Thesis (Ph. D.)--University of California, Los Angeles, 2004. / Includes bibliographical references (p. 222-229). Also available on the Internet.

Submitted by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2015-02-19T13:03:29Z No. of bitstreams: 5 lindomar.pdf: 4197857 bytes, checksum: 529e21e13238b7b71e5ddffb7f4e7b91 (MD5) license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2111 bytes, checksum: f5c843397da71f5d32b775fd8c4cbf56 (MD5) / Approved for entry into archive by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2015-02-20T09:29:04Z (GMT) No. of bitstreams: 5 lindomar.pdf: 4197857 bytes, checksum: 529e21e13238b7b71e5ddffb7f4e7b91 (MD5) license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2111 bytes, checksum: f5c843397da71f5d32b775fd8c4cbf56 (MD5) / Made available in DSpace on 2015-02-20T09:29:04Z (GMT). No. of bitstreams: 5 lindomar.pdf: 4197857 bytes, checksum: 529e21e13238b7b71e5ddffb7f4e7b91 (MD5) license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2111 bytes, checksum: f5c843397da71f5d32b775fd8c4cbf56 (MD5) Previous issue date: 2013-12-17 / Eletrodos constitu?dos de ?-PbO2 foram preparados via eletrodeposi??o, mediante inclus?o dos ?ons Fe3+ e F- na mistura precursora, usando como substratos tela de a?o (ASTM 316) e tecido de carbono, visando a produ??o eletroqu?mica de oz?nio (PEO) em um reator filtro-prensa conduzida na aus?ncia de eletr?lito l?quido. A an?lise das micrografias de MEV para ambos substratos revelaram que em baixas concentra??es dos dopantes houve a forma??o de gr?os bem definidos com uma ?rea superficial uniforme. A an?lise de Raios-X para ambos substratos revelou o desfavorecimento da forma??o da fase ?-PbO2 para a maioria da concentra??o dos dopantes. Estudos cronopotenciom?tricos evidenciaram a estabilidade dos anodos quando sujeitados a intensa evolu??o de gases. Para o eletrodo dopado com 1 mM do ?on Fe3+, a efici?ncia de corrente da PEO foram de 10% e 9,5% com uma velocidade de gera??o de oz?nio de 1,35 g h-1 e 1,40 g h-1 para os substratos de tela de a?o e de tecido de carbono, respectivamente. Os resultados encontrados s?o promissores indicando uma viabilidade do uso desses eletrodos para aplica??o no tratamento de ?gua, por isso, empregou-se o oz?nio produzido eletroquimicamente para tratar ?gua residu?ria proveniente da produ??o de biodiesel na planta piloto da UFVJM. O tratamento oxidativo da ?gua residu?ria foi conduzido num reator em coluna de bolhas via rea??o direta (oz?nio molecular), indireta (radical hidroxila) e mista (O3/HO?) manipulando-se o pH do meio reacional.A caracteriza??o do efluente ozonizado foi efetuada monitorando-se o processo de degrada??o da mat?ria org?nica dissolvida via espectrofotometria. A cin?tica do processo de degrada??o seguiu o modelo de pseudo-primeira ordem. Foi verificado que a constante cin?tica sofre varia??o com o tempo de ozoniza??o revelando, portanto, uma varia??o da recalcitr?ncia com o tempo de rea??o. A demanda de energia requerida no processo de ozoniza??o foi caracterizada por uma energia el?trica por ordem (EEO) de 139 kW h m-3 ordem-1. / Disserta??o (Mestrado) ? Programa de P?s-Gradua??o em Qu?mica, Universidade Federal dos Vales do Jequitinhonha e Mucuri, 2013. / ABSTRACT Electrodes comprised of ?-PbO2 were prepared by electrodeposition, by moans of the inclusion of Fe3+ and F- ions in the precursor mixture, using as substrates steel screen (ASTM 316) and carbon cloth in order to produce ozone in an filter-press electrochemical reactor conducted in the absence of liquid electrolyte. The analysis of SEM micrographs revealed that for both substrates at low dopants concentrations resulted in the formation of well-defined grains with a uniform surface area. X-rays analysis for both substrates showed the inhibition of formation of the ?-PbO2 phase for most of the dopant concentration. Cronopotenciometric studies revealed a good stability of the anodes when they were subjected to the intense gas evolution. For the electrode doped with 1 mM Fe3+, the current efficiency of EOP were 10% and 9.5% for an ozone generation rate of 1.35 g h-1 and 1.40 g h -1 using the steel screen and carbon cloth substrates, respectively. These results are promising, indicating a feasibility of using these electrodes for application in water purification, so the electrochemical ozone produced was applied to treat residuary water obtained from the biodiesel produced in the pilot plant of UFVJM. The oxidative chemical treatment of wastewater was conducted in a bubble column reactor via direct (molecular ozone), indirect (hydroxyl radical) and mixed (O3/HO?) oxidation reaction thrush manipulating the pH of the reaction medium. The characterization of ozonated effluent was assessed by means of monitoring the degradation of the dissolved organic matter using spectrophotometry. The kinetics of the degradation process followed a pseudo-first order model. It was found that the rate constant changes on the ozonation time thus indicating a recalcitrance variation with the reaction time. The energy demand required in the ozonation process was described by an electric energy per order (EEO) of 139 kW h m-3 order-1.

