This diploma thesis deals with problematics of electrochemical power sources with focus on lithium accumulators, their construction and functioning priciple. It also discusses the safety of li-ion batteries with respect to their flammability. In addition, the flame retarders, which help to lower the flammability, are listed. The thesis describes Cyclic Voltammetry and Galvanostatic Cycling with Potencial which are lithium-ion cell measuring methods. In the last part, the influence of various flame retarders on negative electrode is compared based on the conducted tests.

Object my master’s thesis is the design a Medical device uninterruptible power supply with managment system utilizing I2C bus. Norm EN 61000-3-2 define electric parameters for medical device power supply. In case of power supply for medial equipment is expressive accent on increased electric strength. This power supply have usually primary and secondary power circuit. Primary power circuit form line accumulator, which supplies needed output to the load and recharge reserve battery. Secondary is formed battery-pack, which serve as back-up power supply at drop-out prime circle. They have a minimum weight, small proportions, large overall effectivity also charging battery-pack and monitoring battery-pack charging condition. Result whole those master’s thesis is design Medical device uninterruptible power supply with managment system utilizing I2C bus and realization board layout. Resulting characteristics designed supply unit are: Output voltages are 5V/ 3 A , 12V/ 1,5 A and -12V/ 0,1 A. Managment support information about: Line adapter/ battery pack switch, battery-pack charging condition and actuall tempera-ture battery-pack.

This project deals with design and study wireless security device. This device works in ISM band, created by two modules handling secure subject. Microprocessor AVR from company Atmel provides communication between these modules.

This article deals with properties of cathode material of lithium-ion cells study in term of active layer dependence. Aim of the work is to get familiar with problematics of cathode material production and diagnostics and to compare different active layer production methods. The opening of the work is concentrating on rechargeable batteries, mainly lithium-ion batteries and their electrode materials. Practical part is describing method of cathode material production and its characteristics.

Le développement des énergies renouvelables, telles que le solaire photovoltaïque ou l’éolien, est fortement conditionné par la nature intermittente de ces sources d’énergie. Cette intermittence se traduit par un décalage entre pics de production et de consommation. Le stockage de l’énergie électrique revêt donc un caractère primordial dans la gestion de ce décalage. Pour accomplir cette tâche, la technologie lithium-ion est une bonne candidate parmi les technologies de stockage électrochimique de l’énergie. Mais les applications visées exigent des durées de vie bien supérieures à celles requises pour l’électronique portable ou pour les véhicules électriques. En effet les performances des batteries, notamment en termes de capacité, doivent être préservées pendant des durées de 15 à 20 ans. Cette thèse a alors pour but l’étude des mécanismes de vieillissement à long terme d’accumulateurs Li-ion composés d’oxydes lamellaires Li(NixMnyCo1 x y)O2 à l’électrode positive et de graphite à l’électrode négative, en se focalisant sur les interfaces électrode/électrolyte qui sont le lieu privilégié des mécanismes de vieillissement. Ce travail a été réalisé à l'aide de la spectroscopie photoélectronique à rayonnement X (XPS) et de la spectroscopie d’impédance électrochimique (EIS), deux techniques complémentaires particulièrement bien adaptées à l’étude des interfaces, l'une permettant de sonder les environnements chimiques en extrême surface, l'autre donnant la réponse d’un système à une sollicitation électrique sinusoïdale de fréquence variable. La contrainte importante induite par les durées de vie visées (20 ans) ont conduit à simuler le vieillissement à long terme des batteries en leur faisant subir des sollicitations électrochimiques beaucoup plus importantes que lors d’une utilisation normale Les caractérisations par XPS et EIS ont été systématiquement mises en relation avec l’évolution des performances électrochimiques des batteries considérées. Cette étude a permis d'apporter des améliorations aux batteries pour apporter une meilleure réponse à ces phénomènes de vieillissement en termes de maintien des performances: modification de la formulation des électrodes, des électrolytes, de la nature des matériaux actifs, etc. / Development of renewable energy sources such as photovoltaic or wind energy is limited by the intermittent nature of these energy sources. This intermittent nature results in the mismatch between production and consumption peaks. As a result, the storage of electrical energy plays an essential role to manage this mismatch. To this aim, lithium-ion technology appears as a good candidate among other ways of electrochemical storage of energy. However the targeted applications require much greater life span than those commonly admitted for portable electronics or electric vehicles. Battery performances, e.g. rechargeable capacity, should be preserved over 15 or 20 years. This PhD thesis aims at studying the long-term aging mechanisms of Li-ion batteries made up of lamellar oxides Li(NixMnyCo1 x y)O2 at the positive electrode and graphite at the negative electrode. We focused on the electrode/electrolyte interfaces which are the major place of aging processes. The work has been performed by X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS), two complementary techniques especially adapted to the study of interfaces, the former giving access to the chemical environments of atoms at the surface, the latter giving the answer of a system to a sinusoidal electric current with various frequencies. An important technical constraint was the difference between the targeted life span for the application (20 years) and the duration of the thesis (3 years). In order to simulate long-term aging the batteries were submitted to electrochemical stress in much harder conditions than in normal use. XPS and EIS characterizations were constantly related to evolution of electrochemical performances of batteries. This study allowed us during the duration of the project to bring improvements to batteries in order to obtain a better response to aging mechanisms regarding retention of electrochemical performances: e.g. change of electrodes or electrolyte formulation, change of active materials composition, etc.

