As Vibrações Induzidas por Escoamentos (VIEs) são dos problemas dinâmicos mais importantes no projeto de trocadores de calor de tipo carcaça e tubos. Esta interação fluido - estrutura pode gerar vibrações de grande amplitude dos tubos ou partes internas do equipamento, o que pode provocar o impacto entre componentes e até falha por fadiga. Várias bancadas experimentais têm sido construídas para o estudo desta interação fluido - estrutura, no entanto, alguns mecanismos de vibração, principalmente aqueles relacionados com escoamentos bifásicos, não são completamente compreendidos. Portanto, neste trabalho, o projeto de uma estrutura dinâmica para o estudo das vibrações induzidas por escoamento bifásico é apresentado. Esta estrutura é composta por um sistema de fios de aço tensionados que permitem que a primeira frequência de ressonância do tubo seja sintonizada. O tubo instrumentado foi instalado numa seção de testes de tubos rígidos em configuração triangular normal com uma razão de passo transversal e diâmetro de 1,26. Os resultados experimentais foram contrastados com uma modelagem teórica desenvolvida para esta estrutura dinâmica. Pôde-se verificar que a primeira frequência de ressonância e seu fator de amortecimento coincidem com os valores estimados pelo modelo, enquanto que a segunda frequência de ressonância apresenta valor teórico 6,6% maior do que o experimental. A seguir, um estudo experimental no ar foi desenvolvido para o reconhecimento dos modos de vibração e as frequências de ressonância da estrutura dinâmica. O fator de amortecimento no ar também foi estimado, o método de Kennedy - Pancu combinado com o algoritmo ERA foi usado para este fim. Assim que a primeira frequência de ressonância foi reconhecida e sintonizada, testes em escoamentos de água foram realizados. A influência da velocidade do escoamento monofásico de água na amplitude de vibração e nas características da Densidade Espectral (PSD) de aceleração foi analisada. Finalmente, testes em escoamento bifásico foram feitos, a sensibilidade do tubo ao escoamento bifásico fica evidente quando analisadas as amplitudes nas PSDs. Além disso, a influência da fração de vazio na amplitude de vibração e no fator de amortecimento foi revisada, no entanto, resultados de estudos anteriores não foram conferidos pelo alto amortecimento concentrado introduzido por alguns elementos construtivos utilizados. / Flow - Induced Vibration (FIV) is the most critical dynamic issue in the design of heat exchangers. This fluid - structure phenomenon may generate high amplitude vibration of tubes or structural parts, which may lead to impacts between internal components or even failure due to fatigue. Many test benches have been constructed to study this fluid - structure interactions, however, some vibration mechanisms, mostly those related to multiphase flow, are not yet fully understood. Therefore, in this work, the design of a dynamic structure for the study of multiphase flow induced vibration is presented. This structure is composed by a system of tensioned piano wires that allow the first natural frequency of the instrumented tube to be calibrated. The tube was installed in a rigid bundle configured in a normal triangular pattern with pitch-todiameter ratio of 1.26. Then, an experimental study in air environment was performed aiming at addressing the mode shapes and resonance frequencies of the dynamic structure. The damping ratio in air environment was also estimated, the Kennedy - Pancu method in combination with the Eigensystem Realization Algorithm have been used to that purpose. Experimental results in air were compared with a theoretical model. The first resonance frequency and its damping factor presented a good agreement with the model, while the second resonance frequency deviated some 6,6% from the predicted value. Tests in water and multiphase flow were also performed. The influence of water flow velocity on vibration amplitudes and on the Power Spectrum Densities (PSDs) has been analyzed. Finally, tests for two - phase water/air flow were carried out; the tube sensitivity to multiphase flow is evident when the vibration level in acceleration PSDs is by analyzed. Also, the influence of void fraction on vibration amplitude and damping ratio have been addressed, however, previous studies could not be validated due to the high damping introduced by some constructive elements of the structure.

