Kawah Ijen (2386 m) is a stratovolcano located within Ijen Caldera, at the easternmost<p>part of Java island in Indonesia. Since 2010, the volcano has been equipped with seismometers<p>and several sensors (temperature and level) have been immersed in its acidic lake waters and in the acidic river seeping on the volcano flanks. While finding instruments capable of resisting to such extreme conditions (pH~0) has been challenging, the coupling of lake monitoring techniques with seismic data improves the knowledge of the volcanic-hydrothermal dynamics. Moreover, the monitoring capabilities have been considerably<p>enhanced supporting the decision-making of the authorities in case of emergency.<p><p>Several methods and processing techniques were used to analyze the seismic data. Much effort has been given to implement the seismic velocities (Moving Window Cross Spectral Analysis (MWCSA)) calculations. At Kawah Ijen, the frequency band that is less affected by the volcanic tremor and the seasonal fluctuations at the source ranges between 0.5-1.0 Hz. Moreover, a stack of 5 days for the current CCF gives reliable results with low errors and allows to detect fluctuations which are missed using a 10-day stack.<p><p>The background seismic activity mostly consists in low frequency events and a continuous tremor of low amplitude. Fluctuations of the lake temperature and level result from the recharge of the hydrothermal system during the rainy season. Kawah Ijen lake waters are not perfectly mixed and a shallow stratification occurs during the rainy season, because meteoric waters are less dense than the lake fluids.<p><p>Different unrest occurred during our study. Some of them strongly affected the volcanic lake, while others did only weakly. In the first category, a strong unrest commenced in October 2011 with heightened VT (Volcano Tectonic) earthquakes and low frequency events activity, which culminated mid-December 2011. This unrest was correlated with an enhanced heat and hydrothermal fluids discharge to the crater and significant variations of the relative velocities (~1%). This suggests an important build-up of stress into the system. VT earthquakes opened pathways for the fluids to ascend, by increasing the permeability of the system, which latter allowed the initiation of monochromatic tremor (MT) when the steam/gases interacted with the shallow portions of the aquifer. Our calculations evidence a higher contribution of steam in March 2012 that might explain the increase of the MT frequency when bubbles were observed at the lake surface. This period was also characterized by short-lived but strong velocity variations, related to water level<p>rises containing important amount of bubbles, and important heat and mass discharges<p>into the lake. On the contrary, the second category of unrest did only slightly affect the<p>lake system. This could be explained by a dryer hydrothermal system and/or locations of<p>the seismic sources, which were not directly linked to the lake.<p><p>While a magmatic eruption will likely be preceded by a strong seismic activity, the major challenges remain to understand why the unrest we studied did not lead to an eruption and to identify precursory signs of a phreatic eruption. Even a small phreatic eruption would be devastating for the people working everyday in the crater and the ones<p>who live nearby the voluminous acidic lake. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

Les travaux de cette thèse reposent sur l’étude des processus hétérogènes à la surface desparticules minérales en présence d’irradiation UV-A. Nous savons que les poussièresminérales contiennent des oxydes métalliques pouvant absorber la radiation solaire et ainsiactiver une chimie très différente de celle observée à l’obscurité. Un réacteur à écoulementd’aérosols a été utilisé pour étudier les interactions des gaz (SO2, NO2 et O3) avec devéritables poussières minérales, évitant ainsi les artéfacts de mesure liés à la naturemacroscopique des films comme dans les études précédentes.La mise en suspension des poussières minérales a permis d’observer une formation inattenduede nouvelles particules ultrafines en présence de SO2. Le mécanisme proposé pour expliquerce phénomène de nucléation suggère une désorption de radicaux OH photoproduits à lasurface des minéraux vers la phase gazeuse. Ce mécanisme a pu être corroboré par descampagnes de mesure en atmosphère réelle. Nous avons étudié la chimie des échantillons de réelles cendres volcaniques issus de la dernière éruption du volcan Eyjafjallajökull en Islande (2010). Ceci nous a permis d’élaborerdes cinétiques de capture du SO2 sur des films macroscopiques de cendres aboutissant à descoefficients de capture de l’ordre de 10-7. Ces cinétiques couplées à des analyses chimiquesont permis de proposer un mécanisme réactionnel expliquant la formation de sulfate de fer àla surface des cendres. Finalement, nous avons étudié les interactions photochimiques de O3 et NO2 sur les poussièresminérales dans le réacteur à écoulement mettant en évidence un bon accord avec des étudesantérieures sur des surfaces macroscopiques / The objective of this work is to study the heterogeneous processes of mineral dust surfacesunder UV-A radiation. It is know that mineral dust containing metal oxides which can absorbsolar radiation and therefore activate a different chemistry compared to that observed in thedark. In order to avoid measurement artifacts related to the nature of macroscopic films, anaerosol flow tube was developed during this work and applied to study the interactions ofSO2, NO2 and O3 with real mineral dust.An unexpected formation of new particles in the presence of SO2 was observed. In order toexplain this phenomenon, we suggest the desorption of OH radicals from the mineral dustsurface to the gas phase. This mechanism has also been supported by field campaigns.Using real samples of volcanic ash from the last eruption of Eyjafjallajökull in Iceland (2010)allowed us study capture of SO2 on macroscopic ashes films with uptake coefficient around10-7. Associated kinetic experiments combined with chemical analysis allowed us to propose areaction mechanism explaining the formation of iron sulfate on the surface of ashes.Finally, we investigated the photochemical interactions of O3 and NO2 with minerals dustaerosols in the flow tube reactor showing a good agreement with previous data obtained onmacroscopic surfaces.