Li-ion batteries have demonstrated to be a very flexible source with energystorage capability. Due to their scalability and wide range of power and energydensities, they are suitable for several applications. Li-ion storage cantherefore provide different services, the remuneration of which depends onthe electricity market of the country. In this work, two different case studiesof combination of Li-ion batteries with large-scale renewable power plantshave been investigated: batteries with solar PV in India and with wind powerin Sweden. Simulation models have been developed to assess the operationand profitability potential of different services in these two case studies. Themodels have been built using control algorithms, linear optimization (LP) andstochastic programming techniques. The results show that the use of batteriesfor solar power output smoothing under a power purchase agreement canbe a profitable business case in India. Moreover, batteries providing primaryfrequency regulation (FCR-N) in Sweden show to have a positive economicvalue. System breakeven costs to make the stacking of wind power productionimbalance compensation and FCR-N services profitable have been found,which based on conservative price expectations should be achieved by 2022. / Li-ion batterier har visat sig vara en mycket effektiv källa för lagring av energi.Tack vare deras skalbarhet och det breda utbudet av kraft och energidensiteterhar de flera användningsområden. Li-ion batterier kan därför användas föratt tillhandahålla olika typer av tjänster vars ekonomiska ersättning beror avlandets elmarknad. Detta arbete undersöker två fallstudier av Li-ion batterieri kombination med storskaliga kraftverk som drivs av förnybara energikällor:batterier i kombination med solkraft i Indien och vindkraft i Sverige. Simuleringsmodellerhar utvecklats för att undersöka driften och lönsamhetspotentialenför olika tjänster i de två fallstudierna. Modellerna baserar sig påkontrollalgoritmer, linjär optimering och stokastisk programmeringsteknik.Resultaten visar att användningen av batterier för utjämning av solenergi enligtett kraftköpavtal kan vara lönsamma i Indien. Dessutom har användningenav batterier för primärreglering (FCR-N) visat sig ha ett positivt ekonomisktvärde i Sverige. Breakeven kostnaderna för att göra kombinationen av vindkraftsproduktionensbalanskompensering och FCR-N tjänster lönsamma harhittats, vilket ska uppnås senast år 2022 baserat på en konservativ prisprognos.

