Carbon Capture and Storage (CCS) is a legitimate technology option that should be part of a balanced portfolio of mitigation technologies available Post-Kyoto Protocol framework after Paris 2015 and beyond the 2020s or the cost achieving 2 degrees Celsius stabilisation scenario will significantly increase. Oxy-fuel combustion as a CCS technology option increases fuel flexibility. Additionally, oxy-biomass as a bio-energy with CCS (BECCS) technology can achieve negative carbon dioxide (CO2) emissions in sustainable biomass systems. Also, oxygen (O2) production in an air separation unit (ASU) gives potential for extra operational flexibility and energy storage. In this work, new designs of 20 litre spherical (R-20) and 30 litre non-spherical (R-30) ignition chambers have been built at the University of Edinburgh to carry-out dust ignition experiments with different ignition energies for evaluating pulverised fuel ignitability as a function of primary recycle (PR) O2 content for oxy-fuel PF milling safety. A set of coals and biomasses being used (at the time of submitting this work) in the utility pulverised fuel boilers in the UK have been employed. Coal and biomass dusts were ignited in air and oxy-fuel mixtures up to 30 % v/v O2 balance mixture CO2 where peak pressures (Pmax) from ignition were recorded. Pressure ratios (Pmax/Pinitial) were determined the key parameter for positive ignition identification with a value above 2.5 to be considered positive. Particle size effects in coal and biomass ignition were evaluated. Results on biomass were more variable than with coals, requiring a stronger ignition source (5,000 J) mainly due to larger particle sizes. Finer biomass particles behaved similarly to air ignition in 25 % v/v O2 in CO2. Larger particles of biomass did not ignite at all for most cases even reaching 30 % v/v O2 in CO2. A reference coal used, El Cerrejon, behaved as expected with 30 % v/v O2 balance CO2 matching air case; particles between 75-53 microns had lower ignitability than finer below 53 microns but were critical in devolatilisation. Most fuels did not ignite in 21 % v/v in CO2 below 200 g/m3 concentrations. The use of adequate ignition energy strength is needed for the PF mill safety case, with 5,000 J energy required for the biomasses tested. An indication of potential ignition chamber volume and geometry effect has also been observed when comparing results from R-20 and R-30 ignition chambers. Important implications include that oxy-biomass PR with 21 % v/v O2 content would give improved pulverised fuel (PF) milling safety when compared to air firing but reduced ignitability and a 25 % v/v O2 balance CO2 atmosphere would approach to oxy-biomass ignition behaviour in air in mills.

I assess the potential of seismic and time-domain controlled-source electromagnetic (CSEM) methods to monitor carbon dioxide (CO2) migration through the application of a monitorability workflow. The monitorability workflow describes a numerical modelling approach to model variations in the synthetic time-lapse response due to CO2 migration. The workflow consists of fluid-flow modelling, rock-physics modelling and synthetic seismic or CSEM forward modelling. I model CO2 injected into a simple, homogeneous reservoir model before applying the workflow to a heterogeneous model of the Bunter Sandstone reservoir, a potential CO2 storage reservoir in the UK sector of the North Sea. The aim of this thesis is to model the ability of seismic and time-domain CSEM methods to detect CO2 plume growth, migration and evolution within a reservoir, as well as the ability to image a migrating front of CO2. The ability to image CO2 plume growth and migration within a reservoir has not been demonstrated in the field of CSEM monitoring. To address this, I conduct a feasibility study, simulating the time-lapse CSEM time-domain response of CO2 injected into a saline reservoir following the multi-transient electromagnetic (MTEM) method. The MTEM method measures the full bandwidth response. First, I model the response to a simple homogeneous 3D CO2 body, gradually increasing the width and depth of the CO2. This is an analogue to vertical and lateral CO2 migration in a reservoir. I then assess the ability of CSEM to detect CO2 plume growth and evolution within the heterogeneous Bunter Sandstone reservoir model. I demonstrate the potential to detect stored and migrating CO2 and present the synthetic results as time-lapse common-offset time sections. The CO2 plume is imaged clearly and in the right coordinates. The ability to image seismically a migrating front of CO2 remains challenging due to uncertainties regarding the pore-scale saturation distribution of fluids within the reservoir and, in turn, the most appropriate rock-physics model to simulate this: uniform or patchy saturation. I account for this by modelling both saturation models, to calculate the possible range of expected seismic velocities prior to generating and interpreting the seismic response. I demonstrate the ability of seismic methods to image CO2 plume growth and evolution in the Bunter Sandstone saline reservoir model and highlight clear differences between the two rock-physics models. I then modify the Bunter Sandstone reservoir to depict a depleted gas field by including 20% residual gas saturation. I assess the importance and implication of patchy saturation and present results which suggest that seismic techniques may be able to detect CO2 injected into depleted hydrocarbon fields.

