There is a great need in the transportation industry for high strength, high stiffness and lightweight materials with excellent dimensional stability. The use of these materials reduces fuel consumption and greenhouse gas emission as well as malfunctioning of components when subjected to fluctuating temperatures. Metal matrix composites (MMCs) are designed to meet these needs of transportation and other industries. However, their use is limited by lack of information on their thermal behaviour. In addition, reactions that occur in MMCs alter their microstructure and properties. These reactions have been widely investigated using X-ray Diffractometry (XRD) and electron microscopy (EM). However, these techniques cannot provide information such as charge transfer and local elemental structures in materials. Synchrotron X-ray Absorption Spectroscopy (XAS) could be used to identify reaction products in MMCs as well as provide information which XRD and EM cannot provide.<p> The thermal behaviour of Al-Mg alloy A535 containing fly ash particles as well as charge transfer and reactivity in particulate aluminium alloy metal matrix composites (MMCs) were investigated in this work. The materials studied were (i) Al-Cu-Mg alloy AA2618 and its composites reinforced with 10 and 15 vol.% alumina (Al2O3) particles and (ii) Al-Mg alloy A535 and its composites reinforced with a mixture of 5 wt.% fly ash and 5 wt.% silicon carbide, 10 wt.% and 15 wt.% fly ash. The investigative techniques used included Differential Scanning Calorimetry (DSC), Thermomechanical Analysis (TMA), Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), and synchrotron X-ray Absorption Spectroscopy (XAS).<p> The results obtained showed that the coefficient of thermal expansion (CTE) of A535 decreased with the addition of fly ash and silicon carbide. Also, the addition of these particles improved the dimensional stability of the alloy in that the residual strain, åp, cycling strain, åc, and CTE decreased. The results obtained from XAS measurements showed evidence of charge redistribution in the aluminium in AA2618 with the addition of alumina particles. The results obtained from XAS measurements showed evidence of charge redistribution in the aluminium in AA2618 with the addition of alumina particles. The addition of alumina particles into AA2618 increased the p-orbital population and also changed the surface chemistry of the matrix. It was also demonstrated that the XAS technique can be used to determine the presence of various oxides in industrial fly ash and spinel (MgAl2O4) in alumina and fly ash particles extracted from the MMCs.

In this thesis, characterization of two class F fly ashes (FA) from &Ccedil / atalagzi and Sug&ouml / z&uuml / thermal power plants were carried out and their utilization potentials in three different fields were examined. Characterization of sintered samples and determination of their utilization potentials in ceramic industry is the first research area in this thesis. For this purpose, the class F fly ash samples were first pressed into cylindrical specimen without the addition of any organic binders or inorganic additives, and then sintered to form ceramic materials. Effects of sintering temperature and time on sintering characteristics were investigated. In the experiments, the cylindrical specimens were first preheated to 300oC for 1 h to remove moisture and any other gases. The specimens were then fired at the temperatures of 1000oC, 1050oC, 1100oC and 1150oC for the sintering times of 0.5, 1.0, 1.5 and 2.0 hours. Heating rate of 10oC/min was kept constant throughout the experiments. Quality of sintered samples was evaluated in terms of ceramic specifications such as density, water absorption, porosity, shrinkage and splitting tensile strength. In addition, mineralogical and microstructural changes during sintering were determined with X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses. According to literature data, better microstructure, the highest density and strength with the lowest porosity, water absorption and shrinkage values are the indications of the optimum sintering conditions. Based on these specifications, Sug&ouml / z&uuml / fly ash gave better results compared to &Ccedil / atalagzi fly ash, and the optimum conditions were achieved at the sintering temperature of 1150oC for the sintering time of 1.5 hours for both samples. Pozzolanic reactivity of the fly ashes and their utilization potentials in civil engineering applications were also examined in detail during this study. For this purpose, &Ccedil / atalagzi (CFA) and