Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments. / QC 20101110

No description available.

Escoamentos bifásicos estão presentes em diversos processos naturais e industriais, como na indústria de petróleo. Podem apresentar-se em diferentes configurações topológicas, ou, padrões de escoamento, entre eles o escoamento estratificado ondulado e o estratificado com mistura na interface. Os escoamentos bifásicos estratificados óleo-água têm sido utilizados como uma forma conveniente de evitar a formação de emulsões de água em óleo em oleodutos e possuem uma ocorrência comum em poços de petróleo direcionais. Quando a onda interfacial ultrapassa determinado limite geométrico e cinemático, surge o fenômeno do entranhamento de gotas, representado por misturas entre as fases junto à interface que promovem um aumento na queda de pressão. Modelos têm sido apresentados pela literatura na tentativa de descrever o fenômeno do entranhamento de gotas. Neste trabalho é apresentada uma nova proposta de modelagem matemática unidimensional para o entranhamento de gotas com o objetivo de melhorar a previsão dos parâmetros envolvidos, em especial, da fração volumétrica de óleo e da queda de pressão bifásica. Também foi utilizada simulação numérica computacional, CFD (Computational Fluid Dynamics), com o uso de software comercial para obtenção dos valores dos parâmetros do escoamento estratificado ondulado óleo-água (fração volumétrica de óleo, queda de pressão, amplitude e comprimento da onda interfacial). Os resultados da modelagem fenomenológica para entranhamento e os de CFD foram comparados com bancos de dados experimentais. Os resultados em CFD mostram concordância com os resultados experimentais, tanto na análise qualitativa das propriedades geométricas das ondas interfaciais, quanto na comparação direta com os dados para fração volumétrica e queda de pressão. Os resultados numéricos da modelagem fenomenológica para fatores de entranhamento apresentam boa concordância com dados da literatura. / Two-phase flows are present in many natural and industrial processes, such as in the oil industry. They may be found arranged in several flow patterns, including the wavy stratified flow and the stratified with mixing at the interface. The stratified oil-water flow has been used as a convenient way to avoid the formation of emulsions of water in oil and have a common occurrence in directional oil wells. When the interfacial wave exceeds a certain geometric and kinematic limit the phenomenon of drop entrainment arises at the interface, causing an increase of pressure drop. Models have been presented in the literature in an attempt to describe the phenomenon of drop entrainment. In this work, we present a new method for the one-dimensional mathematical modeling of entrainment in order to improve the prediction of oil volume fraction and pressure drop. It was also used a commercial computational fluid dynamics tool (CFD) to obtain the values of flow parameters of wavy stratified oil-water flow, such as oil volume fraction, pressure drop, amplitude and length of the interfacial waves. The results of the phenomenological modeling for entrainment and CFD were compared with experimental databases. The CFD results are in agreement with the experimental results in both the qualitative analysis of the geometric properties of the interfacial waves and in direct comparison with oil-volumetric-fraction and pressure-drop data. The numerical results of the phenomenological model for entrainment factors are in agreement with data from the literature.

Trabalhos de cunho historiográfco que visam resgatar a produção científica e tecnológica de um país tem auxiliado a compreender e a classificar seu nível de desenvolvimento frente a estas questões. Com este trabalho, espera-se dar início no Departamento de Hidráulica e Saneamento (SHS) da Escola de Engenharia de São Carlos, a um levantamento historiográfico da produção tecnológica e científica de seus pós-graduandos e professores. Para tanto, resgata-se um trabalho realizado entre o final da década de 1960 e início da década de 1970, pela Cátedra de Mecânica dos Fluidos (precursora do SHS), que teve como objetivo prever a vazão de água do túnel 2 do Sistema Cantareira de abastecimento de água para a região metropolitana de São Paulo. Nesta galeria foi realizado um ensaio original com circulação de ar, para o qual foram desenvolvidos métodos e técnicas a fim de verificar a vazão e auxiliar no seu dimensionamento, para garantir uma adução de 33 \'M POT.3\'/s. Mediante o levantamento, organização cronológica e análise dos documentos produzidos pelos autores do referido ensaio, resgatam-se as influências teóricas que nortearam as metodologias, as técnicas e tecnologias e analisam-se, de acordo com os registros documentais, a execução e resultados alcançados pelos ensaios. / Works that have as objective to review the scientific and technological production of a country have helped to understand and to measure its level of development regarding these questions. With this work, hopefully a historical survey of the technological and scientific production of its graduate students and teachers begins at the Departamento de Hidráulica e Saneamento (SHS) at the Escola de Engenharia de São Carlos. In this way, a work that was carried out between the end of the 1960\'s and beginning of the 1970\'s, by the chair of fluid mechanics (precursor of the SHS), which had as objective to foresee the water flow rate at tunnel 2 of the Cantareira water project for the metropolitan area of São Paulo. An original test using air circulation was carried out in the tunnel. Methods and techniques were developed in order to verify the flow rate and check its size, to guarantee 33 \'M POT.3\'/s of flow. The documents produced by the authors of the test were surveyed, organized chronologically and analyzed, seeking to infer the theoretical influences that had guided the methodologies, to describe the techniques and technologies and to analyze, in accordance with the document registers, the execution and results reached from the tests.

