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<p>Explosives and rocket fuel are just two prime examples of energetic materials, compounds that contain a combustible fuel and oxidizer within the same substance. Recent advances have enabled the construction of energetic materials through multiple variations of additive manufacturing, principally inkjet, direct-write, fused filament fabrication, electrospray deposition, and stereolithography. Many of the methods used for creating multiple layered objects (three-dimensional) from energetic materials involve the use of highly viscid materials.</p> <p>The focus of this work was to design a process capable of additively manufacturing three-dimensional objects from melt-castable energetic materials, which are known for their low viscosity. An in-depth printer design and fabrication procedure details the process requirements discovered through previous works, and the adaptations available and used to construct an additive manufacturing device capable of printing both energetic and non-energetic (also referred to as inert) melt-castable materials. Initial characterization of three proposed inert materials confirmed their relative similarity in rheological properties to melt-castable energetic materials and were used to test the printer’s performance.</p> <p>Preliminary tests show the constructed device is capable of additively manufacturing melt-castable materials reproducibly in individual layers, with some initial successful prints in three-dimensions, up to three layers. An initial characterization of the printer’s deposition characteristics additionally matches literature predictions. With the ability to print three-dimensional objects from melt-castable materials confirmed, future work will focus on the reproducibility of multi-layered objects and the refined formulation of melt-castable energetic materials.</p>

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With the emergence of modern technologies in manufacturing processes, companies need to adapt themselves to these technologies to stay competitive. Additive Manufacturing is one of the upcoming technologies which will bring major changes to the manufacturing process. AM (Additive Manufacturing) offers flexibility in design, production size, customization, etc., Even though there are numerous advantages from the implementation of AM technologies less than 2% of the manufacturing industries use them for production. The purpose of the thesis was to study the impact of AM on manufacturing industries in 5-10 years and the barriers it is facing for widespread diffusion. Additionally, its impact on Sustainability aspects is also studied. A literature review was conducted to understand the current AM processes, their applications in different manufacturing sectors, their impact on business strategies, operations, and Product Life cycle. From the study, it was concluded that AM technologies are still in their maturing state and has a lot of uncertainties that it must overcome. The most notable barriers being implementation costs, limited materials, and protection of Intellectual property. The thesis also presents the projection for AM in 2030. AM is advantageous for Environmental and Economic sustainability with very little research on Societal sustainability.

Wire and arc additive manufacturing (WAAM) is a manufacturing method using a numerical controlled motion system and a welding system to additively manufacture three dimensional components. The motion system is programmed from three dimensional computer aided design model data (3D-CAD) of the intended geometry which is then sliced in to layers and welded on additively. There are seven process categories within additive manufacturing (AM), each with their own benefits and drawbacks. One of these process categories is directed energy deposition (DED) which uses an energy source to melt material onto a build plate. Instead of filling the build plate with material and selectively melting or sintering the material, DED only deposit material which is to be melted. WAAM is a process within the DED process category. BAE Systems Hägglunds manufactures relatively large components with requirements for mass reduction. Hägglunds has therefor invested in a WAAM laboratory, for testing and investigation on how to utilize this technology to their advantage. During the master thesis a geometrical correlation between the overhang angle and the material deposition on the edges of the overhangs has been found. A slicing strategy utilising this correlation has proven useful in combatting an issue where the top surface of a parallelepiped ends up unwantedly not parallel to the substrate plate. This master thesis has also increased the capability from 30° to 45° overhang angle. A numeric simulation of cooling times in the WAAM process has been developed. The simulation had a maximum error of one minute or about 69 % longer measured than simulated cooling time at worst case.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第24849号 / 工博第5166号 / 新制||工||1987(附属図書館) / 京都大学大学院工学研究科機械理工学専攻 / (主査)教授 泉井, 一浩, 教授 松原, 厚, 教授 平山, 朋子 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

