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Incorporation of Surface Induced Dissociation into a Commercial Ion Mobility - Tandem Mass Spectrometer and Application of Mass Spectrometry Methods for Structural Analysis of Non-covalent Protein ComplexesZhou, Mowei 17 September 2013 (has links)
No description available.
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Ανάπτυξη αναλυτικών μεθόδων για τη μελέτη βιοδραστικών συστατικών του είδους Olea europaea και των αλληλεπιδράσεων αυτών των ουσιών με πεπτίδιαΜπαζώτη, Φωτεινή Ν. 10 February 2009 (has links)
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Experimental and theoretical investigations of intermetallic in transition metal coordination and organometallic complexes / Etudes expérimentales et théoriques des interactions intermétalliques en transition métal coordination et complexes organométalliquesPetrović, Predrag 10 September 2014 (has links)
Ce travail de thèse démontre l’importance d’intégrer des outils théoriques à des observations expérimentales dans le but d’étudier le rôle des interactions non-covalentes et plus précisément de la dispersion dans la chimie des métaux de transition. Plusieurs thèmes ont ainsi été abordés comme les interactions d’empilement entre chélates de métaux de transition à l’état solide; l’influence de la chiralité sur l’oligomérisation en solution de complexes plans carrés de Rh(I) isonitrile; la stabilité et inactivité inhabituelles de complexes de type cis-platine en solution concentrée. Les résultats obtenus par titration calorimétrique isotherme ont permis d’évaluer la capacité de méthodes théoriques à reproduire avec précision les résultats expérimentaux. Les calculs ont démontré qu’un traitement théorique approprié des effets de la dispersion et de la solvatation, donne des valeurs cohérentes avec les résultats expérimentaux. Cependant, des améliorations supplémentaires sont nécessaires. / This thesis has shown the importance of integration of theoretical calculations and experimental investigations in studying the role of non-covalent interactions and particularly dispersion interactions in transition metal chemistry. Several subjects were addressed, such as stacking interactions of chelates in transition metal complexes in solid state, influence of chirality on the oligomerization of Rh(I) isonitrile complexes in solution and the stability of the cis-platin type complexes in concentrated solutions. Isothermal titration calorimetry proved to be very useful in the studies by providing accurate experimental data on the thermochemistry of addressed processes. This data was used to gauge the ability of the theoretical methods to accurately reproduce the experimental results. Calculations have shown that the proper treatment of dispersion effects and solvation by theoretical models gives values in relatively good agreement with experiments, but further improvements are needed.
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Synthèse de nanotubes de carbone monofeuillets individuels et composites modèles polymères - nanotubes de carbone : application à l’effet photovoltaïque / Synthesis of individual single wall carbon nanotubes and composites polymers-carbone nanotubes : application for photovoltaïc effectSalem, Diana 26 March 2012 (has links)
L’objectif de ce travail est d’élaborer des matériaux composites modèles nanotubes de carbone/polymères permettant de tirer profit des propriétés des nanotubes de carbone à l’échelle macroscopique. L’obtention de tels matériaux nécessitant une fonctionnalisation homogène entre les nanotubes de carbone et les polymères, les nanotubes de carbone utilisés doivent être individuels et de même réactivité chimique, donc de même diamètre. Ainsi, ils doivent être synthétisés par CVD par des nanoparticules catalytiques monodisperses et supportées. Dans la première partie, nous avons élaboré une nouvelle méthode générique de synthèse de nanoparticules d’oxydes métalliques supportées. Nous avons principalement détaillé la synthèse de nanoparticules de Fe2O3 dont la distribution en taille est de 1.1 ± 0.3 nm. Dans la deuxième partie, après avoir étudié la stabilité thermique de ces nanoparticules, nous les avons utilisées pour catalyser la croissance des nanotubes de carbone monofeuillets individuels par CVD. La caractérisation des nanotubes obtenus par Raman indique une distribution en diamètre exceptionnellement étroite de 1.27 ± 0.15 nm. Dans la troisième partie, nous avons tout d’abord étudié la mise en solution des nanotubes de carbone par fonctionnalisation non covalente avec un polymère hydrosoluble le POE portant un motif pyrène en bout de chaîne et mis en évidence un phénomène de déplétion qui limite la solubilisation des nanotubes. Nous avons ensuite élaboré des matériaux composites nanotubes de carbone/rrP3HT par fonctionnalisation covalente et non covalente et nous avons étudié l’efficacité de séparation de charge dans les deux cas de fonctionnalisations. / The aim of this work is to develop composite materials carbon nanotubes/polymers to take advantage of properties of carbon nanotubes at macroscopic scale. To get such materials, homogeneous functionalization between carbon nanotubes and polymers is required, carbon nanotubes must be individual with the same chemical reactivity, therefore the same diameter. Thus, they must be synthesized by CVD from monodispersed and supported catalyst nanoparticles. In the first part, we developed a new universal method for the synthesis of metal oxide supported nanoparticles. We mainly detailed the synthesis of Fe2O3 nanoparticles with size distribution of 1.1 ± 0.3 nm. In the second part, after studying the thermal stability of these nanoparticles, we used them to catalyze the growth of individual single wall carbon nanotubes by CVD. The caracterisation of the obtained nanotubes by Raman show exceptionally narrow diameter distribution of 1.27 ± 0.15 nm. In the third section, we first studied the dispersion of carbon nanotubes by noncovalent functionalization withhydro-soluble polymer POE with pyrene as end group and revealed depletion phenomena that limit the solubilization of nanotubes. Then we developed composite materials carbon nanotubes/rrP3HT by covalent and noncovalent functionalisation and we studied the efficiency of charge separation in both cases of functionalization.
