This dissertation involves two different studies. The first concerns the real-time detection of microbial contamination in drinking water using intrinsic fluorescence of the microorganisms. The prototype, “Blinky”, uses LEDs that emit light at 365nm, 590nm, and 635nm for ultraviolet, amber, and red light, respectively. At 365 nm, the cellular components excited include reduced pyridine nucleotides (RPNs), flavins, and cytochromes to distinguish viable bacteria; at 590 nm, the cellular components excited include cytochromes for non-viable bacteria; at 635 nm, the cellular components excited include calcium dipicolinic acid (DPA) for spores. By using these three different wavelengths, the prototype can differentiate between viable and non-viable organisms and also has the potential to detect spores. The aim of this study was to improve the detection limit by modifying the design of the instrument and to establish the detection limit of viable and non-viable bacteria and spores. The instrument was modified by replacing existing LEDs with LEDs that had 50% more intensity. Two additional LEDs were added for amber and red light, bringing the total to four LEDs for each. The LEDs were also positioned closer to the photomultiplier tube so as to increase sensitivity. For UV, only two LEDs were used as previous. The detection limit of the viable bacteria was ~50 live bacteria/L. No change in the intrinsic fluorescence below the concentration of ~10⁸ dead bacteria/L was observed. The results for spore measurements suggested that most of the spores had germinated before or during the measurements and could not be detected. The instrument was successful in detection of viable bacteria and also differentiating viable and non-viable bacteria. The instrument was not successful in detection of spores. The second study was designed to assess the water quality of well construction in southeastern Tanzania. Three designs were tested: Msabi rope pump (lined borehole and covered), an open well converted into a closed well (uncovered well into a covered and lined well), and an open well (uncovered and may or may not be lined). The study looked at the microbial and chemical water quality, as well as turbidity. The survey included 97 water collection points, 94 wells and three rivers. For microbial analysis, heterotrophic plate count (HPC), total coliforms and E. coli tests were performed. Fifteen of these wells were further analyzed for microflora and diversity for wells comparison purposes, using culture methods, followed by polymerase chain reaction (PCR) and genome sequencing. Ten wells out of the fifteen were analyzed for calcium (water hardiness), potassium, nitrates, nitrites, chloride, fluoride, bromide, sulfate, iron, and arsenic. Two water collection points were also selected for organic compound analysis (gasoline components). All samples tested positive for coliforms. Two samples tested positive for Escherichia coli for the lined borehole (Msabi rope pump) and four samples from closed wells. All open wells tested positive for E. coli. There was more microbial diversity in open wells than the closed wells and Msabi rope pumps. Potential bacterial pathogens were detected in seven wells out of the fifteen examined. The wells that tested positive were one Msabi rope pump, one closed well; the rest were from open water sources. Open wells had high turbidity followed by closed wells. Msabi rope pumps had low turbidity comparing to the two wells designs. No traces of gasoline components were detected in any of the water sources. One well out of ten had high amounts of nitrates-nitrogen (> 10 mg/L). The results of this study showed that the Msabi rope pumps performed comparably to the closed wells in terms of microbial quality but performed better with regard to turbidity. The open wells performed poorly in terms of microbial water quality as well and turbidity. There was a statistical difference in HPC, total coliforms, E.coli numbers and turbidity between open wells, closed wells and the Msabi rope pumps. However, there was no statistical difference in HPC, total coliforms and E.coli numbers between the closed wells and Msabi rope pumps. Msabi rope pumps performed better in turbidity

