Department of Advanced Nursing Science / MCur

MENVSC / Department of Hydrology and Water Resources / ABSTRACT Siloam and Tshipise Springs are scalding geothermal springs geologically located within the Soutpansberg Group in the Limpopo Province of South Africa. These geothermal springs are associated with faults and impermeable dykes and are assumed to be of meteoric origin. The optimal use of a geothermal spring largely depends upon its physical and chemical properties as well as the geological controls at source and surrounding pathway to the surface. This study aimed at investigating trace element concentrations in these geothermal springs in order to quantify their impacts on neighbouring soil and vegetation. Impact on vegetation was assessed by incorporating seasonal variations of the trace element mobility from the geothermal springs to the vegetation (Mangifera indica at Siloam and Acacia robusta at Tshipise) via soil. The geothermal spring water, soil and vegetation samples at both sites were collected from May – July (winter) and September – November (summer), 2014. The soil samples were collected at 5 m intervals up to 20 m away from the geothermal spring in each of the sites. The bark and leaf parts of the vegetation were sampled. The control samples for water, soil and vegetation were obtained from Riverside residence at University of Venda, Thohoyandou, Limpopo Province, where there is non-geothermal source of water. The temperature, electrical conductivity (EC), pH and total dissolved solid (TDS) of the geothermal spring water and control samples were determined in situ and in the laboratory. The water samples were acidified for major cations and trace elements determination. There were also non-acidified water samples for major anion analyses. The soil and vegetation samples were digested using microwave and hot block methods, respectively. Concentrations of arsenic (As), antimony (Sb), barium (Ba), beryllium (Be), boron (B), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), mercury (Hg), lanthanum (La), lead (Pb), lithium (Li), manganese (Mn), molybdenum (Mo), nickel (Ni), selenium (Se), tin (Sn), strontium (Sr), tellurium (Te), thallium (Tl), titanium (Ti), tungsten (W), vanadium (V), and zinc (Zn) were determined by inductively coupled plasma – mass spectrometry (ICP-MS) (Agilent 7700 series). Concentrations of calcium (Ca), magnesium (Mg), sodium (Na) and potassium (K) were analysed using inductively coupled plasma – optical emission spectrometry (ICP-OES) (X – Series 2) whereas the concentrations of chloride (Cl-), fluoride (F-), nitrate (NO3-), phosphate (PO42-), bicarbonate (HCO3-) and sulphate (SO42-) were determined by ion chromatography (IC) (Dionex Model DX 500). Results from this study revealed that the geothermal springs were rich in trace elements compared to that from non-geothermal source of water. The mineral elements present were vii mainly due to rock-water interaction in the deep aquifer at both sites. The geothermal spring water is not fit for drinking because it is particularly high in fluoride (F) having 6.66 and 5.97 mg/L at Siloam ; 6.72 and 7.28 mg/L at Tshipise for winter and summer, respectively. Also, high Nickel (Ni) with 462 µg/L and 868 µg/L: Lead (Pb) with 652 µg/L and 211 µg/L at Siloam and Tshipise respectively, for summer season. In addition, it is not suitable for irrigation owing to high sodium absorption ratio (SAR) values which were above the standard guidelines (˂1) by South African Bureau of Standards (SABS) and World Health Organization (WHO) at both sites. In summer season, there were higher trace elements concentrations than in the winter season. The higher concentration values could be attributed to rainfall, which aids in the dissociation of rock particles, resulting in higher concentrations of these elements. Siloam spring water was more mineralised than Tshipise spring water, hence its neighbouring soils and vegetation possess more trace elements concentrations than the latter. Owing to their high mineral elements content, the geothermal spring water flows across the soil, making it vulnerable to sorption of the trace elements. The trace elements present in the surrounding soil of the geothermal spring were as a result of geothermal water and soil pedogenesis. The geothermal water contaminates the surrounding soil with substantial quantity of trace elements, which decreases with the distance from the geothermal spring, making far distanced soil less-contaminated. High levels of Cr, Co, Ni, Cu, Zn and Pb at Siloam soil can be attributed to more minerals present in the spring, therefore making absorption by Mangifera indica inevitable. Soils at Tshipise are moderately concentrated owing to moderate trace elements concentrations from the geothermal spring water. Generally, seasonal variations were observed in the parameters analysed in the geothermal spring water, surrounding soil and vegetation to ascertain the most favourable season in terms of the trace elements concentrations. There were higher concentrations of trace elements in the geothermal spring, particularly during the summer season, compared to the winter season; this leads to more contamination of the surrounding soils and vegetation. This study showed that geothermal spring has potential to enrich the neighbouring soils and vegetation with trace elements, which could result in contamination. It can be concluded that geothermal spring, despite its benefits to humans, also contaminates the surrounding surface soils with toxic trace elements. Soils are a platform for vegetation. Therefore, if the soil is contaminated by toxic elements, there are high possibilities that these trace elements are absorbed by the neighbouring vegetation, which is likely to affect human beings adversely.

