Die vorliegende Arbeit beschreibt eine experimentelle Untersuchung der Schichtbildung von nichtnewtonschen Flüssigkeiten im Tiefdruckverfahren auf nicht saugfähigen Substraten. Das fluiddynamisch bedingte „viscous fingering“ beim Farbspaltungsprozess soll mittels Hydrophobieren der Druckform gehemmt werden. Ziel ist es, möglichst homogene sowie wellenfreie Schichten zu erzeugen. Um ein direkt miteinander vergleichbares Druckergebnis zu erhalten, wird der Druckstoff parallel mit einer unbehandelten und hydrophobierten Form bedruckt. Als Druckstoff werden anstelle von Druckfarbe funktionale Materialien (vorzugsweise PEDOT:PSS) verwendet und variiert, wobei die elektrischen und geometrischen Schichteigenschaften, beispielsweise der elektrische Widerstand und die Rauheit, zur Ermittlung der gesetzten Ziele untersucht wurden. Hiermit und mittels Nutzung einer hydrophobierten Druckform kann eine deutliche Minderung der Wellenbildung (viscous fingering) bei vielen Druckstoffarten beobachtet werden. Die Minderung des viscous fingering im Farbspaltungsprozess und eine nahezu vollständige Leerung der hydrophobierten Tiefdruckform haben einen wesentlichen Nutzwert für den künftigen Einsatz nicht nur für die „gedruckte Elektronik“. / In this work is described experimental research about layer forming from non-Newtonian fluids in gravure printing on non-porous substrates. The viscous fingering, caused through fluid dynamics at splitting of printed material should be decreased by hydrophobic-surface modification of gravure printing form. The aim was to print wave-free homogenous layers. To achieve comparable results, modified and pure form were used simultaneously to print the same material. The printed material was mainly PEDOT:PSS and other, which is used in printed electronics. The properties (surface tension, viscosity) of printed materials were varied by additives. Printing conditions were varied too. The characteristic of printed layers were studied: resistivity, roughness, density, etc. The results shows decreasing of waviness, roughness and viscous fingering in final layer through use of hydrophobic gravure printing form, compared to print results with common printing form. This can be applied not only in the field of printed electronics.

[pt] Filmes finos de líquido estão presentes em uma variedade de sistemas e aplicações. Estamos interessados em filmes compostos por duas camadas, que são comuns no processo de revestimento por cortina. No revestimento por cortina, o líquido cai de uma matriz formando uma cortina formada por um filme fino antes de molhar o substrato em movimento. Um dos limites mais importantes do processo é a ruptura da cortina, que define um limite inferior para a vazão do líquido de revestimento. Consequentemente, este limite inferior da vazão define a espessura mínima viável do filme depositado. Evidências experimentais mostraram que o uso de uma cortina compostas por duas camadas, com uma das camadas sendo mais fina e viscoelástica, pode atrasar a ruptura da cortina para taxas de fluxo mais baixas. A quebra de filmes líquidos de duas camadas, compostas por um líquido newtoniano e um viscoelástico, é estudado por meio da resolução das equações diferenciais que descrevem a evolução da configuração do filme até seu rompimento. O efeito de diferentes parâmetros no tempo de ruptura é determinado. Os resultados mostram o mesmo comportamento observado experimentalmente, a fina camada de líquido viscoelástico retarda o rompimento, estabilizando o filme líquido. / [en] Thin liquid sheets are present in a variety of systems and applications. Here, we are interested in double-layered sheets, which are common in the curtain coating process. In curtain coating, the liquid falls from a die forming a thin curtain before wetting the moving substrate. One of the most important process limits is the curtain breakup, which sets a lower limit for the coating liquid flow rate. Consequently, this flow rate lower limit defines the feasible minimum deposited film thickness. Experimental evidence have shown that using a two-layer curtain, with a viscoelastic thin layer, may delay the curtain breakup to lower flow ratios. The breakup of two-layer liquid sheets, composed of a Newtonian and a viscoelastic liquid, is studied by solving the differential equations that describe the evolution of the liquid sheet configuration until breakup. The effect of different parameters on the breakup time is determined. The results show the same behavior observed experimentally, thin viscoelastic liquid layer delays the breakup, stabilizing the liquid sheet.