If you buy a new electric car today it will take on average about ten years for you to start saving money compared to just continue driving your old gasoline car. It will also take about 4 years until you start saving carbon dioxide emissions, both of this is because of new production costs and emissions. As the EU has banned producing new fossil fuel cars from 2035, it’s just a question of time before the power train in our cars will be electric. This rapid transition will lead to the older generation gasoline cars left by the road, with still usable chassis. This calls for a solution that uses this chassis but swaps out its power train for an electric one, reducing the initial cost and emission to drive electric. But is it that easy? In this mission, we take that technical question into our hands and convert a Swedish classic Volvo 340 from 1979 and give it an electric power train from 2022. We provide a detailed theory about the technology, a guide in choosing the right components, and the legal build requirements to pass the inspection. The conversion is done in an ordinary garage with standard tools and a welder. Using a small power-train with a maximum power of 30kW (40hp) and a battery size of 20kWh gave us a car with a maximum speed of 110km/h and a range of 150km. The project costed a total of 60 000 kronor, including the registration process. The technical legality and registration process went smoothly thanks to the Organisation SFRO (Sveriges fordonsbyggares riksorganisation) which takes care of the technical inspection and handles the paperwork. After one year and 10 000 km of driving and collecting data, we estimate that transitioning from gasoline to electric via a conversion compared to a new electric car reduces the economical investment return time from 10 to 2 years. And saves 8 tons of CO2. The battery used is secondhand. The second-hand market of electric car batteries, mostly from crashed or defective cars is growing and is estimated to be enough to convert the majority of old gasoline cars that are in good condition. The life length of second hand batteries in conversion is estimated to be equal to the rest of the chassis, due to the lower power requirements in conversion builds. We see that this idea has potential on a larger scale due to satisfying the criteria: Enough low complexity to do a conversion (if using common car models), lower cost and CO2 emissions then other options, supply for batteries exists, donor cars exist with chassis in good condition, market size is big enough and it’s legal to modify your car in Sweden and a few other countries. / Det är bara en tidsfråga innan drivlinan i våra bilar kommer att vara elektrisk, eftersom EU har lagt ett förbud mot att producera nya fossilbränslebilar från 2035. Men det är inte det enda trycket på förändring eftersom även bensinpriserna fortsätter att öka. En mycket hög efterfrågan förväntas på elbilar. Men för de flesta är det inte ett ekonomiskt alternativ att köpa en ny elbil, även om användandet är billigare tar det cirka 10 år innan du börjar se besparingar. Även produktionen av nya elbilar släpper ut koldioxid, motsvarande cirka 4 års körning av en bensinbil. Den snabba övergången kommer också att leda till att den äldre generationens bensinbilar skrotas, med fortfarande användbara chassi. Detta kallar på en lösning som använder dessa chassin men byter ut sin drivlinan till en elektrisk, vilket minskar den initiala kostnaden för att köra elbil samtidigt som man sparar in utsläppen från en ny produktion. Men är det verkligen så lätt? Vi tar vi frågan i våra händer och konverterar en svensk klassiker, en Volvo 340 från 1979 och ger den en drivlina från 2022. Vi ger en detaljerad teori om tekniken, en guide för att välja rätt komponenter och lagliga byggkrav för att klara besiktningen. Konverteringen görs i ett vanligt garage med standardverktyg och en svets. Ett år och tusen mil senare av körning och insamling av data uppskattar vi att en övergång från bensin till el via en konvertering jämfört med en ny elbil minskar den ekonomiska avkastningstiden för investeringen från 10 till 2 år. Och sparar 8 ton koldioxid. Batteriet som används är begagnat. Andrahandsmarknaden för elbilsbatterier, främst från kraschade eller defekta bilar, växer och beräknas räcka för att konvertera majoriteten av gamla bensinbilar som är i gott skick. Livslängden för begagnade batterier vid konvertering uppskattas vara lika med resten av chassit, på grund av de lägre effektkraven i konverteringsbyggen. Vi ser att denna lösning har potential i det större perspektivet, främst igenom utbudet och livslängd av batterier och chassin för konverteringar. Men också att kostnaden och kompexiteten är tillräkligt låg om de vanligaste modellerna används. Denna lösning är just nu bara tillgänglig i sverige och ett fåtal andra länder där det är lagigt att modifiera sina bilar.