Department of Ecology and Resource Management / MENVSC

MSCAGR (Animal Science) / Department of Animal Science / The objective of the study was to determine the effects of fertilisation with bio-digester slurry and the inclusion of carbohydrate additives at ensiling on the fermentation characteristics, chemical composition, ruminal degradability, and in vitro digestibility of Napier grass silage. Napier grass planted at the School of Agriculture Experimental Farm, University of Venda in 5 m x 4 m plots replicated three times in a completely randomised design and was irrigated with either biodigester slurry or no bio-digester slurry (tap water) for a period of 12 weeks. After 12 weeks, the Napier was freshly cut and ensiled for 90 days in 1 litre glass jars in a 2 (Control - tap water and slurry irrigation) x 4 (No additive, molasses, maize meal and brown sugar) factorial arrangement. Fermentation quality and nutritive composition were determined using standard protocols. The dry matter (DM) and crude protein (CP) ruminal degradability was determined in sacco by incubating feed samples in nylon bags (external dimension: 6 × 12 cm, pore size of 46 μm) in the rumen in three Bonsmara steers fitted with rumen cannulae for 0, 6, 12, 24, 48, 72, 96 and 120 hours (h). Parameters to describe the dynamics of ruminal degradability of DM and CP were obtained by fitting the data on the exponential equation P = a + b (1 - e-ct) using the NEWAY computer program, where “a” is the rapidly degradable fraction, “b” is the slowly degradable fraction and “c” is the outflow rate. The in vitro DM and CP degradability of rumen undegradable residue collected after 12, 24 and 48 h incubation was determined by sequential digestion in pepsin (abomasal) and pancreatin (small intestine) solutions. Fertilisation with bio-digester slurry increased (P <0.05) CP content of fresh cut Napier grass pre-ensilage. Bio-digester slurry fertilisation with molasses inclusion improved (P <0.05) the silage DM content which improved (P >0.05) fermentation characteristics with pH of 4.2 and lowest NH3-N of 13.3 g/kg. Other chemical compositions and fermentation characteristics were not affected (P >0.05) due to fertilisation x additives treatment combinations. No bio-digester slurry fertilisation with maize meal inclusion increased (P <0.01) DM degradability at 0 h incubation. As time progressed to 24 h, no biodigester slurry fertilisation with no additive included reduced (P <0.01) DM degradability with no difference (P >0.05) on other treatments. Potential DM degradability (a + b) of no bio-digester slurry fertilisation with no additive inclusion silage was reduced (P <0.01). The reduction was associated with low levels (P <0.01) of slowly degradable fraction “b”. In vitro DM and CP digestibility were not affected (P >0.05) due to fertilisation x additives treatment combinations. In conclusion, bio-digester slurry application improved the quality of fresh cut Napier grass, with the combination of bio-digester slurry fertilisation and molasses addition yielding the best silage quality.

