<p dir="ltr">Ice thermal energy storage (ITES) systems have long been an economic way to slash cooling costs in the commercial sector since the 1980s. An ITES system generates cooling in the formation of ice within a storage tank. This occurs during periods of the day when the cost of electricity is low, normally at night. This ice is then melted to absorb the energy within the conditioned space. While ITES systems have been prosperous in the commercial sector, they have yet to take root in the residential sector.</p><p dir="ltr">The U.S. Department of Energy (DoE) has published guidelines for TES. The DoE guidelines include providing a minimum of four hours of cooling, shifting 30-50% of a space’s cooling load to non-peak hours, minimizing the weight, volume, complexity, and cost of the system, creating a system than operates for over 10,000 cycles, enacting predictive control measures, and being modular to increase scale for larger single-family and multi-family homes [1]. The purpose of this research is to develop a model that meets these guidelines.</p><p dir="ltr">After extensive research in both experimental data, technical specifications, existing models, and best practices taken from the works of others a MATLAB model was generated. The modeled ITES system is comprised of a 1m diameter tank by 1m tall. Ice was selected as the PCM. A baseline model was constructed with parameters deemed to be ideal. This model generated an ITES system that can be charged in under four hours and is capable of providing a total of 22.18 kWh of cooling for a single-family home over a four-hour time period. This model was then validated with experimental data and found to have a root mean squared error of 0.0959 for the system state of charge. During the validation both the experimental and model estimation for the water/ice within the tank converged at the HTF supply temperature of -5.2°C.</p><p dir="ltr">With the model established, a parametric analysis was conducted to learn how adjusting a few of the system parameters impact it. The first parameter, reducing the pipe radius, has the potential to lead to a 152.6-minute reduction in charge time. The second parameter, varying the heat transfer fluid (HTF) within the prescribed zone of 0.7 kg/s to 1.2 kg/s, experienced a 4.8-minute increase in charge time for the former and a decrease in charge time by 5.4 minutes for the latter. The third parameter, increasing the pipe spacing and consequently increasing the ratio of mass of water to mass of HTF, yielded a negative impact. A 7.1mm increase in pipe spacing produced a 16.6-minute increase in charge time. Meanwhile, a 14.2mm increase in pipe spacing created a 93.3-minute increase in charge time and exceeded the charging time limit of five hours.</p><p dir="ltr">This functioning model establishes the foundation of creating a residential-scale ITES system. The adjustability and scalability of the code enable it to be modified to user specifications. Thus, allowing for various prototypes to be generated based on it. The model also lays the groundwork to synthesize a code containing an ITES system and a heat pump operating as one. This will aid in the understanding of residential-scale ITES systems and their energy effects.</p>

The fast pyrolysis plant at RISE – ETC, Piteå produces carbon rich chars in bulk from various sources of biomass as feedstock. These in-house manufactured carbon rich chars were upgraded via pyrolysis as well as chemical activation using KOH to enhance their potential as an electrode material for supercapacitors. Commercial activated charcoal (Merck) was also studied and used as a yardstick for comparing performance of our materials. Investigations using EDX show enrichment in carbon content and very low amounts of impurities in the materials prepared from wood char after specific treatments for upgrading. Two-electrode coin cell apparatus with an aqueous electrolyte was used to determine the electrochemical performance of these materials. Wood char after KOH activation shows a high specific capacitance of ~105 Fg-1 at 2 Ag-1 in galvanostatic charge discharge measurements which outperformed activated charcoal used in this study (~68 Fg-1 at 2 Ag-1). This material was tested in a wide range of conditions (current density ranging from 0.1 Ag-1 to 10 Ag-1) and showed specific capacitance from ~90 Fg-1 (for 10 Ag-1) up to ~118 Fg-1 (for 0.1 Ag-1). Fatigue testing for &gt;20000 cycles showed a remarkably high retention (&gt;96%) of capacitance. Currently, most commercial supercapacitors use activated carbon materials prepared from coconut shells as the active electrode material which are not native to Sweden. In this study, we upgrade wood chars produced at RISE – ETC from biomass sources obtained locally (Sweden and Scandinavia) and demonstrate their applicability as supercapacitor electrode materials. / Den snabba pyrolysanläggningen vid RISE - ETC, Piteå, producerar kolrika kol i bulk från olika källor till biomassa som råvara. Dessa interna tillverkade kolrika karaktärer uppgraderades via pyrolys samt kemisk aktivering med hjälp av KOH för att förbättra deras potential som ett elektrodmaterial för superkondensatorer. Kommersiellt aktivt kol (Merck) studerades och användes som en måttstock för att jämföra våra materials prestanda. Undersökningar med EDX visar berikning av kolinnehåll och mycket låga mängder föroreningar i material som framställts av träkol efter specifika behandlingar för uppgradering. Tvåelektrodmyntcellapparater med en vattenhaltig elektrolyt användes för att bestämma den elektrokemiska prestandan hos dessa material. Träkol efter KOH-aktivering visar en hög specifik kapacitans på ~ 105 Fg-1 vid 2 Ag-1 i galvanostatiska laddningsurladdningsmätningar som överträffade aktivt kol som användes i denna studie (~ 68 Fg-1 vid 2 Ag-1). Detta material testades under ett stort antal betingelser (strömtäthet från 0,1 Ag-1 till 10 Ag-1) och visade specifik kapacitans från ~ 90 Fg-1 (för 10 Ag-1) upp till ~ 118 Fg-1 (för 0,1 Ag-1). Trötthetstestning för &gt; 20000 cykler visade en anmärkningsvärt hög retention (&gt; 96%) av kapacitansen. För närvarande använder de flesta kommersiella superkondensatorer aktivt kolmaterial framställt av kokosnötskal som det aktiva elektrodmaterialet som inte är hemma i Sverige. I den här studien uppgraderar vi träkolor som produceras vid RISE - ETC från biomassakällor erhållna lokalt (Sverige och Skandinavien) och visar deras användbarhet som superkapacitorelektrodmaterial.