O escoamento estratificado óleo-água é comum na indústria de petróleo, em particular em poços direcionais e oleodutos. Estudos recentes mostram que o fenômeno de transição de padrões de escoamento de fases separadas pode estar relacionado à estrutura ondulatória da interface do escoamento (problema de estabilidade hidrodinâmica). A transição do padrão estratificado ao padrão estratificado com mistura na interface foi estudada por diversos autores sendo que a física envolvida está clara, e o fenômeno ocorre pelo arrancamento de gotículas da crista da onda interfacial. Técnicas baseadas na análise temporal da estabilidade hidrodinâmica para a proposição de critérios de transição são comumente encontradas na literatura. Entretanto, para certas condições de escoamento, foi observado que o padrão de escoamento estratificado muda ao longo da tubulação. O escoamento adentra a tubulação como estratificado ondulado e alguns diâmetros após a entrada ocorre a transição para o padrão bolhas alongadas. Foi também observado que o ponto no espaço em que o fenômeno ocorre varia com a elevação ou decréscimo das velocidades superficiais das fases. Aparentemente, tal fenômeno ocorre devido a efeitos de tensão interfacial e ângulo de contato. O modelo de dois fluidos unidimensional, a teoria da estabilidade hidrodinâmica linear (análise espacial) e dados experimentais das propriedades da onda interfacial são utilizados para estudo do escoamento, levando a um novo critério de transição em função da velocidade da onda interfacial. O fenômeno de transição espacial do padrão estratificado ocorre fora da região delimitada como estável pela teoria linear; assim, efeitos não lineares são predominantes e uma teoria que leve em consideração tais efeitos se faz necessária. O método das características foi utilizado e buscou-se prever o ponto no espaço em que a transição ocorre. O estudo experimental foi realizado em montagem experimental do Laboratório de Engenharia Térmica e Fluidos; dados experimentais permitiram a obtenção de uma nova carta de fluxo óleo-água e propriedades da onda interfacial. As comparações entre dados e previsões dos modelos são encorajadoras. / The stratified oil-water flow pattern is of common occurrence in the petroleum industry, especially in offshore directional wells and pipelines. Previous studies have shown that the phenomenon of flow pattern transition in stratified flow can be related to the interfacial wave structure (problem of hydrodynamic instability). The transition from stratified flow to stratified with mixture at the interface has been studied by several authors and the physics behind the phenomenon has been already explained, basically by the tearing of droplets from the interfacial wave crest. Techniques based on a temporal analysis of the hydrodynamic stability for the proposition of transition criteria are often found in the literature. However, at certain inlet flow conditions, it was observed that the flow pattern changes along the test line. The flow enters the test line as wavy stratified flow and then, several diameters from the pipe inlet, the transition to elongated-bubbles flow occurs. It was also observed that the location where the transition occurs also changes depending on the phases superficial velocities. It seems that this phenomenon occurs due to interfacial tension and contact angle effects. The one-dimensional two-fluid model, linear stability theory (spatial approach) and experimental data of the interfacial wave properties are used to study the flow and a new transition criterion based on the wave celerity is proposed. The stratified-flow spatial transition occurred outside the region delimitated as stable by the linear theory; so nonlinear effects are prominent. The method of characteristics was used as an attempt to predict the point in space at which the transition occurs. The experimental work was done at the experimental facility of the Thermal-fluids Engineering Laboratory; experimental data allowed a new oil-water flow map and interfacial wave properties were acquired. The agreement between data and prediction is encouraging.