Detailed field mapping (Map, Appendix B) has been conducted in and around the boundaries of a 14x18km, volcanic complex 35km northeast of Molteno in the Eastern Cape Province, South Africa. The structure is interpreted as a subsidence structure, and is filled with two volcaniclastic breccias, numerous lava flows, a number of sedimentary facies, and lies on a base of Clarens Formation overlying Elliot Formation rocks. This is an important study because 'widespread, voluminous fields of basaltic breccias are very rare (see Hanson and Elliot, 1996) and this is the first time that this type of volcanic complex and its deposits have been described. Detailed analyses of the two volcaniclastic breccias revealed changes in colour, clast types, clast sizes, and degree of alteration over relatively short distances both vertically and laterally within a single breccia unit. The variation in clast sizes implies a lack of sorting of the breccias. The lower of the two volcaniclastic breccias fills the subsidence structure, and outcrops between the Stormberg sedimentary sequence and the overlying Drakensberg basalts and was produced from phreatomagmatic eruptions signalling the start of the break-up of Gondwanaland in the mid-Jurassic. The upper volcaniclastic breccia is interbedded with the flood basalts and is separated from the lower breccia by up to 100m of lava flows in places, it is finer-grained than the lower volcaniclastic breccia, and it extends over 10km south, and over 100km north from the volcanic complex. The upper breccia is inferred to have been transported from outside the study area, from a source presumably similar to the subsidence structure in the volcanic complex. The pyroclastic material forming the upper breccia was transported to the subsidence structure as a laharic debris flow, based on its poorly sorted, unwelded and matrix-supported appearance. However, both breccias are unlikely to have been derived from epiclastic reworking of lava flows as they contain glass shards which are atypical of those derived from the autoclastic component of lava flows. The breccias are therefore not "secondary" lahars. There is also no evidence of any palaeotopographic highs from which the breccias could have been derived as gravity-driven flows. Based on the occurrence of three, 1m thick lacustrine deposits, localised peperite, fluvial reworking of sandstone and breccia in an outcrop to the south of the subsidence structure, and channel-lags encountered only in the upper units of the Clarens Formation and only within the subsidence structure, the palaeoenvironment inferred for the subsidence structure is one of wet sediment, possibly a shallow lake, in a topographic depression fed by small streams. Magmatic intrusions below the subsidence structure heated the water-laden, partly consolidated Clarens Formation sandstones, causing the circulation of pore fluid which resulted in the precipitation of minerals forming pisoliths in the sandstones. Intruding magma mixed, nonexplosively, with the wet, unconsolidated sediments near the base of the Clarens Formation (at approximately 100m below the surface), forming fluidal peperite by a process of sediment fluidisation where magma replaces wet sediment and cools slowly enough to prevent the magma fracturing brittly. Formation of fluidal peperite may have been a precursor to the development of FCIs (Fuel Coolant Interactions) (Busby-Spera and White, 1987). The breccias may represent the products of FCIs and may be the erupted equivalents of the peperites, suggesting a possible genetic link between the two. The peperites may have given way to FCI eruptions due to a number of factors including the drying out of the sediments and/or an increase in the volume of intruded magma below the subsidence structure which may have resulted in a more explosive interaction between sediment and magma. Phreatic activity fragmented and erupted the Clarens Formation sandstone, and stream flows reworked the angular sandstone fragments, pisoliths and sand grains into channelised deposits. With an increase in magmatic activity below the subsidence structure, phreatic activity became phreatomagmatic. The wet, partly consolidated Clarens Formation, and underlying, fully consolidated Elliot Formation sediments were erupted and fragmented. Clasts and individual grains of these sediments were redeposited with juvenile and non-juvenile basaltic material probably by a combination of back fall, where clasts erupted into the air fell directly back into the structure, and backflow where material was erupted out of the structure, but immediately flowed back in as lahars. This material formed the lower volcaniclastic breccia. A fault plane is identified along the southwestern margin of the subsidence structure, and is believed to continue up the western margin to the northwestern corner. A large dolerite body has intruded along the inferred fault plane on the western margin of the structure, and may be related to the formation of the lower volcaniclastic breccia, either directly through fluidisation of wet sediment during its intrusion, or as a dyke extending upwards from a network of sill-like intrusions below the subsidence structure. Geochemical analysis of the Drakensberg basalt lava flows by Mitchell (1980) and Masokwane (1997) revealed four distinct basalt types; the Moshesh's Ford, the Tafelkop, the Roodehoek, and the Vaalkop basalts. Basalt clasts sampled from the lower volcaniclastic breccia were shown to belong to the Moshesh's Ford basalt type which does not outcrop in situ within the subsidence structure. This implies that the Moshesh's Ford basalts were emplaced prior to the formation of the lower volcaniclastic breccia, and may have acted as a "cap-rock" over the system, allowing pressure from the vaporised fluids, heated by intruding basalt, to build up. The Moshesh's Ford basalt type was erupted prior to the resultant phreatomagmatic events forming the lower volcaniclastic breccia.