[pt] O projeto de dimensionamento dos revestimentos na indústria de óleo e gás deve garantir a integridade do poço ao longo de todo o seu ciclo de vida, que pode ser de várias décadas. Um carregamento importante a ser considerado surge em consequência da produção, que movimenta os fluidos desde o reservatório até a superfície, aquecendo as partes mais rasas do poço. Este processo de aquecimento expande os fluidos de perfuração e completação que foram confinados nos anulares durante o processo de construção do poço. Esta mudança de volume do fluido é contida pela rigidez dos elementos que o mantém confinado e essa resistência à livre expansão do fluido provoca um aumento de pressão. Em alguns casos, a pressão pode tornar-se tão grande que pode levar o revestimento a colapsar, levando ao abandono de poços e a grandes perdas. Este fenômeno de aumento da pressão é conhecido na indústria do petróleo como anular pressure build-up (APB). O presente trabalho apresenta um modelo térmico para determinar o perfil de temperatura e pressão do fluido monofásico escoando em regime permanente na coluna de produção e a distribuição de temperatura ao longo de todos os elementos do poço. Como os revestimentos não são perfeitamente rígidos, um aumento de temperatura e pressão no poço acarreta na variação do volume do anular, os quais são avaliados de forma acoplada, pois a variação de volume de um anular influencia no outro, assim como os deslocamentos dos revestimentos. O estudo compara os resultados obtidos com um aplicativo comercial, apresentando boa concordância. Além disso, uma análise de sensibilidade é realizada para fornecer uma melhor compreensão do fenômeno. / [en] Casing design projects must ensure well integrity throughout its life, which can be as long as several decades. An important load to be considered appears as a consequence of production. During production, the annuli became heated from the transfer of bottom hole temperature up the well by the produced fluids. With heat-up, the fluids trapped in the annulus began to thermally expand. The expansion induces a volume enlargement, which is restrained by the stiffness of the well structure. This resistance to fluid free expansion keep the fluid confined and can produce a substantial pressure increase. In some cases, pressure may become so great that it can collapse casing, leading to well abandonment and large losses. This pressure increase phenomenon is well-known in the oil industry as annular pressure build-up (APB). In the present study, a monophasic state-state thermal model was developed to determine the oil temperature profile in the tubing and the temperature profile in all structures of the well. As casings are not perfectly rigid, temperature and pressure increase in the well results in annular volume change. Because the well consists of a sequence of casing strings that define the well annuli, the modeling of casing strains should be based on a systematic approach that considers the interaction among the various strings. The study compares results to those obtained with a commercial computer application, presenting good agreement. Further, a sensitivity analysis is performed to provide a better understanding of the phenomenon.

The objective of this study was to examine three well designs: drilled wells (20-30 m deep), closed dug wells (>5 m deep), and hand-dug open wells (<5 m deep), to determine the water quality for improving access to safe and clean water in rural communities. Heterotrophic plate count (HPC), total coliforms (TC), Escherichia coli (E. coli) and turbidity, were used to assess the water quality of 97 wells. Additionally, the study looked at the microflora diversity of the water, focusing on potential pathogens using outgrowth, PCR, and genome sequencing for 10 wells. Concentrations of TC for the open dug wells (4 x 10(4) CFU/100 mL) were higher than the drilled (2 x 10(3) CFU/100 mL) and closed dug wells (3 x 10(3) CFU/100 mL). E. coli concentration for drilled and closed dug wells was <22 MPN (most probable number)/100 mL, but higher for open wells (>154 MPN/100 mL). The drilled well turbidity (11 NTU) was within the standard deviation of the closed well (28 NTU) compared to open dug wells (49 NTU). Drilled and closed wells had similar microbial diversity. There were no significant differences between drilled and closed dug wells. The covering and lining of hand-dug wells should be considered as an alternative to improve access to safe and clean water in rural communities.