In response to the ever-increasing threat of the negative impacts of climate change, there has been a renewed international focus on the integration of renewable energy to meet their demands. One such project is located at Tezpur University in the state of Assam, India. In this project, a large PV project of 1 MWp capacity was installed in 2018, followed by a 91 kWh Li-ion battery system in 2020. While the system has been installed, an optimal operational algorithm (OA) is needed for the system to operate and meet the needs of the connected load. This thesis will consider several OAs for the battery system. The charging schedule for the system will be optimised based on data for the substation system. First, data from the electrical load and power outages with a time resolution of one minute were considered. Upon analysis of this data, an initial algorithm was proposed and its effectiveness was evaluated based on selected key performance indicators (KPIs). Next, a linear programming approach was used to optimise the battery charging schedule based on electricity cost, PV power production, and electric load. Based on the results of the optimisation, input from the proprietors of the energy management system, and results from the initial algorithm, a second advanced algorithm was created and its effectiveness was again evaluated based on the same KPIs. It was found that the two main goals within this project, initiating appropriate charging times to limit grid power usage while also maintaining sufficient energy reserves whenever a power outage occurs. While diesel usage cannot be completely eliminated, it can be greatly reduced for shorter power outages. Additionally, a high degree of load autonomy can be achieved before the diesel generator becomes necessary to activate. / Som svar på det ständigt ökande hotet om klimatförändringens negativa effekter har det skett en förnyad internationell fokus på integrering av förnybar energi för att tillgodose deras behov. Ett sådant projekt finns på Tezpur University i delstaten Assam i Indien. Under detta projekt installerades ett stort solcellsprojekt med en kapacitet på 1 MWp under 2018, med följt av ett 91 kWh Li-ion-batterisystem under 2020. Medan systemet har installerats behövdes en optimal driftalgoritm för att systemet skulle kunna fungera och uppfylla behoven hos den anslutna lasten. I den här avhandlingen kommer flera driftalgoritmer för batterisystemet att diskuteras. Laddningsschemat för systemet kommer att optimeras utifrån data för understationssystemet. Först beaktades data från den elektriska belastningen med en minutupplösning och frekvensen av strömavbrott. Efter analys av dessa data samt föreslogs en första algoritm och dess effektivitet utvärderades utifrån utvalda nyckelindikatorer för prestanda. Därefter användes en metod för multivariabel linjär programmering för att optimera schemat för batteriladdning baserat på elkostnad, produktion av solcellseffekt och elektrisk belastning. På grundval av resultaten av optimeringen, input från ägarna till energihanteringssystemet och resultaten från den ursprungliga algoritmen skapades en andra avancerad algoritm och dess effektivitet utvärderades återigen utifrån samma nyckelindikatorer. Det visade sig att de två huvudmålen inom detta projekt, att initiera lämpliga laddningstider för att begränsa elanvändningen och samtidigt upprätthålla tillräckliga energireserver när ett strömavbrott inträffar. Dieselanvändningen kan inte helt elimineras, men den kan minskas avsevärt vid kortare strömavbrott. Dessutom kan en hög grad av lastautonomi uppnås innan dieselgeneratorn måste aktiveras.