Sug&ouml / z&uuml / (SFA) fly ashes were first subjected to a specific hydraulic classification process developed at CAER (University of Kentucky, Center for Applied Energy Research) to recover ultrafine fly ash particles. The overflow products with average particle sizes of 5.2 &mu / m for CFA and 4.4 &mu / m for SFA were separated from the respective as-received samples with average particle sizes of 39 &mu / m and 21 &mu / m. After the classification stage, the pozzolanic activities of these ultrafine fly ash fractions (UFA) and as-received samples were examined by preparing a number of mortar (mixture of Portland cement (PC), FA or UFA as partial cement replacement, sand and water) and paste (mixture of PC, FA or UFA as partial cement replacement and water) specimens. Control samples containing only PC were also prepared and tested through the experiments for the comparison of the results. In the mortar experiments, three different PC replacement ratios by FA and UFA (10%, 20% and 30%) were used to examine the effects of FA and UFA samples on the fresh and hardened mortar properties such as water requirement, compressive strength, drying shrinkage and water expansion. These mortar tests indicated that ultrafine fractions of &Ccedil / atalagzi (CUFA) and Sug&ouml / z&uuml / (SUFA) fly ashes provided more than 10% reduction in water demand compared to the control sample for 30% PC replacement. The mortar cubes containing CUFA and SUFA samples exhibited also higher strength development rates after 14 days compared to the ones with as-received samples and PC only. At the end of the curing age of 112 days, both CUFA and SUFA provided more than 40% increase in compressive strength compared to the control sample for the PC replacement ratios higher than 20%. As a comparison, SUFA gave better results than CUFA in both water demand and compressive strength tests. The mortar bars prepared with the both FA and UFA samples exhibited very low shrinkage and expansion values. These values decreased generally with increasing PC replacement ratio especially after 14 days. In the paste experiments, thermogravimetric analyses (TGA) of the paste specimens prepared by using only with 20% PC replacement were carried out to determine pozzolanic reactivity of the samples. The difference between the remaining Ca(OH)2 (portlandite) contents in the paste specimens containing the fly ashes and the reference PC paste was used as a measure of pozzolanic reactivity. After 112 days, 68.56% and 62.68% Ca(OH)2 content of PC only pastes were obtained with the pastes containing CUFA and SUFA samples, respectively, corresponding to 11% and 13% more Ca(OH)2 consumptions in reference to the respective as-received samples. X-ray diffraction (XRD) analyses were also performed for comparison of main portlandite peak intensities in the paste specimens containing FA or UFA with those in the PC only paste during cement hydration. According to these XRD analyses, portlandite content in PC/UFA pastes decreased significantly after 14 days compared to the PC only paste. All of these tests and analyses showed that a highly reactive lower cost pozzolan with very fine particle size and higher surface area compared to regular fly ash pozzolans can be produced from both &Ccedil / atalagzi and Sug&ouml / z&uuml / fly ashes using a relatively simple hydraulic classification technology. Cenosphere recovery potentials from &Ccedil / atalagzi and Sug&ouml / z&uuml / fly ashes were also studied in this thesis. Determination of cenosphere content was done under optical microscope by particle counting on the basis of point and area. Based on the point-counting data, CFA and SFA samples originally contain 11.30% and 4.50% cenospheres, respectively. Variations of cenosphere contents in the fly ash samples were examined by using float-sink, screening and air classification tests. The results pointed out that cenosphere contents decreased with decreasing size and increasing density for both samples. According to the float-sink tests, &Ccedil / atalagzi fly ash has much more floating products and more cenospheres than Sug&ouml / z&uuml / fly ash for the same density interval. Based on the air classification results, cenospheres were concentrated in the underflow products, and cenosphere contents increased with increasing air pressure and decreasing motor speed for both samples. The most efficient cenosphere separation technique among the examined methods was screening. Cenosphere contents of CFA and SFA increased to 21.65% and 11.83%, respectively by only using simple screening through 38 &mu / m.

