Nanofibrous separators use in lithium-ion batteries brings many advantages. In contrast to contemporary used commercial separators, nanofibrous ones exhibit higher temperature resistance,ionic conductivity and higher electrolyte uptake. Better ionic conductivity is ensured by porous structure and large specific surface. Fibers creates channels for the ionic species motion. Amorphous texture of nanofibers allows quick lithium ionic species motion within the polymeric matrix of separator. Furthermore, these separators exhibit higher volume of uptaken electrolyte. Further advantage of electrospinned nanofibrous separators are both high porosity and chemical stability.

This diploma thesis focuses on study of positive electrode materials for Li-Ion batteries. Our aim are intercalation materials whose are really perspective materials whose are widely used in this case. The theoretical part of my thesis focus on basic study of Li-ion batteries and their parameters. We studied charging and discharging processes. AFM and SEM were used as additional techniques for study LiCoO2 a Li0,975K0,025CoO2. We tested lifetime and stability of electrode as a perspective material for electrode for Li-ion batteries.

Les accumulateurs commerciaux à base de lithium-ion (LIB) utilisent des matériaux à base de carbone (graphite) comme électrode négative; cependant, la technologie atteint sa limite en raison de la faible capacité spécifique théorique. L'objectif de cette thèse est d'étudier le comportement électrochimique de trois nouvelles anodes à haute capacité (SnSb microsturé, Ti3SiC2 anodisé et nanotubes de Si poreux) comme alternatives au graphite, d'identifier les principaux paramètres responsables de la perte de capacité et de proposer une solution commune pour améliorer leurs performances électrochimiques. Ces matériaux d'électrode présentent une bonne performance électrochimique qui les rend prometteurs pour remplacer le carbone en tant qu'électrode négative pour batteries au Li-ion. Cependant, ils présentent une perte de capacité initiale importante qui doit être résolue avant la commercialisation. Les limitations observées sont attribuées à de nombreux facteurs, et en particulier à la formation et la croissance d’une SEI à la surface des matériaux. En raison de la forte perte de la capacité et du manque d’études détaillées sur les matériaux à base d’étain, en particulier le SnSb, nous avons concentré la suite du travail à la formation et la croissance de la SEI sur cette électrode négative. L'évolution des propriétés électriques, de la composition chimique et de la morphologie du SnSb microstructuré a été étudiée en détail pour comprendre son comportement électrochimique. Pour limiter l’effet de la SEI, nous avons proposé d’appliquer un film protecteur à la surface de l'électrode. / Currently, commercial lithium ion batteries (LIBs) use carbon based materials as negative electrode; however the technology is reaching its limit because of the low theoretical specific capacity. The objective of this thesis is to study the electrochemical behaviour of three different new high capacity anodes (SnSb alloy, anodized Ti3SiC2, and Si nanotubes) as alternative to graphite, identify the main parameters responsible for the capacity fading, and propose a versatile solution to improve their electrochemical performance. These electrode materials exhibit good electrochemical performance which makes them promising candidates to replace carbon as a negative electrode for LIBs. However, their limitation due to capacity fading and the large initial irreversible capacity loss must be resolved before commercialization. The observed limitations are attributed to many factors, and particularly, to the formation and growth of SEI layer which is the common factor for all the three electrode materials. Because of the strong capacity fade and lack of many detailed studies on the Sn-based materials, specifically SnSb, we focus our study to investigate the formation and growth of SEI layer on SnSb electrode. The evolution of the electrical, compositional, and morphological properties have been investigated in detail to understand the electrochemical behavior of micron-sized SnSb. To limit the capacity fade, we propose the use of a protective film on the electrode surface. The electrochemical performance of micron-sized SnSb electrode coated with thermoplastic elastomer protective film, namely poly(styrene-b-2-hydroxyethyl acrylate) PS-b-PHEA has been achieved.