Carbon dioxide enhanced oil recovery (CO2EOR) is a proven and available technology used to produce incremental oil from depleted fields. Although this technology has been used successfully onshore in North America and Europe, projects have maximised oil recovery and not CO2 storage. While the majority of onshore CO2EOR projects to date have used CO2 from natural sources, CO2EOR is now more and more being considered as a storage option for captured anthropogenic CO2. In the North Sea the lack of low cost CO2, in large volumes, has meant that no EOR projects have utilised CO2 as an injection fluid. However CO2EOR has the highest potential of all EOR techniques to maximise recovery from depleted UK oil fields. With the prospect of Carbon Capture and Storage (CCS) capturing large tonnages of CO2 from point source emission sites, the feasibility of CO2EOR deployment in the North Sea is high. This thesis primarily aims to address a number of discrete issues which assess the effectiveness of CO2EOR to both produce oil and store CO2. Given the fundamental shift in approach proposed in North Sea CO2EOR projects, the carbon balance of such projects is examined. Using a life cycle accounting approach on a theoretical North Sea field, we examine whether offshore CO2EOR can store more CO2 than onshore projects traditionally have, and whether CO2 storage can offset additional emissions produced through offshore operations and incremental oil production. Using two design scenarios which optimise oil production and CO2 storage, we find that that net GHG emissions were negative in both ‘oil optimised’ and ‘CO2 storage optimised’. However when emissions from transporting, refining and combusting the produced crude oil are incorporated into the life cycle calculations the ‘oil optimised scenario’ became a net emitter of GHG and highlights the importance of continuing CO2 import and injection after oil production has been maximised at a field. This is something that has not traditionally occurred. After assessing rates of flaring and venting of produced associated gas at UK oil fields it is found that the flaring or venting of reproduced CH4 and CO2 has a large control on emissions. Much like currently operating UK oil fields the rates of flaring and venting has a control on the carbon intensity of oil produced. Here values for the carbon intensity of oil produced through CO2EOR are presented. Carbon intensity values are found to be similar to levels of current UK oil production and significantly lower than other unconventional sources. As well as assessing the climate benefits of CO2EOR, a new assessment of CO2EOR potential in Residual Oil Zones (ROZ) is also made. ROZ resource, which is thought to add significant potential to both the oil reserves and CO2 storage potential in some US basins, is here identified in the North Sea for the first time. Based on the foundation of North Sea hydrodynamics study, this thesis identifies the Pierce field as a candidate ROZ field where hydrodynamic tilting of the oil water contact has naturally occurred leaving a zone of residual oil. To test the feasibility of CO2EOR in such a zone a methodology is presented and applied. Notably the study highlights that in this case study recoverable reserves from the ROZ may approach 20% of total field recoverable reserves and have the capability to store up to 11Mt of CO2. While highlighting the CO2EOR potential in the ROZ the thesis discusses the importance in expanding the analysis to quantify its importance on a basin scale. Discussion is also made on whether new resource identification is necessary in a mature basin like the North Sea. With CO2EOR being considered as a feasible option for storing captured anthropogenic CO2, it is important to assess the security of storage in CO2EOR. Using real geochemical and production data from a pilot CO2EOR development in Western Canada two approaches are used to assess the partitioning of CO2 between reservoir fluids through time. Using a number of correlations it is found that CO2 dissolution in oil is up to 7 times greater than in reservoir brine when saturations between the two fluids are equal. It is found that after two years of CO2 injection solubility trapping accounts for 26% of injected CO2. The finding that significantly more dissolution occurs in oil rather than brine indicates that CO2 storage in EOR is safer than in brine storage. However a number of factors such as the increase in oil/CO2 mobility due to CO2 injection is also discussed. The overall conclusion from the work is that CO2EOR in the North Sea has the potential to be an effective way of producing oil and storing CO2 in the North Sea. A number of design, operational and accounting factors are however essential to operate an exemplar CO2EOR project where low carbon intensity oil can be produced from a mature basin while storing large tonnages of captured anthropogenic CO2.

