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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
451

Vergleich von drei unterschiedlichen Telepathologiesystemen zur primären histologischen Schnellschnittdiagnostik auf der Grundlage einer retrospektiven Studie

Bayer, Gudrun 20 April 2005 (has links)
Ziel der vorliegenden Arbeit ist es, die Frage nach Eignung der Technik, des Aufwands, der Schulung und der Vor- und Nachteile eines Einsatzes der Telepathologie in der Schnellschnitt-Diagnostik zu analysieren. Weltweit wurden verschiedene Telepathologiesysteme entwickelt, die zum Teil für den Schnellschnitt verwendet werden können. Auch an der Charité entstanden mit dem 1.ATM-System, 2.dem TPS-System und 3.dem TELEMIC-System, drei technisch völlig unterschiedliche Systeme. Diese Systeme wurden anhand einer retrospektiven Studie hinsichtlich ihrer Einsatzfähigkeit in der telepathologische Schnellschnitt-Diagnostik untersucht. Um die Systeme untereinander vergleichen zu können, wurden 124 histologische Schnellschnittpräparate aus dem Jahr 1999 herausgesucht (ausschließlich Brustgewebe), die von vier erfahrenen Pathologen mit jedem System erneut bearbeitet wurden. Qualitativ wurden mit dem ATM- und dem TPS-System gleichwertige Ergebnisse wie in der konventionellen Schnellschnitt-Diagnostik erreicht. Das TELEMIC-System war qualitativ aufgrund der hohen Rate von Rückweisungen den anderen Systemen und dem konventionellen Schnellschnitt deutlich unterlegen. Bei den Diagnosezeiten zeigte sich eine leichte Unterlegenheit des TPS-Systems gegenüber dem konventionellen Schnellschnitt. Da es jedoch insbesondere als Möglichkeit der Ferndiagnose eingesetzt wird, fallen die bei der konventionellen Schnellschnitt-Diagnostik nötigen Transportzeiten durch einen Kurier weg. Das ATM-System und das TELEMIC-System sind auch ohne Zurechnung der Transportzeiten zeitlich zum konventionellen Schnellschnitt vergleichbare Systeme. / Target of the available work is it, the question about suitability of the technique, the expenditure, to analyze the training and the pro and cons of an application of the Telepathologie on fresh frozen diagnostics. World-wide different Systems for telepathology were developed, which can be used partially for the fresh frozen diagnostics. At the Charité were developed three technically completely different systems: 1.ATM-System, 2.TPS system and 3.TELEMIC system, These systems were examined on the basis a retrospective study regarding their serviceability on telepathologische fresh frozen diagnostics. In order to be able to compare the systems among themselves, 124 histological fresh frozen preparations were picked out from the year 1999 (excluding chest tissues), which were again processed by four experienced pathologists with each system. Qualitatively with ATM and TPS system equivalent results as on were achieved conventional fresh frozen diagnostics. The TELEMIC system was qualitatively inferior for the other systems and the conventional fresh frozen diagnostics due to the high rate of rejections. With the diagnostic times an easy inferiority of the TPS system showed up in relation to the conventional fresh frozen diagnostics. Since it is used however in particular as possibility of the remote diagnostics, the feed times necessary with the conventional fresh frozen diagnostics are omitted by a courier. The ATM system and the TELEMIC system are also without addition of the feed times temporally to the conventional fresh frozen diagnostics comparable systems.
452

La narration casse-tête: construction de récits complexes au cinéma et au théâtre au moyen de multiples variantes d'une même réalité

Allen, Jeremy Peter 19 June 2024 (has links)
Dans le cadre d'une maîtrise en recherche création, j'ai voulu explorer comment la juxtaposition de variantes d'une même réalité, approche narrative que j'emploie dans ma pratique cinématographique, peut s'appliquer dans une production théâtrale. L'essai qui suit témoigne de ce voyage exploratoire, en partant de ma discipline habituelle, le cinéma, pour aller vers un nouveau territoire de création, celui du théâtre. Le texte de la pièce Frozen, de l'auteur britannique Bryony Lavery, a servi de point de départ pour la recherche. Au cours de deux laboratoires au LANTISS (Laboratoire des nouvelles technologies de l'image, du son et de la scène) à l'Université Laval, mes collaborateurs et moi avons expérimenté avec diverses approches et techniques, empruntés tant du monde du théâtre que de celui du cinéma, pour développer une proposition d'écriture scénique qui intègre l'idée des multiples variantes d'une même réalité. À l'origine, cette proposition d'écriture scénique représentait la finalité de mon projet de maîtrise, mais en cours de recherche le Théâtre de la Bordée s'est intéressé au travail et m'a proposé d'intégrer la pièce dans sa programmation régulière. J'ai donc pu présenter le fruit de mes expérimentations à un large public, dans le cadre d'une production montée dans un théâtre institutionnel de Québec. Le présent texte fait d'abord état des résultats des recherches après la phase des laboratoires, mais avant les représentations publiques à la Bordée. Il examine ensuite comment ces résultats ont pu être appliqués dans le contexte d'une production véritable.
453