Aux Antilles, la disponibilité limitée des ressources en contexte insulaire et l'activité agricole à aux niveaux d'intrants fragilisent les ressources en eau. Dans les zones bananières à forts niveaux d'intrants, des phénomènes de pollution des eaux sont particulièrement marqués, notamment du fait de l'usage d'un pesticide, la chlordécone. La connaissance du fonctionnement des systèmes hydrologiques à l'échelle du bassin versant représente un enjeu primordial pour pouvoir estimer l'exposition de l'écosystème aux pollutions et pour prévoir l'évolution des contaminations dans le temps. L'objectif de la thèse a été de développer une modélisation mécaniste représentant les processus hydrologiques de surface et souterrains à l'échelle d'un bassin versant sur substrat volcanique, sous climat tropical humide, situé en zone bananière en Guadeloupe. En premier a été développé un modèle parcellaire de bilan hydrique adapté au cas des cultures bananières. Il a pour originalité de prendre en compte l'importante redistribution de pluie opérée par le couvert bananier et d'en simuler les effets en matière d'intensité et d'hétérogénéité intra-parcellaire sur les termes du bilan hydrique. Les résultats d'analyse de sensibilité montrent que la redistribution de la pluie augmente le ruissellement de surface ainsi que la percolation, en cohérence avec les observations de terrain, mais impacte peu ou temporairement l'évapotranspiration et l'humidité du sol. Le calage du modèle sur des données expérimentales indiquent une performance améliorée de la simulation du ruissellement par rapport à un modèle ignorant le mécanisme de redistribution. En second, le bassin versant expérimental de Féfé (17.8 ha) a fait l'objet d'une approche de modélisation intégrant processus hydrologiques de surface et souterrains basée sur un chaînage itératif des modèles MHYDAS et MODFLOW. Confrontée à une année hydrologique de mesures de débits à l'exutoire et de piézométries, l'approche de chaînage de modèles de surface et souterrain apparaît pertinente. Une limite majeure est toutefois la non prise en compte de la zone non saturée dans le processus de recharge des aquifères. L'analyse des simulations et de leurs écarts avec les données observées conforte plusieurs hypothèses issues des analyses expérimentales : un ruissellement de surface fortement hortonien, une contribution majeure des écoulement souterrains au débit à l'exutoire. Elle indique toutefois également une indétermination des processus majeurs lors des périodes de fortes pluies. Différentes hypothèses sont proposées qu'il conviendra d'évaluer dans des travaux futurs. Ce travail constitue une première étape pour évaluer les chemins d'écoulement majeurs et les dynamiques des contaminations par les produits phytosanitaires dans un milieu volcanique tropical sous culture bananière. / In the French West Indies (FWI), limited resources supply on island and farming with extensive uses of pesticides have damaged water resources. In environments under intensive banana production, water pollution can be of particular concern, with regards to the use of chlordecone, an insecticide to control the banana weevil. Understanding the hydrological behaviour of a catchment is a challenge in assessing the exposure of the ecosystem to pollutions and in predicting the long-term contamination dynamics. This thesis aimed at developing a model to simulate de surface and underground hydrological processes at the catchment scale on volcanic deposits in a humid tropical area covered by banana plantations in Guadeloupe. First, we developed an original water budget model at the plot scale, adapted to the banana canopy. It takes into account the high rainfall redistribution by banana cover and simulates the effects of modified rainfall intensities and within-plot heterogeneities on the water balance components. The sensitivity analysis showed that rainfall redistribution promotes surface runoff and percolation, in accordance with the field observations, but influences little or only temporarily the average field evapotranspiration and soil moisture. The model calibration tested on experimental data indicated improved runoff production performances compared to a model without rainfall redistribution. Secondly, the Féfé experimental catchment (17.8 ha) was studied with a linked iterative modelling approach (of MHYDAS and MODFLOW) that includes surface and underground hydrological processes. Tested against a year of outlet discharge and water table depth measurements, the linked modelling approach seems appropriate. However, the main limit of this approach was that it does not consider the transfer through the unsaturated zone when simulating the aquifers' recharge. The analysis of the results and of the differences between measured and simulated variables supported the hypothesis, from experimental analyses, that: the surface runoff is mainly Hortonian, groundwater flow is the main contributor to runoff at the catchment outlet. However, there was still uncertainty concerning the main processes during wet periods. Various hypotheses were suggested and should be investigated in future studies. This work represents a first step towards the evaluation of the major flow paths and contamination dynamics of pesticides on volcanic deposits in a humid tropical area covered by banana plantations.