Drilling operations in deepwater (DW) or ultra-deepwater areas, even more in exploratory frontiers, have been increasingly challenging due to the operational complexities and limited available data about the subsurface conditions. In this sense, enhancing safety and minimizing the likelihood of losing well integrity and damage to the environment is a currently essential objective relating to offshore drilling activities. Hence, deepwater well designs should advance to safely meet the challenges related to the progression of well and water depths. The safe construction of these wells requires the application of suitable well design considerations that include well integrity approaches to reduce the risk of an unintended release of formation fluids (oil, gas or water) to the environment during the deepwater drilling operations, in other words a \"Blowout\" occurrence. In this study it is proposed two deepwater well architectural designs, limited to drilling stage, that safely accomplish the well targets and facing several deepwater well complexities, e.g. narrow operating envelopes. Thus, well logging and geological data of two actual pioneer wells drilled in deep and ultradeep water zones in Ceará Basin are used as a basis to construct and assess the drilling operating envelopes, to define the casing shoe depths and well barrier envelope. Furthermore, it is introduced the application of at least two independent Barrier Integrated Sets (BISs) to ensure the well integrity during the 4th phase drilling of the proposed well architectures, as it has recently been required in Brazil by the National Petroleum Agency (ANP) through \"Well Integrity Management System\" (SGIP for its acronym in Portuguese). / As operações de perfuração em áreas de águas profundas ou ultra profundas, ainda mais nas fronteiras exploratórias, têm sido cada vez mais desafiadoras devido às complexidades operacionais e aos limitados dados disponíveis sobre as condições do subsolo. Nesse sentido, aumentar a segurança e minimizar a probabilidade de perder a integridade do poço e os danos ao meio ambiente são objetivos essenciais atualmente relacionados às atividades de perfuração offshore. Portanto, os projetos de poços em águas profundas devem avançar para enfrentar com segurança os desafios associados à progressão do poço e das profundidades da água. A construção segura desses poços requer a aplicação de considerações de projeto adequadas que incluam abordagens da integridade do poço para reduzir o risco de liberação não intencional de fluidos de formação (óleo, gás ou água) para o ambiente durante as operações de perfuração em águas profundas, em outras palavras a ocorrência de \"Blowout\". Neste estudo, são propostos dois projetos arquiteturais de poços em águas profundas, limitados à etapa de perfuração, que cumprem com segurança os objetivos do poço e enfrentam várias complexidades de poços em águas profundas, por exemplo janelas operacionais estreitas. Assim, dados geológicos e de perfilagem de dois poços pioneiros perfurados nas zonas de águas profundas e ultra profundas da Bacia do Ceará são usados como base para a construção e avaliação da janela operacional, para definir as profundidades da sapata do revestimento e do conjunto das barreiras do poço. Além disso, é introduzida a aplicação de pelo menos dois Conjuntos Solidários de Barreiras (CSBs) independentes para garantir a integridade do poço durante a perfuração da 4ª fase das arquiteturas dos poços propostos, como tem sido recentemente exigido no Brasil pela Agência Nacional do Petróleo (ANP), através do \"Sistema de Gerenciamento de integridade de Poços\" (SGIP).