Value, utility and autonomy : a moral-critical analysis of utilitarian positions on the value of prenatal life

De Roubaix, J. A. M. (John Addey Malcolm) 04 1900 (has links)
Thesis (PhD)--University of Stellenbosch, 2005. / ENGLISH ABSTRACT: Problem statement For utilitarians, human beings have intrinsic moral significance based on only two acquired characteristics: sentience, or the ability to suffer, and psychological personhood. Sentience is the entrance-requirement for moral significance, but does not justify a "right to life" claim; at most a "right" not to suffer. Personhood, described as some sort of self-conscious awareness with a concept of the future, may justify a "right to life" claim. However, since personhood is absent in prenatal beings, and only develops some time after birth, the implication is that such beings have little moral significance and may, for instance, be killed "at will". The moral problem that I address in this dissertation is to investigate, assess and evaluate the utilitarian position on the moral status or value of prenatal life. Methodology and results I firstly, on the basis of an extensive literature study, make a detailed analysis of the utilitarian position with reference to a number of themes that I have identified in their argument. This is followed by a critical philosophical evaluation of the utilitarian position, based on six particular arguments: • Utilitarianism is philosophically incoherent. It over-simplifies the moral argument in claiming that consequences are all that matter morally. Its underlying moral theory is at odds with moral claims contained in contemporary notions of human rights and individual justice. It ignores the moral significance of special obligations to special groups. • Utilitarianism potentially has unacceptable consequences. It IS inherently discriminatory and may lead to legitimate "slippery slope" fears. • Utilitarianism clashes with our fundamental moral intuitions on the value of prenatal life. These intuitions are cherished in most world religions. • Contrary to the utilitarian position, speciesism is inevitable to the human condition, especially argued from a position of existential phenomenology. Self- constitution, simultaneous constitution of the world as we know it, and the very possibility of morality are possible only within a particular notion of speciesism. • The potentiality of pre-persons to develop into persons cannot be as convincingly ignored as is done by the utilitarian. • There is a basic and underlying need and intuition to protect vulnerable human beings, of which pre-persons are exemplars. These notions clash with utilitarian theory. As an alternative, I introduce, set out and evaluate a two-phased position on the moral significance of pre-personal human life, a position of respectfulness of prenatal and pre-personal human life based upon its humanity, potentiality and separation-viability. This leads, firstly, to the conclusion of a graded, sliding scale conception of human prepersonal moral significance in line with the level of development and with the actuation of potentiality. Secondly, it leads to the conclusion that the advent of separationsurvivability (viability) is a morally significant cut-off point beyond which the human fetus may "normally" have a justifiable right to the continuation of its life. In as far as the application of my argument is concerned, I develop a "moderate" position with reference to the abortion debate. Whilst I recognize that all human prenatal beings of which it can be argued that they have a reasonable chance to develop their intrinsic potentiality, i.e., to become full-fledged persons, should have the opportunity to do so, I also recognize that neither this position, nor the complexities of life make it possible to hold "absolute" positions on the justifiability of abortion. I explore this extremely problematic notion in the text. That having been said, the advent of separation-survivability may imply a "moral cut-off point", beyond which termination is only rarely justified. I argue that I find no moral hindrance to wellmotivated research on human pre-embryos and stem cells. / AFRIKAANSE