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[pt] Esta dissertação investiga escoamentos multifásicos de deslocamento de fluidos em geometrias anulares envolvidas em operações de cimentação de poços com fluidos espumados. A cimentação desempenha um papel relevante na integridade de poços e algumas aplicações requerem pastas leves com alta resistência à compressão, e o cimento espumado atende a este propósito. Para modelar adequadamente a complexidade do escoamento - que compreende comportamento não-newtoniano e elevada compressibilidade - um modelo tridimensional de dinâmica computacional de fluidos (CFD) foi desenvolvido a partir do código aberto OpenFOAM. As equações de conservação da massa, momento e fases são solucionadas em uma geometria anular, considerando o efeito da pressão na densidade e na reologia dos fluidos, e o método Volume of Fluid (VoF) foi usado para capturar a interface entre fluidos. Os modelos foram validados com soluções exatas para escoamento monofásico axissimétrico com fluidos incompressíveis e compressíveis, e com modelos constitutivos newtonianos e não-newtonianos. Além disso, simulações multifásicas estimaram a eficiência de deslocamento do fluido de perfuração pela pasta de cimento em diferentes condições – constraste de densidade e de viscosidade, ecentricidade e vazões de bombeio – e com diferentes correlações para a reologia dos fluidos espumados. Finalmente, simulações de deslocamento com fluidos com densidade e reologia constante (não-espumados) foram utilizadas para comparação. Os resultados indicam que a eficiência no deslocamento com a técnica de cimentação espumada é superior em condições similares e ilustra que as pastas espumadas são menos suceptíveis a gerarem falhas quanto condições desafiadoras estão presentes. / [en] This master dissertation investigates multiphase displacement flow in annular geometries involved in well cementing operations with foamed cement slurries and spacers. Well cementing plays a relevant role in well integrity and some applications require combining a low-density cement slurry with high compressive strength, and foamed cement suits this purpose. To properly model the displacement complexity involving foamed fluids flow - pressure and temperature dependent densities and non-Newtonian rheology - a 3-dimensional computational fluid dynamics (CFD) model was developed from the open-source OpenFOAM toolbox. The mass, momentum and phase conservation equations are solved in an annular geometry, taking the effect of pressure in the fluid density and rheology, and the volume-of-fluid (VoF) method was used to capture the interface between the fluids. The models were validated using exact solutions for axisymmetric single-phase flow with incompressible and compressible fluids, and Newtonian and non-Newtonian constitutive models. Further, multiphase simulations were performed to estimate the removal efficiency of the drilling fluid by the foamed cement slurry/spacer in different conditions – density and viscosity contrast, eccentricities, and flow rate - and with different correlations for the foamed cement rheological behavior. Finally, the displacement simulations with constant density and rheology displacing fluids (unfoamed) were performed and used to compare the results with the foamed displacing fluids. The results indicate that the displacement efficiency with a foamed cement technique outperforms constant density lightweight cement slurries with similar conditions and are much less sensitive to impairment when challenging conditions are present.