O desenvolvimento de um concreto de alto desempenho aplicado a sistemas de processamento e armazenagem de alimentos em baixas temperaturas teve por objetivo atender às indústrias de alimentos no Brasil que se utilizam da tecnologia do frio em seu processo industrial. A hegemonia mundial do mercado de carnes é brasileira, sendo que nossas indústrias são responsáveis por 33% desse mercado. A ausência de estudos para aprimorar e tornar as plantas industriais mais duráveis e condizentes com a importância do setor foi determinante na delineação do tema desta tese. Desenvolveu-se um concreto de alto desempenho frente às possíveis situações em uma planta industrial: baixas temperaturas em ambientes secos e baixas temperaturas em ambientes sujeitos à umidade. A temperatura mínima a qual foram submetidos os concretos analisados foi de 35°C. O método de dosagem e as diretrizes calcadas no reforço da matriz da pasta de cimento e refinamento de poros mostraram-se como uma alternativa para vencer as agressividades causadas pelas baixas temperaturas ao concreto. Até então, estudos sugeriam um sistema de ar cujos vazios teriam diâmetros em torno de 250 µm espaçados com esta mesma distância entre eles e com conteúdo de 6±1% para a proteção de concretos expostos a baixas temperaturas. A produção de um concreto coeso, com teor de ar de 3,5%, poros com diâmetro médio de 0,02 µm e com área específica de 2,84m²/g, provaram ser duráveis quando expostos ao congelamento e a ciclos de gelo e degelo. O fator de durabilidade para esses concretos foi de 97%. Além da durabilidade, o projeto de dosagem contemplou o aspecto econômico, produzindo 1MPa com 7,8 kg de cimento por metro cúbico de concreto. Os resultados foram obtidos por meio de ensaios dinâmicos, microscopia eletrônica de varredura, porosimetria por intrusão de mercúrio, absorção de água por imersão, além dos ensaios mecânicos de resistência à compressão, à tração na flexão e módulo de elasticidade. / Brazil has rapidly emerged as one of the world\'s leading meat exporters, being responsible by 33% of this market. In face of that, a high performance concrete (HPC), that can be applied to storage and processing system buildings at low temperatures, has been developed with the aim of answering the needs of brazilian food manufacturers that use cooling technology during industrial process. The lack of studies to improve industrial plants and make them more durable was determinant to delineate this thesis subject. A high performance concrete was designed to resist to low temperatures at dry environments as well as at moist ones. Concrete was exposed to a target temperature of -35°C. The dosage method and the guidelines based on the strengthening of bulk cement and the porous refinement showed to be an alternative to overcome the aggressiveness caused by low temperatures to concrete. To this day, studies have suggested air voids systems to protect concrete from low temperature effects. According to them, the air voids should have about 250 µm of diameter, spaced from each other this same distance and with an air content of 6±1%. However, making a cohesive concrete, with 3,5% of air content and an average diameter porous of 0,02 µm with an specific surface of 2,84m²/g, resulted in a durable concrete, even when exposed to frost / thawing cycles. The durability factor of these concretes achieved 97%. Besides durability, the dosage design brought economical advantages, producing 1 MPa with 7,8 kg of cement per cubic meter of concrete. The results were obtained through dynamic tests, scanning electron microscopy, mercury intrusion porosimetry and water absorption by immersion. In addition, tests of compression, tension strength and elastic modulus were carried out.