OPSOMMING: Probleemstelling Utilitariste huldig sterk omlynde standpunte oor die waarde van lewe. Hulle redeneer dat menslike (inderwaarheid, alle lewende) wesens slegs op grond van twee eienskappe intrinsieke morele waarde kan verwerf: sentiëntisme, d.i. die vermoë om lyding te ervaar, en persoonstatus. Sentiëntisme is 'n bepalende vereiste vir morele status, maar regverdig nie 'n "reg op lewe"-aanspraak nie. Persoonsyn, verstaan as 'n vorm van selfbewustheid tesame met 'n bewuste belang by die voortsetting van eie bestaan, mag wel so 'n aanspraak regverdig. Voorgeboortelike (en "voorpersoonlike") wesens is egter nie persone nie; hulle word eers (aansienlik) ná geboorte volwaardige persone. Die implikasie is dat sulke wesens weinig morele status het, en byvoorbeeld, na willekeur gedood mag word. Die morele probleem wat ek in hierdie dissertasie aanspreek is om die utilitaristiese beskouing ten opsigte van die morale status of waarde van voorgeboortelike lewe krities-filosofies te ondersoek en te evalueer. Metodologie en gevolgtrekkings Eerstens maak ek na aanleiding van 'n gedetaileerde literatuurstudie 'n in-diepte analise van van die utilitaristiese posisie aan die hand van 'n aantal temas wat ek in hul argument geïdentifiseer het. Daarna volg 'n krities-filosofiese evaluasie van die utilitaristiese posisie, aan die hand van ses argumente: • Utilitarisme is filosofies onsamehangend. Dit oorvereenvoudig die morele argument deur voor te gee dat gevolge al is wat moreel saakmaak. Die onderliggende utilitaristiese teorie bots met die morele eise vervat in kontemporêre sienings van menseregte en geregtigheid. Dit negeer die morele belangrikheid van spesiale verpligtinge teenoor spesiale belangegroepe. • Utilitarisme het potensieelonaanvaarbare gevolge. Dit IS inherent diskriminerend en kan lei tot onkeerbare glybaan ("slippery slope")-argumente. Utilitarisme bots met ons fundamentele morele intuïsies betreffende die waarde van voorgeboortelike lewe. Hierdie intuïsies word onder meer ondersteun deur die meeste hoofstroom godsdienste. • Spesiësisme is, in kontras met die utilitaristiese beskouing, onafwendbaar vir ons selfverstaan as mense, soos aangetoon kan word met 'n beroep op die eksistensiële fenomenologie. Self-konstituering, gelyktydige konstituering van die wêreld van die mens, en selfs die moontlikheid van moraliteit is slegs moontlik vanuit' n bepaalde spesiësistiese beskouing. • Die potensialiteit van "pre-persone" om tot volwaardige persone te ontwikkel kan nie, soos die utilitaris doen, sonder meer geïgnoreer word nie. • Daar is 'n basiese en onderliggende morele eis om swak en weerlose menslike wesens te beskerm. Hierdie idees bots lynreg met utilitaristiese teorie. As 'n alternatief tot die utilitaristiese beskouing, ontwikkel ek 'n twee-fase posisie betreffende die morele waarde van voorgeboortelike menslike lewe. Ek noem hierdie posisie agting vir voorgeboortelike en voor-persoonlike menslike lewe gebaseer op die menslikheid, potensialiteit en oorleefbaarheid van prenatale mense. Dit lei, eerstens, tot die gevolgtrekking van 'n gegradeerde glyskaal konsepsie van voor-persoonlike menslike morele waarde, min of meer parallel aan die vlak van ontwikkeling en die ontwikkeling van potensialiteit. Tweedens lei dit tot die gevolgtrekking dat die ontwikkeling van lewensvatbaarheid 'n moreel-beduidende afsnypunt is waarna die menslike fetus "normaalweg" aanspraak kan maak op 'n reg dat sy lewe voortgesit moet word. In soverre dit die toepassing van my argument betref, ontwikkel ek 'n "gematigde" posisie vis-á-vis aborsie. Ek redeneer dat alle menslike voorgeboortelike wesens wat 'n redelike kans het dat hul intrinsieke potensialiteit verder sal ontwikkel, die geleentheid daartoe gegun behoort te word. Ek aanvaar ook dat nog hierdie beskouing, nog die kompleksiteit van die menslike bestaan "absolute" posisies moreel regverdig. Die problematiek en inherente spanning tussen hierdie oënskynlik-opponerende posisies word in die teks bespreek. Nogtans beskou ek die ontwikkeling van lewensvatbaarheid as 'n moreel insiggewende afsnypunt waarna terminasie net in buitengewone omstandighede moreel regverdigbaar is.
454