Energy storage systems will likely be needed for future shipboard power systems that supply loads with high power variability such as pulsed power loads. The power generation in shipboard power systems may not be sufficient to satisfy the energy demands of the pulsed power load systems operating in conjunction with other ship service loads. Two fundamental items in evaluating the requirements of an energy storage system are the energy storage capacity and the ratings of the power conversion equipment that interfaces the energy device to the power system. The supply current of pulsed power load systems is aperiodic and cannot be described in terms of active power. Also, the RMS value and thus apparent power are only defined for periodic quantities. Therefore traditional methods of rating power equipment cannot be used. This thesis describes an approach to determine the ratings of an energy storage interface and the energy storage capacity of an energy storage device as a function of load and supply parameters. The results obtained using the proposed approach are validated with the results obtained from the simulation model of the generator supplying a pulsed power load in conjunction with an energy storage system. The energy storage system requirements for various pulsed power load profiles are obtained using the proposed approach. The method used for determining the ratings of an energy storage system utilizes an orthogonal decomposition of pulsed power load system supply current evaluated within a sliding window. The signals obtained from the decomposition are also useful in generating the control reference signals for the energy storage interface. Although the approach and methods are focused on a particular structure of the pulsed power load system, they may be generalized for use in any type of configuration of a pulsed power load system.

This thesis is a part of the research work for Azelio TES.POD (Thermal energy storage. power on demand). It is a patented thermal energy storage system developed by Swedish cleantech company Azelio AB. The objective of this thesis work to find an alternative charging technology system that can be validated to be efficient and safe in operation for the charging of TES.POD. Induction heating technology is chosen as an alternative charging solution. Derived design steps to implement induction heater as a charging unit then selection of PCM container compatible with induction heater. Later simulating to evaluate total flux path in Finite Element Method Magnetics (FEMM) simulation tool which proposes the electrical results. The electrical performance of the induction heater indicates almost 9% higher electrical losses than the charging mechanism of the existing TES.POD design. However, from a safety standpoint, the alternate charging approach appears to be safer in operation than the existing system. Additionally, it reflects better intuitiveness from a manufacturing viewpoint.

