På grund av världens växande befolkning och urbaniseringen blir problem relaterade till fenomenet urbana värmeöar mer och mer påtagliga. Eftersom urbana parker kan minska påfrestningen skapad av urbana värmeöar kan de vara ett kraftfullt verktyg vid klimatdesign i städer. Temperaturen nära en yta bestäms av energiutbytet mellan ytan och luften ovanför och det är därför nödvändigt att man förstår energibalansen vid markytan för att kunna hantera parkernas mikroklimat. Syftet med det här arbetet var att studera skillnaderna mellan energibalansen för olika ytor i parken och i dess omgivning och att relatera skillnaderna i energibalanserna till temperaturskillnaderna. Mätningarna utfördes under tre klara sommardagar i parken Humlegården i centrala Stockholm. Mätutrustningen var monterad på en kärra som flyttades från mätplats till mätplats. Mätplatserna representerade olika typiska ytor i Humlegården och i dess omgivning: en skuggad och en öppen gräsmatta, en öppen och en skuggad grusyta och två asfaltytor, varav en löper i nord-sydlig riktning och en i öst-västlig riktning. Energiflödena beräknades med hjälp av data för luft- och yttemperatur, vindhastighet, luftfuktighet och nettostrålning. Resultaten visade att den tydligaste skillnaden mellan gräs- och grusytorna i parken var att gräsytorna hade ett större nedåtriktat latent värmeflöde under natten och ett mindre markvärmeflöde under hela dygnet. Den mest distinkta skillnaden mellan de skuggade och öppna ytorna i parken var att de skuggade ytorna hade mindre energiflöden under dagen och att de till skillnad från de andra ytorna hade ett nedåtriktat sensibelt värmeflöde under dagen. Den största skillnaden mellan ytorna i och utanför parken var att asfaltytorna hade ett större uppåtriktat sensibelt värmeflöde och markvärmeflöde under natten. Under natten var den svalaste mätplasten den öppna gräsmattan, vilken också var den enda mätplasten med ett nedåtriktat sensibelt värmeflöde under natten. Jämfört med de andra ickeskuggade mätplasterna hade den öppna gräsmattan ett mindre markvärmeflöde. Varmaste mätplasterna under natten var asfaltytorna som även hade ett större uppåtriktat sensibelt och markvärmeflöde än de andra ytorna. Under dagen var de skuggade ytorna i parken de svalaste platserna. De var de enda ytorna med ett nedåtriktat sensibelt värmeflöde och nettostrålningen vid ytan var mindre än för de flesta andra mätplatser. / The world’s growing population and the increasing urbanization has made problems related to the urban heat island phenomenon to become more pronounced and since urban parks reduce the stress produced by the urban heat island they can be powerful tools in urban climate design. The temperature near the surface in a park is determined by the energy exchanges between the surface and the air above and it is therefore necessary to understand the surface energy balance of parks to intelligently manage their thermal microclimate. The objectives of this work were to study how the energy balances differ between different surfaces inside parks and in their built-up surroundings and to relate the surface energy balances to temperature differences. Measurements were conducted during three clear summer days in the park Humlegården located in central Stockholm. The measuring instruments were mounted on a cart, which was transported from observation site to observation site. The observation sites represented typical surfaces found in an urban park and its surroundings: one shaded and one open grass surface, one open and one shaded gravel surface and two paved surfaces representing streets running in the north-south and east-west directions respectively. The energy fluxes were calculated using air and surface temperatures, wind speed, air humidity and net radiation data. The most pronounced differences between the shaded and open surfaces in the park was that the shaded surfaces in general had smaller energy fluxes during daytime and that they had a downward directed sensible heat flux while the open surfaces had an upward directed sensible heat flux during the day. The most significant difference between the grass and the gravel surfaces in the park was that the grass surfaces had a bigger downward directed latent heat flux during the night and a smaller ground heat flux during both day and night. The largest differences between the surfaces inside the park and those in its built-up vicinities were that the paved surfaces had a larger upward directed sensible and ground heat flux during the night than the other surfaces. During the day the north-south directed paved site had a downward directed ground heat flux that was much larger than the ground heat flux for the other sites. The coolest site during the night was the non-shaded grass surface, which was the only site with a downward directed sensible heat flux during the night. Compared to the other nonshaded sites the open grass surface had a much smaller ground heat flux. Warmest sites during the night were the paved surfaces, which had a larger upward directed sensible and ground heat flux than the other surfaces. At the built-up sites the walls also contributed with sensible heat flux, i.e. the total sensible heat flux in the built-up area was larger than what comes from the street surface only. During the day the shaded surfaces in the park were the coolest sites. The shaded surfaces had less net radiation compared to the other non-shaded surfaces and were the only sites that had a downward directed sensible heat flux.

