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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
61

Highly Mismatched GaAs(1-x)N(x) and Ge(1-x)Sn(x) Alloys Prepared by Ion Implantation and Ultrashort Annealing

Gao, Kun 12 January 2015 (has links) (PDF)
Doping allows us to modify semiconductor materials for desired properties such as conductivity, bandgap, and / or lattice parameter. A small portion replacement of the highly mismatched isoelectronic dopants with the host atoms of a semiconductor can result in drastic variation of its structural, optical, and / or electronic properties. Here, the term "mismatch" describes the properties of atom size, ionicity, and / or electronegativity. This thesis presents the fabrication of two kinds of highly mismatched semiconductor alloys, i.e., Ge(1-x)Sn(x) and GaAs(1-x)N(x). The structural and optical properties of the prepared Ge(1-x)Sn(x) and GaAs(1-x)N(x) have been investigated. The results suggest an efficient above-solubility doping induced by non-equilibrium methods of ion implantation and ultrashort annealing. Pulsed laser melting promotes the regrowth of monocrystalline Ge(1-x)Sn(x), whereas flash lamp annealing brings about the formation of high quality GaAs(1-x)N(x) with room temperature photoluminescence. The bandgap modification of Ge(1-x)Sn(x) and GaAs(1-x)N(x) has been verified by optical measurements of spectroscopic ellipsometry and photoluminescence, respectively. In addition, effective defect engineering in GaAs has been achieved by flash lamp annealing, by which a quasi-temperature-stable photoluminescence at 1.3 µm has been obtained. / Dotierung ermöglicht es, die Eigenschaften von Halbleitermaterialien, wie Leitfähigkeit, aber auch Bandabstand und / oder Gitterkonstanten gezielt zu verändern. Wenn ein Halbleiter mit einer kleinen Menge unterschiedliche Fremdatome dotiert wird, kann dies in einer drastischen Modifikation der strukturellen, optischen und / oder elektronischen Eigenschaften resultieren. Der Begriff "unterschiedlich" bedeutet hier die Eigenschaften von Atomgröße, Ioniztät und / oder Elektronegativität. Diese Doktorarbeit beschreibt die Herstellung von zwei Arten von stark fehlangepassten Halbleiterlegierungen: Ge(1-x)Sn(x) und GaAs(1-x)N(x). Die strukturellen und optischen Eigenschaften von Ge(1-x)Sn(x) und GaAs(1-x)N(x) wurden untersucht. Die Ergebnisse deuten auf eine effiziente Dotierung oberhalb der Löslichkeit, induziert durch die Nicht-Gleichgewichtsverfahren Ionenimplantation und Ultrakurzzeit-Ausheilung. Gepulstes Laserschmelzen ermöglicht das Nachwachsen von monokristallinem Ge(1-x)Sn(x), während die Blitzlampenausheilung in der Bildung von GaAs(1-x)N(x) hoher Qualität mit Photolumineszenz bei Raumtemperatur resultiert. Die Änderung der Bandlücke von Ge(1-x)Sn(x) und GaAs(1-x)N(x) wurde durch die optischen Methoden der spektroskopischen Ellipsometrie und Photolumineszenz verifiziert. Darüber hinaus konnte in ausgeheiltem GaAs eine quasi-temperaturstabile Photolumineszenz bei 1,3 µm beobachtet werden.
62

Independent Project in Chemical Engineering and Materials Engineering : A literature study of powder-based additive manufacturing

Feldt, Daniel, Hedberg, Petra, Jarlöv, Asker, Persson, Elsa, Svensson, Mikael, Vennberg, Filippa, You, Therese January 2018 (has links)
The focus of this literary study was additive manufacturing (AM) and the purpose was to find general trends for selected materials that have been additively manufactured and compare them to results from other reviews. The raw materials studied were stainless steels 316L, 17-4 PH, 15-5 PH and 420, as well as tool steel H13 and nickel alloys 625, 718 and Hastelloy X.The AM techniques studied were selective laser melting (SLM), electron beam melting (EBM) and binder jetting (BJG).  A total of 69 articles have been studied to fulfill the purpose above. The articles were used to write a summary of the techniques, compare them to each other and to conventional methods. They were also used to create a database to compile information on mechanical properties, microstructure and process parameters. Based on the database mechanical properties for SLM tend to be higher compared to EBM. This however varied somewhat depending on the processed material. Furthermore the yield and tensile strength obtained from the database for SLM seemed to be higher compared to the values in review articles for almost all materials. Unfortunately not enough values were found for BJG to compare it to SLM and EBM.AM seems to produce weaker, equal and superior products compared to conventional methods. However due to the limited nature of the project and the research found no conclusions can be drawn about any trends, how to achieve the different results or how parameters affect the finished product. To be able to say anything with more certainty more research has to be done. Not only in general concerning the AM techniques, but more studying of existing articles is needed. Finally a standardization on how to reference properties and process parameters is necessary. Currently it is very difficult to compare results or draw conclusions due to different designations, units and a lot of missing essential information.
63