Recent experiments revealed micrometer (µm)-sized Selenium (Se)-doped Germanium (Ge) particles forming a network of inactive phase (Li-Ge-Se) bring superior performance in cycling stability and capacity over un-doped Ge particles. Therefore, based on two states of Li (one for diffusion and another for alloyed reaction), a phaseield model (PFM) is developed incorporating both chemical reaction and Li diffusion to investigate remaining elusive underpinning mechanism. The reaction-diffusion PFM enables us to directly determine the conditions under which the lithiation process is diffusion- and/or reaction-controlled. Moreover, coupling the elasto-plastic deformation, the model allows us to investigate the role of the inactive phase in morphology and stress variation of Se-doped Ge electrode upon lithiation. The numerical results reveal that the tensile hoop stress at the surface of the particles is significantly suppressed due to softness of the inactive Li-Ge-Se phase, in line with the experimental observation of surface fractureree behavior. Further, we find that the soft Li-Ge-Se phase reduces a compressive mean stress at the reaction front, thus alleviating the stress retardation effect on the lithiation kinetics. And, the high Li diffusivity of the amorphous Li-Ge-Se network provides an effective Li diffusion path for inter-particle diffusion, reducing stress difference between the surfaces of neighboring particles. Besides, the constraint between the adjacent particles induces a higher compressive stress at the reaction front impeding the mobile Li insertion during lithiation. Though small c-Ge nano-particle in the Ge0.9Se0.1 microparticle is lithiated faster than large one, the compressive stress is generated at the center of small one for stress equilibrium which causes more retardation effect. Meanwhile, the size difference between adjacent particles increases the principle and shear stresses in the inactive Li-Ge-Se network near adjacent surfaces, which could potentially lead to mechanical failure and debonding of the amorphous network. We believe that the results of this investigation can shed some light on the optimization design of electrodes.

No description available.

京都大学 / 新制・課程博士 / 博士(人間・環境学) / 甲第25385号 / 人博第1127号 / 新制||人||262(附属図書館) / 京都大学大学院人間・環境学研究科相関環境学専攻 / (主査)教授 内本 喜晴, 教授 田部 勢津久, 教授 藤原 直樹, 教授 雨澤 浩史 / 学位規則第4条第1項該当 / Doctor of Human and Environmental Studies / Kyoto University / DFAM

[pt] Debruçando-se especificamente sobre o poema (yùjiēyuàn) – degraus da escada de jade, em tradução de Haroldo de Campos – do poeta clássico chinês Li Bai (701-762), esta pesquisa, inserindo-se no campo dos estudos da tradução, constrói-se por duas vias interligadas: primeiramente, realizo uma análise do poema chinês, cruzando-a com leituras propostas por António Graça de Abreu (s/d), Cristiano Mahaut de Barros Barreto (2011) e Ricardo Primo Portugal e Tan Xiao (2019), para, em seguida, contrastá-la com minhas leituras de um conjunto de traduções do poema para o inglês e o português – sob o marco daquelas feitas por Ezra Pound e Haroldo de Campos –, mirando o exame crítico das diversas escolhas tradutórias em jogo. Na segunda parte, buscando alicerce na exploração do silêncio que depreendo no texto original, realizo eu mesmo exercícios de tradução experimental, justificando minhas escolhas de acordo com as características identificadas e priorizadas na primeira parte do trabalho. A pesquisa reflete sobre caminhos contemporâneos da experimentação na tradução, com ênfase na poesia clássica chinesa, em especial do estilo conciso chamado (juéjù). / [en] Focusing specifically on the poem (yùjiēyuàn) – The Jewel Stairs Grievance, translated by Ezra Pound – by the classical Chinese poet Li Bai (701- 762), this research, situated within the field of translation studies, unfolds through two interconnected avenues: first, I conduct an analysis of the Chinese poem, drawing on interpretations proposed by António Graça de Abreu (n.d.), Cristiano Mahaut de Barros Barreto (2011), and Ricardo Primo Portugal and Tan Xiao (2019), and then contrast them with my readings of a set of translations of the poem into English and Portuguese – particularly focusing on those by Ezra Pound and Haroldo de Campos – aiming at a critical examination of the various translation choices at play. In the second part, grounded in an exploration of the silence I infer from the original text, I engage in experimental translation exercises, justifying my choices according to the identified and prioritized characteristics in the first part of the study. The research reflects on contemporary paths of experimentation in translation, with a focus on classical Chinese poetry, especially the concise style known as (juéjù).

