No / Alpha phase sintering, sinter hardening, and mechanical properties of prealloyed Fe-1.5Mo base powder with and without additions of elemental Si, ferrosilicon, and carbon under various process conditions have been investigated. Liquid paraffin, as a new lubricating agent, was found to be useful in reducing segregation, interparticle and die wall frictions, as well as reducing ejection forces and die and tool wear. It was found that addition of Si to the base powder enhanced the sintering process by stabilisation of the ¿-phase and formation of two kinds of liquid phase at ~1045 and ~1180°C, corresponding to the solidus and liquidus temperatures, respectively. This addition increased the tensile strength of the as sintered Fe-1.5Mo from 174 to 445 MPa owing to massive solid solution strengthening effect of Si. An optimum sinter hardenable alloy, of composition Fe-1.5Mo + 3Si + 1.2C, provided a high sintered density of 7.55 g cm-3, tensile and bend strengths of 764 and 1405 MPa, respectively, with 2.5% elongation, after sintering at 1250°C for 1 h under hydrogen or vacuum using moderate cooling rates of ¿ 20 K min-1. Faster cooling rates caused brittleness and very low UTS for the high carbon steel. Full heat treatment improved the UTS by 200 MPa which was useful only for the high carbon steel with high cooling rates ¿ 30 K min-1. Depending on the cooling rate, the as sintered microstructures consisted of mainly fine or coarse pearlite, bainite, martensite, and some retained austenite with hardness in the range 250-720 HV10. Some proeutectoid grain boundary cementites were also present in the as sintered high carbon steel. This work, therefore, has shown that high densities with acceptable microstructures and good mechanical properties are achievable with single stage compaction and single sintering operations by using the optimum process conditions and alloying composition without the need for a post-sintering heat treatment.

No / Ultrasonic technology provides a powerful and noninvasive method of in-process measurement during injection molding and extrusion. Changes in the velocity, attenuation and reflection coefficients of high frequency sound waves can be related to the state and conditions of the materials through which they propagate. The velocity of an ultrasonic wave changes with density and elastic moduli; this allows information on solidification and material properties to be collected during the molding cycle. The time of flight of the wave is a function of velocity and path length. This paper shows that it can be correlated with the residual wall thickness of polymer in the mold during gas assisted injection molding.

No / Rheological characterisation of hydroxyapatite -high density polyethylene (HA-HDPE) composites has been performed in terms of isothermal compressibility and wall slip. Addition of HA to the polymer melt decreases the compressibility of the melt. The unfilled HDPE was found to exhibit wall slip at shear stresses as low as 0.10 MPa. The flow curves of the composites showed three distinct regions: a gradient at low shear rates; a plateau region; and a gradient at higher shear rate. An increase in rheometer pressure seems to suppress the slip in composites. The 40 vol.-% HA-HDPE composite exhibited two critical shear stresses, one corresponding to wall slip, which occurs in the lower shear rate region of the flow curve, and the other corresponding to a plateau, which is identified with the stick-slip behaviour of unfilled HDPE reported in the literature. The plateau shear stress increased with filler volume fraction and this effect is attributed to the decreased compressibility of the melt. A good correlation with a negative correlation coefficient was found to exist between compressibility and shear stress in the plateau region. The slip observed in unfilled HDPE and at low shear rates in the 40 vol.-% HA- HDPE systems has been explained in terms of a low molecular weight polymer layer formed at the melt/wall interface. The large interfacial slip observed in the plateau region is attributed to complete disentanglement of adsorbed chains from free chains at the melt/wall interface at and beyond the plateau region.

No / Injection moulding techniques have been miniaturised and refined to achieve micromoulding which aims to satisfy the need for mass production of low-cost micro- and nanoscale components. However, the microscale mould cavity features and extreme processing conditions which are inherent in the process can result in larger process variations than conventional injection moulding, with a corresponding increase in the probability of producing an unsatisfactory product. Accurate process diagnosis is required to ensure process reliability but integration of sensors onto the small and highly detailed mould units can be problematic and alternatives may need to be sought. Piezoelectric film ultrasonic transducers were integrated onto the extrusion barrel and mould insert of a micromoulding machine for real-time, non-destructive and non-intrusive process diagnosis with an ultrasonic pulse-echo technique. Polymer degradation owing to excessive heating at the extrusion barrel was successfully probed by measuring the ultrasonic velocities in the polymer at the mould insert. Filling incompleteness of the mould cavity was also sensitively detected by monitoring the ultrasonic energy variation transmitted into the part at different points along the melt flow length. The developed ultrasonic sensors and technique enable optimisation and in-process quality assurance of the moulded parts which ensures that maximum process efficiency can be achieved.

