Quantenkaskadenlaser (QCLs) wurden vor gerade zwanzig Jahren erfunden und haben seitdem stetig im weltweiten Markt der optoelektronischen Bauelemente für den Infrarot an Bedeutung gewonnen. Anwendungsbeispiele für aktuelle und potenzielle Einsatzgebiete von QCLs sind photoakustische Spektroskopie, Umweltüberwachung, Simulation von heißen Körpern, und optische Freiraumdatenübertragung. Rekord optische Leistungen von 14 W und Leistungseffizienzen zwischen 15-35 % wurden bei mittelinfraroten QCLs für Betriebstemperaturen zwischen 80-300 K erreicht. Die weitere Verbesserung dieser Eigenschaften hängt nicht nur von Aspekten wie Wärmemanagement und Chip-Packaging ab, sondern auch von Verbesserungen im Laserdesign zwecks der Reduzierung des Ladungsträgerleckstroms. Dennoch sind die verschiedenen Mechanismen und Komponenten des Leckstroms in Quantenkaskadenlasern leider noch nicht gründlich untersucht worden. Die vorliegende Arbeit liefert a realistische Beschreibung der Ladungsträgertransports in QCLs. Wir beschreiben u.a. Leckströme vom Quantentopf- in höhere Zustände und diskutieren elastische und inelastische Streumechanismen von Ladungsträgern bei mittelinfraroten Quantenkaskadenlasern. Wir illustrieren außerdem die Notwendigkeit zur Berücksichtigung der Elektronentemperatur für eine vollständigere Analyse der Ladungsträgertransporteigenschaften von Quantenkaskadenlasern. Methoden zur experimentellen Ermittlung des temperaturabhängigen Leckstroms in Quantenkaskadenlasern werden präsentiert. Unser Ansatz liefert eine Methode zur effektiven Analyse von der QCL-Leistung und Vereinfacht die Optimierung von QCL aktive Regionen. / Two decades after their invention in 1994, quantum-cascade lasers (QCLs) become increasingly important in the global infrared optoelectronics market. Photoacoustic spectroscopy, environment monitoring, hot object simulation, and free-space communication systems are selected examples of the current and potential applications of QCLs. Record optical powers as large as 14 W and power-conversion efficiencies ranging between 15-35 % have been reported for MIR QCLs for temperatures 80-300 K. Further improvement of these characteristics depends not only of aspects as heat management and chip-packaging, but also on improving the active-region design to reduce several leakage channels of charge carriers. However, mechanisms through which leakage of charge carriers affects QCLs performance have not been thoroughly researched. A better understanding of the several (non-radiative) scattering mechanisms involved in carrier transport in QCLs is needed to design new structures and optimize their performance. This work provides a realistic description of charge carriers transport in QCLs. We discuss in particular carrier leakage from QCL quantum-well confined states into higher and lower states. The two main mechanisms for non-radiative intersubband scattering in MIR QCLs are electron-longitudinal-optical-phonon scattering and interface roughness-induced scattering. We present methods for the experimental determination of the leakage current in QCLs at and above laser threshold, which allowed us to estimate the sheet distributions of conduction band states and better understand the impact of temperature activated leakage on QCLs characteristics. We found that even at temperatures low enough to neglect ELO scattering, carriers leakage due to IFR becomes significant for devices operating at high electron temperatures. Altogether, this approach offers a straightforward method to analyze and troubleshoot new QCL active region designs and optimize their performance.

