京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第20386号 / 工博第4323号 / 新制||工||1670(附属図書館) / 京都大学大学院工学研究科材料化学専攻 / (主査)教授 田中 勝久, 教授 平尾 一之, 教授 三浦 清貴 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

No description available.

Faraday rotation is a valuable tool for detecting magnetic fields. Here, the technique is considered in relation to wind-blown bubbles. In the context of spherical winds with azimuthal or split monopole stellar magnetic field geometries, we derive maps of the distribution of position angle (P.A.) rotation of linearly polarized radiation across projected bubbles. We show that the morphology of maps for split monopole fields are distinct from those produced by the toroidal field topology; however, the toroidal case is the one most likely to be detectable because of its slower decline in field strength with distance from the star. We also consider the important case of a bubble with a spherical sub-volume that is field-free to approximate crudely a “swept-up” wind interaction between a fast wind (or possibly a supernova ejecta shell) overtaking a slower magnetized wind from a prior state of stellar evolution. With an azimuthal field, the resultant P.A. map displays two arc-like features of opposite rotation measure, similar to observations of the supernova remnant G296.5+10.0. We illustrate how P.A. maps can be used to disentangle Faraday rotation contributions made by the interstellar medium versus the bubble. Although our models involve simplifying assumptions, their consideration leads to a number of general robust conclusions for use in the analysis of radio mapping data sets.

Faraday rotation is a process by which the position angle (PA) of background linearly polarized light is rotated when passing through an ionized and magnetized medium. The effect is sensitive to the line-of-sight magnetic field in conjunction with the electron density. This contribution highlights diagnostic possibilities of inferring the magnetic field (or absence thereof) in and around wind-blown bubbles from the Faraday effect. Three cases are described as illustrations: a stellar toroidal magnetic field, a shocked interstellar magnetic field, and an interstellar magnetic field within an ionized bubble.

No description available.

No description available.

We have investigated the Faraday effect of bismuth-doped rare-earth iron-garnets with varying doping levels of gallium from z = 1.0 to 1.35. We used lutetium to control the film's in-plane magnetic properties and found that gallium doping levels above the compensation point caused a loss of anisotropy control, a canted out-of-plane magnetization in the film, and an extremely weak but linear coercivity above 10 micro-Tesla fields. Using these results we focused on in-plane films to create 8 layer stacks of 500 um thick films to achieve a minimum detectable field of 50 pT at 1 kHz. Unlike previous Magneto-Optic (MO) studies that typically used thin films of approximately 1um thickness, we used approximately 400um thick films to allow experimentation with the final, robust, ideal form the MO sensor would take. We measured what most other MO studies with garnets neglected: the magnetic anisotropy axis or structure within the film. Knowledge of this structure is essential in improving the sensitivity of a stacked MO probe. Studying thick films proved to be key to understanding the magnetic anisotropy and domain properties that can degrade or enhance the sensitivity of the Faraday rotation in bismuth doped rare-earth iron-garnets to an applied magnetic field and to pointing the direction of future research to develop the conditions for rugged magnetometer sensors. / Physics

Charge transfer at the organic/inorganic semiconductor interfaces lies at the heart of interfacial photochemistry. While decades of research have shaped the current understanding that interfacial charge transfer depends crucially on energetic driving force and electronic coupling, much less is known about the role played by the spin degree of freedom. In particular, it is not clear how spin states evolve during the charge transfer process. With the advent of group 6 transition metal dichalcogenides (TMDC), a class of two-dimensional layered materials which permits the optical generation of spin-polarized electron-hole pairs in the monolayer limit, we now have the opportunity to investigate if charge transfer at an organic/inorganic interface could enable the transfer of spin polarization. Using time-resolved Faraday rotation and transient absorption spectroscopy, it is found in the MoSe₂/H₂Pc and C60/WS₂ heterostructures that the photoinduced hole transfer from MoSe₂ to H₂Pc and electron transfer from WS₂ to C60 results in spin polarization lifetimes one order of magnitude longer than that of a monolayer. In the WS₂/MoSe₂/H₂Pc heterostructure, the addition of a WS₂ monolayer drives the dissociation of electron-hole pairs bound at the MoSe₂/H₂Pc interface and leads to the observation of nanosecond-long spin polarization at room temperature. These findings evidence the photoinduced transfer of spin polarization, a mechanism which could potentially be exploited to enhance the efficiency and selectivity of photochemical reactions involving angular momentum change, and may be generalized to other organic/inorganic interfaces composed of crystalline semiconductors with spin-momentum locking.