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The overall goal of this research work is to enhance the capabilities of large-format, polymer material extrusion, additive manufacturing (AM) systems. Specifically, the aims of this research are to (1) Construct, and develop a robust workflow for, a large-format, robotic, AM system; (2) Develop an algorithm for determining and relaying proper rotation commands for 5 degree of freedom (DoF) multi-axis deposition; and (3) Create a method for printing a removable support material in large-format AM. The development and systems-integration of a large-format, pellet-fed, polymer, material extrusion (ME), AM system that leverages an industrial robotic arm is presented. The robotic arm is used instead of the conventional gantry motion stage due to its multi-axis printing ability, ease of tool changes for multi-material deposition and/or subtraction, and relatively small machine footprint. A novel workflow is presented as a method to control the robotic arm for layer-wise fabrication of parts, and several machine modifications and workflow enhancements are presented to extend the multi-axis manufacturing capabilities of the robot. This workflow utilizes existing AM slicers to simplify the motion path planning for the robotic arm, as well as allowing the workflow to not be restricted to a single robotic deposition system. To enable multi-axis deposition, a method for generating tool orientations and resulting deposition toolpaths from a geometry's STL file was developed for 5-DoF conformal printing and validated via simulation using several different multi-DOF robotic arm platforms. Furthermore, this research proposes a novel method of depositing a secondary sacrificial support material was created for large-format AM to enable the fabrication of complex geometries with overhanging features. This method employs a simple tool change to deposit a secondary, water-soluble polymer at the interfaces between the part and supporting structures. In addition, a means to separate support material into smaller sections to extend the range of geometries able to be manufactured via large-format AM is presented. The resultant method was used to manufacture a geometry that would traditionally be considered unprintable on conventional large-format AM systems. / Master of Science / Additive manufacturing (AM), also known as 3D printing, is a method of manufacturing objects in a layer-by-layer technique. Large-format AM is typically defined as an AM system that can create an object larger than 1 m3. There are only a few manufacturers in the world of these systems, and all currently are built on gantry-based motion stages that only allow movement of the printer in three principal axes (X, Y, Z). The primary goal of this thesis is to construct a large-format AM system that uses a robotic arm to enable printing in any direction or orientation. The use of an industrial robotic arm enables printing in multiple planes, which can be used to print structures without support structures, print onto curved surfaces, and to purt with curved layers which produces a smoother external part surface. The design of the large-format AM system was validated through successful printing of objects as large as 1.0x0.5x1.2 m, simultaneous printing of a sacrificial support material to enable overhanging features, and through completing multi-axis printing. To enable multi-axis printing, an algorithm was developed to determine the proper toolpath location and relative orientation to the part surface. Using a part's STL file as input, the algorithm identifies the normal vector at each movement command, which is then used to calculate the required tool orientation. The tool orientations are then assembled with the movement commands to complete the multi-axis toolpath for the robot to perform. Finally, this research presents a method of using a second printing tool to deposit a secondary, water-soluble material to act as supporting structures for overhanging and bridging part features. While typical 3D printers can generally print sacrificial material for supporting overhangs, large-format printers produce layers up to 25 mm wide, rendering any support material impossible to remove without post-process machining. This limits the range of geometries able to be printed to just those with no steep overhangs, or those where the support material is easily reachable by a tool for removal. The solution presented in this work enables the large scale AM processes to create complex geometries.

<p dir="ltr">A diffractive optical element (DOE) can manipulate the light to generate the desired profile or shape with micro-structure patterns to alter the phase of the passed light. They are widely used and applied in various experimental and commercial systems because of their complex light manipulation capability, compact and lightweight designs, and holographic imaging ability. </p><p dir="ltr">There are many ways to make DOEs but it is hard to manufacture high precision DOEs with low cost, simple procedures, and capability for 3D structures. The current fabrication of DOEs mainly focuses on nanofabrication techniques, especially photolithography. These methods have a very high resolution and accuracy in nanoscale, but usually require expensive equipment and are limited to planar structures. Additive manufacturing is a low-cost, layer-based manufacturing technique, which is very strong in forming 3D structures. However, the resolution and accuracy of most 3D printers are limited to a micrometer scale, which is not small enough for the diffraction of visible light.</p><p dir="ltr">This research aims to understand the mechanics of modulating the phase of DOEs and improve the manufacturing process of 3D printing to achieve better resolution. Two Photon Polymerization (TPP) and Vat Photopolymerization (VPP) 3D printing techniques were investigated and improved to fabricate application-driven designs from 1D to 2D structures. Different strategies and methods such as drop coating, design of lattice structure, and exposure time controlling, were developed to manipulate the physical structure and material properties to control the phase modulation of DOEs. The results pave the way for the future application of 3D printing to fabricate complicated 3D DOEs. </p><p><br></p>