Os materiais de estrutura perovskita compreendem um vasto grupo de compostos cuja estrutura na sua forma mais simples pode ser representada pela fórmula química ABO3. Uma das principais vantagens que a estrutura perovskita apresenta é o alto grau de flexibilidade em acomodar uma grande variedade de átomos nos sítios A e B, permitindo um maior controle de suas propriedades físicas e químicas bem como a manutenção de sua estrutura básica, mesmo para altas concentrações de átomos substituintes. Devido estas propriedades, estes materiais têm sido aplicados com sucesso como capacitores, varistores, fotoeletrodos, memóriasferroelétricas e sensores de gases. Nas últimas décadas, tem sido reportada a utilização do titanato de estrôncio (SrTiO3, ST) na forma de filmes finos e espessos como sensor de gás oxigênio em altas temperaturas (>500 °C). Recentemente, foi mostrado que o titanato de estrôncio dopado com Fe apresentava uma excelente sensibilidade ao gás ozônio. Entretanto, neste trabalho, somente uma composição foi caracterizada e nem todas as propriedades importantes em relação a esta aplicação foram completamente exploradas. Neste contexto, esta tese de doutorado teve como objetivo verificar o efeito da substituição do átomo de estrôncio pelo lantânio e do titânio pelo Ferro no composto SrTiO3 na forma de pó e filmes finos nanoestruturados com a finalidade de verificar o efeito destas substituições nas propriedades sensoras do material. Inicialmente, com o objetivo de avaliar a influência da adição de La na estrutura do composto ST, amostras na forma de pó do sistema Sr1-xLaxTiO3.(SLT) foram preparadas através do método dos precursores poliméricos. Posteriormente, pelo mesmo método, foram sintetizadas amostras do sistema SrTi1-xFexO3 (STF) e Sr1-XLaxTi1-yFeyO3 (SLTF). A partir das amostras na forma de pó e na forma de solução, filmes finos e espessos foram respectivamente obtidos através das técnicas de deposição por feixe de elétrons (EBD) e spin-coating (SC). As amostras nanoestruturadas na forma de pó e na forma de filmes foram caracterizadas por difração de raios X, espectroscopia de absorção de raios X (XANES) na borda K do Ti e do Fe e espectroscopia de fotoelétrons excitados por raios X (XPS). A análise morfológica foi realizada através das técnicas de microscopia eletrônica de varredura (MEV) e microscopia de força atômica (MFA). As amostras do sistema STF e SLTF na forma de filmes finos foram avaliadas em relação à sensibilidade aos gases O3, NO2, NH3 e CO. Os resultados indicaram que os filmes do sistema SLTF depositados pela técnica de deposição por feixe de elétrons apresentam uma maior sensibilidade ao gás ozônio, enquanto o filme de mesma composição depositado pelo método de spin-coating apresentou uma melhor estabilidade e tempo de recuperação em relação a este mesmo gás. / The perovskite structure materials comprise a large group of compounds with the structure in simple form can be represented by the ABO3. chemical formula. The main advantage that the perovskite structure presents is the high degree of flexibility to accommodate a wide variety of atoms in sites A and B, allowing a greater control of physical and chemical properties of the material, maintaining its structure even for a high concentrations of substituent\'s. Due to these properties, these materials have been successfully applied as capacitors, varistors, photoelectrodes, ferroelectric memories and gas sensors. In the last decade, strontium titanate (SrTiO3, ST) in the form of thin and thick films have been reported as oxygen gas sensor at higher temperatures (> 500 °C). Recently, strontium titanate doped with Fe was used as the first ozone sensor. However, the work was carried out only with a certain composition and some important properties for this application have not been fully exploited. In this context, this PhD thesis aimed to the synthesis of strontium titanate system in powder form and nanostructured thin films with the substitution of Sr for La and Ti for Fe. In order to verify the effect of these substitutions in material properties initially Sr1-xLaxTiO3 (SLT) samples were prepared in powder form by the polymeric precursor method in order to evaluate the influence of the addition of La in the structure of the compound ST. Subsequently, samples were synthesized from SrTi1-x Fex O3 (STF) and Sr1-XLaxTi1-yFeyO3 (SLTF) systems through the polymeric precursors, which were used for the deposition of thin and thick films, which were respectively obtained through electron beam deposition techniques (EBD) and spin-coating (SC). Samples in the form of nanostructured powder and thin films were characterized by X-ray diffraction, X-ray absorption spectroscopy (XANES) at Ti and Fe K-edges and by X-ray photoelectron spectroscopy (XPS). Morphological analysis was performed using the scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The STF and SLTF samples in a thin film form were evaluated towards their sensitivity to O3, NO2, NH3 and CO gases. The results indicated that SLTF films deposited by electron beam deposition technique exhibit higher sensitivity to ozone gas. However the same composition deposited by spin-coating showed a better stability and recovery time relative to the same gas.