Embora seja uma técnica tradicional, empregada largamente em processos industriais, a operação unitária de aeração pode ser otimizada ao se utilizar modelos matemáticos que descrevam seu comportamento hidrodinâmico. Diversas equações se prestam a esse fim, no entanto, avanços tecnológicos, tanto no campo instrumental como computacional, permitiram a obtenção de equações mais realísticas e abrangentes. Neste trabalho foram ajustadas e avaliadas equações para descrever três importantes parâmetros envolvidos na transferência de oxigênio em meio hídrico: coeficiente volumétrico de transferência de massa, fração de vazios e velocidade ascensional de bolhas. Para tanto, ademais da utilização de conceitos teóricos amplamente difundidos no meio acadêmico, empregou-se um conjunto de dados já existente. Essa combinação permitiu a avaliação e aproximação das equações teóricas à realidade experimental através de coeficientes de ajuste empíricos. Foram obtidos os seguintes resultados: a) revisão bibliográfica e sugestão da correlação que melhor descreve o coeficiente volumétrico de transferência de massa; b) correlação que descreve a fração de vazios, a partir da analise da concentração de bolhas segundo distribuições gaussianas; c) correlação que descreve a velocidade ascensional de bolhas em plumas. A complexidade de cada parâmetro obtido deixou clara a importância da análise isolada, precedendo a convolução dos mesmos em um único modelo, pois embora as resposta e recomendações apresentadas não forneçam conclusões definitivas sobre todos os aspectos envolvidos na transferência de oxigênio em meio hídrico, suas considerações pontuais contribuem sobremaneira ao domínio do fenômeno global, beneficiando modelagens matemáticas futuras. / Although it is a traditional technique, widely employed in industrial processes, the unit operation of aeration can be optimized when resorting to mathematical models which describe their hydrodynamic behavior. A range of equations lends itself to this purpose, however, technological advances both in the instrumental as computational field, allowed the achievement of equations more realistic and comprehensives. In this study were adjusted and evaluated equations to describe three important parameters involved in the oxygen transfer in the hydric medium: volumetric mass transfer coefficient, void fraction and upflow bubble velocity. To this end, besides the use of theoretical concepts widely disseminated in the academic literature, it was employed a set of already existing data. This combination allowed the evaluation and approximation of theoretical equations to experimental reality by means of empirical adjustment coefficients. Were obtained the following results: a) literature review and suggestion of the best correlation which describes the volumetric mass transfer coefficient, b) correlation which describes the fraction of voids, from the analysis of the concentration of bubbles by Gaussian distributions, c) correlation which describes the upflow velocity of swarms of bubbles. The complexity of each parameter obtained made clear the importance of the isolated analysis, preceding the convolution of them in a single model because although the answers and recommendations given fail to supply definitive conclusions on all aspects involved in the transfer of oxygen in hydric medium, their specific considerations contribute to the knowledge of the global phenomenon, benefiting deeply future mathematical models.

Orientador: Antonio Carlos Bannwart / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecânica e Instituto de Geociências / Made available in DSpace on 2018-08-23T09:29:35Z (GMT). No. of bitstreams: 1 Daun_LeandroGalvao_M.pdf: 5084421 bytes, checksum: 56e4661dc939fdef8c0383b09f63721f (MD5) Previous issue date: 2013 / Resumo: Os desafios tecnológicos na produção de petróleo e gás têm aumentado consideravelmente nos últimos anos devido à busca por segurança, redução de custos e otimização da produção, como indicado pelo grande número de estudos sobre a garantia de escoamento. Uma grande preocupação está relacionada ao escoamento multifásico em equipamentos submarinos, onde podem ocorrer diferentes padrões de escoamento e fenômenos termo-fluido-dinâmicos. O presente trabalho tem por objetivo avaliar experimentalmente possíveis fenômenos de garantia de escoamento na entrada de um Sistema de Bombeio Centrifugo Submerso em Skid (S-BCSS), como o instalado no campo de Espadarte na costa brasileira. A atenção foi dada a possíveis sinais de surging da BCS, devido à presença de gás na fase líquida e mudança na orientação do escoamento a partir da horizontal para a vertical descendente, a montante da entrada da bomba. As condições de transição entre os padrões de escoamento "bolhas dispersas" e "intermitente" foram investigados em uma linha experimental com configuração do tipo U horizontal com braços superior, inferior e curvas de 90 graus. A tubulação da linha possui diâmetro interno de 60 milímetros e comprimento total de 32 metros, sendo testada com ar e água em uma ampla gama de composições de mistura permitindo a comparação com mapas de fluxo horizontal e vertical descendente encontrados na literatura. O comportamento dos limites de padrões de escoamento foi experimentalmente avaliado, indicando possibilidades de acumulo de gás na curva superior devido à mudança de padrão "bolhas dispersas" para "intermitente" quando há alterações