Pumped hydro energy storages commonly plan their operations on short-term forecasts of the upcoming electricity prices, meaning that errors in these forecasts would entail suboptimal operations of the energy storage. Despite the high investment costs of pumped hydro energy storages, few studies take a holistic approach to the uncertainties involved in such investment decisions. The aim of this study is to investigate how forecast errors in electricity prices affect the chosen size configuration in investment decisions for pumped hydro energy storages. Moreover, sizing decisions are made in the long-term and involve long-term uncertainties in electricity prices. A robust decision-making framework including long-term electricity price scenarios is therefore used to evaluate the effects of including forecast errors in the sizing decision. By simulating the day-to-day operation of the energy storage with short-term forecasts, the effects of including the errors are compared to using perfect information. Using this approach, the most robust capacity is shown to increase by 25 MW, from 2 375 MW to 2 400 MW, when including forecast errors instead of assuming perfect information in the simulations. This indicates that the deviations in short-term forecasts require the pumped hydro energy storage operator to be more flexible in their operations, thus requiring a higher capacity. In addition, the profitability of the energy storage decreased significantly when including forecast errors in the simulations, showing the importance of taking the short-term forecast errors into account in sizing and investment decisions of pumped hydro energy storage. / Driften av pumpkraftverk optimeras med hjälp av kortsiktiga prognoser av elpriser, vilket innebär att fel i dessa prognoser leder till suboptimal drift. Trots att investeringar i pumpkraftverk är kostsamma, har få studier ett holistisk synsätt kring osäkerheter i investeringsbeslutet. Målet med denna studie är att undersöka hur kortsiktiga prognosfel i elpriser påverkar den optimala dimensionering av pumpkraftverk. Investeringsbeslut i pumpkraftverk är långsiktiga och kräver estimat av framtida elpriser, vars karakteristik är osäker. Ett ramverk som bygger på robust beslutstagande, med scenarier över framtida elpriser, används därför för att bedöma effekten av att inkludera kortsiktiga prognosfel i investeringsbeslutet. Genom att simulera den dagliga driften av energilager, undersöks effekten av att inkludera prognosfel jämfört med perfekt information. Med detta tillvägagångsätt ökade den mest robusta kapaciteten med 25 MW, från 2 375 MW till 2 400 MW, när prognosfel inkluderades. Detta visar på att fel i kortsiktiga prognoser kräver pumpkraftverket av vara mer flexibelt, vilket ges av höjdkapacitet. Lönsamheten minskade också signifikant när prognosfel inkluderades, vilket visar på vikten av att ta hänsyn till kortsiktiga prognosfel i beslut kring dimensionering och investering av pumpkraftverk.

Temperature is one of the most important parameters for the performance, safety, and aging of lithium-ion batteries and has been linked to all main barriers for widespread commercial success of electric vehicles. The aim of this thesis is to highlight the importance of temperature effects, as well as to provide engineering tools to study these. The mass transport phenomena of the electrolyte with LiPF6  in EC:DEC was fully characterized in between 10 and 40 °C and 0.5 and 1.5 M, and all mass transport properties were found to vary strongly with temperature. A superconcentrated electrolyte with LiTFSI in ACN was also fully characterized at 25 °C, and was found to have very different properties and interactions compared to LiPF6  in EC:DEC. The benefit of using the benchmarking method termed electrolyte masstransport resistivity (EMTR) compared to using only ionic conductivity was illustrated for several systems, including organic liquids, ionic liquids, solid polymers, gelled polymers, and electrolytes containing flame-retardant additives. TPP, a flame-retardant electrolyte additive, was evaluated using a HEV load cycle and was found to be unsuitable for high-power applications such as HEVs. A large-format commercial battery cell with a thermal management system was characterized using both experiments and a coupled electrochemical and thermal model during a PHEV load cycle. Different thermal management strategies were evaluated using the model, but were found to have only minor effects since the limitations lie in the heat transfer of the jellyroll. / Temperatur är en av de viktigaste parametrarna gällande ett litiumjonbatteris prestanda, säkerhet och åldring och har länkats till de främsta barriärerna för en storskalig kommersiell framgång för elbilar. Syftet med den här avhandlingen är att belysa vikten av temperatureffekter, samt att bidra med ingenjörsverktyg att studera dessa. Masstransporten för elektrolyten LiPF6  i EC:DEC karakteriserades fullständigt i temperaturintervallet 10 till 40 °C för LiPF6-koncentrationer på 0.5 till 1.5 M. Alla masstransport-egenskaper fanns variera kraftigt med temperaturen. Den superkoncentrerade elektrolyten med LiTFSI i ACN karakteriserades även den fullständigt vid 25 °C. Dess egenskaper och interaktioner fanns vara väldigt annorlunda jämfört med LiPF6  i EC:DEC. Fördelen med att använda utvärderingsmetoden elektrolytmasstransportresistivitet (EMTR) jämfört med att endast mäta konduktivitet illustrerades för flertalet system, däribland organiska vätskor, jonvätskor, fasta polymerer, gellade polymerer, och elektrolyter med flamskyddsadditiv. Flamskyddsadditivet TPP utvärderades med en hybridbils-lastcykel och fanns vara olämplig för högeffektsapplikationer, som hybridbilar. Ett kommersiellt storformatsbatteri med ett temperatur-kontrollsystem karakteriserades med b.de experiment och en kopplad termisk och elektrokemisk modell under en lastcykel utvecklad för plug-inhybridbilar. Olika strategier för kontroll av temperaturen utvärderades, men fanns bara ha liten inverkan på batteriets temperatur då begränsningarna för värmetransport ligger i elektrodrullen, och inte i batteriets metalliska ytterhölje. / <p>QC 20150522</p> / Swedish Hybrid Vehicle Center