Ces dix dernières années, la miniaturisation des transistors MOS en technologie planaire sur silicium massif connait une augmentation considérable des effets parasites liés à la réduction de la longueur du canal. Ces effets canaux courts ont pour conséquence de dégrader les performances des transistors, rendant les circuits moins efficaces énergétiquement et plus sensibles aux phénomènes de fluctuations des procédés de fabrication. Ainsi, cette technologie fait face à une vraie barrière pour les noeuds inférieurs à 32nm.Pour répondre aux besoins des dispositifs mobiles alliant hautes performances et basse consommation, la technologie planaire sur isolant complètement désertée (FD-SOI pour Fully depleted Silicon-On-Insulator) apparaît comme une solution adaptée. En effet, grâce à son film de silicium mince et non dopé, le transistor MOS dispose d’un meilleur contrôle électrostatique du canal et d’une faible variabilité de sa tension de seuil. De plus, cette technologie offre la possibilité de moduler la tension de seuil des transistors grâce à une polarisation étendue à ±3V des caissons situés sous la fine couche d’oxyde enterré. Ainsi, cette spécificité apporte aux concepteurs de circuits intégrés un levier supplémentaire permettant de moduler les performances d’un circuit ainsi que d’en optimiser son efficacité énergétique.Le travail de recherche de thèse présenté dans ce mémoire a contribué au développement de la plateforme technologique FD-SOI pour les noeuds 28 puis 14nm. Dans un premier temps, l’exploitation d’un chemin critique extrait d’un coeur de processeur ARM Cortex-A9 a permis d’évaluer à la fois les gains intrinsèques apportés par la technologie FD-SOI ainsi que ceux produits par la modulation de la tension de seuil des transistors par polarisation du substrat. Cette technique permet ainsi de diviser jusqu’à 50 fois le courant statique d’un circuit lorsqu’il est inactif, ou encore par 2 l’énergie totale nécessaire à fréquence constante. Ces nombreuses analyses ont permis, dans un second temps, de proposer plusieurs solutions de conception visant une nouvelle fois à optimiser l’efficacité énergétique des circuits intégrés. Parmi celles-ci, la conception d’une structure à caisson unique permet notamment de résoudre les difficultés de co-intégration multi-VT classique, présentes en FD-SOI. Cette approche offre également aux concepteurs une solution performante pour les circuits fonctionnant avec une très large gamme de tensions d’alimentation. En effet, à l’aide d’une seule tension de substrat, les transistors n et p-MOS peuvent être simultanément rééquilibrés permettant ainsi de réduire fortement la tension minimale d’alimentation du circuit. / Over the last ten years, the scaling of MOSFETs in bulk planar technology is experiencing a significant increase in parasitic phenomenon driven by the reduction of the transistor channel length. These short-channel effects lead to the degradation of transistor performances, making circuits less energy efficient and more sensitive to the manufacturing process fluctuations. Therefore, this technology faces a real barrier for nodes beyond 32nm.To meet the needs of mobile devices, combining high performances and low power consumption, the planar fully depleted silicon-on-insulator (FD-SOI) technology appears to be a suitable solution. Indeed, thanks to its thin-film of silicon and an undoped channel, MOS transistors have an excellent short-channel electrostatic control and a low variability of the threshold voltage given by an immunity to random dopant fluctuation. In addition, this compelling technology enables to adjust the threshold voltage of transistors by applying a wide ±3V back-bias voltage on Wells. Thus, this specific FD-SOI feature brings to IC designers an additional lever to modulate the performance and to optimize the energy efficiency of circuits.The research work presented in this thesis has contributed to the development of FD-SOI technology platform for the 28 and 14nm nodes. Initially, a critical path extracted from an ARM Cortex-A9 processor was used to assess both the intrinsic gains provided by the FD-SOI technology and those produced by modulating the back-bias voltages. This technique enables to divide by up to 50 times the static current of circuits in standby mode, or by 2 the total energy consumption at same frequency. In the second phase, several design solutions are proposed in order to optimize the energy efficiency of circuits again. Among these, the design of a single-Well structure enables to solve the conventional multi-VT co-integration issue, occurring in FD-SOI. Moreover, this novel approach also offers an efficient solution for integrated circuits operating over a wide supply voltage range. Indeed, thanks to a single back-bias voltage, both n and p-MOS transistors could be easily balanced enabling an outstanding minimal supply voltage.