"The ablative Teflon pulsed plasma thruster (PPT) is an onboard electromagnetic propulsion enabling technology for small spacecraft missions. The integration of PPTs onboard spacecraft requires the understanding and evaluation of possible thruster/spacecraft interactions. To aid in this effort the work presented in this thesis is directed towards the development and application of Langmuir probe techniques for use in the plume of PPTs. Double and triple Langmuir probes were developed and used to measure electron temperature and density of the PPT plume. The PPT used in this thesis was a laboratory model parallel plate ablative Teflon® PPT similar in size to the Earth Observing (EO-1) PPT operating in discharge energies between 5 and 40 Joules. The triple Langmuir probe was operated in the current-mode technique that requires biasing all three electrodes and measuring the resulting probe currents. This new implementation differs from the traditional voltage-mode technique that keeps one probe floating and requires a voltage measurement that is often susceptible to noise in the fluctuating PPT plume environment. The triple Langmuir probe theory developed in this work incorporates Laframboise’s current collection model for Debye length to probe radius ratios less than 100 in order to account for sheath expansion effects on ion collection, and incorporates the thin-sheath current collection model for Debye length to probe radius ratios greater than 100. Error analysis of the non-linear system of current collection equations that describe the operation of the current-mode triple Langmuir probe is performed as well. Measurements were taken at three radial locations, 5, 10, and 15 cm from the Teflon® surface of the PPT and at angles of 20 and 40 degrees to either side of the thruster centerline as well as at the centerline. These measurements were taken on two orthogonal planes, parallel and perpendicular to the PPT electrodes. A data-processing software was developed and implements the current-mode triple Langmuir probe theory and associated error analysis. Results show the time evolution of the electron temperature and density. Characteristic to all the data is the presence of hot electrons of approximately 5 to 10 eV at the beginning of the pulse, occurring near the peak of the discharge current. The electron temperature quickly drops off from its peak values to 1-2 eV for the remainder of the pulse. Peak electron densities occur after the peak temperatures. The maximum electron density values on the centerline of the plume of a laboratory PPT 10 cm from the Teflon® surface are 6.6x10^19 +/- 1.3x10^19 m^-3 for the 5 J PPT, 7.2x10^20 +/- 1.4x10^20 m^-3 for the 20 J PPT, and 1.2x10^21 +/- 2.7x10^20 m^-3 for the 40 J PPT. Results from the double Langmuir probe taken at r=10 cm, theta perpendicular=70 degrees and 90 degrees of a laboratory PPT showed good agreement with the triple probe method."

科学研究費補助金 研究種目:基盤研究(A)(2) 課題番号:11305004 研究代表者:後藤 俊夫 研究期間:1999-2001年度

The non-uniform dc glow discharge plasma system is studied by using isolated computer controlled three couples of double probe system (TCDP) in argon gas, simultaneously. TCDP system has been developed to use for magnetized, unmagnetized, and for low oscillating plasma systems by using low pass filter with optically isolated circuitry to minimize the measurement errors with higher resolution and accuracy. Difference in the shapes and diameters of the discharge tube from region to region leads to change in the positive column glow discharge properties. This is because the positive column inhomogeneities, rising from the increase in the electron densities at the small tube radius region than the large one. Therefore, the axial electric field and the electron temperature have been diverted from their normal behavior in the positive column. However, at the large radius regions, the axial electric field seams to stay approximately constant at higher discharge currents. On the other hand, In this work the radial dependence of the electron temperature, density, floating potential, and the normalized probe radius (&amp / #958 / =rp&amp / #955 / D) has been investigated. Since, the probe radius is smaller than Debye length, the orbital motion limited (OML) theory has been used. As a result, the electron temperature (at the center) decreased and density increased with decreasing tube radius, and they have maximum values at the first probe (near the cathode). The electron density ne was observed to decrease and electron temperature Te to increase with increasing the discharge current. The floating potential has less negative value with decreasing tube radius except at the higher currents. Finally, it has been found that the &amp / #958 / is proportional with electron density, but it remains constant depending on the value of Te and ne.

京都大学 / 新制・課程博士 / 博士(エネルギー科学) / 甲第24926号 / エネ博第468号 / 新制||エネ||88(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー基礎科学専攻 / (主査)准教授 南 貴司, 教授 稲垣 滋, 教授 田中 仁 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM

The concept of plasma flow control is a relatively new idea based on using atmospheric plasma placed near the edge of an air foil to reduce boundary layer losses. As with any new concept, it is important to be able to quantify theoretical assumptions with known experimental results for validation. Currently there are a variety of experiments being done to better understand plasma flow control, but one particular experiment is through the use of multi-physics modeling of dielectric barrier discharge actuators. The research in this thesis uses optical measurement techniques to validate computational models of flow control actuators being done concurrently at Virginia Tech. The primary focus of this work is to design, build and test plasma actuators in order to determine the plasma characteristics relating to electron temperatures and densities. Using optical measurement techniques such as plasma spectroscopy, measured electron temperatures and densities to compare with theoretical calculations of plasma flow control under a variety of flow conditions. This thesis covers a background of plasma physics, optical measurement techniques, and the designing of the plasma actuator setups used in measuring atmospheric plasmas. / Master of Science