This thesis introduces and describes a new experimental setup for examining the effects of pulsating inflow to a ventilated enclosure. The study aimed to test the hypothesis that a pulsating inflow has potential to improve ventilation quality by reducing the stagnation zones through enhanced mixing. The experimental setup, which was a small-scale, two-dimensional (2D), water-filled room model, was successfully designed and manufactured to be able to capture two-dimensional velocity vectors of the entire field using Particle Image Velocimetry (PIV). Using in-house software, it was possible to conclude that for an increase in pulsation frequency or alternatively in the flow rate, the stagnation zones were reduced in size, the distribution of vortices became more homogeneous over the considered domain, and the number of vortices in all scales had increased. Considering the occupied region, the stagnation zones were moved away in a favorable direction from a mixing point of view. In addition, statistical analysis unveiled that in the far-field occupied region of the room model, stronger eddies were developed that we could expect to give rise to improved mixing. As a fundamental experimental study performed in a 2D, small-scale room model with water as operating fluid, we can logically conclude that the positive effect of enhanced mixing through increasing the flow rate could equally be accomplished through applying a pulsating inflow. In addition, this thesis introduces and describes an experimental setup for study of air flow over a wall-mounted radiator in a mockup of a real room, which has been successfully designed and manufactured. In this experimental study, the airflow over an electric radiator without forced convection, a common room-heating technique, was measured and visualized using the 2D PIV technique. Surface blackening due to particle deposition calls for monitoring in detail the local climate over a heating radiator. One mechanism causing particle deposition is turbophoresis, which occurs when the flow is turbulent. Because turbulence plays a role in particle deposition, it is important to identify where the laminar flow over radiator becomes turbulent. The results from several visualization techniques and PIV measurements indicated that for a room with typical radiator heating, the flow over the radiator became agitated after a dimensionless length, 5.0–6.25, based on the radiator thickness. Surface properties are among the influencing factors in particle deposition; therefore, the geometrical properties of different finishing techniques were investigated experimentally using a structured light 3D scanner that revealed differences in roughness among different surface finishing techniques. To investigate the resistance to airflow along the surface and the turbulence generated by the surfaces, we recorded the boundary layer flow over the surfaces in a special flow rig, which revealed that the types of surface finishing methods differed very little in their resistance and therefore their influence on the deposition velocity is probably small. / Det övergripande syftet med den första studien i avhandlingen var att undersöka hypotesen att ett pulserande inflöde till ett ventilerade utrymme har en potential till att förbättra ventilationens kvalitet genom att minska stagnationszoner och därigenom öka omblandningen. För genomförande av studien byggdes en experimentuppställning i form av en tvådimensionell (2D) småskalig modell av ett ventilerat rum. Strömningsmediet i modellen var vatten. Det tvådimensionella hastighetsfältet registrerades över hela modellen med hjälp av Particle Image Velocimetry (PIV). Vid ett stationärt tillflöde bildas ett stagnationsområde i centrum av rumsmodellen. Vid ett pulserade inflöde genererades sekundära virvlar. Med en egen utvecklad programvara var det möjligt att kvantifiera statistiken hos virvlarna. Det pulserade inflödet gjorde att inom området där det vid stationärt tillflöde fanns en stagnationszon ökade antalet virvlar i alla storlekar och fördelningen av virvlar blev mera homogen än tidigare. Detta kan förväntas ge upphov till förbättrad omblandning. Baserat på en grundläggande experimentell studie utförd i en småskalig tvådimensionell rumsmodell med vatten som strömningsmedium kan vi logiskt dra slutsatsen att ett pulserande tilluftsflöde har en potential att förbättra omblandningen.  I en fortsatt studie i avhandlingen visuliserades och mättes hastighetsfältet och därefter beräknades statistiska värden av exempelvis medelhastighet, standardavvikelse och skjuvspänning hos hastighetsfluktuationerna i luftströmmen över en väggmonterad radiator med 2D-PIV-teknik.  Bakgrunden till studien är att en bidragande orsak till partikelavsättning på väggytor är turbofores som uppträder vid en turbulent luftström. Studien genomfördes genom uppbyggnad av en fullskalig rumsmodell. Eftersom turbulens spelar en roll vid partikelavsättning genom turbofores är det viktigt att identifiera var det laminära flödet över radiatorn blir turbulent. Resultaten baserat på visualisering och PIV-mätningar indikerade att, för ett rum med denna typ av radiatoruppvärmning, blev flödet över radiatorn turbulent efter en dimensionslös längd lika med 5,0‒6,25 gånger radiatorns tjocklek. Ytors egenskaper är viktiga vid partikelavsättning. Därför har de geometriska egenskaperna hos några olika metoder för ytbehandling undersökts experimentellt med hjälp av en scanner för strukturerat 3D-ljus. Resultaten visar på skillnader i ytråhet hos de olika ytbehandlingsmetoderna. För att undersöka motståndet mot luftströmning längs ytan och den turbulens som genereras av ytorna registrerade vi gränsskiktsflödet över ytorna i en speciell luftströmningsrigg. Detta påvisade att motståndet hos de olika typerna av ytbehandlingsmetoder skilde sig mycket litet åt och därför är troligt vid deras påverkan på depositionshastigheten mycket liten. / <p>QC 20150525</p>