MA (Youth in Development) / Institute for Gender and Youth Studies / This research was conducted in the Thohoyandou Correctional Centre within the Female/Juvenile place found in the Thulamela Municipality in the Vhembe District. It is approximately 200km to the north of Limpopo Provincial capital of Polokwane. It focuses on finding out factors that influence offenders to re-offend again, investigate recidivism among youth offenders and identify some of the problems relating to recidivism. The research consisted of juvenile offenders incarcerated in the Thohoyandou Correctional Centre within the juvenile area. Both groups of sentenced male and female juveniles participated in the study. The research used non-probability sampling. Purposive sampling was used to gather information within the Thohoyandou Correctional Centre. The research used interviews and focus group interviews as methods of collecting data. The interviews were conducted using English and Tshivenda then the responses were translated from Tshivenda to English. The researcher interviewed young offenders who have offended and re-offended. The researcher used grounded theory as a method to analyse data. This method helped the researcher to generate theory from the data collected

MSc (Microbiology) / Department of Microbiology / See the attached abstract below

MCom / Department of Business Management / See the attached abstract below

MESHWR / See the attached abstract below

MEd (Educational Management) / Department of Educational Management / The aim of the study was to investigate challenges confronting SMT members in the implementation of school-based moderation of Mathematics assessment tasks. An in-depth study of literature was undertaken, taking into consideration the following research question: What are the challenges confronting SMT members in the implementation of school-based moderation of Mathematics assessment tasks in the Thohoyandou cluster of the Limpopo Province? The study used the qualitative and quantitative approaches. Purposive sampling was used in the selection of participants for the qualitative data and simple random sampling was used in the selection of participants for the quatitative data. Qualitative data was collected through the interviews and quantitative data was collected through questionnaires. The interview schedule was employed to collect qualitative data and 12 participants (8 SMT members and 4 curriculum advisors for Mathematics in the Thohoyandou cluster) were interviewed. Questionnaires were used to collect quantitative data and were completed by 75 Mathematics teachers. Qualitative data was analysed thematically and quantitative data was analysed through SPSS version 23. The study revealed that: Lack of understanding and knowledge of the process of school-based moderation of mathematics is a serious worm that needs to be addressed soon. Moderation of school-based assessment was not monitored appropriately. The study recommended that the Department of Basic Education should conduct workshops and train SMT members on the importance of school-based moderation to ensure quality teaching and learning of Mathematics.

MESHWR / Department of Hydrology and Water Resources / This study dealt with the influence of climate variability on flood and drought cycles and implications on rainy season characteristics in Luvuvhu River Catchment (LRC) in Limpopo of South Africa. Extreme weather events resulting in hazards such as floods and droughts are becoming more frequent due to climate change. Extreme events affect rainy season characteristics and hence have an influence on water availability and agricultural production. Annual temperature was obtained from Water Research Commission for stations 0723485W, 0766628W and 0766898W from 1950-2013 were used to show/or confirm if there is climate variability in LRC. Daily rainfall data was obtained from SAWS for stations 0766596 9, 0766563 1, 0723485 6 and 0766715 5 were used to detect climate variability and determine the onset, duration and cessation of the rainy season. Streamflow data obtained from the Department of Water and Sanitation for stations A9H004, A9H012, and A9H001 for at least a period of 30 years for each station were used for climate variability detection and determination of flood and drought cycles. Influence of climate variability on floods and droughts and rainy season characteristic were determined in the area of study. Trends were evaluated for temperature, rainfall and streamflow data in the area of study using Mann Kendall (MK) and linear regression (LR) methods. MK and LR detected positive trends for temperature (maximum and minimum) and streamflow stations. MK and LR results of rainfall stations showed increasing trends for stations 0766596 9, and 0766563 1 whereas stations 0723485 6 and 0766715 5 showed decreasing trends. Standardized precipitation index (SPI) was used to determine floods and droughts cycles. SPI results have been classified either as moderately, severely and extremely dry or, moderately, very and extremely wet. This SPI analysis provides more details of dominance of distinctive dry or wet conditions for a rainy season at a particular station. Mean onset of rainfall varied from day 255 to 297, with 0766715 5 showing the earliest onset compared to the rest of the stations. Cessation of rainfall for most of the hydrological years was higher than the mean days of 88, 83 and 86 days in 0766596 9, 0766563 1 and 0723485 6 stations. Mean duration of rainfall varied from 102 to 128, with station 0766715 5 showing shortest duration of rainfall. The results of the study showed that the mean onset, duration and cessation were comparable for all stations except 0766715 5 which had lower values. The study also found that climate variability greatly affects onset, duration and cessation of rainfall during dry years. This led to late onset, early cessation and relatively short duration of the rainfall season. Communities within the catchment must be educated to practice activities such as conservation of indigenous plants, reduce carbon dioxide emissions.