El suelo volcánico de la región de Moquegua en la provincia de Omate es un material de grano mediano, muy frágil y poco denso a su vez; lo cual hace que tenga un mal comportamiento geotécnico. El material proveniente de un talud, se le adicionará conglomerantes como el cemento y la cal para mejorar sus parámetros geotécnicos y evaluar desde un punto de vista más ingenieril. La metodología de esta investigación se inició con los ensayos para caracterizarlos, entre ello se realizó el ensayo de tamizado NTP 339.128 (ASTM D422), el ensayo para determinar el contenido de humedad NTP 339.127 (ASTM D42216); con la finalidad de poder determinar el suelo de estudio. Luego se realizaron ensayos de pH del suelo NTP 339.176 y de compactación Proctor Modificado NTP 339.141 (ASTM D1557), estos se usaron con el propósito de hallar la mejor dosificación de cal para la arena y del Proctor trato de encontrar la máxima densidad seca del suelo para aplicar esa misma densidad en los ensayos de corte. Finalmente, se ensayaron muestras a un Corte Directo NTP 339.171 (ASTM D3080), con la finalidad de obtener los parámetros de ángulo de fricción y cohesión. Las combinaciones de dosificación de cal que se usó para toda la tesis fueron de 4% constante para todas las muestras y de cemento fueron 2%, 4%, 6% y 8%. En suma, se realizaron estos ensayos a 3 y 7 días de curado, con el fin de evaluar el comportamiento y la tendencia de los esfuerzos cortantes a más días. Los resultados más relevantes mostraron que se obtuvieron un aumento de su ángulo de fricción en respecto al suelo natural de 16% para una mezcla de 2% de cemento y 4% de cal, 30% para una mezcla de 4% de cemento y 4% de cal, 28% para una mezcla de 6% de cemento y 4% de cal; y 22.57% para una mezcla de 8% de cemento y 4% de cal; estos resultados son dados para un curado de 3 días. En cambio, para un curado de 7 días se tienen los siguientes resultados de ángulo de fricción respecto al suelo natura de 27% para una mezcla de 2% de cemento y 4% de cal, 37% para una mezcla de 4% de cemento y 4% de cal, 35% para una mezcla de 6% de cemento y 4% de cal; y 29.92% para una mezcla de 8% de cemento y 4% de cal. En cuanto a los esfuerzos de resistencia al corte que se mostraran más adelante, se puede decir que mejoran con respecto al suelo natural, ya sea para un curado de 3 y 7 días. / The volcanic soil of the Moquegua region in the province of Omate is a medium grain material, very fragile and not very dense; which causes him to have a bad geotechnical behavior. The material from a slope will be added with binders such as cement and lime to improve its geotechnical parameters and evaluate from a more engineering point of view. The methodology of this investigation began with the tests to characterize them, among them the NTP 339.128 sieve test (ASTM D422) was performed, the test to determine the NTP 339.127 moisture content (ASTM D42216); in order to determine the study floor. Then, NTP 339.176 soil pH and Modified Proctor NTP 339.141 (ASTM D1557) compaction tests were performed, with the purpose of finding the best lime dosage for the sand and the Proctor trying to find the maximum dry soil density to apply that same density in cutting tests. Finally, samples were tested at a Direct Cut NTP 339.171 (ASTM D3080), in order to obtain the parameters of friction and cohesion angle. The lime dosage combinations that were used for the entire thesis were 4% constant for all samples and cement were 2%, 4%, 6% and 8%. In sum, these trials were performed at 3 and 7 days of cure, in order to evaluate the behavior and tendency of the shear stresses to more days. The results obtained indicate that the friction angle shows an increase in proportion to natural soil of 16% for a mixture of 2% cement and 4% lime, 30% for a mixture of 4% cement and 4 Lime%, 28% for a mixture of 6% cement and 4% lime; and 22.57% for a mixture of 8% cement and 4% lime; These results are given for a 3-day cure. On the other hand, for a 7-day cure, the following friction angle results with respect to the natural soil of 27% for a mixture of 2% cement and 4% lime, 37% for a mixture of 4% cement and 4% lime, 35% for a mixture of 6% cement and 4% lime; and 29.92% for a mixture of 8% cement and 4% lime. / Tesis

