Spelling suggestions: "subject:"catechol oxidation"" "subject:"katechol oxidation""
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On the mechanism of the reaction involved in the aerobic oxidation of catechol when catalyzed by the enzyme, tyrosinase ...Soloway, Saul, January 1941 (has links)
Thesis (Ph. D.)--Columbia University, 1942. / Vita. Bibliography: p. 14.
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The oxidation of catechol-type substrates by tyrosinaseCushing, Merchant Leroy, January 1941 (has links)
Thesis (Ph. D.)--Columbia University, 1941. / Vita. Bibliography: p. 20.
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A biomimetic approach to water-borne surface coatingsBroadbridge, Simon Glenn January 1998 (has links)
No description available.
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Metallopeptides As Model Systems For The Study Of Cu(II)-Dependent Oxidation ChemistryTay, William Maung 01 April 2008 (has links)
Copper is one of the essential metal ions for aerobic organisms. Two well known functions of copper in the biological systems are electron transfer and molecular oxygen interaction. Thus, this metal can be found in haemocyanin, an oxygen carrier protein, and superoxide dismutase, an enzyme that involves in electron transfer. In addition, having a positive redox potential allows copper to be involved in redox chemistry. It is the redox properties of copper that are responsible for many important biochemical processes. Although the copper-containing oxidases have been well studied over the years, certain mechanistic details such as reaction intermediates remain to be elucidated. Several research groups have been trying to study this by trying to mimic the native systems, synthesizing bulky organic molecules with copper-binding and oxidative capabilities. However, these model systems are only applicable in organic solvents at low temperatures. In this study, three naturally occurring peptides, amyloid-ß, bacitracin, and histatin 5, have been shown to display the oxidative chemistry when complexed with CuII. A combination of spectroscopic (UV-Vis and NMR) and reactivity was used in studying their metal-binding properties as well as in elucidating their catalytic mechanism.
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Materials for depollution based on the model of manganese dioxygenasesChaignon, Jérémy, Chaignon, Jérémy 20 December 2013 (has links) (PDF)
The objective of this work is the synthesis of model material for manganese dioxygenase which is an enzyme that oxidizes catechol-like substrates with dioxygen. Our strategy comprises three main steps that form the different chapters of this thesis: - Synthesis and characterization of manganese(II) complexes with tridentate ligands. - Optimization of a microwave-assisted synthesis of a mesoporous silica. - Functionalization of these materials and complex grafting, as well as preliminary catalytic tests. The ligands used are tertiary amines containing an alkyne arm and two coordinating arms with functions such as pyridine, imidazole or carboxylate. The complexes were crystallized and/or characterized by IR, EPR, SQUID and cyclic voltamperometry. Microwave synthesis, based on the conditions of classical hydrothermal synthesis, allowed us to reduce the synthesis time from one day to two hours. The quality of these new materials was verified by IR, TGA, BET and powder XRD. These materials are then bi-functionalized using a molecular stencil patterning mehod with a an azide function for complex grafting via click chemistry and a function pyridine or trimethylsilyl to control the coordinating ability of the metal environment. These complexes and materials are active in catechol oxidation with O2.
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Materials for depollution based on the model of manganese dioxygenases / Matériaux pour la dépollution basés sur le modèle des dioxygénases à manganèseChaignon, Jérémy 20 December 2013 (has links)
L'objectif de cette thèse est la synthèse d'un matériau modèle de la dioxygénase à manganèse, une enzyme oxydant des cycles aromatiques type catéchol grâce au dioxygène. Pour ce faire, nous avons découpé notre stratégie trois étapes constituant les différents chapitres de ce manuscrit : - La synthèse et la caractérisation des complexes de manganèse(II) avec des ligands tridentates. - L'optimisation d'une synthèse de silice mésoporeuse par micro-onde. - La fonctionnalisation des matériaux et le greffage des complexes, ainsi que les tests catalytiques préliminaires.Les ligands utilisés sont des amines tertiaires avec un bras alcyne et deux coordinants type pyridine, imidazole ou carboxylate. Ces complexes ont été cristallisés et/ou caractérisés par IR, RPE, SQUID et voltampérométrie cyclique. La synthèse par micro-onde, basée sur des conditions de synthèse hydrothermale classiquenous a permis de réduire le temps de synthèse d'un jour à deux heures. La qualité de ces nouveaux matériaux a été vérifiée par IR, ATG, BET, et DRX sur poudre. Ces matériaux sont ensuite bifonctionnalisés en utilisant une méthode de pochoir moléculaire avec une fonction azoture pour le greffage du complexe via "click-chemistry" ainsi qu'une fonction pyridine ou triméthylsilyle pour créer un environnement coordinant ou non proche du métal.Ces complexes et matériaux sont actifs dans l'oxydation du catéchol. / The objective of this work is the synthesis of model material for manganese dioxygenase which is an enzyme that oxidizes catechol-like substrates with dioxygen. Our strategy comprises three main steps that form the different chapters of this thesis: - Synthesis and characterization of manganese(II) complexes with tridentate ligands. - Optimization of a microwave-assisted synthesis of a mesoporous silica. - Functionalization of these materials and complex grafting, as well as preliminary catalytic tests. The ligands used are tertiary amines containing an alkyne arm and two coordinating arms with functions such as pyridine, imidazole or carboxylate. The complexes were crystallized and/or characterized by IR, EPR, SQUID and cyclic voltamperometry. Microwave synthesis, based on the conditions of classical hydrothermal synthesis, allowed us to reduce the synthesis time from one day to two hours. The quality of these new materials was verified by IR, TGA, BET and powder XRD. These materials are then bi-functionalized using a molecular stencil patterning mehod with a an azide function for complex grafting via click chemistry and a function pyridine or trimethylsilyl to control the coordinating ability of the metal environment. These complexes and materials are active in catechol oxidation with O2.
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