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Design and Implementation of Quantum Chemistry Methods for the Condensed Phase: Noncovalent Interactions at the Nanoscale and Excited States in Bulk SolutionCarter-Fenk, Kevin D. 01 October 2021 (has links)
No description available.
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Controlled Transfer Of Macroscopically Organized Nanoscopically Patterned Sub–10 nm Features onto 2D Crystalline and Amorphous MaterialsTyson C Davis (9121889) 05 August 2020 (has links)
<div>Surface level molecules act as an interface that mediates between the surface and the environment. In this way, interfacial molecules are responsible for conferring characteristics of relevance to many modern material science problems, such as electrical conductivity and wettability. For many applications, such as organic photovoltaics and nanoelectronics, macroscopic placement of chemical patterns at the sub-10 nm must be achieved to advance next generation device applications.</div><div><br></div><div>In the work presented here, we show that sub-10 nm orthogonal features can be prepared by translating the building principles of the lipid bilayer into striped phase lipids on 2D materials (e.g. highly ordered pyrolytic graphite (HOPG), MoS2). Macroscopic patterning of these nanoscopic elements is achieved via Langmuir Schafer deposition of polymerizable diyne amphiphiles. On the Langmuir trough, amphiphiles at the air water interface are ordered into features that can be observed on the macroscale using Brewster angle microscopy. Upon contact of the 2D material with the air-water interface the macroscopic pattern on the trough is transferred to the 2D material creating a macroscopic pattern consisting of sub-10 nm orthogonal chemistries. We also show here how hierarchical ordering can be accomplished via noncovalent microcontact printing of amphiphiles onto 2D materials. Microcontact printing allows a greater measure of control over the placement and clustering of interfacial molecules.</div><div><br></div><div>The alkyl chain/surface enthalpy has a great deal of influence over the ordering of amphiphiles at the sub-nm scale. Here, we examine this influence by depositing diyne amphiphiles onto MoS2 which has a weaker alkyl adsorption enthalpy compared to HOPG. We found that dual-chain amphiphiles deposited on MoS2 adopt a geometry that maximized the molecule-molecule interaction compared to the geometry adopted on HOPG.</div><div><br></div><div>Finally, we show how the hierarchical pattern of diyne amphiphiles can be transferred off of the 2D material onto an amorphous material. This is done by reacting the amorphous material with the conjugated backbone of the diyne moiety through a hydrosilylation reaction to exfoliate the film from the 2D crystalline material. The resulting polymer ‘skin’ has many applications were controlling interfacial properties of an amorphous material is important.</div>
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Novel Dynamic Materials Tailored by Macromolecular EngineeringZhang, Borui 26 July 2019 (has links)
No description available.