Independent Project in Chemical Engineering and Materials Engineering : A literature study of powder-based additive manufacturing

Feldt, Daniel, Hedberg, Petra, Jarlöv, Asker, Persson, Elsa, Svensson, Mikael, Vennberg, Filippa, You, Therese January 2018 (has links)
The focus of this literary study was additive manufacturing (AM) and the purpose was to find general trends for selected materials that have been additively manufactured and compare them to results from other reviews. The raw materials studied were stainless steels 316L, 17-4 PH, 15-5 PH and 420, as well as tool steel H13 and nickel alloys 625, 718 and Hastelloy X. The AM techniques studied were selective laser melting (SLM), electron beam melting (EBM) and binder jetting (BJG).  A total of 69 articles have been studied to fulfill the purpose above. The articles were used to write a summary of the techniques, compare them to each other and to conventional methods. They were also used to create a database to compile information on mechanical properties, microstructure and process parameters. Based on the database mechanical properties for SLM tend to be higher compared to EBM. This however varied somewhat depending on the processed material. Furthermore the yield and tensile strength obtained from the database for SLM seemed to be higher compared to the values in review articles for almost all materials. Unfortunately not enough values were found for BJG to compare it to SLM and EBM.AM seems to produce weaker, equal and superior products compared to conventional methods. However due to the limited nature of the project and the research found no conclusions can be drawn about any trends, how to achieve the different results or how parameters affect the finished product. To be able to say anything with more certainty more research has to be done. Not only in general concerning the AM techniques, but more studying of existing articles is needed. Finally a standardization on how to reference properties and process parameters is necessary. Currently it is very difficult to compare results or draw conclusions due to different designations, units and a lot of missing essential information.
64

Mechanical properties of trabecular structures produced by SLM, as a function of the trabecular morphology

Johansson, Frida, Klarin, Johanna January 2017 (has links)
Eurocoating, Italy, is a company that works in the biomedical sector. They have for a long time created prostheses from CAD files achieved from customers, and now they want to build their own expertise about the design. The thesis work was a part of a three year long collaborative research project between Eurocoating and University of Trento that was aiming to investigate the prostheses with open-porous surface and trabecular structure, created by Selective Laser Melting. The purpose of the thesis was to investigate and characterize 30 different trabecular structures of Ti-6Al-4V, fabricated by Selective Laser Melting. That includes investigation the effect on the morphology and porosity fraction caused by the manufacturing and the effect on mechanical and physical properties due to the different characterizations of the structures. The thesis work had its foundation in literature studies to receive deep knowledge about the subject. Practical tests were performed to investigate mechanical behaviour under compressive and tensile loading, static friction and wear resistance. The findings from these tests were compared to the porosity fraction and the morphological characterizations. The result stated that the porosity fraction was lower than the designed porosity, and that is was strongly influenced by size of the voids and struts. The strut thickness was higher than the design values, especially on the lateral surface, while the voids size were approximately as designed. Result from the compression test showed a trend of decreasing stiffness and strength with increasing porosity fraction. Also structures with same porosity fraction could have a wide range in mechanical properties which indicates high dependence on the morphological geometry i.e. pore size and shape, strut size and pore distribution. Comparisons between tensile and compression behaviour stated that the structures had a lower strength but a significant higher stiffness in tensile load. All structures from the wear test showed a good resistance while the results from the friction test needs further investigation to be fully understood. The physical and mechanical properties of the trabecular structures was found to be close to those of cortical and trabecular bone in porosity, stiffness and strength. There is a range of variations leading to possibilities to adopt the application depending on customer. Thus, these can be considered as promising structures used biomedical application to optimize osseointegration and secondary long term fixation.
65

Modifikace povrchu materiálu vytvořeného technikou SLM / The use of surface modification for enhancing mechanical properties of SLM bulk materials

Barinka, Michal January 2021 (has links)
This diploma thesis deals with the surface modification of 3D printed metallic materials. The research part presents the most used methods of additive manufacturing and their process parameters influencing the quality of printed components. Defects arising during these processes and the techniques used to eliminate them are also described. In the experimental part of the work, the optimization of electrochemical polishing parameters was performed. The aim was to modify the rough surface of the components and thus prevent the formation of defects on the surface. The mechanical properties were investigated by means of three-point bending under static and dynamic loading. Fractographic analysis was performed on the quarry surfaces.
66