Emerging energy storage applications are driving the demand for Li-ion battery positive electrode materials with higher energy densities and lower costs. The recent production of complete pseudo-ternary phase diagrams of the Li-Mn-Ni-O system generated using combinatorial methods has provided a greater understanding of the impact of initial composition, synthesis temperature, and cooling rate on the phases that form in the final materials. This thesis focuses on the synthesis and characterization of gram-scale positive electrode materials in the Li-Mn-Ni-O system. Structural analysis of these samples has resulted in the production of partial pseudo-ternary phase diagrams focusing on the positive electrode materials region of the Li-Mn-Ni-O system at 800°C and 900°C in air for both quenched and slow cooled compositions. These bulk-scale diagrams support the observations of the combinatorial diagrams, and show similar layered and cubic structures contained within several single- and multi-phase regions. The phases that form at each composition are shown to be dependent on both the reaction temperature and cooling rate used during synthesis. The electrochemical characterization of two composition series near Li2MnO3, one quenched and one slow cooled, is presented. The quenched compositions exhibited reversible cycling at 4.4 V, voltage plateaus and small increases in capacity above 4.6 V, and large first cycle irreversible capacity losses at 4.8 V. In the slow cooled series, all but one composition exhibited initial capacities below 100 mAh/g which began to continually increase with cycling, with several compositions exhibiting capacity increases of 300% over 150 cycles at 4.9 V. In both series, analysis of the voltage and differential capacity plots indicated that significant structure rearrangements are taking place in these materials during extended cycling, the possible origins of which are discussed. Finally, high precision coulometry studies of one Li-deficient and two Li-rich single-phase layered compositions are discussed. These materials exhibit minimal oxidation of simple carbonate-based electrolyte when cycled to high potential, with the Li-deficient composition producing less electrolyte oxidation at 4.6 V vs. Li/Li+ than commercial Li[Ni1/3Mn1/3Co1/3]O2 at 4.2 V. The inherent inertness of this composition may make it suitable for use as a thin protective layer in a core-shell particle.

Les mécanismes mis en jeu lors du cyclage de batteries au Lithium Li//Li1.20Mn0.54Co0.13Ni0.13O2 ont été étudiés avec l’objectif de déterminer l’origine des capacités très élevées délivrées par les oxydes lamellaires « (1-x)LiMO2.xLi2MnO3 ». La caractérisation par diffraction des RX et des neutrons montre que la structure est maintenue et l’existence de fluctuations de composition qui peuvent être assimilées à l’existence de deux phases de compositions voisines. Les résultats des tests électrochimiques et les analyses menées au cours du cyclage en spectroscopie d’absorption des rayons X ont suggéré la participation de l’oxygène aux processus redox. Celle-ci a été confirmée par la préparation et la caractérisation de matériaux désintercalés et réintercalés chimiquement en lithium. Les analyses en microscopie électronique à transmission (HAADF-STEM) et en nanodiffraction, montrent qu’une densification associée à un dégagement d’oxygène a lieu à la périphérie des particules / The charge and discharge mechanism of Li1.20Mn0.54Co0.13Ni0.13O2 was studied using several characterization tools in order to determine the origin of the high capacity observed for the system (1-x)LiMO2.xLi2MnO3 used as positive electrode for Li-ion batteries. The electrochemical results and in operando XAS analyses performed during the 1st cycle of Li//Li1.20Mn0.54Co0.13Ni0.13O2 cells suggested the possible participation of oxygen anion to the redox processes. It was supported by the in-depth analysis of materials prepared by chemical Li deintercalation and reinsertion. The results of XRD, HAADF-STEM and nanodiffraction analyses, combined with electrochemical experiments performed in different conditions (rate, temperature …), revealed that different types of reactions occur in the particles during the 1st cycle. Within the bulk Ni, Co and O are involved in the redox processes, whereas Mn is not: oxygen ions are oxidized in charge and reduced during the next discharge reversibly. At the surface, the same oxidation processes occur during the first charge, but with the release of oxygen gaz and a densification of the lattice. During the next discharge and subsequent cycles, the redox reaction occurring near the surface after the 1st charge involves thus Co, Ni and Mn.