de orientação do escoamento horizontal para vertical descendente. A existência de uma velocidade mínima da mistura capaz de assegurar o arrasto das bolhas pelo líquido foi também investigada. Diferentes correlações para a velocidade de deslizamento e parâmetro de distribuição foram testadas para o cálculo da fração de vazio. Isto foi realizado através da obtenção da velocidade média do gás local, por meio da obtenção de imagens em alta velocidade seguido de um processamento digital das mesmas. A fração de vazio foi calculada a partir da relação entre as velocidades superficiais e locais do gás. Através da comparação entre 2124 pontos experimentais, foi possível obter as melhores correlações de fração de vazio para diferentes intervalos, resultando na obtenção de diferentes valores de velocidades mínimas de mistura / Abstract: The technological challenges in the oil and gas production have increased considerably in recent years due to the search for safety, cost reduction and production optimization, as indicated by the large number of studies on flow assurance. One major concern is the multiphase flow in subsea equipment where different flow patterns and thermo-fluid-dynamic phenomena may occur. The present work is aimed at evaluating experimentally possible flow assurance phenomena at the inlet of a Subsea Skided ESP (mudline ESP) such as one installed at Espadarte field offshore Brazil. Attention was paid to possible surging of the pump due to the presence of gas bubbles within the liquid and change in flow orientation from horizontal to vertical downward upstream the ESP intake. First, the conditions at the transition between dispersed bubbles and intermittent flow were investigated in a horizontal U-type tube with top and down arms and 90-degree bends. A flow circuit of 60mm i.d. size and 32m was built and tested using air and water in a wide range of mixture compositions, allowing comparisons with horizontal and downward flow maps found in the literature. The behavior of flow pattern boundaries was experimentally evaluated and indicated no possibility of gas accumulation on the upper bend due when the flow pattern changes from dispersed bubbles to intermittent as the flow orientation changes from horizontal to downward. The requirement of a minimum mixture velocity capable of ensuring enough drag of the bubbles by the liquid was also investigated. Several different correlations for drift velocity and distribution parameter were tested for calculation of the void fraction. This was achieved by measuring the local average gas velocity using a high speed imaging and digital image processing. The void fraction was calculated from the ratio between superficial and local gas velocities. From comparison with 2,124 data points, the best void fraction correlation for each range was determined, from which reliable values for the minimum mixture velocity were determined / Mestrado / Explotação / Mestre em Ciências e Engenharia de Petróleo

Gypsum board assemblies are now widely used in buildings, as fire resistant walls or ceilings, to provide passive fire protection. The fire resistance of such systems is fundamentally due to the desirable thermal properties of gypsum. Yet there is wide variability in reported values of thermal properties of gypsum at high temperatures and a lack of understanding of its integrity in fire. To evaluate the fire protection performance of gypsum board assemblies, it is essential to quantify its thermal properties and obtain information on its mechanical properties at high temperatures. Gypsum boards shrink and crack at high temperatures, and this leads to collapse of parts of the gypsum boards in fire. Fall-off of gypsum in fire affects the fire resistance of the assembly considerably, and cannot be overlooked when evaluating the fire resistance of gypsum board assemblies. The current research proposes a model to define the temperature-dependent thermal properties of gypsum boards at high temperatures. Thermal conductivity of gypsum is considered as the most influential parameter in conduction of heat through gypsum, and a hybrid numerical-experimental method is presented for extracting thermal conductivity of various gypsum board products at elevated temperatures. This method incorporates a validated one-dimensional Finite Difference heat conduction program and high temperature test results on small samples of gypsum boards. Moreover, high temperature mechanical tests have been performed on different gypsum board products; thermal shrinkage, strength and stress-strain relationships of gypsum products at elevated temperatures are extracted for use in numerical mechanical analysis. To simulate the structural performance of gypsum boards in fire, a two-dimensional Finite Element model has been developed in ABAQUS. This model successfully predicts the complete opening of a through-thickness crack in gypsum, and is validated against medium-scale fire tests designed and conducted as part of this research. Gypsum fall-off in fire is a complex phenomenon; however, it is believed that delaying the formation of through-thickness cracking will delay falling off of gypsum in fire, and hence improve the fire resistance of gypsum board assemblies. Finally, a study has been performed on the effects of various detailing parameters in gypsum board wall assemblies, and recommendations are offered for improving the fire resistance of such systems.