Un modèle numérique d’un arc électrique diffus dans un disjoncteur à vide à champ magnétique axial (AMF) a été développé dans le but de mieux comprendre à terme la transition d’un mode de fonctionnement diffus de l’arc vers un mode plus concentré. Le comportement du plasma d’arc a été simulé depuis la sortie de la zone de mélange cathodique jusqu’à l’entrée de la gaine anodique. Le modèle bidimensionnel est basé sur un système d’équations hydrodynamiques à deux fluides non magnétisés (ions et électrons), incluant les équations de conservation d’énergie ionique et électronique. Il est démontré que les processus d’ionisation et de recombinaison et les effets visqueux sont négligeables. Les transferts radiatifs ne sont pas considérés en première approximation. Outre les forces dues au champ AMF, le modèle inclut les forces dues aux trois composantes du champ magnétique induit par l’arc. Deux régimes d’écoulement des ions, supersonique (aux faibles densités de courant) et subsonique (aux fortes densités de courant), sont considérés. Près de la cathode, les conditions aux limites sont spécifiées à partir de résultats de la littérature. A proximité de l’anode, elles sont basées sur une description simplifiée de la gaine anodique. Les résultats de simulation présentés mettent en évidence une constriction du courant et un comportement différent des ions aux faibles et aux fortes densités de courant, et renseignent sur l’influence de divers paramètres (intensité du courant, distance interélectrode). Ce travail présente également une étude expérimentale, basée sur des visualisations par vidéo rapide de l’arc et des mesures pyrométriques de la température de la surface de l’anode / A model of a diffuse arc in a vacuum circuit breaker with an axial magnetic field (AMF) has been developed with the ultimate aim to better understand the transition of the arc from a diffuse mode to a more confined mode. The interelectrode plasma is simulated from the exit of the mixing region on the cathode side to the entrance of the anode sheath. The two-dimensional model is based on the solution of a system of two-fluid (ions and electrons) hydrodynamic equations, including in particular the energy balance equations relative to both the ions and the electrons, which are treated as non-magnetized particles. It is demonstrated that ionisation and recombination processes, as well as viscous effects, can be neglected. Radiation losses are not taken into account in a first approximation. In addition to the forces due to the AMF, the model considers the forces created by the three components of the magnetic field induced by the arc current. The possibility of both supersonic (at low current density) and subsonic (at high current density) ionic flow regimes is considered. On the cathode side, the boundary conditions are specified using results from the literature. On the anode side, they are based on a simplified description of the anode sheath. The simulation results presented show a constriction of the current lines, emphasize the differences in the behaviour of the ions at low and high current densities, and provide some insight on the influence of various operating parameters (arc current, gap length). The present work comprises also an experimental study, based on high-speed camera visualisations of the arc and measurements of the temperature at the anode surface