Ce travail est consacré à l’étude de la dynamique ultrarapide d’électrons chauds photo-excité dans des structures plasmonique. L’intérêt particulier de ce domaine réside dans le fait que les SPs, en raison de leurs caractéristiques spatio-temporelles spécifique, offrent un nouvel attrait technologique pour les processus de transport d’information ultra-rapide aux nano-échelles. Dans ce contexte, ce manuscrit offre une compréhension et une exploitation de l’une des principales limitations des technologies à base de SP : les pertes par effet Joule. Nous exploitons le fait que le mécanisme d’absorption des plasmons dans les métaux est suivi par la génération d’électrons chauds à l’échelle femtoseconde, ainsi les pertes peuvent être considrées comme une conversion d’énergie plasmon-électrons chauds. Cette conversion d’énergie est mesurée à l’aide d’une technique pompe-sonde laser femtoseconde. Nous lançons des impulsions SP que nous sondons sur des centaines de femtosecondes grace aux variations de permittivité diélectrique induites par le gaz d’électrons chaud accompagnant la propagation de SP. Le profil de température électronique est par conséquent une image de la distribution de densité de puissance de plasmon (absorption) non élargi spatialement et temporellement par diffusion de porteurs d’énergie. Nous avons pu démontrer la capacité de relier la mesure de température électronique à l’absorption du SP, révélant une absorption anormale autour d’une fente nanométrique. Les résultats expérimentaux sont en accord quantitatif avec les prédictions théoriques de la distribution de densité de puissance. Dans une seconde partie, nous avons étudié les pertes plasmoniques et leurs caractéristiques lors de sa propagation sur un film métallique semi-infini. Nous avons déterminé la vitesse de l’onde thermique électronique et son atténuation. Dans la dernière partie, nous utilisons une structure en pointe pour guider adiabatiquement et focaliser le plasmon à l’extrémité. Nous avons démontré ainsi la génération d’un point chaud nanométrique et avons mis en évidence un retard dans l’échauffement des électrons à l’extrémité de la pointe. Les perspectives et les questions ouvertes sont également discutées. / In this work we explored the ultrafast dynamics of photo-excited hot electrons in plasmonic structures. The particular interest of this field resides on the fact surface plasmons (SP), because of their unrivaled temporal and spatial characteristics, provide a technological route for ultrafast information processes at the nanoscale. In this context, this manuscript provides a comprehension and the harnessing of one of the major limitation of the SP-based technologies : absorption losses by Joule heating. We exploit the fact that the mechanism of plasmon absorption in metals is followed by generation of hot electrons at femtosecond time scale, thus losses can be seen as a plasmon-to-hot-electron energy conversion. This energy conversion is measured with femtosecond pump-probe technique. Femtosecond SP pulses are launched and probed over hundred femtoseconds through the permittivity variations induced by the hot-electron gas and which accompany the SP propagation. The measured electron temperature profile is therefore an image of plasmon power density distribution (absorption) not broadened spatially and temporally by energy carrier diffusion. As an important result we demonstrated the capability to link the electronic temperature measurement to the plasmonic absorption, revealing an anomalous light absorption for a sub- slit surroundings, in quantitative agreement with predictions of the power density distribution. In a second part we studied plasmon losses and their characteristics when they propagate on semi-infinite metal film. We determined the electronic thermal wave velocity and damping. In the last part we used a focusing taper-structure to adiabatically guide and focus the plasmon at the apex. Was demonstrated the generation of a nanoscale hot spot and put in evidence a delayed electron heating at the taper apex. Perspectives and the remaining open questions are also discussed.

No description available.