Soy contains many bioactive molecules known to elicit anti-cancer effects. One such peptide, Lunasin, has been shown to selectively act on newly transformed cells while having no cytotoxic effect on non-tumorigenic or established cancer cell lines. In this study we attempt to understand the developmental effects of Lunasin overexpression in vivo and create reagents that will help us understand Lunasin’s anti tumorigenic effects in an intact organism. cDNA encoding lunasin and EGFP-lunasin were cloned into pUAST and microinjected into Drosophila embryos. Tissue-specific overexpression of EGFP-Lun in the resulting transgenic lines was accomplished by crossing transgenics to various GAL4 driver lines. Progeny were assessed for phenotypic alterations and no phenotypic abnormalities were observed in tissues expressing EGFP-Lunasin, supporting current studies that show Lunasin does not affect normal cells. Previous studies have localized Lunasin to the nuclear compartment. To test if this was the case for EGFP-Lun, subcellular localization of EGFP-Lun was determined via fluorescence microscopy. Salivary glands from EGFP-Lun expressing individuals were dissected, fixed, and mounted in Vectashield® with the nuclear stain, DAPI. Our results demonstrate that EGFP-Lun, like native Lunasin, is localized to the nucleus. Eight transgenic lines were mapped to specific chromosomes and EGFP-Lun transgenic line GEJ1-L2 was balanced in preparation for use in tumor suppression studies. In summary, we have created and characterized transgenic flies capable of overexpressing Lunasin under the control of the GAL4/UAS system. Localization of EGFP-Lunasin to the nucleus and data on the phenotypic consequence of its overexpression in flies is presented. Finally, reagents created as part of this thesis will aid experiments aimed at understanding the effects of Lunasin on benign and invasive tumors.

There is a great need in the transportation industry for high strength, high stiffness and lightweight materials with excellent dimensional stability. The use of these materials reduces fuel consumption and greenhouse gas emission as well as malfunctioning of components when subjected to fluctuating temperatures. Metal matrix composites (MMCs) are designed to meet these needs of transportation and other industries. However, their use is limited by lack of information on their thermal behaviour. In addition, reactions that occur in MMCs alter their microstructure and properties. These reactions have been widely investigated using X-ray Diffractometry (XRD) and electron microscopy (EM). However, these techniques cannot provide information such as charge transfer and local elemental structures in materials. Synchrotron X-ray Absorption Spectroscopy (XAS) could be used to identify reaction products in MMCs as well as provide information which XRD and EM cannot provide.<p> The thermal behaviour of Al-Mg alloy A535 containing fly ash particles as well as charge transfer and reactivity in particulate aluminium alloy metal matrix composites (MMCs) were investigated in this work. The materials studied were (i) Al-Cu-Mg alloy AA2618 and its composites reinforced with 10 and 15 vol.% alumina (Al2O3) particles and (ii) Al-Mg alloy A535 and its composites reinforced with a mixture of 5 wt.% fly ash and 5 wt.% silicon carbide, 10 wt.% and 15 wt.% fly ash. The investigative techniques used included Differential Scanning Calorimetry (DSC), Thermomechanical Analysis (TMA), Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), and synchrotron X-ray Absorption Spectroscopy (XAS).<p> The results obtained showed that the coefficient of thermal expansion (CTE) of A535 decreased with the addition of fly ash and silicon carbide. Also, the addition of these particles improved the dimensional stability of the alloy in that the residual strain, åp, cycling strain, åc, and CTE decreased. The results obtained from XAS measurements showed evidence of charge redistribution in the aluminium in AA2618 with the addition of alumina particles. The results obtained from XAS measurements showed evidence of charge redistribution in the aluminium in AA2618 with the addition of alumina particles. The addition of alumina particles into AA2618 increased the p-orbital population and also changed the surface chemistry of the matrix. It was also demonstrated that the XAS technique can be used to determine the presence of various oxides in industrial fly ash and spinel (MgAl2O4) in alumina and fly ash particles extracted from the MMCs.

Interfacial adhesion and friction are significant factors in determining the reliability of small-scale mechanical devices such as with MEMS and the computer head/disk interface (HDI). As the interface spacing becomes smaller, operational failure via stiction has become a growing concern in these systems. Fundamentally, interface failure is related to mechanical instability of the interface caused by capillary effects. When liquid is present in a small-scale interface, large concave meniscus curvatures often develop at the liquid-vapor interface, leading to negative pressures in the liquid film and large tensile forces on the surfaces. When the elastic restoring force cannot balance the capillary force, the interface will lose its stability and collapse into intimate contact (jump-on). In addition, when the elastic bodies are then pulled away from contact, separation may occur suddenly and is related to another form of instability (jump-off). The jump-on and jump-off behaviors determine the strength of interfacial adhesion. In this study, the interaction between two elastic bodies coupled via a small liquid bridge was investigated. Geometries of two half-spaces and two sphere contact were considered. Stable equilibrium configurations were determined, and the mechanical stability of the interface was examined. Jump-on and jump-off conditions were given out. Then the theory was applied to study the approach and detachment processes of two elastic spheres in the presence of a liquid bridge. Critical values of the control variables at jump-on and jump-off were found. The pull-off force was calculated as a measure of interfacial adhesion. The results provide insight on some experimental data in the literature.