A mecânica celular jaz nas propriedades materiais da membrana plasmática, fundamentalmente uma bicamada fosfolipídica com espessura de dimensões moleculares. Além de forças elásticas, tal material bidimensional também experimenta tensões viscosas devido ao seu comportamento fluido (presumivelmente newtoniano) na direção tangencial. A despeito da notável concordância entre teoria e experimentos biofísicos sobre a geometria de membranas celulares, ainda não se faz presente um método computacional para simulação de sua (real) dinâmica viscosa governada pela lei de Boussinesq-Scriven. Assim sendo, introduzimos uma formulação variacional mista de três campos para escoamentos viscosos de superfícies fechadas curvas. Nela, o fluido circundante é levado em conta considerando-se uma restrição de volume interior, ao passo que uma restrição de área corresponde à inextensibilidade. As incógnitas são a velocidade, o vetor curvatura e a pressão superficial, todas estas interpoladas com elementos finitos lineares contínuos via estabilização baseada na projeção do gradiente de pressão. O método é semi-implícito e requer a solução de apenas um único sistema linear por passo de tempo. Outro ingrediente numérico proposto é uma força que mimetiza a ação de uma pinça óptica, permitindo interação virtual com a membrana, onde a qualidade e o refinamento de malha são mantidos por remalhagem adaptativa automática. Extensivos experimentos numéricos de dinâmica de relaxação são apresentados e comparados com soluções quasi-analíticas. É observada estabilidade temporal condicional com uma restrição de passo de tempo que escala como o quadrado do tamanho de malha. Reportamos a convergência e os limites de estabilidade de nosso método e sua habilidade em predizer corretamente o equilíbrio dinâmico de compridas e finas elongações cilíndricas (tethers) que surgem a partir de pinçamentos membranais. A dependência de forma membranal com respeito a uma velocidade imposta de pinçamento também é discutida, sendo que há um valor limiar de velocidade abaixo do qual um tether não se forma de início. Testes adicionais ilustram a robustez do método e a relevância dos efeitos viscosos membranais quando sob a ação de forças externas. Sem dúvida, ainda há um longo caminho a ser trilhado para o entendimento completo da mecânica celular (há de serem consideradas outras estruturas tais como citoesqueleto, canais iônicos, proteínas transmembranares, etc). O primeiro passo, porém, foi dado: a construção de um esquema numérico variacional capaz de simular a intrigante dinâmica das membranas celulares. / Cell mechanics lies on the material properties of the plasmatic membrane, fundamentally a two-molecule-thick phospholipid bilayer. Other than bending elastic forces, such a two-dimensional interfacial material also experiences viscous stresses due to its (presumably Newtonian) surface fluid tangential behaviour. Despite the remarkable agreement on membrane shapes between theory and biophysical experiments, there is no computational method for simulating its (actual) viscous dynamics governed by the Boussinesq- Scriven law. Accordingly, we introduce a mixed three-field variational formulation for viscous flows of closed curved surfaces. In it, the bulk fluid is taken into account by means of an enclosed-volume constraint, whereas an area constraint stands for the membranes inextensible character. The unknowns are the velocity, vector curvature and surface pressure fields, all of which are interpolated with linear continuous finite elements by means of a pressure-gradient-projection scheme. The method is semi-implicit and it requires the solution of a single linear system per time step. Another proposed ingredient is a numerical force that emulates the action of an optical tweezer, allowing for virtual interaction with the membrane, where mesh quality and refinement are maintained by adaptively remeshing. Extensive relaxation experiments are reported and compared with quasi-analytical solutions. Conditional time stability is observed, with a time step restriction that scales as the square of the mesh size. We discuss both convergence and the stability limits of our method, its ability to correctly predict the dynamical equilibrium of the tether due to tweezing. The dependence of the membrane shape on imposed tweezing velocities is also addressed. Basically, there is a threshold velocity value below which the tethers shape does not arise at first. Further tests illustrate the robustness of the method and show the significance of viscous effects on membranes deformation under external forces. Undoubtedly, there is still a long way to track toward the understanding of celullar mechanics (one still has to account other structures such as cytoskeleton, ion channels, transmembrane proteins, etc). The first step has given, though: the design of a numerically robust variational scheme capable of simulating the engrossing dynamics of fluid cell membranes.

AD is regarded as a sustainable technology that could assist the UK Government meet internationally agreed GHG emission targets by 2050. However, the mature status of the technology is based on expensive systems that rely on high energy feedstock to be profitable. Meanwhile, the natural biodegradation of cow slurry is a recognised contributor to climate change despite having a relatively low CH4 potential because of the large volumes produced. Economic mixing is essential to the cost-effectiveness of farm AD but techniques applied are not always appropriate as slurry is a shear thinning thixotropic Herschel-Bulkley fluid and therefore challenging to mix. The apparent viscosity of slurry and the shear stress induced was most influenced by solids content (exponential change) followed by temperature (linear). Most shear thinning occurred before a rising shear rate of 20s-1 was achieved with the fluid acting near-Newtonian above. Thixotropic recovery occurred within 1 hour of resting. Rheological values were also much higher than previously reported. Highest CH4 production occurred in the first 10 days of the batch process using a range of mixing regimes with different shear rates and rest periods. During fed-batch operations, changing shear rate had a minimal effect on CH4 production using a 30-day HRT whereas shorter rest periods increased production. Specific CH4 production rate was highest when feeding and mixing coincided. However, when HRT was reduced (OLR increased) the CH4 produced by all mixed regimes significantly increased with highest values being achieved using high intensity mixing rested for short periods. Lower HRTs also requires smaller digesters. Parasitic mixing energy invariably had the most influence on net energy production. Signs of instability were evident after 20 days using the low HRT. Significant microbial adaptation was also observed as the experiments progressed. The research outcomes demonstrate that mixing regime and HRT can be managed to maximise net energy production whilst reducing capital expenditure.