Diverse forage mixtures have improved resilience to drought, improved persistence, ability to adapt to changing environmental conditions, reduced fertilizer costs, improved root mass and greater soil carbon sequestration but do they improve forage and animal production. The objective was to determine if complex native forage mixtures provide superior nutritional quality throughout the grazing season as compared to simple native mixtures. Three studies were conducted in 2007 at Swift Current, SK to evaluate forage production potentials, nutritive qualities and in vitro dry matter digestibility of native and tame forage species common to or having potential in Southwestern Saskatchewan. In study one, plots were seeded in 2006 on Chernozemic Orthic Brown Swinton Loam soils and consisted of 11 native and three tame monoculture species common to southwestern Saskatchewan. Clippings at a 5 cm stubble height occurred on June 20 and every 28 days after until October 10. Forage DM production, in vitro OMD, NDF, ADF, ADL, CP, Ca and P concentrations were measured. As species matured, production and OMD declined (P¡Ü0.05) but NDF, ADF and ADL concentrations increased (P¡Ü0.05). There were harvest date by species differences (P¡Ü0.05) in forage production and nutritional qualities of C3 and C4 grass and legume species. Study two examined the in situ CP, NDF and DM disappearance of six selected species harvested in the fall. EDNDF and ADDM values did not differ (P>0.05) among C3 grasses. The C4 grasses had higher (P<0.05) EDNDF and EDDM and the legume, Canadian milkvetch had the highest (P<0.05) EDDM but lowest EDNDF. Study three occurred in 2005, 2006 and 2007 to determine if complex native forage mixtures had superior forage and animal production as compared to simple forage stands. Grazing occurred from June through August to achieve 60% utilization. Animal weights and available, cage and residual forage yields were taken to determine production and utilization. Forage production and quality did not differ (P>0.05) between simple and complex forage mixtures but animal production (AUD ha-1) was higher on complex native mixtures. Overall results showed; 1) C3 and C4 grass and legume species have different growth patterns and qualities that can improve forage quality and degradability of the stand throughout the grazing season, 2) forage and animal production benefits associated with complex native forage mixtures largely depend on environmental conditions like temperature and moisture.

Diverse forage mixtures have improved resilience to drought, improved persistence, ability to adapt to changing environmental conditions, reduced fertilizer costs, improved root mass and greater soil carbon sequestration but do they improve forage and animal production. The objective was to determine if complex native forage mixtures provide superior nutritional quality throughout the grazing season as compared to simple native mixtures. Three studies were conducted in 2007 at Swift Current, SK to evaluate forage production potentials, nutritive qualities and in vitro dry matter digestibility of native and tame forage species common to or having potential in Southwestern Saskatchewan. In study one, plots were seeded in 2006 on Chernozemic Orthic Brown Swinton Loam soils and consisted of 11 native and three tame monoculture species common to southwestern Saskatchewan. Clippings at a 5 cm stubble height occurred on June 20 and every 28 days after until October 10. Forage DM production, in vitro OMD, NDF, ADF, ADL, CP, Ca and P concentrations were measured. As species matured, production and OMD declined (P¡Ü0.05) but NDF, ADF and ADL concentrations increased (P¡Ü0.05). There were harvest date by species differences (P¡Ü0.05) in forage production and nutritional qualities of C3 and C4 grass and legume species. Study two examined the in situ CP, NDF and DM disappearance of six selected species harvested in the fall. EDNDF and ADDM values did not differ (P>0.05) among C3 grasses. The C4 grasses had higher (P<0.05) EDNDF and EDDM and the legume, Canadian milkvetch had the highest (P<0.05) EDDM but lowest EDNDF. Study three occurred in 2005, 2006 and 2007 to determine if complex native forage mixtures had superior forage and animal production as compared to simple forage stands. Grazing occurred from June through August to achieve 60% utilization. Animal weights and available, cage and residual forage yields were taken to determine production and utilization. Forage production and quality did not differ (P>0.05) between simple and complex forage mixtures but animal production (AUD ha-1) was higher on complex native mixtures. Overall results showed; 1) C3 and C4 grass and legume species have different growth patterns and qualities that can improve forage quality and degradability of the stand throughout the grazing season, 2) forage and animal production benefits associated with complex native forage mixtures largely depend on environmental conditions like temperature and moisture.