Expansive soils are a worldwide problem especially in the regions where climate is arid or semi arid. These soils swell when they are exposed to water and shrink when they dry. Cyclic swelling and shrinkage of clays and associated movements of foundations may result in cracking of structures. Several methods are used to decrease or prevent the swelling potential of such soils like prewetting, surcharge loading, chemical stabilization etc. Among these, one of the most widely used method is using chemical admixtures (chemical stabilization). Cyclic wetting and drying affects the swell &ndash / shrink behaviour of expansive soils. In this research, the effect of cyclic swell &ndash / shrink on swell percentage of a chemically stabilized expansive soil is investigated. Class C Fly Ash is used as an additive for stabilization of an expansive soil that is prepared in the laboratory environment by mixing kaolinite and bentonite. Fly ash was added to expansive soil with a predetermined percentage changing between 0 to 20 percent. Hydrated lime with percentages changing between 0 to 5 percent and sand with 5 percent were also used instead of fly ash for comparison. Firstly, consistency limits, grain size distributions and swell percentages of mixtures were determined. Then to see the effect of cyclic swell &ndash / shrink on the swelling behavior of the mixtures, swell &ndash / shrink cycles applied to samples and swell percentages were determined. Swell percentage decreased as the proportion of the fly ash increased. Cyclic swell-shrink affected the swell percentage of fly ash stabilized samples positively.

In this work, feasibility of utilizing municipal incinerator fly ash (MIFA) of different sources as a substitute of raw materials for steel-making in a mini-mill was studied. Also studied included the efficacy of this mode of melting treatment and recycling. Under the condition of adding 1 wt% MIFA to scrap iron/scrap steel for partial replacement of lime, the L9 orthogonal arrays of Taguchi methods were utilized to investigate the effects of MIFA melting treatment of different sources by an electric arc furnace (EAF). Four experimental factors (i.e., scrap iron mass, lime mass, coke mass, and MIFA mass) were selected to study their effects on Pb leaching of EAF dust and slag. Test results for MIFA obtained from Plants K1, K2, and K3 show that EAF dust remains hazardous as it is originally a listed waste. On the other hand, slag so generated remains nonhazardous based on the TCLP results. The experimental results of EAF dust and slag were further subjected to the analysis of variance (ANOVA) and regular analysis. Using this process, the optimal operating conditions with respect to the leached Pb concentration would be as follows: (1) Plant K1(injection mode operation)--87 tons of scrap iron, 1.4 tons of lime, 0.4 ton of coke, and 0.9 ton of MIFA; (2) Plant K2(injection mode operation)--90 tons of scrap iron, 1.4 tons of lime, 0.7 ton of coke, and 1.1 tons of MIFA; (3) Plant K2(one-time-charge mode operation)--90 tons of scrap iron, 1.4 tons of lime, 0.9 ton of coke, and 0.7 ton of MIFA; (4) Plant K3(injection mode operation)--85 tons of scrap iron, 1.4 tons of lime, 0.7 ton of coke, and 0.9 ton of MIFA; and (5) Plant K3(one-time-charge mode operation)--87 tons of scrap iron, 1.5 tons of lime, 0.4 ton of coke, and 0.7 ton of MIFA. In this study, using MIFA from Plant K2 as an example, it was found that it required 29-35 kg of lime per ton of steel billets produced when MIFA was added. Under a normal operation of EAF steel-making, however, it required 35-45 kg of lime per ton of steel billets produced based on the past experience. In average, when MIFA is added, it needs only 32 kg of lime per ton of steel billets produced as compared to 40 kg of lime for regular steel-making. In other words, it would result in a reduction of 8 kg of lime per ton of steel billets produced by using this novel process. Based on an average monthly production of 20,973 tons of steel billets and a unit cost of 2,200 NT$ per ton of lime, a monthly saving of lime cost would be 369,125 NT$. Namely, about 4.4 million NT$ per year. In addition, it was also found that using this novel process to melt MIFA would not deteriorate the quality of steel billets and bars produced.