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Theoretical and Experimental Study of Cooperativity Effects in Noncovalent InteractionsEstarellas Martín, Carolina 07 September 2012 (has links)
L’any 2002 tres grups de recerca, entre ells el nostre grup, van demostrar teòricament que la interacció entre anions i anells aromàtics electrodeficients, anomenada interacció anió–, era favorable. Des de llavors s’ha dut a terme un intens estudi de la seva naturalesa física fins la total comprensió. Aquesta tesi es basa amb l’estudi de la interacció anió– des de tres punts de vista. Primerament, la investigació es basa en el disseny teòric de motius estructurals per donar lloc a un receptor on la interacció anió– siga molt favorable, per posteriorment avaluar la força de la interacció experimentalment en dissolució. A continuació, es va analitzar la interrelació entre un gran nombre de combinacions d’interaccions no covalents. A partir d’aquest estudi es defineixen nous conceptes i es proposen diferents formules per calcular efectes de cooperativitat. Finalment, hem anat un pas més enllà en l’estudi de la interacció analitzant: 1) l’impacte de la interacció anió– a sistemes biològics; 2) la influència de modificacions a l’anió sobre la naturalesa física de la interacció. / In 2002 three research groups, among them our research group, theoretically demonstrated that the interaction between anions and electron-deficient aromatic rings, named anion– interaction, was favourable. Since then, an intense study of its physical nature has been performed to understand it completely. This thesis is based on the study of the anion– interaction from three points of view. Firstly, theoretical design of binding units to build a receptor and to obtain the most favourable binding based on anion– interactions. The binding properties of these receptors have been experimentally assessed in solution. Secondly, we have studied the interplay between a great combination of noncovalent interactions. From this study, new concepts and formula to calculate cooperativity effects have been described. Finally, we have study one step further the anion– interaction analysing: 1) the impact of anion– interaction in biological systems; 2) how the modifications in the anion influence the physical nature of the interaction.
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DEVELOPMENT OF THERMALLY CONTROLLED LANGMUIR–SCHAEFER CONVERSION TECHNIQUES FOR SUB-10-NM HIERARCHICAL PATTERNING ACROSS MACROSCOPIC SURFACE AREASTyler R Hayes (9754796) 14 December 2020 (has links)
<div> As hybrid 2D materials are incorporated into next-generation device designs, it becomes more and more pertinent that methods are being developed which can facilitate large-area structural control of noncovalent monolayers assembled at 2D material interfaces. Noncovalent functionalization is often leveraged to modulate the physical properties of the underlying 2D material without disrupting the extended electronic delocalization networks intrinsic to its basal plane. The bottom-up nanofabrication technique of self-assembly permits sub-10-nm chemical patterning with low operational costs and relatively simple experimental designs.</div><div> The Claridge Group is interested in leveraging the unique chemical orthogonality intrinsic to the cellular membrane as a means of creating sub-10-nm hydrophilic-hydrophobic striped patterns across 2D material interfaces for applications ranging from interfacial wetting to large-area molecular templates to guide heterogeneous nanoparticle assembly. Using Langmuir–Schaefer conversion, standing phases of polymerizable amphiphiles at the air-water interfaces of a Langmuir trough are converted (through rotation) to lying-down phases on 2D material substrates. Using room temperature substrates, transfer of amphiphiles to a lowered substrate results in small domains and incomplete surface coverage.</div><div> Recognizing that heating the substrate during the LS conversion process may lower the energy barriers to molecular reorientation, and promote better molecular domain assembly, we developed a thermally controlled heated transfer stage that can maintain the surface temperature of the substrate throughout the deposition process. We found that heating during transfer results in the assembly of domains with edge lengths routinely an order of magnitude larger than transfer using room temperature substrates that are more stable towards rigorous repeat washing cycles with both polar and nonpolar solvents.</div><div> To promote the effectiveness of the LS conversion technique beyond academic environments for the noncovalent functionalization 2D material substrates for next-generation device designs, we designed and built a thermally controlled rotary stage to address the longstanding scaling demerit of LS conversion. First, we report the development of a flexible HOPG substrate film that can wrap around the perimeter of the heated disk and can be continuously cycled through the Langmuir film. We found that thermally controlled rotary (TCR) LS conversion can achieve nearly complete surface coverage at the slowest translation speed tested (0.14 mm/s). TCR–LS facilitates the assembly of domains nearly 10,000 μm<sup>2</sup> which were subsequently used as molecular templates to guide the assembly of ultranarrow AuNWs from solution in a non-heated rotary transfer step. Together, these findings provide the foundation for the use of roll-to-roll protocols to leverage LS conversion for noncovalent functionalization of 2D materials. A true roll-to-roll thermally controlled LS conversion system may prove to be advantageous and a cost-efficient process in applications that require large areas of functional surface, or benefit from long-range ordering within the functional film.</div>
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