Yes / The process of capturing and storing carbon dioxide (CCS) was previously considered a crucial and time-sensitive approach for diminishing CO2 emissions originating from coal, oil, and gas sectors. Its implementation was seen necessary to address the detrimental effects of CO2 on the atmosphere and the ecosystem. This recognition was achieved by previous substantial study efforts. The carbon capture and storage (CCS) cycle concludes with the final stage of CO2 storage. This stage involves primarily the adsorption of CO2 in the ocean and the injection of CO2 into subsurface reservoir formations. Additionally, the process of CO2 reactivity with minerals in the reservoir formations leads to the formation of limestone through injectivities. Carbon capture and storage (CCS) is the final phase in the CCS cycle, mostly achieved by the use of marine and underground geological sequestration methods, along with mineral carbonation techniques. The introduction of supercritical CO2 into geological formations has the potential to alter the prevailing physical and chemical characteristics of the subsurface environment. This process can lead to modifications in the pore fluid pressure, temperature conditions, chemical reactivity, and stress distribution within the reservoir rock. The objective of this study is to enhance our existing understanding of CO2 injection and storage systems, with a specific focus on CO2 storage techniques and the associated issues faced during their implementation. Additionally, this research examines strategies for mitigating important uncertainties in carbon capture and storage (CCS) practises. Carbon capture and storage (CCS) facilities can be considered as integrated systems. However, in scientific research, these storage systems are often divided based on the physical and spatial scales relevant to the investigations. Utilising the chosen system as a boundary condition is a highly effective method for segregating the physics in a diverse range of physical applications. Regrettably, the used separation technique fails to effectively depict the behaviour of the broader significant system in the context of water and gas movement within porous media. The limited efficacy of the technique in capturing the behaviour of the broader relevant system can be attributed to the intricate nature of geological subsurface systems. As a result, various carbon capture and storage (CCS) technologies have emerged, each with distinct applications, associated prices, and social and environmental implications. The results of this study have the potential to enhance comprehension regarding the selection of an appropriate carbon capture and storage (CCS) application method. Moreover, these findings can contribute to the optimisation of greenhouse gas emissions and their associated environmental consequences. By promoting process sustainability, this research can address critical challenges related to global climate change, which are currently of utmost importance to humanity. Despite the significant advancements in this technology over the past decade, various concerns and ambiguities have been highlighted. Considerable emphasis was placed on the fundamental discoveries made in practical programmes related to the storage of CO2 thus far. The study has provided evidence that despite the extensive research and implementation of several CCS technologies thus far, the process of selecting an appropriate and widely accepted CCS technology remains challenging due to considerations related to its technological feasibility, economic viability, and societal and environmental acceptance.

Yes / Capturing and storing CO2 (CCS) was once regarded as a significant, urgent, and necessary option for reducing the emissions of CO2 from coal and oil and gas industries and mitigating the serious impacts of CO2 on the atmosphere and the environment. This recognition came about as a result of extensive research conducted in the past. The CCS cycle comes to a close with the last phase of CO2 storage, which is accomplished primarily by the adsorption of CO2 in the ocean and injection of CO2 subsurface reservoir formation, in addition to the formation of limestone via the process of CO2 reactivity with reservoir formation minerals through injectivities. CCS is the last stage in the carbon capture and storage (CCS) cycle and is accomplished chiefly via oceanic and subterranean geological sequestration, as well as mineral carbonation. The injection of supercritical CO2 into geological formations disrupts the sub-surface’s existing physical and chemical conditions; changes can occur in the pore fluid pressure, temperature state, chemical reactivity, and stress distribution of the reservoir rock. This paper aims at advancing our current knowledge in CO2 injection and storage systems, particularly CO2 storage methods and the challenges encountered during the implementation of each method and analyses on how key uncertainties in CCS can be reduced. CCS sites are essentially unified systems; yet, given the scientific context, these storage systems are typically split during scientific investigations based on the physics and spatial scales involved. Separating the physics by using the chosen system as a boundary condition is a strategy that works effectively for a wide variety of physical applications. Unfortunately, the separation technique does not accurately capture the behaviour of the larger important system in the case of water and gas flow in porous media. This is due to the complexity of geological subsurface systems, which prevents the approach from being able to effectively capture the behaviour of the larger relevant system. This consequently gives rise to different CCS technology with different applications, costs and social and environmental impacts. The findings of this study can help improve the ability to select a suitable CCS application method and can further improve the efficiency of greenhouse gas emissions and their environmental impact, promoting the process sustainability and helping to tackle some of the most important issues that human being is currently accounting global climate change. Though this technology has already had large-scale development for the last decade, some issues and uncertainties are identified. Special attention was focused on the basic findings achieved in CO2 storage operational projects to date. The study has demonstrated that though a number of CCS technologies have been researched and implemented to date, choosing a suitable and acceptable CCS technology is still daunting in terms of its technological application, cost effectiveness and socio-environmental acceptance.