This thesis describes improvements on newly-discovered high-strength pozzolan-based materials fabricated via a low-cost chemical reaction that takes place between 90 and 115 ℃ for 3 to 24 hours. The reported results focus on pozzolan constituents acquired from Coal Combustion Products (CCPs) such as cenospheres, fly ash C and F, as well as bottom ash. The thesis reports on various types of these materials with specific gravity ranging from 0.5 to 1.6; compressive strength ranging from 300 to 3600 psi, and compressive modulus ranging from 50 to 240 ksi. In addition to their good mechanical properties under compression that are attractive for the building and construction industries, the materials further exhibit great potential for applications as energy absorption cores in sandwich construction that could extend their value in other industries including the automotive and aerospace industries. For example, the load-displacement curve exhibits a short elastic zone followed by a long load-plateau; while the materials crush through a controlled vertical cracking process. Additionally, an attempt was made to further decrease the manufacturing cost of the material by investigating incorporation of chemicals that accelerates dehydration of the mixture. One such successful chemical reported in this thesis is aluminum phosphate; while it is not conclusive how the chemical improves any major property.

The presented doctoral thesis “Fly ash impact in forest ecosystems in Northeastern Germany - an assessment and regionalization approach” intends to (a) test if the field assessment of ferrimagnetic susceptibility can be used as cost efficient method to get information on fly ash deposition impacted chemical site properties. (b) develop a regionalization approach to bridge the gap from plot-wise assessed data to spatial management information. The thesis is a follow-up of extensive research activities by the Institute for Soil Science and Site Ecology on industrial deposition in Dübener Heide and Upper Lusatian region which started in the early 1960ies and were intensified from the middle of the 1990ies on. A central topic of these research activities was the assessment of the impact of fly ash deposition on chemical soil properties. A major challenge was to transfer the assessed chemical characteristics from plot to region and to aggregate the measured values to provide an information basis, which can be used for a site potential and risk oriented forest management. This challenge was picked up by the joint research project “ENFORCHANGE” (FKZ 0330634 K, German Federal Ministry of Education and Research). The presented thesis was carried out in the frame of this project during the period 2005 - 2009. The thesis was conceived as cumulative work, which includes ten papers in total. Five articles are published in peer-reviewed journals (ISI listed, 1 paper still in revision), and five are part of books or conference proceedings. • Chapter 1 “Introduction” gives an overview on the motivation, idea and structure of the thesis. • In chapter 2 “Aims and Scope of the presented work” information on the background and frame of the study within the project ENFORCHANGE is given. • Chapter 3 “Background and State of the Art” deals with the history of fly ash deposition in the model region Dübener Heide. • Chapter 4 “Material and Methods” gives information on fly ash and presents the spatial assessment design and the hereon based approaches for up-scaling and correlation of magnetic susceptibility with selected chemical characteristics. • Chapter 5 “Results” presents results of the spatial modeling and linear regression based approach to use ferrimagnetic susceptibility for predicting the contents of selected base cations, selected acid and heavy metal cations and Black Carbon. • Chapter 6 “Discussion and Conclusions” compares the assumptions and findings in the different articles, discusses contradictory findings and open questions and provides a comprehensive evaluation of the outcomes. Final conclusions are drawn and an outlook is given. A key finding of the thesis is that the industrial complex Bitterfeld was the most important source of fly ash deposited in the model region Dübener Heide. The power plant Zschornewitz plays only a minor role contrary to the research hypothesis formulated in ENFORCHANGE. Related to the targets of the thesis, spatial variation