Mesure sans référence de la qualité des vidéos haute définition diffusées avec des pertes de transmission / No-Reference Video Quality Assessment of High Definition Video Streams Delivered with Losses

Boujut, Hugo 24 September 2012 (has links)
Les objectifs de ce travail de thèse ont été: d’une part de détecter automatique-ment les images gelées dans des vidéos télédiffusées; et d’autre part de mesurer sans référencela qualité des vidéos télédiffusées (IP et DVB-T). Ces travaux ont été effectués dans le cadred’un projet de recherche mené conjointement par le LaBRI et la société Audemat WorldCastSystems.Pour la détection d’images gelées, trois méthodes ont été proposées: MV (basée vecteurde mouvement), DC (basée sur les coefficients DC de la DCT) et SURF (basée sur les pointscaractéristiques SURF). Les deux premières méthodes ne nécessitent qu’un décodage partieldu flux vidéo.Le second objectif était de mesurer sans référence la qualité des vidéos télédiffusées (IP etDVB-T). Une métrique a été développée pour mesurer la qualité perçue lorsque le flux vidéoa été altéré par des pertes de transmission. Cette métrique "Weighted Macro-Block ErrorRate" (WMBER) est fondée sur la mesure de la saillance visuelle et la détection des macro-blocs endommagés. Le rôle de la saillance visuelle est de pondérer l’importance des erreursdétectées. Certaines améliorations ont été apportées à la construction des cartes de saillancespatio-temporelle. En particulier, la fusion des cartes de saillance spatiale et temporelle aété améliorée par rapport à l’état de l’art. Par ailleurs, plusieurs études ont montré que lasémantique d’une scène visuelle avait une influence sur le comportement du système visuelhumain. Il apparaît que ce sont surtout les visages humains qui attirent le regard. C’est laraison pour laquelle nous avons ajouté une dimension sémantique aux cartes de saillancespatio-temporelle. Cette dimension sémantique est essentiellement basée sur le détecteurde visage de Viola Jones. Pour prédire la qualité perçue par les utilisateurs, nous avonsutilisé une méthode par apprentissage supervisé. Cette méthode offre ainsi la possibilité deprédire la métrique subjective "Mean Opinion Score" (MOS) à partir de mesures objectivestelles que le WMBER, PSNR ou SSIM. Une expérience psycho-visuelle a été menée avec 50sujets pour évaluer ces travaux. Cette base de données vidéo Haute-Définition est en coursde transfert à l’action COST Qualinet. Ces travaux ont également été évalués sur une autrebase de données vidéo (en définition standard) provenant de l’IRCCyN / The goal of this Ph.D thesis is to design a no-reference video quality assessment method for lossy net-works. This Ph.D thesis is conducted in collaboration with the Audemat Worldcast Systemscompany.Our first no-reference video quality assessment indicator is the frozen frame detection.Frozen frame detection was a research topic which was well studied in the past decades.However, the challenge is to embed a frozen frame detection method in the GoldenEagleAudemat equipment. This equipment has low computation resources that not allow real-time HD video decoding. Two methods are proposed: one based on the compressed videostream motion vectors (MV-method) and another one based on the DC coefficients from thedct transform (DC-method). Both methods only require the partial decoding of the com-pressed video stream which allows for real-time analysis on the GoldenEagle equipment.The evaluation shows that results are better than the frame difference base-line method.Nevertheless, the MV and the DC methods are only suitable with for MPEG2 and H.264video streams. So a third method based on SURF points is proposed.As a second step on the way to a no-reference video quality assessment metric, we areinterested in the visual perception of transmission impairments. We propose a full-referencemetric based on saliency maps. This metric, Weighted Mean Squared Error (WMSE), is theMSE metric weighted by the saliency map. The saliency map role is to distinguish betweennoticeable and unnoticeable transmission impairments. Therefore this spatio-temporal saliencymaps is computed on the impaired frame. Thus the pixel difference in the MSE computationis emphasized or diminished with regard to the pixel saliency. According to the state of theart, several improvements are brought to the saliency map computation process. Especially,new spatio-temporal saliency map fusion strategies are designed.After our successful attempt to assess the video quality with saliency maps, we develop ano-reference quality metric. This metric, Weighted Macro-Block Error Rate (WMBER), relies on the saliency map and the macro-block error detection. The macro-block error detectionprovides the impaired macro-blocks location in the frame. However, the impaired macro-blocks are concealed with more or less success during the decoding process. So the saliencymap provides the user perceived impairment strength for each macro-block.Several psycho-visual studies have shown that semantics play an important role in visualscene perception. These studies conclude that faces and text are the most attractive. Toimprove the spatio-temporal saliency model a semantic dimension is added. This semanticsaliency is based on the Viola & Jones face detector.To predict the Mean Opinion Score (MOS) from objective metric values like WMBER,WMSE, PSNR or SSIM, we propose to use a supervised learning approach. This approach iscalled Similarity Weighted Average (SWA). Several improvements are brought to the originalSWA.For the metrics evaluation a psycho-visual experiment with 50 subjects has been carriedout. To measure the saliency map models accuracy, a psycho-visual experiment with aneye-tracker has also been carried out. These two experiments habe been conducted in col-laboration with the Ben Gurion University, Israel. WMBER and WMSE performances arecompared with reference metrics like SSIM and PSNR. The proposed metrics are also testedon a database provided by IRCCyN research laboratory.
455

Nouvelles voies d’accès à des acides alpha-aminés énantioenrichis par mémoire de chiralité ou chiralité gelée / Memory of chirality or frozen chirality of tertiary aromatique amides : access to enantioenriched alpha-amino acids