Thesis (MScEng)--Stellenbosch University. / ENGLISH ABSTRACT: Carbon dioxide (CO2) is classified as the main greenhouse gas (GHG) contributing to global warming. Estimates by the Intergovernmental Panel on Climate Change (IPCC) suggest that CO2 emissions must be reduced by between 50 to 85% by 2050 to avoid irreversible impacts. Carbon capture and storage (CCS) strategies can be applied to de-carbonize the emissions from fossil-fueled power plants. Compared to other CCS techniques, post-combustion capture (PCC) is most likely to be implemented effectively as a retrofit option to existing power plants. At present however CCS is not yet commercially viable. The main challenge with CCS is to reduce the inherent energy penalty of the CO2 separation stage on the host plant. Seventy-five to eighty percent of the total cost of CCS is associated with the separation stage. There are several technologies available for separating CO2 from power plant flue gas streams. Reactive absorption with aqueous amine solutions has the ability to treat low concentration, low pressure and large flux flue gas streams in industrial-scale applications. It is most likely to be the first technology employed commercially in the implementation of CCS. The energy required for solvent regeneration however, is high for the standard solvent used in reactive absorption processes, i.e. MEA. This leads to a reduction in thermal efficiency of the host plant of up to 15%. Alternative solvent formulations are being evaluated in an attempt to reduce the energy intensity of the regeneration process. The main objective of this study was to establish a novel, simplified thermodynamic method for solvent screening. Partial solubility parameters (PSPs) were identified as the potential basis for such a method. The major limitation of this approach is that the model doesn’t account for effects from chemical reaction(s) between materials, e.g. CO2 reacting with aqueous alkanolamine solutions; considering only the effects from dissolution. The EquiSolv software system was developed based on PSP theory. The Hansen 3-set PSP approach was used to describe the equilibrium behaviour of CO2 absorbing in task specific solvents. The Hansen theory was expanded to a 4-set approach to account for contributions from electrostatic interactions between materials. The EquiSolv program was used successfully to screen large sets of solvent data (up to 400 million formulations) in the search for suitable alternative solvent formulations for CO2 absorption. The secondary objective of this study was to evaluate the ability of the proposed PSP model to accurately predict suitable alternative solvents for CO2 absorption through preliminary experimental work. A series of CO2 absorption experiments were conducted to evaluate the absorption performance of predicted alternative solvent formulations. The predicted alternative solvent formulations exhibited a significant improvement in absorption performance (up to a 97% increase in the measured absorption capacity) compared to conventional solvent formulations. Statistical analysis of the experimental results has shown that there is a statistically significant concordant relationship between the predicted and measured rankings for the absorption performance of the predicted solvent formulations. Based on this it was concluded that PSP theory can be used to accurately predict the equilibrium behaviour of CO2 absorbing in task specific solvents. Recently ionic liquids (ILs) have been identified as potential alternatives to alkanolamine solutions conventionally used for CO2 absorption. Absorption experiments were conducted as a preliminary assessment of the absorption performance of ILs. Results have shown ILs to have significantly improved performance compared to conventional alkanolamine solvents; up to a 96% increase in the measured absorption capacity compared to conventional solvents. Future work should focus on developing task specific ionic liquids (TSILs) in an attempt to reduce the energy intensity of solvent regeneration in CO2 absorption processes. / AFRIKAANSE OPSOMMING: Koolsuurgas (CO2) word geklassifiseer as die vernaamste kweekhuis gas (GHG) wat bydra to globale verwarming. Beramings deur die Interregeringspaneel oor Klimaatsverandering (IPKV) toon aan dat CO2 emissies teen 2050 verminder moet word met tussen 50 en 85% om onomkeerbare invloede te vermy. Verskeie koolstof opvangs en bergings (KOB) strategieë kan toegepas word ten einde die koolstof dioksied konsentrasie in die emissies van kragstasies wat fossielbrandstowwe gebruik, te verminder. Naverbranding opvangs (NVO) is die mees aangewese KOB tegniek wat effektief toegepas kan word op bestaande kragstasies. Tans is KOB egter nog nie kommersieël lewensvatbaarvatbaar nie. Die hoof uitdaging wat KOB in die gesig staar is om die energie boete inherent aan die CO2 skeidingstap te verminder. Tussen vyf-en-sewentig en tagtig persent van die totale koste van KOB is gekoppel aan die skeidingstap. Daar is verskeie metodes beskikbaar vir die skeiding van CO2 uit die uitlaatgasse