This thesis deals with the study of parameters of diaphragm discharge in liquids. NaCl solution of different conductivity was used as a conductive medium. Conductivities were adjusted in the range from 220 to 1000 µS cm-1. Two diagnostic methods were used for the study of plasma parameters. The first one was employed in the laboratory of plasma chemistry at Faculty of Chemistry, Brno University of Technology, namely the optical emission spectroscopy. The second method used for plasma diagnostics was the time resolved ICCD camera at the Laboratoire de Physique des Plasmas at the École Polytechnique in Paris. The reactor for the diagnostics by optical emission spectroscopy had the volume of 4 l, and it was made of polycarbonate. PET diaphragm was placed in the barrier separating the cathode and the anode space. Electrodes were made of titanium coated with platinum. Electric power source supplied a constant DC voltage of maximum 5 kV and electric current up to 300 mA. Spectrometer Jobin Yvon TRIAX 550 with CCD detector was used during the experiments in order to measure overview spectra within the range from 200 to 900 nm as well as OH molecular spectra and Hß line spectra. All spectra were scanned in both discharge polarities, i.e. at the cathode and the anode part of reactor. The basic parameters of the discharge plasma were calculated from the spectra, that means rotational and electron temperature and electron density. Another part of experiment consisted of measurements by the ICCD camera iStar 734. Two types of reactors were used. The first one was the same as the reactor for the measurements by the optical emission spectroscopy. The second one was also made of polycarbonate, but the volume of conductive solution was 110 ml, only. HV electrodes made of stainless steel were placed in this reactor. Ceramic diaphragm (Shapal-MTM) was used in both reactors. Diaphragms had different thickness and diameter of holes. ICCD camera acquired photographs with details of processes of the bubbles generation and discharge operation (propagation of plasma channels), depending on solution conductivity, dimensions of the diaphragm, and with respect to the electrode part of the reactor.

This thesis presents results on the theoretical description of ion acceleration using ultra-short ultra-intense laser pulses. It consists of two parts. One deals with the very general and underlying description and theoretic modeling of the laser interaction with the plasma, the other part presents three approaches of optimizing the ion acceleration by target geometry improvements using the results of the first part. In the first part, a novel approach of modeling the electron average energy of an over-critical plasma that is irradiated by a few tens of femtoseconds laser pulse with relativistic intensity is introduced. The first step is the derivation of a general expression of the distribution of accelerated electrons in the laboratory time frame. As is shown, the distribution is homogeneous in the proper time of the accelerated electrons, provided they are at rest and distributed uniformly initially. The average hot electron energy can then be derived in a second step from a weighted average of the single electron energy evolution. This result is applied exemplary for the two important cases of infinite laser contrast and square laser temporal profile, and the case of an experimentally more realistic case of a laser pulse with a temporal profile sufficient to produce a preplasma profile with a scale length of a few hundred nanometers prior to the laser pulse peak. The thus derived electron temperatures are in excellent agreement with recent measurements and simulations, and in particular provide an analytic explanation for the reduced temperatures seen both in experiments and simulations compared to the widely used ponderomotive energy scaling. The implications of this new electron temperature scaling on the ion acceleration, i.e. the maximum proton energy, are then briefly studied in the frame of an isothermal 1D expansion model. Based on this model, two distinct regions of laser pulse duration are identified with respect to the maximum energy scaling. For short laser pulses, compared to a reference time, the maximum ion energy is found to scale linearly with the laser intensity for a simple flat foil, and the most important other parameter is the laser absorption efficiency. In particular the electron temperature is of minor importance. For long laser pulse durations the maximum ion energy scales only proportional to the square root of the laser peak intensity and the electron temperature has a large impact. Consequently, improvements of the ion acceleration beyond the simple flat foil target maximum energies should focus on the increase of the laser absorption in the first case and the increase of the hot electron temperature in the latter case. In the second part, exemplary geometric designs are studied by means of simulations and analytic discussions with respect to their capability for an improvement of the laser absorption efficiency and temperature increase. First, a stack of several foils spaced by a few hundred nanometers is proposed and it is shown that the laser energy absorption for short pulses and therefore the maximum proton energy can be significantly increased. Secondly, mass limited targets, i.e. thin foils with a finite lateral extension, are studied with respect to the increase of the hot electron temperature. An analytical model is provided predicting this temperature based on the lateral foil width. Finally, the important case of bent foils with attached flat top is analyzed. This target geometry resembles hollow cone targets with flat top attached to the tip, as were used in a recent experiment producing world record proton energies. The presented analysis explains the observed increase in proton energy with a new electron acceleration mechanism, the direct acceleration of surface confined electrons by the laser light. This mechanism occurs when the laser is aligned tangentially to the curved cone wall and the laser phase co-moves with the energetic electrons. The resulting electron average energy can exceed the energies from normal or oblique laser incidence by several times. Proton energies are therefore also greatly increased and show a theoretical scaling proportional to the laser intensity, even for long laser pulses.