De nombreux critiques avaient détecté chez Jean Giono (1895-1970) la présence d’un vide affectant non seulement le sujet de son oeuvre mais aussi sa poétique. L’ennui, cette « brusque et radicale conscience du rien », le mensonge qui « reconstruit un monde au-dessus de l’abîme » (R. Ricatte) ou bien encore le « travail des sensations » vécu comme un « barrage contre le vide » (S. Vignes) sont des effets parmi d’autres d’un manque et d’une absence déterminante. Le vide explique aussi l’anonymat et les lacunes biographiques de ses personnages, les nombreux blancs et silences, les ellipses narratives et sémantiques, les césures et les discontinuités narratives... Il ne suffisait cependant pas de reconnaître l’existence d’un vide, d’un manque originaire dans cette oeuvre. Il fallait encore connaître sa nature. De quoi le monde gionien est-il vide ? La réponse se trouve paradoxalement dans ce que l’auteur s’est efforcé de ne jamais décrire ou plutôt dans ce qu’il a toujours décrit « en blanc » (J. Giono). En nous penchant sur ce qui, dans ses romans, était toujours décrit sans l’être, nous nous sommes aperçus que rien ne manquait davantage que Dieu. Dieu brille par son absence dans son oeuvre. Il est celui qu’il se refuse à décrire positivement car il est pour lui « le néant absolu », « l’absence de tout » (J. Giono). La théologie imprimée dans ses romans est une ‘‘théologie blanche’’. Sa vision du monde et de l’homme est toujours, et très délibérément, sans dieu/Dieu. Comme le dit le narrateur du Déserteur à propos des peintures pieuses et des ex-voto de son personnage : « il n’y a pas de dieu dans tout ça ». En analysant l’oeuvre gionienne à la lumière de cette absence, quatre ensembles de romans se sont dégagés selon un ordre qui dépasse les distinctions classiques établies, d’une part, entre une première et une seconde « manières », d’autre part, entre le « Cycle du Hussard » et les « Chroniques romanesques ». Ces quatre ensembles romanesques sont autant d’itinéraires de l’homme sans dieu/Dieu. Nous avons distingué celui de « l’humanisme païen », celui de l’héroïsme sublime, celui tragique voire tragi-comique des hommes condamnés à la chute, celui enfin des « âmes fortes » qui veulent se faire dieux en l’absence de dieu/Dieu. L’immense « chasse au bonheur » dont l’oeuvre romanesque de Giono est l’expression a rapport avec le ciel, un ciel sans dieu/Dieu. / Many critics spotted in Giono’s novels (1895-1970) the presence of a kind of emptiness which affected both his main topic and his poetry. Boredom « this sudden and drastic consciousness of nothingness », lie « which rebuilts a world on top of despair » (R. Ricatte) or « the work of sensations » (S. Vignes) felt as « a barrier against nothingness » reflect a void and a defining absence among other effects. This emptiness gives an explanation to his characters’ anonymity and gaps in biography, to the many gaps and silences, narrative and semantic ellipses, narrative caesura and discontinuities. Acknowledging the existence of a void, of an original emptiness, was not enough, its specific nature must be defined. What is missing in Giono’s world ? What is his world made of ? Paradoxically speaking the answer lies in what the author struggled not to describe or more precisely in what he described « en blanc » (J. Giono). Analysing what is described in his novels without really being described, I have realized that the One who is missing is God. God is conspicuous by his absence in his works. He is the one he refuses to describe positively as he is « the absolute absence ». The theology expressed is a ‘‘white theology’’. His view of the world and his vision of mankind, are always and in their tiniest details a vision without God. As the narrator of Le Déserteur puts it when he alludes to his main character’s votive offerings : « God is absent from all this. » Studying Giono’s works in the light of this absence, four collections of novels emerged according to an uncommon classification : on the one hand between a first and a second « manner » and on the other hand between « le Cycle du Hussard » and « les Chroniques romanesques ». These four collections of novels are routes taken by mankind without God. I have set apart : « a pagan humanist » route, a « sublime heroic » route, the tragic if ever tragicomic route of mankind doomed to their downfall, the last one the route of « strong souls » who strive to turn gods without God. The huge « quest for happiness » which is at the heart of Giono’s novels is related to heaven but a heaven without God.

