No description available.

No description available.

No description available.

No description available.

Santiago is the 7th largest major city of Latin America with almost 8 million inhabitants and is situated in a fairly closed watershed, surrounded on the eastern side by the high Andean mountain chain with altitudes of 5,000 m. From the Andean mountains, the Mapocho River and a set of large and small streams transport -often torrentially- water and sediment. In thirty years, Santiago has increased its size two fold, replacing previous agricultural lands, native forests and shrubs with urban land uses, and occupying rivers beds and streams. These land use and cover changes have had dramatic environmental consequences. The mentioned urban dynamic has produced a city in constant collision with the natural system. This structural disarticulation produces many environmental problems such as an increase in city’s surface and air temperatures, an accelerated disappearance of vegetation, a major interruption in wind, sediment and water flows, and finally, increasing people’s exposure to environmental hazards. Since streams, canals and rivers are structural components of Santiago’s landscape, they can function as key links between the urban-social and natural system and provide multiple ecosystem services, helping to reduce environmental problems and ensure long-term urban sustainability. Traditionally, the analysis of river and streamsides has been focused on rural and natural landscapes as well as on environmental protection and nature conservation. Nowadays, there is an increasing interest and necessity to understand the environmental status, functions and possibilities of riparian zones in urban environments in order to delineate and plan greenways, which provide social and ecological benefits. Green infrastructure such as urban greenways is a key component of sustainable cities. Few studies have been conducted to evaluate the socio-ecological status of urban riparian zones and even fewer to assess these areas in terms of their potential as multifunctional greenways. New efforts should be conducted to develop analytical application-oriented frameworks in the green infrastructure field. This research elaborates and proposes a transferable conceptual-methodological framework for evaluating the potential for multifunctional riparian greenway development. An analytical application-oriented framework to assess the potential for multifunctional green infrastructure development is proposed by articulating and improving three analyses hitherto used separately: multicriteria, least cost path and opportunities-challenges. The Mapocho River was selected for the application and testing of the proposed conceptual-methodological framework to contribute to multifunctional green infrastructure planning in Santiago as a city representative of the structure and processes of megacities in Latin America. First, the main ecological and social characteristics of the Mapocho’s riparian zone are analyzed, making a synthesis of the socio-ecological status. Second, the suitability to provide multiple ecosystem services of the riparian zone is spatially explicitly modelled, first separately, as mono-functional suitability, and then, integrated into a multifunctional suitability evaluation. Third, the opportunities and challenges perceived by government actors are identified and analyzed as well as those derived from an institutional and regulatory analysis. Finally, the assessment phase concludes with a discussion on the main potential for the development of a greenway, resulting from the synthesis and integration of the most relevant findings of the suitability and opportunities analysis The socio-ecological status of the riparian zones is characterized by being highly altered in ecological terms, diverse in social terms, and highly used by the metropolitan transport infrastructure with a concentration of green areas in a few municipalities. This means that the riparian zone provides limited physical support for important social and ecological functions characteristic of these zones in urban environments: habitat, aesthetic, cooling, transport route and flood mitigation. The results reveal a significant east-west gradient in the socio-ecological status of riparian zone, which gradually decreases from east to west. The riparian zone of the Mapocho River in Santiago has good suitability as a wind corridor, providing a cooling effect and to mitigate flood hazards. The main challenges for the development of a multifunctional urban greenway in the Mapocho River corresponds to low levels of inter-jurisdictional and inter-sectoral coordination and cooperation, maintenance costs and the existence of urban highways in the zone. On the contrary, the main opportunities are the existence of important sectors of vacant land, increased political and social importance of urban green areas and the existence of a set of consolidated riparian parks. In synthesis, the assessment developed in the Mapocho River identifies the most important aspects to be considered and the greatest potentialities to capitalize in planning a multifunctional greenway along the Mapocho River. This is key when thinking about a possible master plan for the Mapocho River that returns the river to the city and values it as an axis for urban integration. The development of a multifunctional greenway in Santiago can considerably contribute to the social and ecological connectivity and thereby mitigate the socio-ecological segregation and disconnection characteristic of cities in the region. It may also contribute significantly to reconcile urban growth with ecological health and people’s quality of life, maintaining functions and key ecosystem services and mitigating the negative effects of urbanization.