Ce travail est consacré à la modélisation mathématique et numérique des écoulements eau-air en conduite qui interviennent notamment dans les centrales de production d’électricité ou les réseaux d’eaux usées. On s’intéresse particulièrement aux écoulements mixtes caractérisés par la présence de régimes stratifiés pilotés par des ondes gravitaires lentes, de régimes en charge ou secs (conduite remplie d’eau ou d’air) pilotés par des ondes acoustiques rapides, et de poches d’air piégées. Une modélisation précise de ces écoulements est nécessaire afin de garantir le bon fonctionnement du circuit hydraulique sous-jacent. Alors que la plupart des modèles disponibles dans la littérature se concentrent sur la phase eau en négligeant la présence de l’air, un modèle bicouche compressible prenant en compte les interactions eau-air est proposé dans cette thèse. Sa construction réside dans l’intégration des équations d’Euler barotropes sur la hauteur de chaque phase et dans l’application de la contrainte hydrostatique sur le gradient de pression de l’eau. Le modèle obtenu est hyperbolique et satisfait une inégalité d’entropie en plus d’autres propriétés mathématiques notables, telles que l’unicité des relations de saut ou la positivité des hauteurs et densités de chaque phase. Au niveau discret, la simulation d’écoulements mixtes avec le modèle bicouche compressible soulève plusieurs défis en raison de la disparité des vitesses d’ondes caractérisant chaque régime, des processus de relaxation rapide sous-jacents, et de la disparition de l’une des phases dans les régimes en charge ou sec. Une méthode à pas fractionnaires implicite-explicite est alors développée en s’appuyant sur la relaxation rapide en pression et sur le mimétisme avec les équations de Saint-Venant pour la dynamique lente de la phase eau. En particulier, une approche par relaxation permet d’obtenir une stabilisation du schéma en fonction du régime d’écoulement. Plusieurs cas tests sont traités et démontrent la capacité du modèle proposé à gérer des écoulements mixtes incluant la présence de poches d’air piégées. / The present work is dedicated to the mathematical and numerical modelling of transient air-water flows in pipes which occur in piping systems of several industrial areas such as nuclear or hydroelectric power plants or sewage pipelines. It deals more specifically with the so-called mixed flows which involve stratified regimes driven by slow gravity waves, pressurized or dry regimes (pipe full of water or air) driven by fast acoustic waves and entrapped air pockets. An accurate modelling of these flows is necessary to guarantee the operability of the related hydraulic system. While most of available models in the literature focus on the water phase neglecting the air phase, a compressible two-layer model which accounts for air-water interactions is proposed herein. The derivation process relies on a depth averaging of the isentropic Euler set of equations for both phases where the hydrostatic constraint is applied on the water pressure gradient. The resulting system is hyperbolic and satisfies an entropy inequality in addition to other significant mathematical properties, including the uniqueness of jump conditions and the positivity of heights and densities for each layer. Regarding the discrete level, the simulation of mixed flows with the compressible two-layer model raises key challenges due to the discrepancy of wave speeds characterizing each regime combined with the fast underlying relaxation processes and with phase vanishing when the flow becomes pressurized or dry. Thus, an implicit-explicit fractional step method is derived. It relies on the fast pressure relaxation in addition to a mimetic approach with the shallow water equations for the slow dynamics of the water phase. In particular, a relaxation method provides stabilization terms activated according to the flow regime. Several test cases are performed and attest the ability of the compressible two-layer model to deal with mixed flows in pipes involving air pocket entrapment.