Mai, Thi thoa 16 March 2012 (has links)
Les acides α-aminés non protéinogènes sont des composés riches d’applications et peuvent donner accès à des composés possédant des propriétés biologiques intéressantes ou à des analogues de peptides. Ainsi, de nombreuses méthodes de synthèse asymétrique ont été développées. Parmi celles-ci, seulement quelques méthodes utilisent la chiralité d’acides α -aminés tertiaires naturels pour accéder à des acides α -aminés quaternaires et il n’existe que peu de synthèses asymétriques absolues d’acides α -aminés tertiaires.Notre équipe a précédemment développé une méthode de synthèse d’acides α-aminés quaternaires reposant sur le concept de la mémoire de chiralité. Cette méthode utilise la chiralité axiale d’amides aromatiques tertiaires pour l’alkylation stéréoselective d’énolates d’acides aminés. Lors de ma thèse, nous avons souhaité appliquer cette méthode d’alkylation stéréosélective d’énolate à d’autres types de réaction tels que la réaction d’aldolisation (utilisant un aldéhyde comme électrophile, et dans ce cas il est nécessaire de contrôler un second centre asymétrique), la réaction d’arylation (utilisant un sel de diaryliodonium comme électrophile) ou à la synthèse totale des composés biologiques intéressants. Des résultats préliminaires encourageants obtenus dans des réactions d’aldolisation (dans le cas avec du benzaldéhyde), d’arylation ainsi que dans la synthèse du précurseur de la L-Méthyl DOPA seront présentés.D’autre part, nous exposerons également la stratégie de synthèse des dérivés d’acides α-aminés tertiaires et des aminoalcools, qui utilise le concept de la chiralité gelée. Cette méthode repose sur l’emploi de la chiralité axiale dynamique des amides aromatiques tertiaires, qui est gelée dans un cristal chiral, et une réaction d’alkylation stéréosélective d’énolate conduisant à des acides aminés énantiomériquement enrichis. En effet, en partant de la glycine, nous avons réussi à trouver un composé de départ qui cristallise dans un groupe d’espace chiral, qui donne donc des cristaux chiraux après la cristallisation. Après avoir trouvé des conditions optimales pour la réaction d’allylation, plusieurs autres électrophiles ont été employés avec succès. Les produits alkylés sont obtenus avec des rendements allant jusqu’à 80% et des excès énantiomériques allant jusqu’à 96% sans utiliser d’autre source de chiralité externe que celle du cristal. L’ouverture de ces composés conduit à la formation des acides α-aminés tertiaires énantiomériquement enrichis. Il s’agit donc d’une synthèse asymétrique absolue d’acides α-aminés. / Non proteinogenic α-amino acids can lead to compounds which exhibit interesting biological properties, or peptides analogues. Numerous methods for asymmetric synthesis of these compounds have been developed. However, few examples have used the chirality of natural tertiary α-amino acids for the synthesis of quaternary α-amino acids, and few examples of asymmetric absolute synthesis to access to tertiary α -amino acids have been described so far. Our research group has previously developed a synthesis of enantioenriched quaternary α-amino acids, based on memory of chirality and using the axial chirality of tertiary aromatic amides for stereoselective alkylation of an enolate of an amino acid.This thesis focuses on expending this methodology to other type of reactions, for example, aldolisation reactions (using an aldehyde as electrophile, in this case it is necessary to control the second asymmetric center), arylation reactions (using a diaryliodonium salt as electrophile) or to the the total synthesis of compounds exhibiting interesting biological properties. Herein, we will show our preliminary results in aldolisation reactions (with benzaldehyde), in arylation reactions and also in the total synthesis of L-Methyl DOPA.On the other hand, we will also present an enantioselective synthesis of tertiary α-amino acids derivatives and of amino alcohols based on the principle of frozen chirality. The strategy uses the dynamic axial chirality of tertiary aromatic amides, which is frozen in chiral crystal, and a stereoselective alkylation reaction of enolate leads to enantioenriched α-amino acids. A compound synthesized from glycine has been finally selected to optimise the asymmetric allylation reaction. These optimales conditions were then successfully employed with various electrophiles. Alkylated products were obtained in yield up to 80% and enantiomeric excesses up to 96% using only chirality of crystal. The deprotection of alkylated products leads to the formation of enantienriched α-amino acids.
456

Disneys Frost : ”A Frozen Heart Worth Mining” / Disney’s Frozen : ”A Frozen Heart Worth Mining”