Cette thèse apporte des éléments sur la compréhension de la gestion de l'eau et de ses effets sur les performances électriques d'une PEMFC au moyen de modélisations multi-échelle des transferts. Une analyse du transport couplé de charges et de matière dans les pores de la membrane est proposée. La présence d'eau liquide est prise en compte dans les GDL (écoulements diphasiques) et les couches actives (noyage). Le couplage de ces modèles à une description des transferts de matière le long des canaux d’alimentation permet de mettre en évidence une répartition non-uniforme des concentrations en eau, des flux et donc de la densité de courant. Les résultats numériques sont comparés à des données expérimentales (coefficient de partage de l'eau et performance électrique locale) obtenues au laboratoire sur deux piles. Ceci permet de valider les modèles de fonctionnement du cœur de pile et d'alimenter la réflexion sur la connaissance et la modélisation des transferts d'eau dans le cœur de pile / This works contributes to the understanding of water management of polymer electrolyte membrane fuel cell and of its links with the electrical performances. More specifically, the manuscript deals with the multi-scale modelling of transport phenomena. An analysis of coupled mass and charge transfer in the pores of a polymer membrane is presented. The presence of liquid water is considered in the GDL (two-phase flow) and in the active layers (flooding). The description of these phenomena is associated with that of gas depletion along the bipolar plate channels. This allows to emphasize the non-uniformity of water concentration, of the fluxes and as a consequence, of current density. The numerical results are compared with experimental data (water transport coefficient, local electrical performances) measured on two different fuel cells. This comparison validates at least partially the numerical models and provides further information for the analysis of water management within PEMFC

Le présent travail de recherche concerne l'étude de la convection de Rayleigh-Bénard-Marangoni dans un récipient cylindrique doté d'un fond en substrat solide. Le substrat solide est chauffé sur sa face inférieure par un flux de chaleur localisé. L'étude comporte deux parties : La première partie du travail consiste en une modélisation physique du problème associée à des simulations numériques. Les équations de Navier-Stokes et de l'énergie sont résolues en 3D par une méthode de volumes finis. Un transfert de chaleur conjugué solide-liquide est considéré. Des morphologies originales de cellules (type et nombre) sont observées, elles dépendent des conditions géométriques, des nombres adimensionnels qui régissent la physique de l'écoulement (nombre de Prandtl, de Rayleigh et de Marangoni ainsi que du rapport des conductivités thermiques du substrat solide et du fluide). Les transferts de chaleur sont aussi évalués pour chaque cas d'étude. Dans la deuxième partie, nous allons détaillons une étude expérimentale de la convection de Rayleigh-Bénard-Marangoni dans la même configuration que celle étudiée numériquement. Les structures convectives et leurs évolutions sont étudiées à partir d’images relevées par thermographie infra-rouge. Différents modes d'organisation des cellules convectives ont pu être mis en évidence pour ce type de chauffage à flux thermique imposé non uniforme. / The present research work concerns the study of Rayleigh-Bénard-Marangoni convection in a cylindrical container with a solid substrate base. This solid substrate is heated by a localized heat flux on its underside. The study is divided into two parts : The first part of the work consists of a physical modelling of the problem associated with numerical simulations. The Navier-Stokes and energy equations are solved by using a 3D finite volume method. A conjugate solid-liquid heat transfer is considered. Original morphology of cells (type and number) are observed, they are linked to the geometrical conditions, the dimensionless numbers which govern the physical problem (Prandtl, Rayleigh and Marangoni numbers and the ratio of solid substrate to liquid thermal conductivities). The heat transfers are also evaluated in each case. In the second part of the work, we present an experimental study of Rayleigh-Bénard-Marangoni convection in the same configuration as that studied numerically. Convective structures and their evolutions are studied from images recorded by infrared thermography. Different modes of organization of convective cells have been highlighted for this type of heating with imposed non-uniform heat flux.