Les vallées tunnels sont les structures de drainage d'eau de fonte les plus imposantes de l'environnement sous-glaciaire. L'inaccessibilité des milieux sous-glaciaires actuels limitent nos connaissances des mécanismes impliqués dans leurs formations, des paramètres contrôlant leur morphologie et de leurs influences sur la dynamique glaciaire. Ce travail présente une nouvelle approche expérimentale visant à mieux contraindre la formation et le fonctionnement des systèmes de vallées tunnels. Cette approche repose sur le développement d'un nouveau dispositif expérimental simulant la circulation d'eau pressurisée au sein d'un substrat poreux et perméable sous une couverture visqueuse. Les résultats des expériences menées avec ce dispositif ont permis de déterminer des relations étroites entre les paramètres du substrat et les modalités de l'écoulement d'eau sur la formation et la morphologie des vallées tunnels. Les résultats issus des expériences démontrent que ce dispositif permet de recréer des systèmes de vallées tunnels. L'étude de ces vallées expérimentales suggèrent que la topographie du substrat et la production d'eau de fonte joue un rôle primordial sur la genèse des vallées tunnels et sur leurs morphologies. Deux morphotypes de vallées tunnels ont pu être identifiés avec des morphologies et des mécanismes de formation indépendants. L'analyse de la dynamique de la calotte sus-jacente a permis de mettre en évidence un lien étroit entre le développement des vallées tunnels et la dynamique des "ice streams". L'évolution de la capacité de drainage des vallées tunnels semble contrôler la dynamique glaciaire en régulant le flux de glace transitant dans les "ice streams". / Tunnel valleys are major components of the subglacial meltwater drainage system. The inaccessibility of modern subglacial environments reduces our knowledge on the mechanisms involved in tunnel valleys formation, the parameters controlling their morphology and their influence on ice-sheet dynamics. This work presents a new experimental approach aiming to better assess the processes of tunnel valleys development. This approach relies on the development of a new experimental device simulating a pressurized water flow within a porous and permeable substratum underneath a viscous layer simulating the ice-sheet. The main results of the experiments conducted with this device have demonstrated the influence of both substratum properties and meltwater drainage on tunnel valleys formation and morphology. Using the device, we first manage to reproduce tunnel valley systems experimentally. Analyses conducted on these valleys experimental valleys suggest that the substratum topography and meltwater production play a key role on tunnel valleys genesis and morphology. Two tunnel valleys morphotypes have been identified, each one being charaterized by a unique morphology and mechanism of formation. Monitoring of the experimental ice sheet during tunnel valley formation shows close relationship between tunnel valleys development and "ice streams" dynamics. The evolution of tunnel valley drainage capacity seems to have a strong influence on ice sheet stability by regulating ice flux within "ice stream corridors".

<p>The coupled transport of water and heat, involving freezing and thawing, in the road structure and its immediate environment is important to consider for optimal design and maintenance of roads and when assessing solute transport, of e.g. de-icing salt, from roads. The objective of this study was to develop mechanistic models, and measurement techniques, suitable to describe and understand water flow and heat flux in road structures exposed to a cold climate. </p><p>Freezing and thawing was accounted for by implementing new routines in two numerical models (HYDRUS1D/2D). The sensitivity of the model output to changes in parameter values and operational hydrological data was investigated by uncertainty and sensitivity analyses. The effect of rainfall event characteristics and asphalt fractures on the subsurface flow pattern was investigated by scenario modelling. The performance of water content reflectometers (WCR), measuring water content, was evaluated using measurements in two road structure materials. A numerical model was used to simulate WCR sensor response. The freezing/thawing routines were stable and provided results in agreement with laboratory measurements. Frost depth, thawing period, and freezing-induced water redistribution in a model road was greatly affected by groundwater level and type of subgrade. The simulated subsurface flow patterns corresponded well with published field observations. A new method was successful in enabling the application of time domain reflectometer (TDR) calibration equations to WCR output. The observed distortion in sampling volume for one of the road materials could be explained by the WCR sensor numerical model. Soil physical, hydrological, and hydraulic modules proved successful in simulating the coupled transport of water and heat in and on the road structure. It was demonstrated in this thesis that numerical models can improve the interpretation and explanation of measurements. The HYDRUS model was an accurate and pedagogical tool, clearly useful in road design and management.</p>