van kragstasies. Reaktiewe absorpsie met waterige oplossings van amiene kan gebruik word om lae konsentrasie, lae druk en hoë vloei uitlaatgasstrome in industriële toepassings te behandel. Dit is hoogs waarskynlik die eerste tegnologie wat kommersieël aangewend sal word in die toepassing van KOB. Die oplosmiddel wat normalweg vir reaktiewe absorpsie gebruik word (d.w.s. MEA) benodig egter ‘n groot hoeveelheid energie vir regenerasie. Dit lei tot ‘n afname in die termiese doeltreffendheid van die voeder aanleg van tot 15%. Alternatiewe oplosmiddelstelsels word tans ondersoek in ‘n poging om the energie intensiteit van die regenerasieproses te verminder. Die hoof doelwit van hierdie studie was om ‘n nuwe, ongekompliseerde termodinamiese metode te vestig vir die keuring van alternatiewe oplosmiddels. Parsiële oplosbaarheidsparameters (POPs) is geïdentifiseer as ‘n moontlike grondslag vir so ‘n metode. Die model beskryf egter slegs die ontbindings gedrag van materiale. Die effekte van chemise reaksie(s) tussen materiale, bv. die tussen CO2 en waterige oplossings van alkanolamiene, word nie in ag geneem nie. Die POP teorie het gedien as grondslag vir die ontwerp van die EquiSolv sagteware stelsel. Die Hansen stel van drie POPs is gebruik om die ewewigsgedrag te beskryf van CO2 wat absorbeer in doelgerig-ontwerpte oplosmiddels. Die Hansen teorie is verder uitgebrei na ‘n stel van vier POPs om die bydrae van elektrostatiese wisselwerking tussen materiale in ag te neem. Die EquiSolv program is verskeie kere met groot sukses gebruik vir die sifting van groot stelle data (soveel as 400 miljoen formulasies) in die soektog na alternatiewe oplosmiddels vir CO2 absorpsie. Die sekondêre doelwit van die studie was om die vermoë van die voorgestelde POP model om geskikte alternatiewe oplosmiddels vir CO2 absorpsie akkuraat te voorspel, te ondersoek deur voorlopige eksperimentele werk. ‘n Reeks CO2 absorpsie eksperimente is gedoen ten einde die absorpsie werkverrigting van die voorspelde alternatiewe oplosmidels te ondersoek. ‘n Verbetering in absorpsie werkverrigting van tot 97% is gevind vir die voorspelde oplosmiddels vergeleke met die van oplosmiddels wat tipies in die industrie gebruik word. Statistiese ontleding van die eksperimentele resultate het getoon dat daar ‘n beduidende ooreenstemming tussen die voorspelde en gemete rangskikking van die voorspelde oplosmiddels se werkverrigting bestaan. Dus kan POP teorie gebruik word om die absorpsie van CO2 in doelgerig-ontwerpte oplosmiddels akkuraat te beskryf. Ioniese vloeistowwe (IVs) is onlangs geïdentifiseer as moontlike alternatiewe oplosmidels vir die alkanolamien oplossings wat normaalweg gebruik word vir CO2 absorpsie. Absorpsie eksperimente is gedoen ten einde ‘n voorlopige raming van die absorpsie werkverrigting van IVs te bekom. Daar is bevind dat IVs ‘n beduidende verbetering in werkverrigting toon in vergelyking met die alkanolamien oplosmiddels wat normaalweg gebruik word. ‘n Verbetering in absorpsie werkverrigting van tot 96% is gevind vir die voorspelde IV-bevattende oplosmiddels vergeleke met die van oplosmiddels wat tipies in die industrie gebruik word. Die fokus van toekomstige navorsing moet val op die ontwikkeling van doelgemaakte ioniese vloeistowwe (DGIVs) in ‘n poging om die energie intensiteit van oplosmiddel regenerasie in CO2 absorpsie prosesse te verminder.

Many geoscientists endorse Carbon Capture and Storage (CCS) as a potential strategy for mitigating emissions of greenhouse gases. Deep saline aquifers have been reported to have larger CO 2 storage capacity than other formation types because of their availability worldwide and less competitive usage. This work proposes an analytical model for screening potential CO 2 storage sites and investigates injection strategies that can be employed to enhance CO 2 storage. The analytical model provides of estimates CO 2 storage efficiency, formation pressure profiles, and CO 2 –brine interface location. The results from the analytical model were compared to those from a sophisticated and reliable numerical model (TOUGH 2 ). The models showed excellent agreement when input conditions applied in both were similar. Results from sensitivity studies indicate that the agreement between the analytical model and TOUGH2 strongly depends on irreducible brine saturation, gravity and on the relationship between relative permeability and brine saturation. A series of numerical experiments have been conducted to study the pros and cons of different injection strategies for CO 2 storage in confined saline aquifers. Vertical, horizontal, and joint vertical and horizontal injection wells were considered. Simulations results show that horizontal wells could be utilized to improve CO 2 storage capacity and efficiency in confined aquifers under pressure-limited conditions with relative permeability ratios greater than or equal to 0:01. In addition, joint wells are more efficient than single vertical wells and less efficient than single horizontal wells for CO 2 storage in anisotropic aquifers.

No description available.