This study focuses on the design, fabrication, and characterization of deterministically engineered, three-dimensional architectures to be used as high-performance electrodes in energy storage applications. These high-surface-area architectures are created by the robotically-assisted sequential electrodeposition of structural and sacrificial layers in an alternating fashion, followed by the removal of the sacrificial layers. The primary goal of this study is the incorporation of these highly laminated architectures into the battery electrodes to improve their power density without compromising their energy density. MEMS technologies, as well as electrochemical techniques, are utilized for the realization of these high-power electrodes with precisely controlled characteristic dimensions. Diffusion-limited models are adopted for the determination of the optimum characteristic dimensions of the electrodes, including the surface area, the thickness of the active material film, and the distance between the adjacent layers of the multilayer structure. The contribution of the resultant structures to the power performance is first demonstrated by a proof-of-concept Zn-air microbattery which is based on a multilayer Ni backbone coated with a conformal Zn film serving as the anode. This primary battery system demonstrates superior performance to its thin-film counterpart in terms of the energy density at high discharge rates. Another demonstration involves secondary battery chemistries, including Ni(OH)2 and Li-ion systems, both of which exhibit significant cycling stability and remarkable power capability by delivering more than 50% of their capacities after ultra-fast charge rates of 60 C. Areal capacities as high as 5.1 mAh cm-2 are reported. This multilayer fabrication approach is also proven successful for realizing high-performance electrochemical capacitors. Ni(OH)2-based electrochemical capacitors feature a relatively high areal capacitance of 1319 mF cm-2 and an outstanding cycling stability with a 94% capacity retention after more than 1000 cycles. The improved power performance of the electrodes is realized by the simultaneous minimization of the internal resistances encountered during the transport of the ionic and electronic species at high charge and discharge rates. The high surface area provided by the highly laminated backbone structures enables an increased number of active sites for the redox reactions. The formation of a thin and conformal active material film on this high surface area structure renders a reduced ionic diffusion and electronic conduction path length, mitigating the power-limiting effect of the active materials with low conductivities. Also, the highly conductive backbone serving as a mechanically stable and electrochemically inert current collector features minimized transport resistance for the electrons. Finally, the highly scalable nature of the multilayer structures enables the realization of high-performance electrodes for a wide range of applications from autonomous microsystems to macroscale portable electronic devices.

Master of Science / Department of Mechanical and Nuclear Engineering / Donald L. Fenton / Emergency cooling systems are applied to any application where the loss of cooling results in damage to the product, loss of data, or equipment failure. Facilities using chilled water for cooling that experience an electrical power outage, even a small one, would cause the chiller to shut down for 20 minutes or more. If emergency cooling is not available, temperatures would continue to increase to dangerous levels, potentially damaging the facility. Examples of facilities that could be protected by having emergency cooling systems are data centers, hospitals, banks, control rooms, laboratories, clean rooms, and emergency shelters among others. This project addresses the current lack of information and methods needed to correctly design emergency cooling systems. Three application uses were investigated for the possible benefits of having emergency cooling systems. The software TRNSYS was used to simulate five typical emergency cooling systems for each of the three applications. The characteristics and differences of the systems developed from the simulations were then analyzed and documented. The five systems simulated include a pressurized chilled water tank (parallel), atmospheric chilled water tank (parallel and series), low temperature chilled water tank (parallel), and ice storage tank (series). Simulations showed that low temperature chilled water tanks were less stratified than regular chilled water tanks by approximately 10%. Simulations also showed that the differences between atmospheric and pressurized tanks were negligible. Each tank discharged energy in the same manner and managed to replenish itself in the same amount of time. Examination of the different system configurations showed that tanks in series with the thermal load have issues with recharging due to its inability to isolate itself from the thermal load. It was also observed that while low temperature chilled water and ice storage tanks had the potential of reducing the storage tank volume, the amount of time ragged cooling will last is decreased by at least a factor of two. The examination of the five systems produced the desired design methodologies needed to address the lack of information on emergency cooling systems. With the reported information designers can effectively engineer systems to meet their needs.