The present thesis demonstrates and discusses polymeric ion and mixed ion-electron conductors for rechargeable batteries based on lithium viz. lithium-ion and lithium-sulphur batteries. The proposed polymer ion conductors in the thesis are discussed primarily as potential alternatives to conventional liquid and solid-crystalline electrolytes in lithium-ion batteries. These discussions are part of Chapters 2-4. On the other hand, the polymer based mixed ion-electron conductor is demonstrated as a novel electrode for lithium-Sulphur battery in Chapter 5. Possibility of application of polymer ion conductors is discussed in the context of Li-S battery in Chapter 6. A distinct correlation between the physical properties and electrochemical performance of the proposed conductors is highlighted in detail in this thesis. Systematic investigation of the ion transport mechanism in the polymeric ion conductors has been carried out using various spectroscopic techniques at different time and length scales. Such detailed investigations demonstrate the key structural and physical parameters for design of alternative polymer conductors for rechargeable batteries. Though the thesis discusses the various polymeric conductors in the context of lithium-based batteries, it is strongly felt that the design strategies are equally likely to be beneficial for different battery chemistries as well as for other electrochemical generation and storage devices. A brief discussion of the contents and highlights of the individual chapters are described below: The thesis comprises of six Chapters. Chapter 1 briefly reviews the important developments and materials of lithium-based batteries, with specific focus on Li-ion and Li-S batteries. It starts with discussions on different types of liquid, solid crystalline and solid-like electrolytes. Their materials characteristics, advantages and disadvantages are discussed in the context of secondary batteries such as lithium-ion and lithium-sulphur batteries. As prospective alternative electrolytes polymer based soft matter electrolytes are discussed in detail. Special emphasis is given to the recent developments in polymer electrolytes and their ion conduction mechanism, which are central themes to this thesis. The importance of investigation of charge transport, typically ion, on electrochemical processes is also briefly discussed in Chapter 1. A brief discussion about the characteristics, materials and non-trivialities of the electrochemical storage process in Li-S battery is also reviewed. Chapter 2A demonstrates a binary polymer physical network based gel (PN-x) electrolyte, comprising of an ionic liquid confined inside a binary polymer system for electrochemical devices such as secondary batteries. The synthesis, physical property and electrochemical performances are studied as a function of content of one of the polymers in this Chapter. A physical network of two polymers with different functional groups leads to multiple interesting consequences. The polymer physical network characteristics determine all physical properties including electrochemical property of the ionic liquid integrated PN based GPE. The conductivities of the proposed gel are nearly an order in magnitude higher than the unconfined ionic liquid electrolyte and displays good dimensional stability and electrochemical performance in a separator-free battery configuration. The ac-impedance spectroscopy, steady shear viscosity measurement, dynamic rheology are employed to study physical properties of the proposed gel polymer electrolyte. Chapter 2B discusses the detailed investigations of the ion transport mechanism of the gel polymer electrolyte, as discussed in Chapter 2A. Ion conduction mechanism is investigated in the light of ion diffusion and solvent dynamics of the entrapped ionic liquid inside the polymer. The studies reveal a heavy influence of network characteristics on the ion conduction mechanism. The influence of solvent dynamics on the ion transport is drastically altered by polymer physical network. Consequently, a drastic change in the ion mobility and nature of predominant charge carrier is observed in the polymer physical network based gel electrolyte. A clear transformation from dual ion conductivity to a predominantly anion conductivity is observed on going from single polymer to a dual polymer network. The spectroscopic tools such as pulsed field gradient nuclear magnetic resonance (PFG–NMR), Brillouin light scattering spectroscopy, ac-impedance spectroscopy, FT-Raman and FTIR spectroscopy were used to elucidate the ion transport mechanism in the Chapter. Chapter 3 demonstrates a simple design strategy of gel polymer electrolyte comprising of a lithium salt (lithium bis(trifluoromethanesulfonyl) imide, LiTFSI) solvated by two plastic crystalline solvents, one a solid (succinonitrile, abbreviated as SN) and another a (room temperature) ionic liquid (1-butyl-1-methyl-pyrrolidinium bis(trifluoromethane sulfonyl) imide, (abbreviated as IL) confined inside a linear network of poly(methyl methacrylate) (PMMA). The concentration of the IL component determines the physical properties of the unconfined electrolyte