<p>Föreliggande uppsats studerar Friedensreich Hundertwassers (1928-2000) organiska/vegetativaarkitektur, begränsad till utvalda signifikativa arkitekturelement på fyra olika bildnivåer, frånöversiktsbild till en avgränsad del av ett mindre utrymme. Den byggnad som avses är kvarteretDie Grüne Zitadelle i Magdeburg, Tyskland. Uppsatsen är tudelad i den meningen att den utgårifrån nämnd arkitektur och analyseras/syntetiseras enligt Erwin Panofskys ikonologiska metod. Urdenna första analys framvaskas relevanta dikotomier, en metod som i sin ursprungliga form ärHeinrich Wölfflins komparativa. Dock jämförs inte Hundertwassers verk genom epokskiljandestilfaktorer, utan genom jämförande med en konstnär som enligt tidigare forskning anses varanärliggande Hundertwasser. Denne arkitekt är Antoni Gaudí (1852-1926), verket för analysen ärCasa Milá i Barcelona i Spanien. Syftet med uppsatsen är att genom dikotomierna experimentelltjämföra arkitekterna och deras verk, och forskningsinriktningen ligger i att urröna omdikotomierna kan blottlägga insikter om skillnader och/eller likheter som annars kunde varit svåraatt identifiera. Resultatet visar att arkitekterna tolkat filosofin på delvis lika och delvis olika sätt.Sammanfattande har Hundertwasser ett betydligt mer individualiserat formspråk avseende designifikativa arkitekturelementen. Oavsett om den dubbla metoden tillför nya kunskaper eller inte,torde dikotomierna kunna fungera som stöd för arkitekturanalyser och som hjälp vidkonstreflektion.</p>

The need to reduce humankind reliance on fossil fuels by exploiting sustainably the planet renewable resources is a major driving force determining the focus of modern material research. For this reason great interest is nowadays focused on finding alternatives to fossil fuels derived products/materials. For the short term the most promising substitute is undoubtedly biomass, since it is the only renewable and sustainable alternative to fossil fuels as carbon source. As a consequence efforts, aimed at finding new synthetic approaches to convert biomass and its derivatives into carbon-based materials, are constantly increasing. In this regard, hydrothermal carbonisation (HTC) has shown to be an effective means of conversion of biomass-derived precursors into functional carbon materials. However the attempts to convert raw biomass, in particular lignocellulosic one, directly into such products have certainly been rarer. Unlocking the direct use of these raw materials as carbon precursors would definitely be beneficial in terms of HTC sustainability. For this reason, in this thesis the HTC of carbohydrate and protein-rich biomass was systematically investigated, in order to obtain more insights on the potentials of this thermochemical processing technique in relation to the production of functional carbon materials from crude biomass. First a detailed investigation on the HTC conversion mechanism of lignocellulosic biomass and its single components (i.e. cellulose, lignin) was developed based on a comparison with glucose HTC, which was adopted as a reference model. In the glucose case it was demonstrated that varying the HTC temperature allowed tuning the chemical structure of the synthesised carbon materials from a highly cross-linked furan-based structure (T = 180oC) to a carbon framework composed of polyaromatic arene-like domains. When cellulose or lignocellulosic biomass was used as carbon precursor, the furan rich structure could not be isolated at any of the investigated processing conditions. These evidences were indicative of a different HTC conversion mechanism for cellulose, involving reactions that are commonly observed during pyrolytic processes. The evolution of glucose-derived HTC carbon chemical structure upon pyrolysis was also investigated. These studies revealed that upon heat treatment (Investigated temperatures 350 – 900 oC) the furan-based structure was progressively converted into highly curved aromatic pre-graphenic domains. This thermal degradation process was observed to produce an increasingly more hydrophobic surface and considerable microporosity within the HTC carbon structure. In order to introduce porosity in the HTC carbons derived from lignocellulosic biomass, KOH chemical activation was investigated as an HTC post-synthesis functionalisation step. These studies demonstrated that HTC carbons are excellent precursors for the production of highly microporous activated carbons (ACs) and that the porosity development upon KOH chemical activation is dependent on the chemical structure of the HTC carbon, tuned by employing different HTC temperatures. Preliminary testing of the ACs for CO2 capture or high pressure CH4 storage yielded very promising results, since the measured uptakes of both adsorbates (i.e. CO2 and CH4) were comparable to top-performing and commercially available adsorbents, usually employed for these end-applications. The combined use of HTC and KOH chemical activation was also employed to produce highly microporous N-doped ACs from microalgae. The hydrothermal treatment of the microalgae substrate was observed to cause the depletion of the protein and carbohydrate fractions and the near complete loss (i.e. 90%) of the microalgae N-content, as liquid hydrolysis/degradation products. The obtained carbonaceous product showed a predominantly aliphatic character indicating the presence of alkyl chains presumably derived from the lipid fractions. Addition of glucose to the initial reaction mixture was found out to be extremely beneficial, because it allowed the fixation of a higher N amount, in the algae derived HTC carbons (i.e.  60%), and the attainment of higher product yields (50%). Both positive effects were attributed to Maillard type cascade reactions taking place between the monosaccharides and the microalgae derived liquid hydrolysis/degradation products, which were in this way recovered from the liquid phase. KOH chemical activation of the microalgae/glucose mixture derived HTC carbons produced highly microporous N-doped carbons. Although the activation process led to a major reduction of the N-content, the retained N-amount in the ACs was still considerable. These features render these materials ideal candidates for supercapacitors electrodes, since they provide extremely high surface areas, for the formation of electric double-layer, coupled to abundant heteroatom doping (i.e. N and O) necessary to obtain a pseudocapacitance contribution. / Die Notwendigkeit, die Abhängigkeit der Menschheit von fossilen Brennstoffen zu reduzieren ist die treibende Kraft hinter aktuellen Forschungsanstrengungen in den Materialwissenschaften. Folglich besteht heutzutage ein erhebliches Interesse daran Alternativen zu Materialien, die aus fossilen Resourcen gewonnen werden, zu finden. Kurzfristig ist zweifellos Biomasse die vielversprechendste Alternative, da sie aus heutiger Sicht die einzige nicht-fossile, nachhaltige und nachwachsende Kohlenstoffquelle ist. Konsequenterweise werden die Antrengungen neue Syntheseansätze zur Konvertierung von Biomasse und ihren Derivaten in kohlenstoffbasierten Materialien forwährend erhöht. In diesem Zusammenhang hat sich die Hydrothermalkarbonisierung (HTC) als sehr vielseitiges Werkzeug zur Konvertierung von Biomasse-basierten Ausgangsstoffen in funktionale Kohlenstoffmaterialien herausgestellt. Dennoch gibt es bisher wenige Ansätze um rohe Biomasse, genauer gesagt Lignicellulose, direkt in funktionale Materialien umzusetzen. Könnte der direkte Einsatz von roher Biomasse Verfahren wie der HTC zugänglich gemacht werden, würde dies die Nachhaltigkeit des Verfahrens immens steigern. Daher wurde in dieser Dissertation die Hydrothermalkarbonisierung von kohlenhydratreicher (d. h. Lignicelluse) und proteinreicher (d. h. Microalgae) Biomasse systematisch analysiert. Diese Untersuchung galt dem Ziel einen besseren Einblick in das Potential dieser thermochemischen Verarbeitungsmethode funktionale Kohlenstoffmaterialien aus unverarbeiteter Biomasse hervorzubringen zu gewinnen. Die hergestellten Materialien wurden mittels chemischer Aktivierung nachträglich weiter behandelt. Dieser zusätzliche Verarbeitungsschritt ermöglichte die Herstellung hochporöser aktiverter Kohlenstoffe (AC). Die aus Lignicellulose gewonnenen ACs zeigten exzellente Eigenschaften bei der Aufnahme von CO2 und der Hochdruckspeicherung von CH4 währen die aus Microalgae gewonnen Eigenschaften an den Tag legten (z. B. hohe Oberfläche und N-Dotierung), welche sie zu vielversprechenden Materialien für Superkondensatoren machen. Die in dieser Dissertation präsentierte Arbeit zeigte außergewöhnliche Fortschritte in Richtung der Anwendung von unbehandelter Biomasse als Ausgangsmaterial für die Produktion von funktionalen Kohlenstoffen.