Syftet med den här studien är att göra en teknoekonomisk utvärdering av processer för förvätskning av CO2 med hjälp av Aspen Plus. Ett flertal förvätskningsprocesser från tidigare studier jämfördes och från dessa valdes två förvätskningsprocesser ut för fortsatta studier och simuleringar. Dessa två förvätskningsprocesser var ett internt kylt förvätskningssystem och ett externt kylt förvätskningssystem av Øi et al., Energy Procedia 86 (2016) 500-510, som kallats system A, samt av Seo et al., International Journal of Greenhouse Gas Control 35 (2015) 1-12 kallat system B. Dessa två olika processer simulerades för teknisk analys med hjälp av Aspen Plus. Aspen Economical Analyzer (AEA) användes för att göra den ekonomiska analysen. I dessa simuleringar användes ett massflöde på 45 ton/h inkluderat vatteninnehåll, i jämförelse med tidigare studier med högre massflöden runt 100 ton/h. Elektricitet-och kylbehovet undersöktes i ett flertal olika fall med varierande kyltemperatur mellan kompressorerna. Två fall med integrering av fjärrvärme samt två fall med en värmepump undersöktes också med varierande återgående temperatur på fjärrvärmevattnet. Detta gjordes för att undersöka hur mycket värme som kan tillvaratas från förvätskningsprocessen. Vidare bestämdes även investeringskostnader samt driftskostnader med hjälp av AEA. Från detta bestämdes även den årliga kostnaden av kapitalet, CAPEX, och kostnaden att förvätska CO2 räknades ut i form av €/ton.  Resultaten visade att integrering av fjärrvärme samt värmepumpar är användbart för att tillvarata på så mycket värme som möjligt från förvätskningssystemen. I de fall med en värmepump samt en återgående temperatur på 47°C i fjärrvärmenätet hade ett COP på 3.07 samt 3.15 för system A samt system B vardera. Kostanden att förvätska CO2 var 17.42 €/ton för system A samt 17.75 €/ton för system B utan använding av en värmepump samt en återgående temperatur på 47°C i fjärrvärmenätet. Vid integrering av en värmepump gick kostnaden av förvätskning upp till 20.85 €/ton för system A samt 21.69 €/ton för system B. Kostnaden av förvätskning dominerades av driftskostnader med kostnaden av kapitalet har en mindre påverkan. Utnyttjandegraden har även en stor påverkan på kostanden av förvätskning, då lägre kapaciteter visade sig leda till markant högre förvätskningskostnader. När intäkterna från fjärrvärmeproduktionen adderades till kostnadskalkylen, minskade kostnaden av förvätskning, speciellt för de system med en värmepump, där priset minskade till 10.26 €/ton för system A eller 10.98 €/ton för system B. I linje med tidigare studier pekar även dessa resultat på att det ekonomiska optimumet sammanfaller med energioptimum. Resultaten visade även att system A, det internt kylda systemet, hade den lägsta förvätskningskostanden och minsta elektricitetsförbrukningen med och utan värmepump, och därför är system A optimalt för småskalig CO2 förvätskning. / The aim of this study is to do a technoeconomical analysis on CO2 liquefaction systems using Aspen Plus. Several liquefaction systems from previous studies were compared, and from these, two liquefaction systems were chosen for further studies and simulations. These liquefaction systems were namely an internal liquefaction system and an external liquefaction system by Øi et al., Energy Procedia 86 (2016) 500-510, called system A and Seo et al., International Journal of Greenhouse Gas Control 35 (2015) 1-12, called system B. These systems were simulated for technical analysis using Aspen Plus, and Aspen Economical Analyzer (AEA) was used for economical studies. A small-scale liquefaction system was studied with a mass flow rate of 45 tonne/h including the water content, as compared to other studies with higher mass flow rates of around 100 tonne/h. The electricity demand and cooling demand were studied in several cases of interstage cooling between compressors. Furthermore, two cases of district heating as well as two cases of heat pumps were studied with varying return temperatures of the district heating water. This was done to study how much heat could be recovered from the liquefaction process. Furthermore, the capital expenses as well as the operating expenses were also determined using AEA. From this, the annual CAPEX and the cost of CO2 was calculated in terms of €/tonne CO2.  The results showed that district heating and heat pumps can be useful to recover heat from the liquefaction processes. The simulations that included a heat pump and assumed a return temperature of 47°C had a COP of 3.07 and 3.15 for system A and B respectively. The determined cost of production was 17.42 €/tonne for system A and 17.75 €/tonne for system B when not using a heat pump and a return temperature of 47°C in the district heating grid. However, when adding a heat pump the total production cost (TPC) increased to 20.85 €/tonne for system A, and 21.69 €/tonne for system B. It was also shown that the TPC is highly dominated by the operating expenses while the total capital investment has a smaller impact on the TPC. The capacity is also important for the TPC as lower capacities was shown to lead to significantly increased production costs. When taking the revenue streams from district heating into account the TPC was decreased, in particular for the systems including the heat pumps, where the TPC for system A was 10.26 €/tonne while for system B it was 10.98 €/tonne. In accordance with previous studies it was shown that the economical optimum is closely related to the energy optimum. It was concluded that as system A, the internal liquefaction system, had the lowest TPC and electricity input with and without the heat pump and thus it is the optimal configuration for small-scale CO2 liquefaction.

