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The progress of the silicon-based complementary-metal-oxide-semiconductor (CMOS) technology is mainly contributed to the scaling of the individual component. After decades of development, the scaling trend is approaching to its limitation, and there is urgent needs for the innovations of the materials and structures of the MOS devices, in order to postpone the end of the scaling. Atomic layer deposition (ALD) provides precise control of the deposited thin film at the atomic scale, and has wide application not only in the MOS technology, but also in other nanostructures. In this dissertation, I study rapid thermal processing (RTP) treatment of thermally grown SiO2, ALD growth of SiO2, and ALD growth of high-k HfO2 dielectric materials for gate oxides of MOS devices. Using a lateral heating treatment of SiO2, the gate leakage current of SiO2 based MOS capacitors was reduced by 4 order of magnitude, and the underlying mechanism was studied. Ultrathin SiO2 films were grown by ALD, and the electrical properties of the films and the SiO2/Si interface were extensively studied. High quality HfO2 films were grown using ALD on a chemical oxide. The dependence of interfacial quality on the thickness of the chemical oxide was studied. Finally I studied growth of HfO2 on two innovative interfacial layers, an interfacial layer grown by in-situ ALD ozone/water cycle exposure and an interfacial layer of etched thermal and RTP SiO2. The effectiveness of growth of high-quality HfO2 using the two interfacial layers are comparable to that of the chemical oxide. The interfacial properties are studied in details using XPS and ellipsometry.

Thesis (PhD)--University of Stellenbosch, 2002. / ENGLISH ABSTRACT: The main aim of this research programme was to compare the relative performance of different insulator materials used in South Africa when subjected to a severe marine pollution environment. A test programme and procedure, test facility and instrumentation were established. Some novel instrumentation and monitoring equipment were developed and built specifically for this research programme, supported by data analysing software programs. In order to compare material performance only, all non-material design variables between the test insulators had to be removed (e.g. creepage distance, connecting length, inter-shed spacing, profile, etc.). To achieve this some of the test insulators had to be specially manufactured. Leakage current, electrical discharge activity, climatic and environmental data was collected successfully over a one-year test period, starting with new test insulators. The peak and energy values of the leakage current were identified as the two main parameters needed to describe the leakage current activity on the test insulators. A correlation was found between the climatic and environmental data and the leakage current data, and it was found that the leakage current can be determined successfully from some of the climatic and environmental parameters monitored by using multiple regression techniques. Surface conductivity and energy were found to be the best parameters to show the maximum and continuous interaction of the insulator material surface with the electrolytic pollution layer. A natural ageing and pollution test procedure was developed, which has become a South African standard and is gaining international acceptance. A model and hypothesis are proposed to describe the electrical discharge activity that takes place on the test insulators and explain the difference in leakage current performance of the various materials. Keywords: Insulator, Pollution, High Voltage, Leakage current, Material performance. / AFRIKAANSE OPSOMMING: Die hoofdoel van hierdie navorsingsprogram was om die relatiewe prestasie van verskillende isolatormateriale wat in Suid-Afrika gebruik word te vergelyk in 'n swaar besoedelde marine omgewing. 'n Toetsprogram en prosedure, toets fasiliteit en instrumentasie is gevestig. 'n Paar nuwe instrumente en moniteer toerusting is ontwikkel en gebou spesifiek vir hierdie navorsingsprogram, gesteun deur data analise sagteware programme. Ten einde slegs materiaalprestasie te vergelyk, moes alle nie-materiaal ontwerpsveranderlikes tussen die toetsisolators verwyder word (bv. kruipafstand, konnekteer lengte, tussen-skerm spasiëring, profiel, ens.). Om dit reg te kry moes sommige van die toetsisolators spesiaal vervaardig word. Lekstroom, elektriese ontladingsaktiwiteit, klimaat en omgewingsdata is suksesvol versameloor 'n een-jaar toetsperiode, beginnende met nuwe toets isolators. Die piek en energie waardes van die lekstroom is identifiseer as die twee hoof parameters wat nodig is om die lekstroomaktiwiteit op die toetsisolators te beskryf. 'n Korrelasie is gevind tussen die klimaat- en omgewingsdata en die lekstroom data, en dit is gevind dat die lekstroom data suksesvol bepaal kan word van sekere van die klimaat- en omgewingsparameters wat gemoniteer is deur veelvoudige regressie tegnieke te gebruik. Oppervlakskonduktiwiteit en energie is gevind die beste parameters te wees om die maksimum en kontinue interaksie van die isolatormateriaaloppervlak met die elektrolitiese besoedelingslaag aan te toon. 'n Natuurlike veroudering en besoedeling toetsprosedure is ontwikkel, wat 'n Suid-Afrikaanse standaard geword het en besig is om internastionale aanvaarding te wen. 'n Model en hipotese word voorgestelom die elektriese ontladingsaktiwiteit wat op die toetsisolators plaasvind te beskryf en om die verskil in lekstroomprestasie van die verskeie materiale te verduidelik. S/eufelwoorde: Isolator, Besoedeling, Hoog Spanning, Leek stroom, Materiaal prestasie.