Die Röntgenabsorptionsspektroskopie (XAS) ist eine element-spezifische Charakterisierungs-methode, welche es erlaubt die elektronische und chemische Struktur der SEI zu untersuchen. In dieser Arbeit stelle ich ein neues Verfahren vor, das die Transmissions-XAS von Flüssigkeiten und Dünnschicht-Batterieelektroden unter in-situ Bedingungen mit weicher Röntgenstrahlung ermöglicht. Thematisch ist die Arbeit in zwei Teile gegliedert. Das neuartige Verfahren wird zunächst umfangreich vorgestellt und dann zur Untersuchung der Solid Electrolyte Interphase (SEI) auf Silizium angewendet. Das Verfahren basiert auf einer elektrochemischen Halbzelle, die mit einem Stapel aus zwei Siliziumnitrid-Membranfenster ausgestattet ist, um den Elektrolyten einzuschließen. Eines der Membranfenster ist gleichzeitig der Träger für die Dünnschicht-Siliziumanode, die Ladezyklen mit einer Kathode aus metallischem Lithium durchläuft. Nachdem sich die SEI gebildet hat, wird mittels eines Röntgenstrahls von hoher Intensität vorsätzlich eine Blase erzeugt, um überschüssigen Elektrolyten abzudrängen und einen dünnen Elektrolytfilm über der SEI zu stabilisieren. Durch den Elektrolytfilm bleibt die SEI in-situ. Das erzeugte System aus Blase, Elektrolytfilm, SEI und Siliziumanode wird dann mittels Transmissions-XAS untersucht. Im zweiten Teil meiner Arbeit werden dann Silizium Dünnschicht-Anoden mit dem vorgestellten Verfahren am Elektronenspeicherring BESSY II in Berlin untersucht. Bei der elektrochemischen Charakterisierung zeigen die Dünnschicht-anoden alle für die De-/Lithiierung von Silizium üblichen Merkmale. Als Hauptbestandteile der SEI wurden Lithiumacetat, Li Ethylendicarbonat oder -monocarbonat, Li Acetylacetonat, LiOH und LiF ermittelt. Darüber hinaus deuten Anzeichen von Aldehyden auf flüssige Einschlüsse in einer möglich-erweise porösen SEI Struktur hin. / X-ray Absorption Spectroscopy (XAS) is an element-specific technique, which allows to probe the electronic and chemical structure of the SEI. In this work, I introduce a novel approach for transmission XAS on liquids and thin-film battery electrode materials under in-situ conditions in the soft X-ray regime. Thematically, this work is divided into two parts: 1) the introduction of this novel method and 2) its application to investigate the Solid Electrolyte Interphase (SEI) on silicon thin film anodes. The presented technique is based on an electrochemical half-cell equipped with a sandwich of two silicon nitride membrane windows to encapsulate the electrolyte. One of the membranes acts as substrate for the silicon thin-film anode, which is cycled with a metallic lithium counter-electrode. After the SEI has formed, a gas bubble is intentionally introduced through radiolysis by a high intensity X-ray to push out excessive electrolyte and stabilize a thin electrolyte layer on top of the SEI, keeping it in-situ. The obtained stack comprised of bubble, electrolyte thin-layer, SEI and anode, is then probed with transmission XAS. The second part of this work utilizes the presented method to investigate the SEI on amorphous silicon anodes at the BESSY II synchrotron facility in Berlin. The anodes’ electrochemical characterization shows all significant features of silicon’s de-/lithiation. The SEI’s main components are determined as Li acetate, Li ethylene di-carbonate or Li ethylene mono-carbonate, Li acetylacetonate, LiOH, and LiF. Additionally, the evidence for aldehyde species indicates possible liquid inclusions within a presumably porous SEI morphology.

Lithium alloys with metallic or semi-metallic elements are attractive candidate materials for the next-generation rechargeable Li-ion battery anodes, thanks to their large specific and volumetric capacities. The key challenge, however, has been the large volume changes, and the associated stress buildup and failure during cycling. The chemo-mechanics of alloy-based electrode materials entail interactions among diffusion, chemical reactions, plastic flow, and material property evolutions. In this study, a continuum theory of two-way coupling between diffusion and deformation is formulated and numerically implemented. Analyses based on this framework reveal three major conclusions. First, the stress-to-diffusion coupling in Li/Si is much stronger than what has been known in other electrode materials. Practically, since the beneficial effect of stress-enhanced diffusion is more pronounced at intermediate or higher concentrations, lower charging rates should be used during the initial stages of charging. Second, when plastic deformation and lithiation-induced softening take place, the effect of stress-enhanced diffusion is neutralized. Because the mechanical driving forces tend to retard diffusion when constraints are strong, even in terms of operational charging rate alone, Li/Si nano-particles are superior to Li/Si thin films or bulk materials. Third, the diffusion of the host atoms can lead to significant stress relaxation even when the stress levels are below the yield threshold of the material, a beneficial effect that can be leveraged to reduce stresses because the host diffusivity in Li/Si can be non-negligible at higher Li concentrations. A theory of coupled chemo-mechanical fracture driving forces is formulated in order to capture the effect of deformation-diffusion coupling and lithiation-induced softening on fracture. It is shown that under tensile loading, Li accumulates in front of crack tips, leading to an anti-shielding effect on the energy release rate. For a pre-cracked Li/Si thin-film electrode, it is found that the driving force for fracture is significantly lower when the electrode is operated at higher Li concentrations -- a result of more effective stress relaxation via global yielding. The results indicate that operation at higher concentrations is an effective means to minimize failure of thin-film Li/Si alloy electrodes.