Binary systems comprising of compact objects like neutron stars (NS) and/or black holes (BH) lose their energy and angular momentum via gravitational waves (GW). Radiation reaction due to the emission of GW results in a gradual shrinking of the binary orbit and an accompanying gradual increase in the orbital frequency. The preliminary phase of the binary evolution when the radiation-reaction time-scale is much larger than the orbital time-scale is called the inspiral phase. GW emitted during the final stages of the inspiral phase constitute one of the most important sources for the ground-based laser interferometric GW detectors like LIGO, VIRGO and the proposed space-based detector LISA. For the ground-based detectors, NS and/or stellar mass BH binaries are primary sources, while for LISA super-massive BH (SMBH) binaries are potential targets. Inspiralling compact binaries (ICB) are among the prime targets for interferometric detectors because using approximation schemes in general relativity (GR) like the post-Minkowskian (PM) and the post-Newtonian (PN) approximations one can compute the GW emitted by them with sufficient accuracy both for their detection and parameter estimation leading to GW astronomy. The extreme weakness of gravitational interactions implies that if a GW signal from an ICB is incident on a detector, it will be buried in the noisy detector output. Therefore, sophisticated data analysis techniques are required for detecting the signal in presence of the dominant noise and also estimating the parameters of the signal. From the pre-calculated theoretical waveforms called templates, one already knows the structure of the waveform from an ICB. The technique for detecting signals which are of known form in a noisy detector is matched filtering. This technique consists of cross-correlating the output of a noisy detector assumed to contain the signal of known form with a set of templates. It then finds an ‘optimal’ template that would produce, on average, the highest signal-to-noise ratio (SNR). The efficient performance of matched filtering as a data-analysis strategy for GW signals from ICB presupposes very accurate theoretical templates. Slight mismatches between the signal and the template will result in a loss of signal to noise ratio. Computing very accurate theoretical templates and including effects such as eccentricity are challenging tasks for the theoreticians. This thesis addresses some of the issues related to the waveform modelling of the ICB and their implications for GW data analysis. It is known theoretically that compact binaries reduce their eccentricity through the emission of GW. When GW signals from prototype ICB reach the GW detector bandwidth, their orbits are almost circular. Hence one usually models the binary orbit to be circular for computation of the search templates. The waveform from an ICB in a circular orbit is, at any given PN order of approximation, a linear combination of a finite number of harmonics of the orbital frequency. At the lowest order of approximation, called the Newtonian order, the waveform comprises a single harmonic at twice the orbital frequency. Inclusion of higher order PN corrections lead to the appearance of higher harmonics of the orbital frequency. Since the amplitudes of the higher harmonics contain higher powers of the PN expansion parameter, relative to the Newtonian order, they are referred to as amplitude corrections. The phase of each harmonic, determined by the orbital phase, is known upto 3.5PN order (nPN is the order of approximation equivalent to terms ~(v/c)2n beyond the Newtonian order, where v denotes the binary’s orbital velocity and c is the speed of light). Matched filtering is more sensitive to the phase of the signal rather than its amplitude, since the correlation builds up as long as the signal and the template remain in phase. Motivated by this fact, search templates so far have been a waveform model involving only the dominant harmonic (at twice the orbital frequency), although the phase evolution itself is included upto the maximum available PN order. Such waveforms, in which all amplitude corrections are neglected, but the phase is treated to the maximum available order, are called restricted waveforms (RWF) and these are generally used in the data-analysis of ground-based detectors and also simulated searches for the planned LISA. However, recent studies, in the case of ground-based interferometers, showed that going beyond the RWF approximation could improve the efficiency of detection as well as parameter estimation of the inspiral signal. After a brief overview of the properties of GW and their detection strategies in chapter 1, in chapters 2 and 3, we investigate the implications of going beyond the RWF, in the context of the planned space-based Laser Interferometric Space Antenna (LISA). The sensitivity of ground-based detectors is limited by seismic noise below 20Hz. On the other hand, the space-based LISA will be designed to be sensitive to GWs of frequency (10−4 _1)Hz. The most important source in this frequency band are supermassive BH (SMBH) binaries. There is strong observational evidence for the existence of SMBH with masses in the range of in most galactic nuclei. Mergers of such galaxies result in SMBH binaries whose evolution is governed by the emission of GW. Observation of the GW from SMBH binaries at high redshifts is one of the major science goals of LISA. These observations will allow us to probe the evolution