Persdotter, Klara January 2015 (has links)
Den här studien syftar till att undersöka hur och vad Disney kommunicerar till sin publik genom deras film Frost (2013). Eftersom Disney idag står för en dominerande part av filmunderhållningen för barn bär de också ett ansvar för de budskapen de förmedlar genom sina filmer, då barn kan komma att påverkas av dem. I den här studien har Frost (2013) studerats genom en kvalitativ textanalys med hjälp av Peter Dahlgrens metod för att analysera medietext, med fokus på textens uppbyggnad och den narrativa dynamiken i medietexten (filmen). Analysen har gjorts utifrån ett normkritiskt perspektiv. Analysen visade att Frost bryter sig loss från flera av Disneys tidigare mönster och strukturer och lyckas skapa en mindre förutsägbar saga. Analysen visade också framträdandet av en ny roll; den falska skurken, som användes just i syftet att skapa en mindre förutsägbar saga. Till skillnader från flera tidigare porträtteringar av Disney-prinsessor visar Frost två feminint starka och självständiga kvinnliga karaktärer, som agerar på eget bevåg. Frost ifrågasätter också Disneys tidigare attityd kring att kärlek kan uppstå vid första ögonkastet, samt att romantisk kärlek är det starkaste och mest värdefulla typen av kärlek. För första gången någonsin porträtterar Frost familjekärlek som starkare än romantisk kärlek. / This study aims to examine how and what Disney is communicating to its audience through its movie Frozen (2013). Since Disney currently is a dominant party of the movie entertainment for children they bear a great responsibility for the messages they convey through their movies, as children may be influenced by them. In this study, Frozen (2013) has been studied by a qualitative text analysis using Peter Dahlgren's approach for analyzing media text, with focus on the textual construction and the narrative dynamics of the media text (the movie). The analysis was made based on a norm-critical perspective. The analysis showed that Frozen breaks free from many of Disney's past patterns and structures and manages to create a less predictable tale. The analysis also showed the emergence of a new role; the fake villain, used precisely in order to create a less predictable tale. In differences from several earlier portrayals of the Disney Princess Frozen shows two feminine strong and independent female characters, who act on their own authority. Frozen also questions Disney's previous attitude concerning that love can arise at first sight, and that romantic love is the strongest and most valuable type of love. For the first time in forever in a Princess movie Frozen manages to portray love between family members as stronger than romantic love.
457

Natural hydrate-bearing sediments: Physical properties and characterization techniques

Dai, Sheng 27 August 2014 (has links)
An extensive amount of natural gas trapped in the subsurface is found as methane hydrate. A fundamental understanding of natural hydrate-bearing sediments is required to engineer production strategies and to assess the risks hydrates pose to global climate change and large-scale seafloor destabilization. This thesis reports fundamental studies on hydrate nucleation, morphology and the evolution of unsaturation during dissociation, followed by additional studies on sampling and pressure core testing. Hydrate nucleation is favored on mineral surfaces and it is often triggered by mechanical vibration. Continued hydrate crystal growth within sediments is governed by capillary and skeletal forces; hence, the characteristic particle size d10 and the sediment burial depth determine hydrate morphologies in natural sediments. In aged hydrate-bearing sand, Ostwald ripening leads to patchy hydrate formation; the stiffness approaches to the lower bound at low hydrate saturation and the upper bound at high hydrate saturation. Hydrate saturation and pore habit alter the pore size variability and interconnectivity, and change the water retention curve in hydrate-bearing sediments. The physical properties of hydrate-bearing sediments are determined by the state of stress, porosity, and hydrate saturation. Furthermore, hydrate stability requires sampling, handling, and testing under in situ pressure, temperature, and stress conditions. Therefore, the laboratory characterization of natural hydrate-bearing sediments faces inherent sampling disturbances caused by changes in stress and strain as well as transient pressure and temperature changes that affect hydrate stability. While pressure core technology offers unprecedented opportunities for the study of hydrate-bearing sediments, careful data interpretation must recognize its inherent limitations.
458

Effet des corrélations locales sur le couplage électron-phonon dans le LSCO en DFT+DMFT

Groulx, Julien 07 1900 (has links)
No description available.
459

Análise da competitividade da produção agrícola e do processamento da cadeia agroindustrial de suco de laranja concentrado congelado no estado do Paraná