The purpose of the study is to explore the possibility to use the experimental prototyping technique called Wizard of Oz as a requirements engineering technique in multimedia development with a focus on how to capture (and test) requirements for system responses in on-going GUI dialogues between user and system. The Wizard-of-Oz technique makes it possible to try interactive prototypes with users or in the development team without needing any programming to be conducted first. In a tourism context interactive prototypes made in the Wizard-of-Oz system called Ozlab were used to produce live answers to tourists. The prototyped information kiosk was offered as a complement to the already running tourist information website. The available surveys and web statistics regarding tourist information system could not provide non-functional requirements. Instead, three interviews and one observation were conducted, leading up to the four experiments where the WOz technique was tried as a requirements engineering technique in addition to the traditional data collection methods. The results of this study show how a graphical Wizard-of-Oz tool can be used as a complement to traditional requirements elicitation methods. The study also shows limitations to WOz based requirements engineering work; subject experts are needed in the wizard team, for example. The study also resulted in several developments of the experimental tool itself; the web feature was exploited much further than originally conceived by the Ozlab developers.

Magister Artium (Psychology) - MA(Psych) / South Africa's Language-in-Education Policy is one of additive multilingualism, but in reality this policy is not adhered to, in that most black children are being educated through the medium of English from Grade 4. This type of instruction affects the development of academic language proficiency in their primary language, as these children are not engaging in cognitively demanding tasks in their primary or first language. The Woodcock Muñoz Language Survey (WMLS) is a test to assess academic language proficiency in Additive Bilingual Education, and is extensively used in the United States of America (USA) for this purpose. It is important to note that the proposed study is a sub-study of a larger study, in which the original WMLS (American-English version) was adapted into English and Xhosa, to be used in South Africa to assess additive bilingual programmes. For this sub-study, the researcher was interested in examining the overall equivalence of the adapted English version of the WMLS. Owing to insufficient tests evaluating academic language proficiency in the South African context, the significance, as well as the overall aim, of the study is to ensure that the issues of group difference and item bias have been assessed to ensure that the adapted English version of the WMLS is suitable to be used across English first-language and Xhosa first-language speakers. Because this is a sub-study, the researcher (of the sub-study) has conducted an exploratory quantitative study with the use of Secondary Data. The researcher has used the framework of equivalence as a theoretical framework in order to examine the research question. Given the use of existing data, the procedures of the collection of the data by the researcher of the larger study have been outlined in the Methodology section of the present study. The sample consisted of 198 English and 197 Xhosa first-language speakers. / South Africa

No description available.