This thesis aims to bring clarity to the dimensioning aspects and limiting factors of the modular multilevel converter (MMC). Special consideration is given to the dc capacitors in the submodules as they are a driving factor for the size and weight of the converter. It is found that if the capacitor voltages are allowed to increase by 10% the stored energy must be 21 kJ/MW in order to compensate the capacitor voltage ripple. The maximum possible output power can, however, be increased by injecting a second-order harmonic in the circulating current. A great advantage of cascaded converters is the possibility to achieve excellent harmonic performance at low switching frequencies. Therefore, this thesis also considers the relation between switching harmonics, capacitor voltage ripple, and arm quantities. It is shown that despite subharmonics in the capacitor voltages, it is still possible to achieve periodic arm quantities. The balancing of the capacitor voltages is also considered in further detail. It is found that it is possible to balance the capacitor voltages even at fundamental switching frequency although this will lead to a comparably large capacitor voltage ripple. Therefore, in order to limit the peak-to-peak voltage ripple, it is shown that a predictive algorithm can be used in which the resulting switching frequency is approximately 2–3 times the fundamental frequency. This thesis also presents two new submodule concepts. The first submodule simply improves the trade-off between the switching frequency and capacitor voltage balancing. The second submodule includes the possibility to insert negative voltages which allows higher modulation indices compared to half-bridge submodules. A brief comparison of cascaded converters for ac-ac applications is also presented. It is concluded that the MMC appears to be well suited for ac-ac applications where input and output frequencies are close or equal, such as in interconnection of ac grids. In low-frequency applications such as low-speed drives, however, the difficulties with handling the energy variations in the converter arms are much more severe in the MMC compared to the other considered topologies. / <p>QC 20141010</p>

Thesis (MScEng)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: As the push continues for increased use of renewables on the electricity grid, the problem of energy storage is becoming more urgent than ever. Flywheels with wound, composite rotors represent an efficient and environmentally friendly option for energy storage. They have already been applied successfully for voltage control on electrical rail networks and for bridging power in backup UPS systems, but lately they have also proven useful for grid-scale frequency regulation. For flywheels to be deployed on a wider scale, the high cost associated with the technology will have to be addressed. An important driver of cost is the density at which energy can be stored. Currently, flywheel designs do not consistently achieve high energy density, and this study investigates the reasons for this. A critical analysis is made of the design methodologies that have been proposed in the available literature, and some improvements are suggested. Most notably it is shown that significant improvements in energy density may be possible if the design optimization problem is formulated carefully. In addition, the problem of material selection is discussed, because material properties have a significant influence on energy density. Some guidance is given for flywheel designers on how to choose an optimal set of materials without invoking undue computational effort. It is hoped that these suggestions may be carried forward as a topic of further research. / AFRIKAANSE OPSOMMING: Namate die aanvraag vir hernubare energie op die elektrisiteit netwerk vergroot, word die probleem van energie berging van kardinale belang. Vliegwiele met silindriese rotors van samegestelde materiale bied ’n effektiewe en omgewingsvriendelike opsie vir energieberging. Hierdie tipe vliegwiele is reeds suksesvol aangewend vir spanningsbeheer op elektriese spoornetwerke en om oorbruggingskrag te voorsien aan rugsteun sisteme. Meer onlangs is hulle ook nuttig bewys vir die regulasie van frekwensie op die elektrisiteit netwerk. Grootskaalse aanwending van vliegwiele kan egter slegs oorweeg word indien die hoë koste van die tegnologie aangespreek word. Een van die onderliggende redes vir die hoë koste van vliegwiele is die relatiewe lae digtheid waarby energie geberg kan word, en hierdie studie ondersoek die redes hiervoor. Die ontwerpmetodiek wat in die beskikbare literatuur voorgestel is, word krities geanaliseer en ’n paar verbeteringe word aanbeveel. Mees noemenswaardig is die opmerklike verbeteringe in energie-digtheid wat soms moontlik is indien die optimerings-probleem deurdag geformuleer word. Omdat materiaaleienskappe ’n bepalende invloed op energie digtheid uitoefen word die probleem van materiaalseleksie ook verder bespreek. ’n Paar riglyne vir die seleksie van ’n optimale stel materiale sonder om oordrewe berekenings-inspanning te veroorsaak, word aan vliegwielontwerpers gegee. Hierdie voorstelle kan hopelik in die toekoms verder deurgetrap word as onderwerp vir verdere studies.