Sabes, Jair Júnior Sanches 05 October 2012 (has links)
Made available in DSpace on 2016-06-02T19:52:00Z (GMT). No. of bitstreams: 1 5215.pdf: 2573740 bytes, checksum: b0159c517597ec5097315a913808cb47 (MD5) Previous issue date: 2012-10-05 / Financiadora de Estudos e Projetos / Brazil is the largest producer and exporter of the world market of frozen concentrated orange juice (FCOJ), and the State of São Paulo stands out as the largest producer and exporter of that commodity in Brazil. In recent years, the State of Paraná has increased its production and export of FCOJ. Through the survey of secondary data and interviews with key players, this study identified and evaluated the main critical aspects of the competitiveness of the agri-food chain of FCOJ in Paraná. Through the rapid appraisal method (method of quick research) were possible to evaluate 11 drivers of competitiveness, focusing on the links of agricultural production and processing of that chain. A total of 24 interviews were conducted, using questionnaires and interviews screenplays. It was possible to identify which are the drivers of competitiveness, considered in the context of this research, which are considered favorable, neutral and unfavorable for the competitiveness of the links of agricultural production and processing of the agri-food chain of FCOJ in Paraná. From these analyses it was also possible to verify that none of the drivers of competitiveness, considered in this dissertation, was regarded as very favorable or very unfavorable for the competitiveness of the link of agricultural production of that chain. From these analyses it was also possible to verify that none of the drivers of competitiveness, considered in this dissertation, was regarded as very favorable for the competitiveness of the link of processing of that chain, and only a driver of competitiveness, of the set of drivers considered in this dissertation, was regarded as very unfavorable for the competitiveness of the link of processing. The analyses allowed to point out proposals for public policies and private strategies to enhance the competitiveness. In a general context, it was possible to conclude that the links of agricultural production and processing of the agri-food chain of FCOJ in Paraná have a great potential to continue to expand in Paraná. The citriculture in Paraná has a great potential to expand because it has a good technology, a good production capacity and productivity and a sufficient amount of available agricultural land to extend the exploration of the citriculture in Paraná, in addition, the economic agents that act in the citriculture in Paraná have contracts for the supply of orange to the economic organizations that have manufacturing plants that produce FCOJ in Paraná, so these contracts ensure the sale of the most part of the Paraná s orange production, which is good for the citrus growers who act in Paraná. The processor sector of orange also has a great potential to expand in Paraná because it has agro-industrial technologies of good level and a good production capacity, in addition to be able to expand without great difficulties its manufacturing capacity of FCOJ, moreover, the existence of contracts for orange supply between economic organizations who act in processing and citrus growers in Paraná, secures the supply of oranges, considered of good quality, for the producing plants of FCOJ installed in Paraná. / O Brasil é o maior produtor e exportador do mercado mundial de suco de laranja concentrado congelado (SLCC), sendo que o Estado de São Paulo destaca-se como o maior produtor e exportador nacional dessa commodity. Nos últimos anos, o Estado do Paraná tem aumentado a sua produção e exportação de SLCC. Por meio de levantamento de dados secundários e de entrevistas com agentes-chaves, identificou-se e avaliou-se os principais aspectos críticos da competitividade da cadeia agroindustrial de SLCC no Paraná. Por meio do método rapid appraisal (método de pesquisa rápida) foi possível avaliar 11 direcionadores de competitividade, com foco nos elos de produção agrícola e de processamento dessa cadeia. Um total de 24 entrevistas foram realizadas, utilizando-se de questionários e roteiros de entrevistas. Foi possível identificar quais são os direcionadores de competitividade, considerados no âmbito desta pesquisa, que são considerados favoráveis, neutros e desfavoráveis para a competitividade dos elos de produção agrícola e de processamento da cadeia agroindustrial paranaense de SLCC. A partir dessas análises também foi possível verificar que nenhum dos direcionadores de competitividade, considerados nesta dissertação, foi considerado como muito favorável ou muito desfavorável para a competitividade do elo de produção rural da cadeia agroindustrial paranaense de SLCC. A partir dessas análises também foi possível verificar que nenhum dos direcionadores de competitividade, considerados nesta dissertação, foi considerado como muito favorável para a competitividade do elo de processamento da cadeia de SLCC no Paraná, e somente um direcionador de competitividade, do conjunto de direcionadores considerados nesta dissertação, foi considerado como muito desfavorável para o desempenho competitivo do elo de processamento. As análises permitiram apontar propostas de políticas públicas e estratégias privadas que possam aumentar a competitividade. Em um contexto geral, pode-se concluir que os elos de produção rural e de processamento da cadeia agroindustrial de SLCC no Paraná têm um grande potencial para continuar a se expandir no território paranaense. A citricultura, no Paraná, tem um grande potencial para se expandir porque ela dispõe de boa tecnologia, de boa capacidade de produção e produtividade e de quantidade de terra agrícola disponível considerada como suficiente para ampliar a exploração da atividade citrícola no estado, além disso, os agentes econômicos que atuam na citricultura paranaense possuem contratos de fornecimento de laranja com as organizações econômicas que possuem usinas produtoras de SLCC instaladas no Paraná, assim, esses contratos asseguram a comercialização da maior parte da produção paranaense de laranja, o que é algo bom para os citricultores que atuam no Paraná. Já o setor processador de laranja também tem um grande potencial para se expandir no Paraná porque ele dispõe de tecnologias agroindustriais de bom nível e de boa capacidade de produção, além de ter condições de ampliar, sem maiores dificuldades, a sua capacidade de fabricação de SLCC, além disso, a existência de contratos de suprimento de laranja entre as organizações econômicas que atuam no processamento citrícola e os citricultores, no Estado do Paraná, assegura o abastecimento de laranja, considerada de boa qualidade, para as usinas produtoras de SLCC instaladas no Paraná.
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Estabilidade da polpa de caju congelada obtida com o uso de conservantes, pasteurizada e concentrada / Physical and chemical stability of frozen cashew pulp obtained with the use of preservatives, pasteurized and concentrated