of SMBHs and structure formation and provide an unique opportunity to test General Relativity (and its alternatives) in the strong field regime of the theory. Observing SMBH coalescences with high (100-1000) SNR is crucial for performing all the aforementioned tests. The LISA bandwidth (10−4_ 1)Hz determines the range of masses accessible to LISA because the inspiral signal would end when the system’s orbital frequency reaches the mass-dependent last stable orbit (LSO). In the test-mass approximation, the angular velocity ι at LSO is given by where M is the total mass of the binary. Search templates using the RWF, which contains only the dominant harmonic at twice the orbital frequency, cannot extract power in the signal beyond This further implies that the frequency range [0.1, 100] mHz corresponds to the range for the total mass of BH binaries that would be accessible to LISA. In chapter 2, we show that inclusion of higher harmonics will enhance the mass-range of LISA (for the same frequency range) and allow for the detection of SMBH binaries with total masses higher than The template employed in chapter 2 includes amplitude corrections upto 2.5PN order, while keeping the phase upto 3.5PN order. We call this template the full waveform (FWF). The FWF defined above contains higher harmonics of the orbital frequency, the highest of them being 7 times the orbital frequency. For a SMBH binary with total mass the dominant harmonic at LSO is less than the lower cut-off of the LISA bandwidth. Therefore, if one uses the RWF as a search template, this system is ‘invisible’ to LISA. However, the seventh harmonic can still enter the LISA bandwidth and produce a significant SNR and thus allow its detection. With the FWF, LISA can observe sources which are favoured by astronomical observations, but not observable with the RWF. More specifically, with the inclusion of all known harmonics LISA will be able to observe SMBH coalescences with total mass (and mass-ratio 0.1) for a low frequency cut-off of 10−4Hz (10−5Hz) with an SNR up to ~ 60 (~30) at a distance of 3 Gpc. The orbital motion of LISA around the Sun induces frequency, phase and amplitude modulations in the observed GW signal. These modulations carry information about both the source’s location and orientation. Determination of the angular coordinates of the source also allows determination of the luminosity distance of SMBH binaries. Therefore, SMBH binaries are often referred to as GW “standard sirens” (analogous to the electromagnetic “standard candles”). LISA would also be able to measure the “redshifted” masses of the component black holes with good accuracy for sources up to redshifts of a few. However, GW observations alone cannot provide any information about the redshift of the source. If the host galaxy or galaxy cluster is known one can disentangle the redshift from the masses by optical measurement of the redshift. This would not only allow one to extract the “physical” masses, but also provide an exciting possibility to study the luminosity distance-redshift relation providing a totally independent confirmation of the cosmological parameters. Further, this combined observation can be used to map the distribution of black hole masses as a function of redshift. Another outstanding issue in present day cosmology in which LISA can play a role is the dark energy and its physical origin. Probing the equation-of-state-ratio (w(z)) provides an important clue to the question of whether dark energy is truly a cosmological constant (i.e., w = -1). Assuming the Universe to be spatially flat, a combination of WMAP and Supernova Legacy Survey (SNLS) data yields significant constraints on Without including the spatial flatness as a prior, WMAP, large-scale structure and supernova data place a stringent constraint on the dark energy equation of state, For this to be possible, LISA should (a) measure the luminosity distance to the source with a good accuracy and (b) localize the coalescence event on the sky with good angular resolution so that the host galaxy/galaxy cluster can be uniquely identified. Based on analysis with the RWF, it is found that LISA’s angular resolution is not good enough to identify the source galaxy or galaxy cluster, and that other forms of identification would be needed. Secondly, weak lensing effects would corrupt the distance estimation to the same level as LISA’s systematic error. In chapter 3, we study the problem of parameter estimation in the context of LISA, but using the FWF. We investigate systematically the variation in parameter estimation with PN orders by critically examining the role of higher harmonics in the fast GW phasing and their interplay with the slow modulations induced due to LISA’s motion. More importantly, we explore the improvement in the estimation of the luminosity distance and the angular parameters due to the inclusion of higher harmonics in the waveform. We translate the error in the angular resolution to obtain the number of galaxies (or galaxy clusters) within the error box on the sky. We find that independent of the angular position of the source on the sky, higher harmonics improve LISA’s performance on both counts raised in earlier works based on the RWF. We show that the angular resolution enhances typically by a factor of ~2-500 (greater at higher masses) and the error on the estimation of the luminosity distance goes down by a factor of ~ 2-100 (again, larger at higher masses). For many possible sky positions and