The coupled transport of water and heat, involving freezing and thawing, in the road structure and its immediate environment is important to consider for optimal design and maintenance of roads and when assessing solute transport, of e.g. de-icing salt, from roads. The objective of this study was to develop mechanistic models, and measurement techniques, suitable to describe and understand water flow and heat flux in road structures exposed to a cold climate. Freezing and thawing was accounted for by implementing new routines in two numerical models (HYDRUS1D/2D). The sensitivity of the model output to changes in parameter values and operational hydrological data was investigated by uncertainty and sensitivity analyses. The effect of rainfall event characteristics and asphalt fractures on the subsurface flow pattern was investigated by scenario modelling. The performance of water content reflectometers (WCR), measuring water content, was evaluated using measurements in two road structure materials. A numerical model was used to simulate WCR sensor response. The freezing/thawing routines were stable and provided results in agreement with laboratory measurements. Frost depth, thawing period, and freezing-induced water redistribution in a model road was greatly affected by groundwater level and type of subgrade. The simulated subsurface flow patterns corresponded well with published field observations. A new method was successful in enabling the application of time domain reflectometer (TDR) calibration equations to WCR output. The observed distortion in sampling volume for one of the road materials could be explained by the WCR sensor numerical model. Soil physical, hydrological, and hydraulic modules proved successful in simulating the coupled transport of water and heat in and on the road structure. It was demonstrated in this thesis that numerical models can improve the interpretation and explanation of measurements. The HYDRUS model was an accurate and pedagogical tool, clearly useful in road design and management.

Made available in DSpace on 2016-08-31T13:24:10Z (GMT). No. of bitstreams: 1 JeovanizelioFG_DISSERT.pdf: 2944061 bytes, checksum: b719d6cdb79773d0a7ede20c0370bab2 (MD5) Previous issue date: 2009-08-28 / The knowledge of the characteristics and dimensions of wetted bulb is substantially important in the measured of the drip irrigation. Due to the complexity of the physical phenomena involved in the infiltration and redistribution process of water in the soil, develop a mathematical model that simulates the flow of water in the soil is not a very simple task. The objective of this work was developed a mathematical model semi-analytic for predicting dimensions of wetted bulb that it depends on parameters of easy obtaining in the field, just as, the superficial diameter of the wetted bulb. The model allows the simulation of the format and dimensions of the wetted bulb for three different forms: when the diameter of the bulb is given in two depths of easy obtaining in the field, that is, in the surface of the soil and in the depth of 10 cm; starting from the superficial diameter and standards existent for the maximum depth in agreement with the texture of the soil; starting from the surfaces of answers. The mathematical model was obtained by numeric simulation of the equations that govern the flow of water in the soil, originating like this, semi-analytic solution for the formation of the wetted bulb. The model was validate, starting from field data of a soil with medium texture after compared with the simulate data. The accomplished comparisons demonstrate that the proposed model predicting the dimensions of the wetted bulb satisfactorily and it can be used as auxiliary tool in the measurement of the drip irrigation. / O conhecimento das características do bulbo molhado é substancialmente importante para o dimensionamento da irrigação por gotejamento. Devido à complexidade dos fenômenos físicos envolvidos no processo de infiltração e redistribuição de água no solo, desenvolver um modelo matemático que simule o fluxo de água no solo é uma tarefa não muito simples. O objetivo desse trabalho é desenvolver um modelo matemático semi-analítico para estimar as dimensões do bulbo molhado que depende de parâmetros de fácil obtenção no campo, tal como o diâmetro superficial do bulbo molhado. O modelo permite a simulação do formato e as dimensões do bulbo molhado por três formas diferentes: quando é dado o diâmetro do bulbo em duas profundidades de fácil obtenção no campo, isto é, na superfície do solo e na profundidade de 10 cm; a partir do diâmetro superficial e padrões existentes para a profundidade máxima de acordo com a textura do solo; a partir das superfícies de respostas. O modelo matemático foi obtido por simulação numérica das equações que governam o fluxo de água no solo, originando assim, solução semi-analítica para a formação do bulbo molhado. O modelo foi validado, a partir de dados de campo de um solo com textura média e, em seguida comparados com os dados simulados. As comparações realizadas demonstram que o modelo proposto estima satisfatoriamente as dimensões do bulbo molhado e pode ser utilizado como ferramenta auxiliar no dimensionamento da irrigação por gotejamento.