Internal combustion engines have dealt with increasingly restricted emissions requirements. After-treatment devices are successful in bringing emissions into compliance, but in-cylinder combustion control can reduce their burden by reducing engine out emissions. For example, oxides of nitrogen (NOx) are diesel combustion exhaust species that are notoriously difficult to remove by after-treatment. In-cylinder conditions can be controlled for low levels of NOx, but this produces high levels of soot potentially leading to increased particulate matter (PM). The simultaneous reduction of NOx and PM can be realized through a combustion process known as low temperature combustion (LTC). In this study, the typical definition of LTC as the defeat of the inverse relationship between soot and NOx is not applicable as a return to the soot-NOx tradeoff is observed with increasing exhaust gas recirculation (EGR). It is postulated that this effect is the result of an increase in the hot ignition equivalence ratio, moving the combustion event into a slightly higher soot formation region. This is important because a simple emissions based definition of LTC is no longer helpful. In this study, the manifestation of LTC in the calculated heat release profile is investigated. The conditions classified as LTC undergo a two-stage ignition process. Two-stage ignition is characterized by an initial cool-flame reaction followed by typical hot ignition. In traditional combustion conditions, the ignition is fast enough that a cool-flame is not observed. By controlling initial conditions (pressure, temperature, and composition), the creation and duration of the cool-flame event is predictable. Further, the effect that injection timing and the exhaust gas recirculation level have on the controlling factors of the cool-flame reaction is well correlated to the duration of the cool-flame event. These two results allow the postulation that the presence of a sufficiently long cool-flame reaction indicates a combustion event that can be classified as low temperature combustion. A potential method for identifying low temperature combustion events using only the rate of heat release profile is theorized. This study employed high levels of EGR and late injection timing to realize the LTC mode of ordinary petroleum diesel fuel. Under these conditions, and based on a 90 percent reduction in nitric oxide and no increase in smoke output relative to the chosen baseline condition, a two part criteria is developed that identifies the LTC classified conditions. The criteria are as follow: the combustion event of conventional petroleum diesel fuel must show a two-stage ignition process; the first stage (cool-flame reaction) must consume at least 2 percent of the normalized fuel energy before the hot ignition commences.

Between 1985 and 1997 a hip hop culture emerged in Halifax, Nova Scotia through rap music artists' live performances at various venues, and by releasing original music on commercial and non-commercial cassette tapes and compact discs. This thesis examines the evolution of this grassroots musical culture through the lenses of Halifax's geography, innovative musical and technological trends, ever-present racial politics, and a strong "do-it-yourself" ethic. This thesis argues that hip hop in Halifax during these years can be divided into two eras distinguished by dynamic racial and stylistic changes. While the 1980s saw a predominantly Black hip hop community take root around Uniacke Square and Gottingen Street, the 1990s saw a geographic and demographic shift as the rap music scene expanded and competed with the mainstream music scene of the city. In doing so, the integrated downtown hip hop community produced a significant amount of work, overcoming institutional opposition

The objective of this study was to determine dairy cattle preference amongst four species of cool-season forage grasses: eight orchardgrasses (Dactylis glomerata L.), five tall fescues [Schedonorus arundinaceus (Schreb.) Dumort.], five perennial ryegrasses (Lolium perenne L.), and six festuloliums [xFestulolium braunii (K. Richt.) A. Camus.]; 24 cultivars in total. Each grazing trial utilized four Holstein-Friesian heifers over six hours. Maturity differences were eliminated by having animals graze only vegetative material. After six grazing trials (three each in 2014 and 2015), consistent results in animal preference were not found; three of the six trials did show preference (P

abstract: The intent of this research is to determine if cool roofs lead to increased energy use in the U.S. and if so, in what climates. Directed by the LEED environmental building rating system, cool roofs are increasingly specified in an attempt to mitigate urban heat island effect. A typical single story retail building was simulated using eQUEST energy software across seven different climatic zones in the U.S.. Two roof types are varied, one with a low solar reflectance index of 30 (typical bituminous roof), and a roof with SRI of 90 (high performing membrane roof). The model also varied the perimeter / core fraction, internal loads, and schedule of operations. The data suggests a certain point at which a high SRI roofing finish results in energy penalties over the course of the year in climate zones which are heating driven. Climate zones 5 and above appear to be the flipping point, beyond which the application of a high SRI roof creates sufficient heating penalties to outweigh the cooling energy benefits. / Dissertation/Thesis / M.S. Built Environment 2011