As mobile devices are nowadays used regularly and everywhere, their energy consumption has become a central concern for their users. However, mobile applications often do not consider energy requirements and users have to install and try them to reveal information on their energy behavior. In this paper, we compare mobile applications from two domains and show that applications reveal different energy consumption while providing similar services. We define microbenchmarks for emailing and web browsing and evaluate applications from these domains. We show that non-functional features such as web page caching can but not have to have a positive influence on applications' energy consumption.

Föreliggande uppsats studerar Friedensreich Hundertwassers (1928-2000) organiska/vegetativaarkitektur, begränsad till utvalda signifikativa arkitekturelement på fyra olika bildnivåer, frånöversiktsbild till en avgränsad del av ett mindre utrymme. Den byggnad som avses är kvarteretDie Grüne Zitadelle i Magdeburg, Tyskland. Uppsatsen är tudelad i den meningen att den utgårifrån nämnd arkitektur och analyseras/syntetiseras enligt Erwin Panofskys ikonologiska metod. Urdenna första analys framvaskas relevanta dikotomier, en metod som i sin ursprungliga form ärHeinrich Wölfflins komparativa. Dock jämförs inte Hundertwassers verk genom epokskiljandestilfaktorer, utan genom jämförande med en konstnär som enligt tidigare forskning anses varanärliggande Hundertwasser. Denne arkitekt är Antoni Gaudí (1852-1926), verket för analysen ärCasa Milá i Barcelona i Spanien. Syftet med uppsatsen är att genom dikotomierna experimentelltjämföra arkitekterna och deras verk, och forskningsinriktningen ligger i att urröna omdikotomierna kan blottlägga insikter om skillnader och/eller likheter som annars kunde varit svåraatt identifiera. Resultatet visar att arkitekterna tolkat filosofin på delvis lika och delvis olika sätt.Sammanfattande har Hundertwasser ett betydligt mer individualiserat formspråk avseende designifikativa arkitekturelementen. Oavsett om den dubbla metoden tillför nya kunskaper eller inte,torde dikotomierna kunna fungera som stöd för arkitekturanalyser och som hjälp vidkonstreflektion.

No description available.