The Paris Agreement aims to limit global warming to 1.5 degrees Celsius, and Sweden has set a goal toreach net-zero emissions by 2045. Carbon Capture and Storage (CCS) is one method that can reducecarbon dioxide emissions. The industry and transportation sectors are the biggest sources of emissionsin Sweden, requiring technological developments and increased investment to reduce their carbondioxide (CO2) emissions. The Geological Survey of Sweden (SGU) is responsible for controls,supervision, operation, and construction of activities connected with carbon dioxide (CO2) storage. SGUbelieves that the storage conditions in Sweden are poor. Sedimentary, basaltic and ultramafic rock ispreferable for CO2 storage, but finding the right sort of bedrock at the right depth and with the rightvolumes and porosity is the challenge. Hence it is in question to collaborate with nations in the northern sea, in order to transport and storageCO2 which would lessen the burden of needing to build new infrastructure. There are a few upcomingCarbon Capture and Utilisation (CCU) projects in Sweden but from the industry’s point of view, thepriority seems to be mostly on Bio-CCS. However, there is still interest for CCS technology in industrialproduction such as steel or cement and also Direct Air Capture (DAC) in the near future. Due to thehigh cost of CCS, funding through the Swedish Energy Agency and EU is vital in order to make iteconomically viable. Other Cost reducing solutions such as relocation on old oil and gas fields orarranging CCS hubs are possible. In summary, this study concludes that CCS is not currently a feasible technique in order to reduce CO2 from the atmosphere, given the current state and costs for it. If the technology becomes more energyefficient and when financial means are in place, the future is bright for CCS. It is extremely relevantthat this technology continues to develop into a better, cheaper and faster way to capture CO2 and reduceemissions of the effective greenhouse gases. / Parisavtalet syftar till att begränsa den globala uppvärmningen till 1,5 grader Celsius och Sverige harockså satt som mål att nå nettonollutsläpp till år 2045. Ett sätt att nå dessa mål kan vara med teknikenför Carbon Capture and Storage (CCS) som är en metod för att minska koldioxidhalten i atmosfären.Den här rapporten syftar till att undersöka med hjälp av litteraturstudier och intervjuer hur genomförbarCCS är som teknik för att minska koldioxidutsläppen samt hur man även kan minska på den befintligamängden koldioxid som redan finns i luften. Huvudfokuset är att undersöka hur CCS fungerar och vilkakostnader som är involverade. Eftersom koldioxid (CO2) är en av de växthusgaser som bidrar mest tillden globala uppvärmningen är det viktigt att vidta åtgärder för att minska den. Det är inte bara utsläppenav CO2 som måste minska utan även mängden CO2 som redan finns i atmosfären. Forskning kring CCSär därför viktig för att hitta nya sätt att effektivisera metoden och göra den mer genomförbar. Naturvårdsverket ger ut en årlig rapport som utvärderar landets framsteg mot att nå sina miljömål,inklusive “Begränsad klimatpåverkan”. Rapporten konstaterar att även om EU och Sverige har minskatutsläppen ökar de fortfarande globalt sett. Industri- och transportsektorn identifieras som de störstautsläppskällorna i Sverige. Den svenska förordningen om CCS regleras av miljöbalken som testar kollagringi geologiska formationer som en miljöfarlig verksamhet och den separerade CO2 ses som avfall.Sverige har ännu inte någon kommersiell CCS-anläggning men regeringen har föreslagit att svenskaindustrier bör införa CCS för att minska dessa utsläpp. Både Sverige och EU har investerat i att utvecklateknik för att minska användningen av fossila bränslen och underlätta för användningen av CCS. CCS processen består av tre huvudsteg: avskiljning och separering av CO2, transport samt lagring elleråteranvändning. Alla typer av nuvarande CCS-metoder kräver en stor mängd energi och de flesta avdem separerar CO2 från industriella förbränningar. Direct Air Capture (DAC) är en annaninfångningsteknik som är mer flexibel när det gäller placering, men också dyrare än de andra teknikerna.Transporten av den infångade CO2 kan ske med lastbil, tåg, fartyg eller rör. De mest genomförbaraalternativen är dock rörledningar och via fartyg på grund av deras transportkapacitet. Rörledningarkräver en välutvecklad infrastruktur, vilket gör dem kostsamma, men de är det mest genomförbaraalternativet för att separera CO2 från landbaserade anläggningar och transportera dem till närliggandelagringsplatser. Geologisk lagring av CO2 kan göras både på land och till havs. Injektion till dengeologiska formationen vid