O uso de pinturas \"frias\", em coberturas e fachadas, é uma estratégia utilizada para melhorar a sensação térmica dos usuários por meio do aumento desempenho térmico das edificações, potencializar a eficiência energética e mitigar ilhas de calor. Por outro lado, a exposição ao longo do tempo pode alterar a capacidade refletiva dessas superfícies, devido à deposição de sujidades e crescimento microbiológico. Esse estudo tem o objetivo de avaliar a manutenção da capacidade refletiva, a alteração da cor, do aspecto e da emissividade de pinturas expostas por três anos ao envelhecimento natural. Para esse estudo foram produzidos, em laboratório, dois grupos de tintas tipo premium, para uso em superfícies externas de fachadas e coberturas, com dois acabamentos: acetinado (PVC 30%) e fosco (PVC 50%), nas cores: branco, cinza, amarelo e marrom, que são cores usualmente utilizadas em fachadas e coberturas no Brasil. Um grupo é composto por tintas convencionais, formuladas com pigmentos inorgânicos naturais e orgânicos. O outro grupo é composto por tintas formuladas com pigmentos, com alta capacidade de refletância solar na região do infravermelho próximo, conhecidos como pigmentos \"frios\". Ainda há um terceiro grupo de tintas que foi coletado do mercado e utilizado como referência. Na exposição ao envelhecimento natural o microclima é um dos fatores determinantes no tipo de degradação da pintura, por isso esse estudo contempla os três microclimas predominantes do Estado de São Paulo: rural (Pirassununga), urbano (São Paulo) e costeiro (Ubatuba). Nesse trabalho estão sendo apresentados os resultados obtidos com três anos de exposição e já foi possível observar redução da refletância inicial, alteração de cor (diminuição do índice L luminosidade) e indícios de crescimento microbiológico. / The application of cool paints, on roofs and facades components, is a strategy to improve indoor thermal comfort for users in rooms that are not air conditioned. Increasing the thermal performance of buildings, enhance thermal efficiency and mitigate urban heat island. On the other hand, the exposure of paints over time can change reflectance capability of the surface, due to dirty deposition and microbiological colonization. The objectives of this study is evaluate the level of maintenance of reflectance, emissivity, color and visual aspects of paints after three years of natural aging exposure. Two groups of \"premium\" type paints, formulation recommended for applications on facades and roofs, we prepared in laboratory. Each group of paints was produced with two sheen type, two ratios pigment to binder, gloss finish (PVC 30%) and silk finish (PVC 50%), for the colors white, yellow, grey and brown, which are the most used colors in facades and roofs in Brazil. One group, the standard paint, was produced with natural inorganic and organic pigments and the other group was produced with cool pigments, which has high solar reflectance capacity in the near-infrared spectrum. Additionally, a third group of paints was acquired from the market and used as reference data. The microclimate is one of the key factors for paint degradation by natural aging, so in this study was considered three major microclimates of São Paulo State: rural (Pirassununga City),urban (São Paulo city) and oceanic climate (Ubatuba). The present study shows the results of the paints after three years exposure, which was observed significant reduction in reflectance, color change (reduction of the luminance L index) and evidences of microbiological colonization.