orientations of the source, the inaccuracy in our measurement of the dark energy would be at the level of a few percent, so that it would only be limited by weak lensing. We conclude that LISA could provide interesting constraints on cosmological parameters, especially the dark energy equation-of-state, and yet circumvent all the lower rungs of the cosmic distance ladder. Having emphasized the need to consider the FWF as a more powerful template, in chapter 4 we calculate a higher order term in the amplitude corrections of the waveform. In chapters 2 & 3, the FWF incorporated amplitude corrections upto 2.5PN order. In chapter 4 the waveform is calculated upto 3PN order. Recent progress in Numerical Relativity (NR) has resulted in computation of the late inspiral and subsequent merger and ringdown phases of the binary evolution (where PN theory does not hold good) by a full-fledged numerical integration of the Einstein field equations. A new field has emerged recently consisting of high-accuracy comparisons between the PN predictions and the numerically-generated waveforms. Such comparisons and matching to the PN results have proved currently to be very successful. They clearly show the need to include high PN corrections not only for the evolution of the binary’s orbital phase but also for the modulation of the gravitational amplitude. This leads to one more motivation for the work in this chapter: providing the associated spin-weighted spherical harmonic decomposition to facilitate comparison and match of the high PN prediction for the inspiral waveform to the numerically-generated waveforms for the merger and ringdown. For the computation of waveforms from the inspiralling compact binaries one needs to solve the two-body problem in general relativity. The nonlinear structure of general relativity prevents one from obtaining a general solution to this problem. The two-body problem is tackled using the multipolar post-Minkowskian (MPM) wave generation formalism. The MPM formalism describes the radiation field of any isolated post-Newtonian source. The radiation field is first of all parametrized by means of two sets of radiative multipole moments. These moments are then related (by means of an algorithm for solving the non-linearities of the field equations) to the so-called canonical moments which constitute some useful intermediaries for describing the external field of the source. The canonical moments are then expressed in terms of the operational source moments obtained by matching to a PN source and are given by explicit integrals extending over the matter source and gravitational field. The extension of the waveform by half a PN order requires as inputs the relations between the radiative, canonical and source multipole moments for general sources at 3PN order. We also require the 3PN extension of the source multipole moments in the case of compact binaries. The waveform in the far-zone consists of two types of terms, instantaneous and hereditary. The instantaneous terms are determined by the dynamical state of the binary at the retarded time. The hereditary terms, on the other hand, depend on the entire past history of the source. These terms originate from the nonlinear interactions between the various multipole moments and also from backscattering off the curved spacetime generated by the waves themselves. In this chapter, we compute the contributions of all the instantaneous and hereditary terms (which include tails, tails-of-tails and memory integrals) up to 3PN order. The end results of this chapter are given in terms of both the 3PN plus and cross polarizations and the separate spin-weighted spherical harmonic modes. Though most of the sources will be in circular orbits by the time the GWs emitted by the system enter the sensitivity band of the laser interferometers, astrophysical scenarios such as Kozai mechanism could produce binaries which have nonzero eccentricity. Studies have shown that filtering the signal from an eccentric binary with circular orbit templates could significantly degrade the SNR. For constructing a phasing formula for eccentric binaries one has to compute the energy and angular momentum fluxes carried away by the GWs and then compute how the orbital elements evolve with time under gravitational radiation reaction. The far-zone energy and angular momentum fluxes, like the waveform, contain both instantaneous and hereditary contributions. The complete 3PN energy flux and instantaneous terms in the 3PN angular momentum flux are already known. In chapter 5, the hereditary terms in the 3PN angular momentum flux from an ICB moving in quasi-elliptical orbits are computed. A semi-analytic method in the frequency domain is used to compute the hereditary contributions. At 3PN order, the quasi-Keplerian representation of elliptical orbits at 1PN order is required. To calculate the tail contributions we exploit the doubly periodic nature of the motion to average the 3PN fluxes over the binary’s orbit. The hereditary part of the angular momentum flux provided here has to be supplemented with the instantaneous part to obtain the final input needed for the construction of templates for binaries moving in elliptical orbits, a class of sources for both the space based detectors and the ground based ones. Using the hereditary contributions in the 3PN energy flux, we also compute the 3PN accurate hereditary contributions to the secular evolution of the orbital elements of the quasi-Keplerian orbit description.