Drilling operations in deepwater (DW) or ultra-deepwater areas, even more in exploratory frontiers, have been increasingly challenging due to the operational complexities and limited available data about the subsurface conditions. In this sense, enhancing safety and minimizing the likelihood of losing well integrity and damage to the environment is a currently essential objective relating to offshore drilling activities. Hence, deepwater well designs should advance to safely meet the challenges related to the progression of well and water depths. The safe construction of these wells requires the application of suitable well design considerations that include well integrity approaches to reduce the risk of an unintended release of formation fluids (oil, gas or water) to the environment during the deepwater drilling operations, in other words a \"Blowout\" occurrence. In this study it is proposed two deepwater well architectural designs, limited to drilling stage, that safely accomplish the well targets and facing several deepwater well complexities, e.g. narrow operating envelopes. Thus, well logging and geological data of two actual pioneer wells drilled in deep and ultradeep water zones in Ceará Basin are used as a basis to construct and assess the drilling operating envelopes, to define the casing shoe depths and well barrier envelope. Furthermore, it is introduced the application of at least two independent Barrier Integrated Sets (BISs) to ensure the well integrity during the 4th phase drilling of the proposed well architectures, as it has recently been required in Brazil by the National Petroleum Agency (ANP) through \"Well Integrity Management System\" (SGIP for its acronym in Portuguese). / As operações de perfuração em áreas de águas profundas ou ultra profundas, ainda mais nas fronteiras exploratórias, têm sido cada vez mais desafiadoras devido às complexidades operacionais e aos limitados dados disponíveis sobre as condições do subsolo. Nesse sentido, aumentar a segurança e minimizar a probabilidade de perder a integridade do poço e os danos ao meio ambiente são objetivos essenciais atualmente relacionados às atividades de perfuração offshore. Portanto, os projetos de poços em águas profundas devem avançar para enfrentar com segurança os desafios associados à progressão do poço e das profundidades da água. A construção segura desses poços requer a aplicação de considerações de projeto adequadas que incluam abordagens da integridade do poço para reduzir o risco de liberação não intencional de fluidos de formação (óleo, gás ou água) para o ambiente durante as operações de perfuração em águas profundas, em outras palavras a ocorrência de \"Blowout\". Neste estudo, são propostos dois projetos arquiteturais de poços em águas profundas, limitados à etapa de perfuração, que cumprem com segurança os objetivos do poço e enfrentam várias complexidades de poços em águas profundas, por exemplo janelas operacionais estreitas. Assim, dados geológicos e de perfilagem de dois poços pioneiros perfurados nas zonas de águas profundas e ultra profundas da Bacia do Ceará são usados como base para a construção e avaliação da janela operacional, para definir as profundidades da sapata do revestimento e do conjunto das barreiras do poço. Além disso, é introduzida a aplicação de pelo menos dois Conjuntos Solidários de Barreiras (CSBs) independentes para garantir a integridade do poço durante a perfuração da 4ª fase das arquiteturas dos poços propostos, como tem sido recentemente exigido no Brasil pela Agência Nacional do Petróleo (ANP), através do \"Sistema de Gerenciamento de integridade de Poços\" (SGIP).

[pt] O objetivo deste estudo foi ampliar o conhecimento em mecânica de rochas evaporíticas e aplicar a mecânica computacional na modelagem numérica do comportamento estrutural de poços de petróleo em zonas de sal. Amostras de rochas evaporíticas de anidrita, halita, carnalita e taquidrita pertencentes à sequência evaporítica Ibura da Formação Muribeca, testemunhadas em poços de petróleo, foram submetidas a ensaios laboratoriais de mecânicas de rochas, em especial a ensaios triaxiais de fluência sob diferentes condições de estado de tensões e temperaturas. Nas mesmas condições de ensaio triaxial de fluência a taquidrita desenvolveu deformação axial específica de cerca de 107 vezes maior que a halita e 2,7 vezes maior que a carnalita, sendo que a anidrita permanece essencialmente indeformável. Para os ensaios triaxiais de fluência com a halita na temperatura de 86 graus Celsius foi possível definir o mecanismo duplo de deformação por fluência, enquanto que para a carnalita e a taquidrita isto ocorreu nas temperaturas de 130 e 86 graus Celsius, respectivamente. A taxa de deformação por fluência em regime permanente obtida por simulação numérica reproduziu fielmente os resultados experimentais dos ensaios triaxias de fluência, com erro relativo inferior a 1 por cento. Através dos ensaios