The Great Australian Bight (GAB) is an extensive W-E striking continental margin basin that drifted northwards during the Cenozoic following rifting and separation from Antarctica in the mid/late Cretaceous. Seafloor spreading accelerated in the mid-Eocene and was associated with local volcanism. The mid-Eocene succession of the GAB is conspicuously mounded and separates a dominantly siliciclastic succession below from a fully marine carbonate succession above. The mounded succession was penecontemporaneous with major changes in global climate, oceanographic conditions and tectonic re-organization in the region, and thus may hold important clues as to the palaeo-environmental changes associated with these changes. The mid Eocene has so far only been described locally or in passing, usually by studies focused on either the siliciclastics below or the carbonates above. It was therefore chosen as a major focus point for the research project reported herein. Exploration activity in the GAB has been limited despite the presence of a working petroleum system and large target structures, but industry interest has increased over the past few years leading to 3D seismic surveys being acquired in the GAB. The focus for exploration is the Cretaceous succession beneath the relatively thin Cenozoic cover, which however, is still important in terms of shallow hazards and as overburden to the anticipated productive sections. As is often the case, the new 3D seismic data shows many overburden features in great detail and thus affords new insights to be gained that improve our understanding of the post-rift evolution of the marginThis thesis expands upon and reinterprets a pre-existing sequence framework in the Cenozoic GAB based from ODP Leg 182 results. A vast database of 2D and 3D seismic surveys has been integrated with exploration wells and borehole data and several surfaces have been calibrated to borehole and well constraints, then mapped to the maximum lateral extent across the available dataset. Surface mapping provided new insight into sequence deposition and palaeoenvironmental settings. Structure maps and thickness maps highlight key depocentre locations and trends over the Cenozoic GAB as well as stacked mass debris aprons. The newly discovered sequences raise new questions regarding trigger mechanisms in a-seismic areas and feed into industry geohazard perception models. The base surface of the Cenozoic framework hosts a plethora of mounded features across shelf and basinal section. All mounds within the dataset have been mapped. A set a bryozoan reef mounds have been interpreted lying parallel to the margin as linear complexes over 500 km. They coincide with the underlying siliciclastic delta clinoform breakpoints and provide insight into the changing palaeoenvironment at the 43 Ma mark, cessation of siliciclastics and regional marine transgression. Further mound mapping aided by 3D attribute extractions along the base Cenozoic unconformity led to the interpretation of a series of enigmatic igneous-based mounded features. The discoveries have been included in a comparative study, comparing all mounded features (igneous or carbonate) and contrasting their individual characteristics of geometry, seismic facies, dimension in order to understand mound origin and emplacement. A new grouping of mounds in the GAB has been established, the origin and emplacement mechanisms of which contribute to the global knowledge base.

Les étoiles de petite masse (naines M) forment la composante stellaire dominante de notre galaxie et contribuent à la majeure partie de la matière baryonique dans la galaxie. Notre compréhension de la galaxie repose donc sur la connaissance de cette composante peu lumineuse. Par ailleurs, un nombre grandissant d’exoplanètes sont découverte autour de naines M, y compris des super-terres. L’étude des naines M a ainsi des implications importantes sur la physique stellaire, permettant de comprendre les processus en jeu dans ces atmosphères froides. Ces astres restent cependant peu connus du fait de leur faible luminosité intrinsèque. La description de ces étoiles nécessite une validation empirique fort, notamment en ce qui concerne les effets de l’abondance chimique sur la physique des atmosphères froides.Le but de cette thèse est de déterminer les paramètres fondamentaux des naines M et de tester les modèles d’atmosphères d’étoiles froides.Dans la première partie nous comparons des spectres calibrés dans le visible et l’infrarouge des composantes de système triple LHS 1070 avec des spectres synthétiques. Cette étude permet d’améliorer notre compréhension de la formation de la poussière dans les atmosphères très froides. Ce travail est étendu à un échantillon de naines M et permet de déterminer l’échelle de température des naines M. La seconde partie présente l’analyse des spectres à haute résolution de 21 naines M de faible métallicité (sous naines). Nous analysons en détail les signature moléculaires et atomiques dans le spectre. La comparaison avec des spectres synthétiques permet de mesurer les paramètres stellaires des étoiles et de déterminer avec précision leur métallicité. Ce travail doit initier des recherches futures. En particulier nous voulons étendre cette étude dans le domaine proche-infrarouge pour s’assurer que les résultats obtenus sont cohérents du domaine optique jusqu’à l’infrarouge proche. / Very Low-Mass stars (M dwarfs) are an important source of information for probing the lowmass end of the main sequence, down to the hydrogen burning limit. They are the dominantstellar component of the Galaxy and make up the majority of baryonic matter in the Galaxy.Moreover, an increasing number of M dwarfs are now known to host exoplanets, includingsuper-Earth exoplanets. The determination of accurate fundamental parameters for M dwarfshas therefore relevant implications for both stellar and Galactic astronomy as well as planetology.Despite their large number in the Galaxy, M dwarfs remain elusive objects and themodelling of their photosphere has long remained a challenge (molecular opacities, dust cloudformation). The description of these stars therefore need a strong empirical basis, or validation.In particular, the effect of metallicity on the physics of cool atmospheres are still poorly known,even for early-type M-dwarfs.[...]