of magnetic susceptibility was predicted with high precision by a multiple linear regression model. A slightly differing set of model parameters  according to their explanatory value for three selected depth levels  improved the prediction quality. The selection of the parameters supported understanding the major drivers for magnetic particle deposition, storage, and vertical displacement in the forest soils. Humus layer (depth level 6-10 cm), horizontal distance to Bitterfeld and soil type (Podzol, semi-terrestrial sites) were the most important variables. These variables point to a slowed-down humus dynamic, which causes the accumulation of fly ash in the humus layer. In depth level 11 – 15 cm, variables such as “aspect” gain in importance, which describe the exposure against the major wind direction and thus indicate the probability and of deposition. For the mineral horizon (depth level 21-25 cm), exposition and especially stand properties are most important. The latter gives evidence for the intensity of deposition caused by surface roughness. Therefore, the variables “coniferous” and “mixed” stands were highly relevant for the model. Variable correlations between mass susceptibility and selected base cations, acid cations and heavy metals have been found. When using a linear regression model, a prediction of Ca and Mg and of Mn was possible. The model performance was lower for Fe, Al, Cd and Black Carbon. A possible reason was the use of different plot types: the assessment of magnetic susceptibility and chemical soil properties was well harmonized at the ENFORCHANGE plots considering the sampling material and sampling location. A comparable harmonization could not be achieved at a number of monitoring plots, which were included into the analysis to broaden the data base. Comparing the results from the linear regression model based prediction with the results achieved by multiple regression based spatial modeling lead to the conclusion that the mul¬tiple regression approach is more promising: by using other model parameters such as orographic, climatic or stand parameters together with magnetic susceptibility, the prediction quality of the deposed agents could be improved and small scale variations in nutrient potentials and risks driven by fly ash deposition could be better recognized and made available for forest management decisions. / Die vorgelegte Doktorarbeit “Fly ash impact in forest ecosystems in Northeastern Germany - an assessment and regionalization approach” (Flugascheeinträge in Waldökosysteme in Nordostdeutschland  ein Erfassungs- und Regionalisierungsansatz) verfolgte die Ziele (a) zu testen, ob sich die Erfassung der ferrimagnetischen Suszeptibilität eignet, um kosteneffizient quantitative und / oder qualitative Informationen zu den eingetragenen Flugaschemengen und den in der Folge veränderten bodenchemischen Potenzialen zu erheben (b) zu testen, ob der Indikator „ferrimagnetische Suszeptibilität“ genutzt werden kann, um Informationen über Flugascheeinträge von der punktbezogenen Erfassung auf einen regionalen Maßstab hoch zu skalieren. Grundlage dieser Zielstellungen sind Forschungsarbeiten zu der Frage der langfristigen Wirksamkeit und ökologischen Bedeutung von Industrieexhalationen auf Waldökosysteme, die am Institut bereits in den 1960ziger Jahren begonnen wurden und verstärkt seit Mitte der 1990ziger Jahre fortgeführt wurden. Auf ihrer Basis wurde die Herausforderung eines kostengünstigen und flächenbezogenen Erhebungsansatzes identifiziert und formuliert. Die vorgelegte Arbeit ordnete sich in diese Forschungsarbeiten ein und führte sie im Rahmen des Verbundforschungsvorhabens ENFORCHANGE ((FKZ: 0330634 K, Bundesministerium für Bildung und Forschung) von 2005 - 2009 fort. Die Doktorarbeit ist als kumulative Arbeit angelegt, im Rahmen derer insgesamt 10 Publikationen zusammengefasst wurden. Davon sind 5 in internationalen Journalen bereits publiziert, akzeptiert oder in einem Fall in Begutachtung; 5 weitere Publikationen wurden ergänzend und auf speziellere Themen bezogen in Proceedings oder Buchbeiträgen publiziert. Die Arbeit gliedert sich in 5 Abschnitte: • Kapitel 1 (Einleitung) gibt einen kurzen Überblick zur Motivation und Struktur der Doktorarbeit. • In Kapitel 2 (Ziele und Rahmen der Arbeit) wird der Arbeitsansatz im Rahmen des Verbundforschungsvorhabens ENFORCHANGE vorstellt. • Kapitel 3 