and when confined inside the polymer network in gel polymer electrolyte. Intrinsic dynamics of one plastic crystal influences the conduction mechanism of gel polymer electrolytes. The enhanced disordering in the plastic phase of succinonitrile by IL doping alters both the local ion environment and viscosity. The proposed plastic crystal electrolytes show predominantly anion conduction (tTFSI ≈ 0.5) however, lithium transference number (tLi ≈ 0.2) is nearly an order higher than the ionic liquid electrolyte (IL-LiTFSI) (tLi ≈ 0.02-0.06), discussed in Chapter 2. The gel polymer electrolyte displayed high mechanical compliability, stable Li-electrode | electrolyte interface, low rate of Al corrosion and stable cyclability. The promising electrochemical performance further justifies simple strategy of employing mixed physical state plasticizers to tune the physical properties of polymer electrolytes requisite for application in rechargeable batteries. Chapter 4A proposes a novel liquid dendrimer–based single ion conducting liquid electrolyte as potential alternative to conventional molecular liquid solvent–salt solutions and conventional solid polymer electrolytes for rechargeable batteries, sensors and actuators. The physical properties are investigated as a function of peripheral functionalities in the first generation poly(propyl ether imine) (G1-PETIM)–lithium salt complexes. The change in peripheral group simultaneously affects the effective physical properties viz. viscosity, ionic conductivity, ion diffusion coefficients, transference numbers and also the electrochemical response. The specific change from ester (–COOR) to cyano (–CN) terminated peripheral group resulted in a remarkable switch over from a high cation (tLi+ = 0.9 for –COOR) to a high anion (tPF6- = 0.8 for –CN) transference number. Chapter 4B presents an analysis of the frequency dependent ionic conductivity of single ion dendrimer conductors by using time temperature scaling principles (TTSPs) and dielectric modeling of the electrode polarization. The TTSP provides information on the salt dissociation and number density of mobile charges and hence provides direct insights into the ion conduction mechanism. Summerfield and Baranovskii–Cordes scaling laws, which are well known TTSPs, have been applied to analyze the ion conductivity. The electrode polarization, which quantifies the number density of mobile charges and ionic mobility, is studied using Macdonald-Coelho model of electrode polarization. The combination of these two theoretical investigations of the experimental data emanating from one technique i.e. ac– impedance spectroscopy, predicts independently the contributions of the effect of mobile ion charges and ionic mobility to ion conduction mechanism. In Chapter 5 focus shifts from polymer ion conductors to polymer mixed ion-electron conductor. The polymer mixed ion-electron conductor is demonstrated as a novel electrode material for Li-S battery. A simple strategy to overcome the challenges towards practical realization of a stable high performance Li–S battery is discussed. A soft mixed conducting polymeric network is utilized to configure sulphur nanoparticle. The soft matter network provides efficient and distinct pathways for lithium and electron conduction simultaneously. A lithiated polyethylene glycol (PEG) based surfactant tethered on ultra-small sulphur nanoparticles and wrapped up with polyaniline (PAni) (abbreviated as S-MIEC) is demonstrated here as an exceptional cathode for Li–S batteries. The S-MIEC is characterized by several methods: powder-X-ray diffraction (PXRD), thermo gravimetric analysis (TGA), fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), ac-impedance spectroscopy and dc current-voltage measurements are performed to evaluate conductivity of S-MIEC cathode. Electrochemical studies such as cyclic voltammetry, galvanostatic charge-discharge cycling, galvanostatic intermittent titration (GITT) are performed to demonstrate feasibility of S-MIEC in the Li–S battery performance. Chapter 6 provides a brief summary of the work carried out as part of this thesis and also demonstrates the future perspective of the present work. Potential of the polymer physical network based gel polymer electrolytes, which are discussed in Chapter 2A-B for lithium-ion batteries, are demonstrated in Li-S battery. The proposed polymer physical network confines higher order lithium polysulfides (typically Li2S8) dissolved in tetraethylene glycol dimethyl ether (TEGDME) based electrolyte (TEGDME-1M LiTFSI). The three dimensional polymer network is proposed to be formed by physical blending of the poly(acrylonitrile) (PAN) with the copolymer of AN and poly(ethylene glycol) methyl ether methacrylate (PEGMA), [ P(AN–co–PEGMA)]. We extend here the similar synthetic approaches as described in Chapter 2A. The approach proposed and demonstrated in this concluding Chapter is expected to mitigate some of the major issues of Li-S chemistry. The proposed Li2S8 confined gel electrolyte exhibits moderately high values of ionic conductivity, 2 × 10-3 Ω-1cm-1 and shows a stable capacity of 350 mAhg-1 over 30 days in a separator free Li-S battery.