Virlane Kelly Lima da Silva 03 January 2013 (has links)
CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / O caju destaca-se dentre as espÃcies frutÃferas nativas do Nordeste, por possuir elevada potencialidade para o consumo in natura e processamento industrial. A polpa e o suco sÃo importantes componentes da dieta humana por serem considerados uma fonte natural de carboidratos, carotenoides, vitaminas e compostos fenÃlicos, substÃncias com alto potencial antioxidante, e tÃm despertado o interesse de diferentes grupos de pesquisa. Este trabalho teve como objetivo estudar a estabilidade da polpa de caju com conservantes, pasteurizada e concentrada congelada durante 12 meses de armazenamento, atravÃs de determinaÃÃes quÃmicas, fÃsico-quÃmicas e microbiolÃgicas e a elaboraÃÃo de nÃctar e suco tropical adoÃado, estudando a estabilidade sensorial dos mesmos durante 360 dias de armazenamento da polpa. As polpas nÃo apresentaram interaÃÃo significativa para pH, sÃlidos solÃveis, acidez titulÃvel e coordenada de cor a. O pH e os sÃlidos solÃveis variaram com o tempo mas mantiveram-se dentro dos padrÃes da legislaÃÃo. A acidez nÃo variou com o armazenamento. A coordenada de cor a* ajustaram ao modelo cÃbico. O Ãcido ascÃrbico variou de 190,65 a 308,45mg/100g na polpa com conservantes, 170,95 a 299,70 mg/100g na polpa pasteurizada e de 514,68 a 865,42mg/100g na polpa concentrada, valores estes bastante expressivos. Pigmentos escuros solÃveis, luminosidade, hue, croma, carotenoides, teor de polpa, aÃÃcares totais apresentaram interaÃÃo significativa e foram avaliados por regressÃo variando com o tempo de armazenamento, exceto a coordenada de cor b*. Os teores de aÃÃcares totais mantiveram-se em torno de 10,01 a 13,25% nas polpas com conservantes e pasteurizadas a 24 a 27% na polpa concentrada, sendo estes em sua maioria representados por aÃÃcares redutores. As anÃlises microbiolÃgicas confirmaram a eficÃcia das etapas de processamento, tratamento tÃrmico e concentraÃÃo na manutenÃÃo da qualidade microbiolÃgica, uma vez que nÃo foi observado crescimento de microrganismos durante o perÃodo de armazenamento. Os nÃctares e os sucos tropicais adoÃados de caju apresentam-se na faixa de aceitaÃÃo sensorial em todos os atributos avaliados. O congelamento das polpas de caju com conservantes, pasteurizada e concentrada à viÃvel uma vez que nÃo ocorrem perdas significativas na qualidade dos produtos. A polpa de caju concentrada apresentou as melhores notas nos atributos sensoriais avaliados. / The cashew (Anacardium occidentale, L.) has a great economic importance to the Northeast region, notably for the great acceptance by consumers, both for their sensory properties (color, aroma, flavor, texture) as for its nutritional and functional values. It stands out among the fruit species native to the Northeast because it has high potential for fresh consumption and industrial processing. The cashew and cashew apple juice are important components of the human diet because they are considered a natural source of carbohydrates, carotenoids, vitamins and phenolic compounds, substances with high antioxidant potential, and have attracted the interest of various research groups. This work aimed to study the stability of cashew apple pulp with preservatives, pasteurized and concentrated frozen storage for 12 months, through to chemical, physical-chemical and microbiological analysis. And production of cashew apple nectar and cashew apple sweetened tropical juice and sensorial stability during 360 days of storage of the pulp. The pulps showed no significant interaction for pH, soluble solids, acidity and color coordinated. The pH and soluble solids varied with time but remained within standards legislation. The acidity no change during the storage. The color coordinate set to the cubic model. The parameters vitamin C ranged from 190.65 to 308.45 in the pulp with preservatives, 170.95 to 299.70 in the pulp pasteurized and from 514.68 to 865.42 mg/100g in concentrated pulp, these values very expressive. Dark pigments soluble, brightness, hue*, chroma*, carotenoids, pulp content, total sugar showed significant interaction were assessed by regression with time varying storage except color coordinate b. The concentration of total sugars remained around 10.01 to 13.25% for pulps with preservatives and pasteurized,and to 24 to 27% in the concentrated pulp, which are mostly represented by sugars. The microbiological analyses confirmed the effectiveness of the processing, thermal treatment and concentration in the maintenance of the microbiological quality, once growth of microorganisms was not observed in the product during the storage period. The cashew apple nectars and juices sweetened have good acceptability in all sensory attributes. The frozen pulps cashew with preservatives, pasteurized and concentrated is viable since no significant losses occur in the quality of products.

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