Die Protonentherapie von Aderhautmelanomen wird vor allem für die Behandlung von Tumoren nahe kritischer Strukturen (Sehnerv) und bei großen Tumoren angewandt. Dabei ist die begrenzte Reichweite der Protonen vorteilhaft, die scharf begrenzte Dosisfelder im Auge ermöglicht, und das an den Tumor grenzende gesunde Gewebe bestmöglich schont. Daher erfolgt die Positionierung der Patienten und der Strahlenfelder in der Augentumortherapie, wie auch die regelmäßigen Konstanzprüfungen, mit einer Reichweitengenauigkeit in Wasser von 0,1 mm. Mit einem Multi-Leaf Faraday Cup (MLFC) kann die Reichweite der Protonen in kurzer Zeit sehr genau gemessen werden. Dabei misst der MLFC die differentielle Fluenz der Protonenstrahlen, also das Reichweitenprofil. Er besteht aus einem Stapel Folien, abwechselnd leitend und isolierend. Eindringende Protonen deponieren eine zusätzliche Ladung in der Folie in der sie stoppen. Durch eine gleichzeitige Strommessung an allen Folien misst der MLFC relativ schnell die Reichweite der Protonen. Aufgabe dieser Arbeit ist es, einen MLFC entsprechend den Anforderungen der Augentumortherapie zu entwickeln, aufzubauen und mögliche Anwendungspotentiale zu untersuchen. Dafür wurden Monte-Carlo-Rechnungen mit MCNPX 2.6 und SRIM durchgeführt, verschiedene Folienstapel an Luft und im Vakuum untersucht, verschiedene Messelektroniken zur gleichzeitigen Messung von Strömen im pA-Bereich in vielen Kanälen getestet, ein Absorbersystem für einen variablen Messbereich von 30 MeV bis 70 MeV aufgebaut und die entsprechende Mess- und Steuersoftware in LabVIEW 2011 entwickelt. Es wurde die Genauigkeit der Reichweitenmessungen untersucht und gezeigt, dass der MLFC durch seine Mobilität eine schnelle Energiebestimmung an unterschiedlichen Experimentierplätzen erlaubt. In der Therapie ist neben der einfachen Bestimmung der maximalen Reichweite der Protonen auch die regelmäßige Kontrolle der Modulation der ausgedehnten Bragg-Kurven möglich. / Proton therapy of uveal melanomas is primarily used for the treatment of tumors near critical structures (optic nerve) and in large tumors. The great advantage of protons is their sharply limited range in tissue, which leads to sharp defined dose fields in the eye and the dose absorbed by the healthy tissue around the tumor can be reduced. Therefore, the positioning of the patient and the radiation fields, as well as the regular control measurements in the eye tumor therapy requires an accuracy of 0.1 mm in water. A Multi-Leaf Faraday Cup (MLFC) gives the opportunity to measure the proton range relatively fast and accurate. The MLFC measures the differential fluence, which means the range profile of the proton beam. It consists of a stack of sheets, alternating conductive and insulating, and the penetrating protons bring their additional charge into the sheet in which they stop. By measuring the corresponding current in each conducting sheet at the same time, the MLFC can quickly measure the range of the protons. The task of this work is to develop a MLFC with respect to the requirements of the eye tumor therapy and to explore possible application potentials. Therefore, Monte Carlo calculations with MCNPX 2.6 and SRIM were conducted, various foil stacks were studied in air and in vacuum, different measurement electronics for measuring currents in the pA range in many channels simultaneously were tested, a system of degraders for a variable measuring range from 30 MeV to 70 MeV was developed and the corresponding measurement and control software was written in LabVIEW 2011. The accuracy of the range measurements was examined and it was shown that a quick energy measurement at different target stations can be made by the MLFC due to its mobility. In therapy, in addition to the determination of the maximum range of the proton beam, the regular monitoring of the modulation of the extended Bragg-curves is in principle possible.

L’essor des télécommunications par fibre optique nécessite l’insertion en sortie des lasers d’un isolateur optique intégré protégeant celui-ci des réflexions qui le déstabilisent. Ce composant existe à l’heure actuelle sous forme massive, mais son intégration sur la même plaquette que le laser pose problème du fait de la difficulté à intégrer les bons matériaux magnétooptiques sur les substrats usuels de l’optique guidée. Dans cette perspective, l’intégration de nanoparticules magnétiques dans un sol-gel déposé sur les guides optiques est une voie prometteuse, développée par le laboratoire Hubert Curien. Cette thèse a eu pour but d’étudier de manière plus systématique le composant non-réciproque qui entre dans la fabrication des isolateurs à conversion de mode, à savoir le rotateur non-réciproque. Deux études poussées, l’une théorique, l’autre expérimentale, recoupées entre elles par des modèles numériques, ont été mises en oeuvre au cours des années de cette thèse. L’étude théorique a permis de tenir compte tous les paramètres ayant une influence sur l’état de polarisation de la lumière dans un guide magnétooptique, y compris les dichroïsmes souvent négligés. L’étude pratique, à partir d’échantillons sur verre réalisés en collaboration avec l’IMEP-LAHC et le laboratoire PHENIX, a abouti à une caractérisation quasi complète des effets magnétooptiques — longitudinaux et transverses — dans les guides et de l’influence des paramètres de fabrication sur ceux-ci. Au final, ces résultats nous ont donné une compréhension plus complète du fonctionnement des guides magnétooptiques, et nous ont permis de prédire les paramètres optimaux qu’il faudra mettre afin de fabriquer, dans un futur proche, l’isolateur complet sur une seule plaque de verre / The development of optical-fiber telecommunications requires the insertion of optical isolator between lasers and fibers, in order to protect them against perturbating reflexions. This component is currently inserted in a bulk form, but the goal is to integrate it on the same wafer than the laser; nevertheless, this is problematic due to the difficulty to integrate good magnetooptical materials on usual substrates as glass or silicon. One of the promising way to achieve this, developped by the Laboratoire Hubert Curien, is the embedding of magnetic nanoparticles into a sol-gel matrix deposited above the optical guides. This thesis aimed at studying more deeply the main non-reciprocal component of integrated mode conversion optical isolators: the non-reciprocal rotator. A theorical and a practical study have both been performed, with numerical simulations to confront them. The theorical study aimed at describing the evolution of propagation in magnetooptical waveguides with respect to all effects, even absorption and dichroïsm. Then a practical study was performed on glass samples engineered in collaboration with IMEP-LAHC and the PHENIX laboratory, and lead to a full measurement of longitudinal and transverse magnetooptical effects, and their evolution related to the fabrication parameters of the samples. Finally, these results gave us a comprehensive view of how magnetooptical waveguides behave, and we were able to predict the good parameters to choose in order to construct, in a close future, a glass-integrated optical isolator