Interactive handheld electronic displays use hydrogenated amorphous silicon (a-Si:H) thin film transistor (TFT) as a backplane and a Touch Screen Panel (TSP) on top as an input device. The low mobility and instability of a-Si:H TFT threshold voltage are major two issues for driving constant current as required for Active Matrix Organic Light Emitting Ddiode (AMOLED) displays. Low mobility is compensated by increasing transistor width or resorting to more expensive material TFTs. On the other hand, the ever increasing threshold voltage shift degrades the drain current under electrical operation causing OLED display to dim. Mutual capacitive TSP, the current cell phone standard, requires two layers of metals and a dielectric to be put in front of the display, further dimming the device and adding to visual noise due to sun reflection, not to mention increased integration cost and decreased yield. This thesis focuses on the aforementioned technological hurdles of a handheld electronic display by proposing a dual-gate TFT used as an OLED current driving TFT and a novel phase response readout scheme that can be applied to a one metal track TSP. Our dual-gate TFT has shown on average 20% increase in drive current over a single gate TFT fabricated in the same batch, attributed to the aid of a top channel to the convention bottom channel TFT. Furthermore the dual gate TFT shows three times the Poole-Frenkel current than the single gate TFT attributed to the increase in gate to drain overlap. The dual-gate TFT shows a 50% improvement in threshold voltage shift over a single gate TFT at room temperature, but only ~8% improvement under 75ºC. This is an important observation as it shows an accelerated threshold voltage shift in the dual-gate. This difference in the rate of threshold voltage change under varying temperature is attributed to the difference in interface states, supporting Libsch and Kanicki’s multi-level temperature dependant dielectric trapping model. The phase response TSP readout scheme requires IC only on one side of the display. Cadence Spectre simulation results showed that both touch occurrence and touch position can be obtained using only one metal layer.

Thermal management and energy input are required to maintain working fluids, i.e., liquefied natural gas, liquid nitrogen, and multi-phase fluids within their optimal working conditions. Increasing a pipes thermal resistance, e.g., utilizing vacuum insulation, is one method of minimizing energy input. A dual-wall concentric pipe employing a vacuum in the annulus, along with low emissivity surface coatings, is an achievable and economically viable solution. In this study, an experimental setup was designed and utilized to measure the air leakage mass flow rate for single-wall unloaded and mechanically loaded dual-wall fiber reinforced polymeric composite specimens. The mass flow rates were used to develop intrinsic permeability coefficients to quantify leakage, and to determine the maximum serviceable pipe length for a mechanical vacuum pump. In addition, thermal resistance equations were developed to quantify the theoretical heat loss, and an economic study was performed to ascertain the viability for three applications. / Applied Mechanics

Made available in DSpace on 2015-05-14T12:56:03Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 2756793 bytes, checksum: 52c334e99949464b4e3237ddf1e202c6 (MD5) Previous issue date: 2014-02-25 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / The transport of materials through the tooth enamel is conventionally derived from the diffusion process, which leads to a number of limitations, because the pores of the enamel are extremely small, requiring a certain extension, as occurs in adhesive techniques by the etching process. An alternative method to this technique is the electrokinetic flow (EKF), which promotes the unidirectional flow of substances through the pores of the enamel by applying an external electric field. Based on this premise it was promoted the infiltration of a composite resin with low viscosity (Icon DMG, Hamburg, Germany) on the surface of 20 extracted human teeth by EKF, using an electric field (1.5V) in two stages: (1) infiltration of potassium chloride 0.1M (KCl) during 3h and (2) infiltration of the resin during 2h. Longitudinal histological sections of &#8776; 100&#956;m were analyzed by fluorescence microscopy and polarized light microscopy associated with the "polscopesingle"system, after 24h of dehydration and along 50, 100, 150, 200, 250, 300, 350, 400, 450 and 500&#956;m deep. Electric voltage (&#956;A) presented to be positive during infiltration. Images from Fluorescence Microscopy revealed fluorescence of the infiltrated enamel areas for all samples, from the surface to the dentin-enamel junction (DEJ), indicating the formation of a hybrid layer with average depth of 1627.66 &#956;m and a standard deviation of 284.20 &#956;m. The records of the phase delay during dehydration of the infiltrated and non-infiltrated areas did not present changes in the infiltrated area. It was observed that the water was replaced by the resin (p<0.000001), with high effect size (>0.8). Based on these results, it was concluded that the EKF resulted in infiltration