The aim of this study is to contribute to an understanding of the need for collaboration in creating education plans and school placements for children and youth placed in out-of-home care. By interviewing nine representatives from social services, the municipal education department and primary and secondary schools, this study addresses tensions that arise in school planning in the critical phases for this target group: prior to placement in out-of-home-care and upon return home.Previous studies have found that children and youth placed in out-of-home care receive insufficient support for their education, and that collaboration functions better when the collaboration is well-anchored in organizational management, but worse, at an operational level, when there is less understanding of the collaborating partners’ competences and guidelines. This study has used the theory of institutional logics as a framework to highlight the material practices (routines and role descriptions) and symbolic constructions (intentions and values) that constitute each institution’s motive for organizational collaboration in providing schooling for children and youth in out-of-home-care. Through qualitative semi-structured interviews inspired by narrative method, it has emerged that social services are driven by an urgent logic, the education department by a judicial logic and the schools by both a pragmatic and a holistic logic. By creating procedures based on the interviewees' statements regarding prioritized tasks, the framework of institutional logics has clarified the tensions that arise when contrasting logics compete in the critical phases of child and youth placement. These tensions consist of a dichotomy between care and education, neither party seeing the entirety of the needs of the clients/students and shortcomings in communication. This study has also highlighted the presence of institutional voids in the collaboration process. There are elements in collaboration that the parties cannot influence, such as laws and guidelines on confidentiality, approaches to guardians of children and youth in placement as well as difficulties in collaborating with other municipalities as each one has different routines and expectations. / Syftet med denna studie är att bidra med kunskap om samverkan kring planering av skolgång och skolbyte för placerade barn och unga. Genom intervjuer med nio representanter från socialtjänst, utbildningsförvaltning och skola har denna studie kunnat presentera de spänningar som uppstår i planerandet av skolgång i de särskilt kritiska faserna inför en placering och när placerade flyttar hem igen.  Tidigare studier har funnit att placerade barn och unga inte får de förutsättningar de behöver för att klara skolan och att samverkan fungerar bättre när det är väl förankrat i ledningen men sämre på verksamhetsnivå där det finns mindre kunskap om samverkansparternas befogenheter och riktlinjer. Studien har använt teorin om institutionella logiker som teoretiskt ramverk för att synliggöra de materiella praxis (rutiner och rollbeskrivningar) och symboliska konstruktioner (intentioner och ingångsvärden) som utgör var samverkansparts rationalitet och motiv till samverkan inom det organisatoriska fält som är planering av skolgång för placerade barn och unga. Genom kvalitativa semistrukturerade intervjuer med inspiration av narrativ metod och tematisk analys har det framkommit att socialtjänsten drivs av en akut logik, utbildningsförvaltningen av en rättslig logik och skolan av både en pragmatisk och en holistisk logik. Genom att skapa gångordningar utifrån intervjupersonernas utsagor om prioriterade arbetsuppgifter i samverkan har logikerna kunnat synliggöra de spänningar som uppstår när logikerna möts i de kritiska faserna. Dessa spänningarna består av en dikotomi mellan behandling och utbildning, att ingen av parterna ser helheten i placerades ärenden och att det brister när det kommer till överlämning av information till varandra. Genom det teoretiska begreppet institutionella vakuum har studien synliggjort att det finns element inom samverkan som parterna inte kan påverka. Det gäller till exempel frågor om lagar och riktlinjer kring sekretess, förhållningssätt till vårdnadshavare samt svårigheten att samverka med externa kommuner när alla kommuner har olika rutiner och förväntningar.