Optimalizace parametrů SLM procesu při zpracování hliníkové slitiny AW2618 / SLM process parameters optimization for processing of AW2618 aluminum alloy

Těšický, Lukáš January 2017 (has links)
The diploma thesis deals with possibilities for processing aluminium alloy EN AW 2618 using Selective laser melting (SLM). The theoretical part contains basic knowledge about production by this technology and possibilities of evaluation of relative density of samples. It also contains an overview of the current state of knowledge about the processing of aluminium alloys by SLM technology. Above all, aluminium alloys of the series 2000, where the main alloying element is copper. In the experimental part testing samples were designed based on the research. These samples can be divided into three areas: single-track specimens, volume samples and samples for tensile testing. Single-track and volume samples were used to find appropriate processing parameters to achieve a relative density close to full volume of material. For this purpose, the effect of the different scanning strategies on the relative density of the sample were examined. The limiting factor has been the occurrence of small cracks in the broad range of parameters studied. Mechanical properties of samples produced by SLM were compared with extruded material. It was found that the material processed by SLM achieves only half the yield strength and tensile strength of extruded material. This is mainly due to the occurrence of small cracks and other defects in the structure of the material.
67

Zpracování Al-Sc hliníkové slitiny technologií SLM / Processing of Al-Sc aluminum alloy using SLM technology

Skulina, Daniel January 2017 (has links)
Master's thesis deals with the experimental determination of process parameters reaching densities >99 % for scandium modified aluminium alloy (Scalmalloy®) processed by SLM. The alloy achieves higher mechanical properties than the AlSi10Mg aluminum alloy commonly used. The theoretical part deals mainly with the results of Scalmalloy® alloys. Experimental bodies, testing methodology and evaluation method were designed on the basis of the theoretical parts,. The practical part is divided into four main stages: experimental determination of process parameters, a description of the effect of the parameters used on the relative density achieved, examination of the influence of process parameters on surface quality and mechanical testing. The mechanical properties were determined for the best parameters.
68

Univerzální úsťové zařízení na útočnou pušku / Universal muzzle device for an assault rifle

Rušar, Filip January 2017 (has links)
This diploma thesis deals with the design of a universal muzzle device for the assault rifle. The device is designed to produce Selective Laser Melting. The main objective is the elimination negative effects of gunshot. The paper explores possibilities of using porous structures for this type of equipment. The influence of individual types of porous structures on the flow of gases is monitored. The universal muzzle device itself is optimized using CFD analyzes. The device was made using SLM technology and experimentally verified. His impact on the impact, gun lift, noise and flame elimination was investigated.
69

Mechanické vlastnosti Al slitiny připravené pomocí procesu SLM / Mechanical properties of Al alloy prepared by SLM process

Vitásek, Ladislav January 2017 (has links)
The master's thesis deals with properties of aluminium alloys prepared by SLM process. The teoretical part of thesis is focused on decribtion of selective laser melting technology, metallurgical defects and mechanical properties of aluminium alloys processed by this technology. The experimental part of this thesis deals with selections of the SLM process parameters suitable for samples preparation in bulk. Tensile testing at room temperature was used for evaluation of basic mechanical properties. Metallographic and fractographic analyses were performed for evaluation of the microstructure and fracture mechanisms. The materials characteristics obtained on SLM samples were compared with the properties of the same materials grade produced by conventional technologies.
70

Vývoj procesních parametrů slitiny mědi pro 3D tisk tenkostěnných struktur / Process parameters development for copper thin walls manufacturing via 3D printing

Klimek, Ľubomír January 2018 (has links)
In the work is used the processing of metallic material by the method of Selective Laser Melting. The main objective is to verify and describe the influence of the individual process parameters entering the production process when processing the alloy Cu7.2Ni1.8Si1Cr with SLM. This alloy contains 90 % copper. The first theoretical part of the thesis describes so far processed copper alloys with a high content of copper using the method of Selective Laser Melting. The practical part then deals with the specification of the main process parameters, which are optimized in the next part of the work solution. On the basis of the information obtained experimental bodies have been created, which will be tested and analyzed in several steps. The work focuses on thin-walled samples, which have a perspective use in the creation of highefficiency heat exchangers. The main results that the work deals with are the relative density and mechanical properties of the material. Also, great emphasis is placed on the resulting surface quality

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