umfasst eine Auswertung von Veröffentlichungen zur Geschichte und den ökologischen Auswirkungen der Flugascheeinträge am Beispiel der Modellregion Dübener Heide. • In Kapitel 4 wird der methodische Ansatz der Arbeit vorgestellt, der von einem Vortest zur Eignung der Erfassung der magnetischen Suszeptibilität über die Ableitung eines flächigen Erhebungsansatzes bis hin zur Frage der Modellbildung und Korrelation mit chemischen Kenngrößen reicht. • Kapitel 5 beinhaltet die Ergebnisse der räumlichen Modellbildung und der Korrelation der magnetischen Suszeptibilität mit ausgewählten Basen-, Säure- und Schwermetallkationen sowie mit Schwarzem Kohlenstoff. • Kapitel 6 diskutiert, vergleicht und bewertet die Ergebnisse der den Veröffentlichungen zugrunde liegenden Studien und zieht ein abschließendes Resumé. Ein Schlüsselergebnis der vorgelegten Arbeit belegt, dass entgegen der ursprünglichen Arbeitshypothese des Projektverbundes ENFORCHANGE nicht das mehr als 100 Jahre alte Kraftwerk Zschornewitz die wesentliche Quelle für die Flugascheeinträge in der Modellregion Dübener Heide war, sondern der räumlich entfernter gelegene, aber deutlich größere Industriekomplex Bitterfeld. Bezogen auf die Zielsetzung der vorgelegten Arbeit, konnte mithilfe multipler Regressionsverfahren und auf Basis von Feldaufnahmen der ferrimagnetischen Suszeptibilität in einem regelmäßigen Stichprobenraster ein hoch auflösendes räumliches Modell gebildet werden. Unter Berücksichtigung weiterer Modellparameter, die schrittweise hinsichtlich ihres Erklärungswertes ausgewählt wurden, konnten mikrotopographische und vegetationsbedingte Informationen genutzt werden, um die räumliche Variabilität des magnetischen Signals differenziert darzustellen. Damit ergibt sich eine Planungsgrundlage, die die bisher genutzte, auf Waldschadensansprachen basierende Stratifizierung in Zonen unterschiedlicher Eintragsintensität mit Bezug zur Planungseinheit deutlich detaillierter untersetzt. Der Versuch, auf Flugascheeintragsmengen, respektive -vorräte zu schließen ließ sich hingegen auf Basis der verfügbaren Daten nicht umsetzen. Die Korrelationsbeziehungen der von Volumen- in den Massenbezug umgerechneten Suszeptibilität mit Basen-, Säure und Schwermetallkationen sowie Schwarzem Kohlenstoff fielen heterogen aus. Eine gute Vorhersage auf Basis eines linearen Regressionsmodells konnte für Ca, Mg und Mn getroffen werden, wohingegen die Modellqualität für Fe, Al sowie Cd und Schwarzen Kohlenstoff deutlich schlechter zu beurteilen war. Dies ergab sich zum einen aus der verfügbaren Datenbasis, die keine durchgängige Harmonisierung für die Erhebungen der Suszeptibilität und der chemischen Kennwerte erlaubte. Zum anderen geht diese Erkenntnis mit Ergebnissen aus der Regionalisierung einher, die einen Einbezug weiterer Modellparameter und die Nutzung multipler anstelle linearer Regressionsmodelle nahe legt.

This is an in-depth analysis of coal fire burning power plants, their effects on human health and the environment. It also employed case study data from Tampa Electric Company’s Big Bend facility to examine environmental infractions at that facility. Tampa Electric Company’s Big Bend Utility Plant, violated the Clean Air Act, which led to a lawsuit filed by the Department of Justice on behalf of the United States Environmental Protection Agency and the Florida Department of Environmental Protection in 1997. This case study details the lawsuit, and subsequent settlement as well as Tampa Electric Company’s record of compliance since 2000. This study examines the area surrounding the plant, and impacts the facility may cause local residents and the ecosystem in this part of Florida. Several questions are explored in this case study revolving around environmental justice and environmental racism. Did the actions taken by the Department of Justice in 2000 on behalf of the Environmental Protection Agency and the people of the State of Florida through its Department of Environmental Protection fit the corporate crimes that Tampa Electric were accused of in the lawsuit? Has this company been compliant with state and federal law as required by the settlement? Finally, has the Tampa Electric Company maintained their commitment to provide environmental justice for the communities surrounding the Big Bend Utility Plant or would their actions fit a definition for the crime of corporate environmental violence?