of the resin into the enamel nanochannels. / O transporte de materiais através do esmalte dentário é limitado já que convencionalmente depende do processo de difusão, em virtude do volume nanométrico dos poros do esmalte. Um método alternativo pode ser o uso do Fluxo Eletrocinético (FEC), que promove o fluxo unidirecional de substâncias através dos poros do esmalte pela aplicação de um campo elétrico externo. Por conseguinte, este estudo promoveu a infiltração de resina fluida na superfície de 20 dentes humanos extraídos através do FEC, utilizando um campo elétrico de 1,5 volt em duas etapas: (1) infiltração de Cloreto de Potássio (KCl) 0,1M por 3h (2) infiltração da resina Icon (DMG, Alemanha) por 2h. Cortes histológicos por desgaste com &#8776; 100&#956;m foram analisados por Microscopia de Fluorescência (MF) e por Microscopia de Luz Polarizada (MLP) associada ao sistema single polscope , durante a desidratação das amostras por um período de 24h e analisando pontos histológicos a 50, 100, 150, 200, 250, 300, 350, 400, 450 e 500&#956;m a partir da superfície de áreas infiltradas e não infiltradas. A variação da corrente elétrica (mA) mostrou-se positiva durante a infiltração. As imagens da MF demonstraram fluorescência do esmalte na região infiltrada desde a superfície até a junção amelo-dentinária (JAD), indicando a formação de uma camada híbrida com profundidade média de 1627,66 &#956;m e desvio padrão de 284,20 &#956;m. Comportamentos distintos foram identificados para as áreas infiltrada e não infiltrada durante a desidratação. A área não infiltrada perdeu água, conforme verificado através da redução do retardo de fase. A área infiltrada não perdeu água, uma vez que o retardo manteve-se constante, sugerindo que a água fracamente aderida foi substituída pela resina durante a infiltração. As diferenças estatísticas entre os pontos histológicos das duas áreas foram calculadas através do teste de Mann-Whitney, com nível de significância de 5%, confirmando que a água foi substituída pela resina (p< 0,000001), com alta magnitude do efeito (>0,8). Portanto, pode-se concluir que a utilização do FEC resultou na infiltração da resina nos nanocanais do esmalte, formando camada híbrida de grande profundidade.

Leakage and blockage of oil and gas pipeline systems, water pipelines, pipe-work of process plants and other pipe networks can cause serious environmental, health and economic problems. There are a number of non-destructive testing (NDT) methods for detecting these defects in pipeline systems such as radiographic, ultrasonic, magnetic particle inspection, pressure transient and acoustic wave methods. In this study, the acoustic wave method and a modal frequency technique, which based on a roving mass method, are used. The aim of the thesis is to employ acoustic wave propagation based methods in conjunction with stationary wavelet transform (SWT) to identify leakage and blockage in pipe systems. Moreover, the research is also aimed at using the difference of modal frequencies of fluid-filled pipes with and without defects and a roving mass, and consequently, to develop a roving mass-based defect detection method for pipelines. In the study, the acoustic finite-element analysis (AFEA) method is employed to simulate acoustic wave propagation in small and large air-filled water-filled straight pipe and pipe networks with leakage and blockage but without flow. Computational fluid dynamics (CFD) analysis was also employed to simulate acoustic wave propagation in air-and water-filled pipes with flow, leakage and blockage. In addition, AFEA was used to predict the modal frequencies of air- and water-filled pipes with leakage and blockage in the presence of a roving mass that was traversed along the axis of the pipes. Experimental testing was conducted to validate some of the numerical results. Two major experiments were performed. The first set of experiments consisted of the measurement of acoustic wave propagation in a straight air-filled pipe with leakage and blockage. The second set of experiments concerned the measurement of acoustic wave propagation in an air-filled pipe network comprising straight pipe, elbows and T-piece and flange. The AFEA and CFD analysis of fluid-filled pipe can be used to simulate the acoustic wave propagation and acoustic wave reflectometry of a fluid-filled pipe with leakage and blockage of different sizes down to a small leakage size of 1mm diameter and a blockage depth of 1.2mm in a pipe. Similarly, the AFEA method of a static fluid-filled pipe can be used to simulate acoustic wave modal frequency analysis of a fluid-filled pipe with leakage and blockage of different sizes down to a leakage of 1mm diameter and a blockage depth of 1.2mm. Moreover, the measured signal of acoustic wave propagation in an air-filled can be successfully decomposed and de-noised using the SWT method to identify and locate leakages of different sizes down to 5mm diameter, and small blockage depth of 1.2mm. Also, the SWT approximation coefficient, detail and de-noised detail coefficient curves of an air-filled pipe with leakage and blockage and a roving mass give leakage and blockage indications that can be used to identify, locate and estimate the size of leakage and blockage in a pipe.