Natural Language (NL) mechanics are seemingly underutilized within modern game development and may be capable of inducing unexpected levels of agency within its users. This study focuses specifically on NL Input (NLI) and examines its capability of inducing an experience of agency, control, and freedom through an interactive fiction with a database searching context. To get a more nuanced result, a version of the artefact but with an NL Understanding (NLU) system will also be tested to create a baseline. Due to the limited time and resources, the NLU version will be employing the Wizard of Oz (WOZ) method. In total, five NLI tests and four NLU tests were performed and interview results indicated full experience of control and mixed experience of freedom and agency in both versions. Possible causes include the participants‘ genre preference and the limited content in the artefact.

The purpose of the study is to elaborate the Wizard-of-Oz (WOz) technique by using it at a distance for design and elicitation of requirements and requests as part of a Participatory Design process (i.e. remotely - where the wizard and participant are located in different geographical locations). This study aims at evaluating what the salient traits in the participatory discussions are by using the WOz technique at a distance, what similarities there are in function or expression between non-verbal expressions in GUI-ii and ordinary physical interviews, and how WOz at a distance fit into the current state of the Participatory design field. In an early design phase of a project, ten experimental WOz-at-a-distance sessions and five face-to-face interviews were held. The experimental sessions’ focus was on the codesign of early drafts of the interaction design for a digital tool for the planning of crisis management exercises. The interaction design was developed with a WOz system. The sessions offered co-design between a designer and a co-designer by having joint access to a graphical user interface (GUI), and to verbally communicate with each other. These sessions had a twofold approach where the focus could shift seamlessly between design and walkthrough. The results from this study show that WOz at a distance, as used in this study, offers an approach for a seamless switch between design-phase and evaluation-phase in the form of walkthroughs. Having the GUI present as a boundary object whilst discussing the GUI and its interaction design enables a natural way of designing and evaluating the functions and interaction design of the upcoming system. The results also show that even if the participatory discussion lacks the face-to-face meeting between the interlocutors there are some similarities between those discussions and the face-to-face interviews in function and use of non-verbal expressions. Participatory discussions, when using WOz technique at a distance is a method where the participatory mindset is prominent and is a flexible approach that fits well with the overarching views on Participatory design.

Master of Regional and Community Planning / Department of Landscape Architecture/Regional and Community Planning / John W. Keller / During the Industrial Revolution, economist Alfred Marshall published his classic book entitled Principles of Economics, in which he suggests that the external economies of scale (positive externalities) produced by the clustering of many small innovative businesses could rival the internal economies of scale achieved by a few large vertically-integrated businesses. The distinction between these two models of industrial organization, one based on many small innovative firms and the other based on a few large conglomerated firms, is the basis of cluster development theory. This distinction has been further developed in the economic development literature through the significant contributions of Schumpeter (creative destruction), Jacobs (necessary inefficiency), and Porter (diamond model). Modern cluster development theory expands upon the work of these classic theorists. Contributions relevant to this study include Markusen’s cluster typologies, Press and Feldman’s cluster lifecycle phases, Munnich’s rural knowledge cluster framework, and Doloreux’s case study of a rural innovation system. This case study applies the lessons of cluster development theory to an emerging cluster of businesses in Wamego, Kansas that share the common Wizard of Oz theme. While this cluster is not a “traditional” cluster (it does not benefit from positive externalities relating to product or process), it does create positive marketing externalities that significantly affect the local economy. This report names the cluster (Oz Cluster), identifies the typological structure of the cluster (hub and spoke), profiles the key actors and decisions which are shaping this emerging cluster, and concludes with lessons learned from the Oz Cluster and alternative scenarios for further cluster development. The Oz Cluster model of economic development demonstrates how communities can profit from niche-based tourism. Such economic development must focus on the establishment and growth of regionally competitive businesses with strategic competitive advantages. Alternative scenarios for further cluster development include: 1) expand the Oz theme; 2) diversify the cluster; and 3) maintain current level of success.

No description available.