In present finite element study, the dynamics of incompressible isothermal flows of Newtonian and two generalised non-Newtonian models through complex mixing-separating planar channel and circular pipe filled with and without porous media, including Darcy's term in momentum equation, is presented. Whilst, in literature this problem is solved only for planar channel flows of Newtonian and viscoelastic fluids. The primary aim of this study is to examine the laminar flow behaviour of Newtonian and inelastic non-Newtonian fluids, and investigate the robustness of the numerical algorithm. The rheological properties of non-Newtonian fluids are defined utilising a range of constitutive equations, for inelastic non-Newtonian fluids non-linear viscous models, such as Power Law and Bird-Carreau models are used to capture the shear thinning behaviour of fluids. To simulate such complex flows, steady-state solutions are sought employing time-dependent finite element algorithm. Temporal derivatives are discretised using second order Taylor series expansion, while, spatial discretisation is achieved through Galerkin approximation in combination to deal with incompressibility a pressure-correction scheme adopted. In order to achieve the algorithm of semi-implicit form Darcy's-Brinkman equation is utilized for the conversion in Darcy's terms and diffusion, while Crank-Nicolson approach is adopted for stability and acceleration. Simple and complex flows for various complex flow bifurcations of the combined mixing-separating geometries, for both two-dimensional planar channel in Cartesian coordinates, as well as axisymmetric circular tube in cylindrical polar coordinates system are investigated. These geometries consist of a two-inverted channel and pipe flows connected through a gap in common partitions, initially filled with non-porous materials and later with homogeneous porous materials. Computational domain is having variety it has been investigated with many configurations. These computational domains have been appeared in industrial applications of combined mixing and separating of fluid flows both for porous and non-porous materials. Fully developed velocity profile is applied on both inlets of the domain by imposing analytical solutions found during current study for porous materials. Numerical study has been conducted by varying flow rates and flow direction due to a variety in the domain. The influence of varying flow rates and flow directions are analysed on flow structure. Also the impact of increasing inertia, permeability and power law index on flow behaviour and pressure difference are investigated. From predicted solution of present numerical study, for Newtonian fluids a close agreement is realised between numerical solutions and experimental data. During simulations, it has been noticed that enhancing fluid inertia (flow rates), and permeability has visible effects on the flow domains. When the Reynolds number value increases the size and power of the vortex for recirculation increases. Under varying flow rates an early activity of vortex development was observed. During change in flow directions reversed flow showed more inertial effects as compared with unidirectional flows. Less significant influence of inertia has been observed in domains filled with porous media as compared with non-porous. The power law model has more effects on inertia and pressure as compared with Bird Carreau model. Change in the value of permeability gave significant impact on pressure difference. Numerical simulations for the domain and fluids flow investigated in this study are encountered in the real life of mixing and separating applications in the industry. Especially this purely quantitative numerical investigation of flows through porous medium will open more avenues for future researchers and scientists.

In the introduction this thesis classifies different conceptions of the relationship between science and faith. Then, it focuses on common topics of natural science and theology in secondary education. It summarises and reflects the experience of teaching practice and deals with the practical options for Christian issues which the students are usually interested in. The topics are presented in relation to a specific high school curricula and sorted into three parts: Death and dysthanasia, Time and rheology, Deus vere ludens et homo ludens. Some practical examples and recommendation for teaching practice are also mentioned.