L'écoulement de jeu est un phénomène très important dans les turbomachines. Il provient du mouvement relatif entre la pale et la paroi d'extrémité, et la différence de pression à travers la pale. L'écoulement de jeu est extrêmement complexe pour sa nature tridimensionnelle et instable, et son existence conduit à de nombreux effets défavorables, par exemple, les pertes de performance aérodynamique et les émissions de bruit. C'est pourquoi l'écoulement de jeu a motivé de nombreuses recherches expérimentales et numériques. Afin d'améliorer la compréhension du écoulement de jeu et le bruit de large bande associé, une campagne de recherche a été menée au LMFA. En ce qui concerne l'écoulement de jeu, cette campagne de recherche comprend une expérience avec des technologies de mesure avancées, un calcul zonal LES et une série de calculs RANS / URANS. L'expérience et les simulations considèrent une configuration simple de l'écoulement de jeu à un faible nombre de Mach. Les résultats expérimentaux et numériques sont analysés de façon systématique et approfondie dans la présente étude. Enfin, des efforts sont déployés pour la modélisation et la prédiction du bruit à large bande avec des résultats expérimentaux et numériques. On observe dans l'expérience un système à multiple-tourbillon, avec une tourbillon de jeu intense. Les différentes analyses sur les caractéristiques d'écoulement montrent un bon accord entre l'expérience et le ZLES dans la région du écoulement de jeu. L'approche zonale (RANS-LES) s'avère être un outil puissant pour fournir une description détaillée du écoulement de jeu, avec un coût de calcul limité. Cependant, les calculs RANS et URANS surestiment globalement la diffusion de la tourbillon. En outre, l'oscillation du tourbillon de jeu est étudiée en utilisant des champs instantanés de PIV et l'amplitude d'oscillation est évaluée. La réponse dynamique de la tourbillon de jeu est également étudiée avec URANS aux fréquences choisies. Deux modèles de prédiction du bruit en champ lointain, correspondant à deux sources acoustiques différentes, sont reformulés et mis en oeuvre avec les données de champ proche des simulations numériques. Ces prédictions sont comparées aux mesures à champ lointain. En utilisant les données ZLES, le modèle de l’écoulement de jeu sur-estime le bruit généré dans la région de jeu. Le modèle de bruit de bord de fuite est implémenté avec les données ZLES et les données RANS et fournit une très bonne prédiction dans une large bande de fréquence. / The tip-leakage flow is a common flow feature in turbomachines. It originates from the relative motion between the blade tip and the end-wall, and the pressure difference across the blade. The tip-leakage flow is extremely complex for its three-dimensional unsteady nature, and its existence leads to many unfavourable effects, such as aerodynamic performance losses and noise emissions. These issues have motivated extensive experimental and numerical researches from both aerodynamic and aeroacoustic points of view. In order to improve the understanding of the tip-leakage flow and its associated broadband noise, a research campaign has been carried out at LMFA. Regarding the tip-leakage flow, this research campaign includes an experiment with advanced measurement technologies, a zonal LES computation and a series of RANS/URANS computations. Both the experiment and the simulations consider a single-airfoil configuration at low Mach number. Experimental and numerical results are analysed systematically and thoroughly in the current study. Finally, efforts are put on the broadband noise modelling and prediction based on the experimental and numerical results. A multi-vortex system with an intense tip-leakage vortex is observed in the experiment. The various analyses of the flow characteristics show a good agreement between the experiment and the ZLES in the blade tip region. The zonal (RANS-LES) approach proves itself to be a powerful tool to provide a detailed description of the tip-leakage flow, with a limited computational cost. However, the RANS and URANS computations globally over-estimate the diffusion of the tip-leakage vortex. Furthermore, the random oscillation of the tip-leakage vortex is investigated using PIV instantaneous flow fields and the wandering amplitude is evaluated. The dynamic response of the tip-leakage vortex is also studied with URANS at selected frequencies. Two far-field noise prediction models, corresponding to two different acoustic sources, are reformulated and implemented with the near-field data from the numerical simulations. These predictions are compared to the far-field measurements. Using the ZLES data as input, the blade-tip self-noise model is found to over-estimate the noise generated in the blade-tip region. The trailing-edge noise model is implemented with the time-averaged ZLES and the RANS near-field data, and yields a very good prediction within a broad range of frequency.