laboratoriais foram obtidos os parâmetros geomecânicos de fluência das rochas ensaiadas e a seguir aplicados nos modelos numéricos de simulação, construídos para avaliar a influência de diversos parâmetros nos estudos de estabilidade de poços e integridade de revestimentos. A desconsideração da interação geomecânica entre estruturas salíferas e o maciço hospedeiro pode conduzir a falhas na perfuração de poços próximos a tais estruturas devido ao processo de halocinése do sal que altera o estado de tensões gravitacional. / [en] The aim of this study was to increase knowledge of evaporitic rock mechanics and apply computational mechanics in numerical modeling of structural behavior of oil wells in areas of salt. Evaporitic rock samples of anhydrite, halite, carnallite e tachyhydrite and belonging to the evaporitic sequence Ibura from the Muribeca formation, coring in oil wells, were subjected to laboratory tests of rock mechanics, especially the triaxial creep under different states of stress and temperature. Under the same conditions of triaxial creep tachyhydrite developed specific axial strain rate about 107 times that of halite and 2.7 times that of carnallite, and anhydrite remains essentially undeformed. For the triaxial creep of halite in the temperature of 86 degrees Celsius it was possible to define the double mechanism creep law, while for carnallite and tachyhydrite this occurred at temperatures of 130 and 86 degrees Celsius, respectively. The creep rate in steady state condition obtained by numerical simulation accurately reproduced the experimental results of the triaxial creep tests, with a relative error less than 1 percent. Through laboratory tests geomechanical creep parameters of the tested rocks were obtained and then applied in numerical simulation models, designed to evaluate the influence of various parameters in the well stability and casing design. The lack of consideration of the geomechanical interaction between the salt structures and the host rock can lead to drilling failures in wells near such structures due to the salt halokinesis process that changes the gravitational stress state.

[pt] Este trabalho apresenta o crescimento de pressão no anular causado pela fluência do sal e relaciona com o cálculo deste fenômeno quanto ao efeito térmico, que é normalmente conhecido por APB (annular pressure build-up). Este fenômeno não é modelado em softwares comerciais e deve ser considerado em poços de pré-sal. O cálculo de APB considera três mecanismos geradores de pressão no anular: expansão térmica do fluido do anular, expansão do tubing e influxo e efluxo do fluido confinado no anular. Mudanças no volume do anular, causados pela fluência do sal, podem ser tratadas como um quarto mecanismo, equivalente ao influxo de fluido no cálculo do APB. O cálculo deste fenômeno pode ser incorporado a um modelo de cálculo acoplado ( multistring casing design ) através da programação do APB causado pelo efeito de expansão térmica dos fluidos confinados e o APB causado pela fluência do sal. Para isso é necessário adotar um modelo constitutivo para descrever o comportamento de fluência desta rocha em função do estado de tensão, perfil de temperatura, tipo de sal, tempo decorrido, energia de ativação e outros fatores. Os efeitos de APB devido à fluência do sal podem ser mais pronunciados quando a sapata do revestimento é assentada em um intervalo de sal com elevado gradiente de sobrecarga e elevado gradiente geotérmico. Não considerar o efeito da fluência do sal no crescimento de pressão do anular (APB) pode causar um dimensionamento inadequado de revestimento ou packoff e levar a perda da integridade do poço. / [en] This paper presents the annular pressure build-up caused by salt creep and link to current calculation of this phenomenon due to thermal effect, which is commonly known as APB. This phenomenon is not currently modeled on commercial software and should be considered in subsalt wells. The calculation of APB considers three generator mechanisms: thermal expansion of annular fluid, influx or efflux and tubing buckling. Changes in the annular volume, caused by salt creep, may be treated as a fourth mechanism, equivalent to the influx in current calculation of APB. The calculation of this phenomenon can be incorporated into a multistring casing design model by programming the thermal expansion effect and the APB caused by salt creep. This requires adopting a constitutive model to describe the creep behavior of rock for differential stress, temperature profile, salt type, salt thermal activation and other factors. When the casing shoe is seated in deep salt sections with high overburden gradient and high temperature from the produced hydrocarbons, effects of APB due to salt creep and thermal effects may be more pronounced. Not considering the salt creep effect in the annular pressure build-up (APB) can lead to inadequate casing design and possible loss of well integrity.