécanistique (processus d'oxydation radicalaire en chaîne ramifié) qui a conduit à un schéma cinétique dont la résolution, dégrossie par voie analytique, est en définitive obtenue par voie numérique. Ce modèle permet de simuler les courbes cinétiques d'évolution de la structure chimique du PP dans toute l'étendue des intervalles de température et de pression étudiés. Les paramètres cinétiques, déterminés par méthode inverse, prennent des valeurs physiquement raisonnables. Le nombre et la diversité des tests de validité du modèle (dosage des carbonyles et des hydroperoxydes) permettent de garantir sa pertinence. L'étude des stabilisants, outre le fait qu'elle complète le modèle, a permis de déterminer des paramètres cinétiques jusqu'ici inconnus, et de mettre en évidence l'existence de processus élémentaires (en particulier une réaction phénol-oxygène) jusqu'ici ignorés. Enfin, l'accélération du vieillissement dûe à l'extraction des stabilisants par un milieu aqueux environnant a été prouvée, et sa modélisation, bien qu'incomplète, ne semble pas inaccessible, ce qui permet d'envisager une prédiction non empirique de la durée de vie des géotextiles.

LLean premixed combustion systems, attractive for low NOx performance, are inherently susceptible to thermo-acoustic instabilities - the interaction between unsteady heat release and excited acoustic wave effects. In the present work, a hybrid, coupled Large Eddy Simulation (LES) CFD approach is described, combining the computational efficiency of incompressible reacting LES with acoustic wave effects captured via an acoustic network model. A flamelet approach with an algebraic Flame Surface Density (FSD) combustion model was used. The ORACLES experiments - a perfectly premixed flame stabilised in a 3D sudden expansion - are used for validation. Simulations of the inert flow agree very well with experimental data, reproducing the measured amplitude and distribution of turbulent fluctuations as well as capturing the asymmetric mean flow. With reaction the measured data exhibit a plane wave acoustic mode at 50Hz. The influence of this plane wave must be incorporated into the LES calculation. Thus, a new approach to sensitise the incompressible LES CFD to acoustic waves is adopted. First an acoustic network model of the experimental geometry is analysed to predict the amplitude of the 50Hz mode just before the flame zone. This is then used to introduce a coherent plane wave at the LES inlet plane at the appropriate amplitude, unlike previous LES studies, which have adopted a "guess and adjust" approach. Incompressible LES predictions of this forced flow then show good agreement with measurements of mean and turbulent velocity, as well as for flame shape, with a considerable improvement relative to unforced simulations. To capitalise on the unsteady flame dynamics provided by LES, simulations with varying forcing amplitude were conducted and analysed. Amplitude dependent Flame Transfer Functions (FTFs) were extracted and fed into an acoustic network model. This allowed prediction of the stable/unstable nature of the flame at each forcing amplitude. An amplitude at which the flame changed from unstable to stable would be an indication that this coupled approach was capable of predicting a limit cycle behaviour. With the current simple FSD combustion model almost all cases studied showed a stable flame. Predictions showed considerable sensitivity to the value chosen for the combustion model parameter but specially to the acoustic geometric configuration and boundary conditions assumed showing evidence of limit cycle behaviour for some combinations. Nevertheless, further work is required to improve both combustion model and the accuracy of acoustic configuration and boundary condition specification.

Energy methods are used extensively in the formulation of discrete system models. They simplify the systematic integration of diverse kinematic schemes, and are well suited for characterizing complex energy domain coupling effects. Continuum mechanics models are by contrast normally based on partial differential equation descriptions of the physical system. The research presented here develops a new Hamiltonian method for the simulation of distributed parameter electromagnetic and thermo-electromagnetic systems. It expands the application of current system dynamics modeling techniques, to encompass complex distributed parameter electromagnetic systems. / text

The development of IT has a huge influence on variation of society. More and more computers are applied at home or industry. The change of society of course influences and school. Pupils glad fully learn to work with computer, they easily reclaim all innovations and adjust them in real life. IT is not isolated discipline in school. All teachers use computers during their lessons. I have noticed, that pupils remember details, themes, lessons much better when computer is used. I made up an idea to make a teaching programme „The modelling of thermo physics in VII – X classes“. The aims of program 1. To teach pupils to apply notions and formulas of subject „Warmth“. 2. To seal skills of pupils by repeating similar tasks. 3. To supply tests of learned themes, this would help to test the knowledge of pupils. In my programme will be disputed aggregates state and transformation of material, also the conditions needed for transformations. Program consists of two parts: 1. The teaching programme. 2. Examination programme. In first part I will introduce a pupil with existing problems, formulas, nature law, appearances. While solving tasks I will leave some freedom to a pupil. A pupil will be able always to use help and explanations. This part is a side-kick for a teacher explaining new topic. This is the theory part which includes all topics of „Warmth“. In second part I have organized tests, which will help to check the knowledge of pupils and also will help to find out the gaps... [to full text]