No description available.

<p>A wide variety of phase evolution phenomena observed in solids such as intermetallic growth at the junction between two metals subjected to high temperature, growth of oxide on metal surfaces due to atmospheric exposure and void evolution induced by electromigration in microelectronic devices for example, can be classified as being driven by reaction-diffusion processes. These phase evolution phenomena have a significant impact on material reliability for critical applications, and therefore, there is a requirement for modeling such reaction-diffusion driven phase evolution phenomena. It is difficult to analyze these due to the complexity of modeling the evolving interface between solid phases. Additional complexity is  due to the multi-physics nature of the diffusive and reactive processes. Diffusion in solids is driven by a variety of stimuli such as current, temperature and stress, in addition to the chemical potential. Therefore, there is a need for a model that accounts for the influence of such factors on phase evolution. In this thesis,  a generalized continuum based reaction-diffusion theory for phase and void evolution in solid state is developed. The derivation starts off with generalized interface balance laws for mass, momentum and energy. The thermodynamic entropy inequality for irreversible phase growth is derived for arbitrary anisotropic and inhomogeneous surface stress. These interface relations are combined with governing relations in the material bulk for the temperature, stress, electrical and concentration fields, to develop a general model capable of analyzing and describing phase evolution in solids. This theory is then applied to a variety of intermetallic phase and void evolution phenomena observed in microelectronics.</p> <p><br></p> <p>Electromigration induced voiding in thin metal films is an example of phase evolution that is an important reliability concern in microelectronics. Studies have reported that the electromigration induced void growth rate is inversely related to the adhesion of metal thin films with the base and capping layers. Electromigration experiments are performed on fabricated test devices with Cu thin films with SiNx and TiN capping layers. The observations from electromigration experiments on thin Cu metal films at a range of temperatures indicate that the contribution of interface adhesion strength to electromigration resistance decreases with an increase in temperature. The generalized reaction-diffusion theory developed here is modified to develop an expression to account for the effect of base and passivation layer adhesion and temperature on electromigration resistance of metal thin films. The void growth rates measured in the experiments are analyzed with the expression for void growth rate to estimate the interface adhesion strength for the Cu-TiN and Cu-SiNx interfaces. </p> <p><br></p> <p>Demand for increased bandwidth, power efficiency and performance requirements have resulted in a trend of reduction in size and pitch of Cu pillar-Solder micro-bump interconnects used in heterogeneously integrated packages. As the size of micro-bumps reduce, reliability challenges due to voiding in the solder joint and the growth of Cu-Sn intermetallics are observed. The underlying reaction-diffusion mechanisms responsible for Cu-Sn intermetallic growth and voiding in solder joints are unclear at this stage and require further investigation. The current practice of material characterization in micro-bumps involve destructive cross-sectioning and polishing of the micro-bumps after testing. These processes result in loss of continuity in the samples used for the experiments, and material removal due to abrasive polishing might result in a loss of critical information. Therefore, a novel test device capable of non-destructive characterization of Cu-Sn intermetallic growth and voiding in sub-30 micron size micro-bumps is designed and fabricated in this work. The fabricated test devices are subjected to thermal aging for over 1000 h and the underlying reaction-diffusion mechanisms behind the intermetallic phase and void evolution are investigated. </p> <p><br></p> <p>A reaction-diffusion mechanism is proposed explaining the evolution of  various Cu-Sn intermetallic phases and solder joint void observed from experiments. Using the reaction-diffusion mechanism inferred from the thermal aging experiments and the generalized reaction-diffusion theory for phase evolution developed in this thesis, a sharp interface model is developed for the evolution of Cu-Sn intermetallic phases and solder joint void. The diffuse interface phase field equivalent equations for the sharp interface model governing equations are developed using matched formal asymptotic analysis. The evolution of Cu-Sn intermetallic phase and voids in the solder joint are simulated for different temperatures and current density to demonstrate the validity of the phase field and sharp interface models.  </p> <p><br></p>

No description available.