lagringsplatser sker via borrhål. CO2 förvätskas och ersätter denursprungliga vätskan i bergmaterialets porer i berggrunden och reagerar så småningom med berget ochbildar nya mineraler i berggrunden. Sveriges Geologiska Undersökning (SGU) ansvarar för kontroller, tillsyn, drift och uppförande avverksamheter kopplade till CO2-lagring. Geologin i Sverige lämpar sig dock generellt sett inte förlagring av CO2, förutom för vissa sydliga områden. Nordsjön har en del gynnsamma förutsättningar förCO2-lagring och det finns även potentiella geologiska formationer i södra Östersjön. Sedimentära,basaltiska eller ultramafiska bergarter är att föredra för geologisk CO2-lagring. Den största utmaningenär att hitta rätt sorts berggrund på rätt djup och med rätt volym och porositet. Den största svårigheten med CCS är den höga kostnaden, vilket bidrar till att hämma den utbreddaanvändningen. Kostnaden för CCS inkluderar olika faktorer som infångningsmetod, transportmedel,lagringsplats och övervakning över lagringen. Bland dessa är infångningen den dyraste fasen avtekniken, följt av lagring, transport och övervakning. Kostnaderna för varje fas har analyserats över2olika intervaller med hänsyn till lägre, medelstora och högre kostnader men även beroende på regiondå kostnaden kan variera beroende på ländernas förutsättningar. Infångningsfasen av CCS har betydande kostnadsvariationer beroende på vilken metod som används,renheten hos den infångade CO2 samt den energi som krävs för avskiljningsprocesserna.Högkoncentrerade CO2-strömmar har lägre bearbetningskostnader än lågkoncentrerade. DAC är förnärvarande den dyraste infångningsmetoden. Transportkostnader för CO2 inkluderar kostnaderrelaterade till infrastruktur, drift, underhåll, konstruktion och markanvändning. Kostnaden för transportmed rör beror på faktorer som diameter, avstånd och flödeshastighet. Högre flödeshastigheter genomrörledningar kan minska transportkostnaderna. Lagringskostnader för CO2 omfattar utgifter förborrning, infrastruktur, projektledning, licensiering och platsval. Geologisk lagring på land är förnärvarande mer kostnadseffektivt på grund av de utmaningar och högre kostnader som är förknippademed geologisk lagring till havs. Övervakningskostnader är till exempel screening och utvärdering avlagringsplatser samt uppgifter som datainsamling, platsrankning, brunnsinstallation och seismiskautvärderingar. Att minska energitillgången för infångning, förbättra val av lösningsmedel vid separationsfasen,återanvända och utveckla befintlig infrastruktur är exempel som kan hjälpa till att sänka kostnadernaför CCS-processen och främja en bredare användning. Ett annat förslag för att öka den ekonomiskalönsamheten är genom att implementera CCS nav eller kluster. Dessa CCS nav eller kluster ger företagmöjligheten att samordna infrastrukturen för sina CCS-anläggningar. Detta kan lindra den ekonomiskabördan att bygga upp egen kostsam infrastruktur. Nedlagda olje- och gasfält kan återbrukas för CCS- anläggningar då efterfrågan av fossila bränslenminskar. Istället för att riva ner verksamheterna för fossilt bränsle, exploatera ny mark och borra nyahål kan olje- och gasfälten i exempelvis norra haven återbrukas för CCS- anläggningar. Danmark är ettav de första länderna som har tagit initiativet att omvandla oljeanläggningar till koldioxidlagringanläggningar. Det är möjligt att söka om ekonomiskt stöd från Energimyndigheten eller EU för att få stöd till främstBio-CCS projekt men även andra. Detta är i syfte för att underlätta en fri marknad för tekniker somimplementerar koldioxidinfångst. Ambitionen med detta stödsystem är för att realisera en infångst av10 miljoner CO2 via Bio-CCS och minst 2 miljoner CO2/år för andra CCS tekniker. Genom omvändauktion får det företag som kan erbjuda infångad CO2/ton med Bio-CCS teknik för lägst pris, ta del avstödsystemet. EU har även initiativ att finansiera CCS-projekt genom CETPartnership eller EU:sinnovationsfond vars syfte är att stödja forskning och innovation inom CCS. Sammanfattningsvis kom denna studie fram till att CCS inte är genomförbart idag som en teknik för attminska CO2 från atmosfären med hänsyn till nuläget och kostnaderna för att implementera. Om teknikenenergi effektiviseras och när ekonomiska medel finns på plats är framtiden ljus för CCS. Det är oerhörtrelevant att denna teknik fortsätter att utvecklas till ett bättre, billigare och snabbare sätt att fånga uppCO2 och minska utsläppen av de effektiva växthusgaserna. Regeringen och industrin måste därförsamarbeta bättre för att underlätta regelverk som främjar och möjliggör samarbete inom CCS-branschendå många myndigheter lyfter fram att CCS är en nödvändig teknik för framtiden för att uppnå klimatneutralitet.