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Lorsqu'elle est chauffée, la roche peut subir une microfissuration thermique, qui influence ses propriétés physiques, mécaniques, thermiques, et de transport. La surveillance de la microfissuration thermique en laboratoire a été principalement réalisée pendant le chauffage, et rarement lors du refroidissement ou du chauffage cyclique que la roche subit dans les volcans et les réservoirs géothermiques. Un nouvel appareil a été élaboré pour surveiller les émissions acoustiques et mesurer les vitesses des ondes élastiques à haute température. L'état de fissuration a été évalué grâce à un nouvel algorithme d'analyse microstructurale, et l'influence des microfissures sur les propriétés des roches a été mesurée et modélisée. Selon la microstructure, la microfissuration peut avoir lieu pendant le chauffage ou le refroidissement, et les microfissures existantes peuvent s’ouvrir et se fermer de façon réversible avec des changements de température, et influencer les propriétés de la roche. / Rock may undergo thermal microcracking when heated, affecting its physical, mechanical, thermal, and transport properties. Thermal microcrack monitoring in the laboratory has mainly been performed during heating, and rarely during the cyclic heating and cooling relevant for volcanoes and geothermal reservoirs. For this, a new dedicated apparatus for the acoustic emission monitoring and wave velocity measurement at high temperatures was elaborated, building on previous designs. Microcrack damage was assessed with a new algorithm for quantitative microstructural analysis, and the influence of thermal microcracks on rock properties was measured and modelled. Depending on the rock type and initial microcrack content, microcracking occurred during either heating, cooling, or neither, and existing microcracks reversibly opened or closed with increasing temperature. In Earth's crust, the evolution of rock properties with temperature may be significant and is determined by the microstructure.

A quartz diorite intrusion of probable early Tertiary age that crops out over at least 6 square miles in the Palo Verde Ranch area in Pinal County, Arizona was mapped as a distinct intrusion. The quartz diorite intrudes an area comprising Pinal Schist, Oracle granite, andesitic flows, granoaplite, and dike rocks including both pegmatite and diabase. Two major physical features, the Owl Head Buttes and Chief Buttes volcanic areas, both remnants of an extensive early Tertiary series of flows of intermediate composition that covered the area, now remain as lava-capped buttes above the pediment. Weak but persistent fracture-controlled copper mineralization is found in the quartz diorite and the Pinal Schist at or near their mutual contacts in the form of chrysocolla, malachite, black copper oxides, chalcocite, chalcopyrite, and bornite, in decreasing order. Pyrite is rare. Alteration related to northeast and northwest-trending fractures increases in intensity from the common propylitic to argillic to the northeast toward the San Juan claims area. A barely discernible increase in copper sulfides mirrors the alteration zoning, although geochemical sampling showed background copper in the quartz diorite to be more uniform away from fractures.

The Pantano Formation comprises 1,250 m of alluvial, fluvial, lacustrine, and volcanic rocks deposited in a basin formed in response to regional extension during mid- Tertiary time in southeastern Arizona. During deposition, the locations and composition of sediment source areas varied as contemporaneous uplift occurred adjacent to the basin. The lower half of the formation was deposited as alluvial fans that prograded northward, westward, and southward; the upper half was deposited during southwestward retreat of alluvial fan deposition and the onset of lacustrine deposition. An andesite flow separates the two depositional regimes. Radiometric dates of 24.4 ± 2.6 m.y. B.P. for the andesite and 36.7 ± 1.1 m.y. B.P. for a rhyolitic tuff disconformably underlying the formation indicate that deposition occurred during Oligocene to early Miocene time. Proper stratigraphic sequencing and description, paleocurrent analysis, and gravel provenance study aided in understanding the depositional history of the formation.