Les opérations géométriques appliquées aux maillages 3D introduisent des dis torsions géométriques qui peuvent être visibles pour un observateur humain. Dans cette thèse, nous étudions l’impact perceptuel de ces distorsions. Plus précisément, notre objectif est de calculer le seuil à partir duquel les distorsions géométriques locales deviennent visibles. Afin d’atteindre notre but, nous définissons tout d’abord des caractéristiques perceptuelles pour les maillages 3D. Nous avons ensuite effectué une étude expérimentale des propriétés du système visuel humain (sensibilité au contraste et effet du masquage visuel) en observant un maillage 3D. Les résultats de ces expériences sont finalement utilisés pour proposer un algorithme qui calcule le seuil de visibilité relatif à une distorsion locale. L’algorithme proposé s’adapte aux différentes conditions d’affichage (résolution et taille de l’écran), d’illumination et au type de rendu. Enfin, nous montrons l’utilité d’un tel algorithme en intégrant le seuil de visibilité dans le pipeline de plusieurs opérations géométriques (ex: simplification, subdivision adaptative) / Geometric operations applied to a 3D mesh introduce geometric distortion in the form of vertex displacement that can be visible to a human observer. In this thesis, we have studied the perceptual impact of these geometric distortions. More precisely, our goal is to compute the threshold beyond which a local geometric distortion becomes visible. In order to reach this goal, we start by evaluating perceptually relevant properties on 3D meshes. We have then performed a series of psychophysical experiments in which we measured the visibility threshold relative to various properties of the Human Visual System (contrast sensitivity and visual masking). The results of these experiments allowed us to propose an algorithm that computes the visibility threshold relative to a local geometric distortion. This algorithm is capable of adapting to the different display condition of 3D meshes (resolution, display size, illumination condition and rendering). Finally, we showcase the utility of our work by integrating the developed perceptual method in several geometric operations such as mesh simplification and adaptive subdivision

O Teste de software é uma atividade de garantia da qualidade que tem por finalidade diminuir o número de defeitos do software. Esta atividade contribui para redução do custo de manutenção e para a melhora da qualidade do software, durante o processo de desenvolvimento. Isso tem motivado a investigação e proposta de estratégias, técnicas, critérios e ferramentas de teste para diferentes paradigmas de desenvolvimento, tais como procedimental, orientado a objetos e orientado a aspectos. Vários estudos experimentais têm sido desenvolvidos para avaliar e comparar critérios de teste. Grande parte desses experimentos foram realizados com programas construídos sob um mesmo paradigma ou desconsiderando a influência do mesmo sobre os resultados. Entretanto, é importante avaliar o impacto de um paradigma específico sobre a atividade de teste uma vez que alguns defeitos podem estar relacionados ao seu uso. Este trabalho apresenta um estudo experimental realizado para caracterizar e avaliar o custo de aplicação e a dificuldade de satisfação de critérios de teste, comparando dois paradigmas: o orientado a objetos e o procedimental. O estudo considera critérios de teste funcionais e estruturais e utiliza um conjunto de programas do domínio de Estrutura de Dados. Os termos e fases do processo de experimentação controlada foram usados, à medida em que estes se mostraram adequados, para definir e executar o presente estudo. Os objetivos com a execução dessa pesquisa foram obter resultados iniciais sobre as questões investigadas bem como gerar artefatos que sirvam de base para a definição e condução de futuros experimentos e a criação de pacotes de laboratório. Além disso, pretende-se apoiar, por meio dos materiais gerados, o treinamento e o ensino da atividade do teste de software / Software Testing is a quality assurance activity that aims at reducing the number of software faults. This activity contributes for the reduction of maintenance costs and for software quality improvement during the development process. These factors have motivated the investigation and proposal of several testing strategies, techniques, criteria and tools for different programming paradigms, such as procedural, object-oriented and aspect-oriented. Regarding testing criteria, many experimental studies have been performed to evaluate and compare them. In general, these experiments comprise programs developed under the same paradigm or this influence over the results. However, some faults can be paradigm-related and it is important to evaluate its impact on the testing activity. This work presents an experimental study developed to characterize and evaluate the application cost and strength of testing criteria, comparing two programming paradigms: object-oriented and procedural. This study considers functional and strutural testing criteria and uses a set of programs from the data structure domain. Terms and phases from controlled experimentation process were used, as long as they showed to be adequated, to define and execute the present study. The research aims at obtaining initial results about the questions investigated as well as generating artifacts which support the definition and conduction of future experiments and the creation of laboratory packages. In addition, it intends to support, through the materials generated, the training and teaching of software testing activity