Feedback control of MEMS devices has the potential to significantly improve device performance and reliability. One of the main obstacles to its broader use is the small number of on-chip sensing options available to MEMS designers. A method of using integrated piezoresistive sensing is proposed and demonstrated as another option. Integrated piezoresistive sensing utilizes the inherent piezoresistive property of polycrystalline silicon from which many MEMS devices are fabricated. As compliant MEMS structures flex to perform their functions, their resistance changes. That resistance change can be used to transduce the structures' deflection into an electrical signal. This dissertation addresses three topics associated with integrated piezoresistive sensing: developing an empirical model describing the piezoresistive response of polycrystalline-silicon flexures, designing compliant MEMS with integrated piezoresistive sensing using the model, and implementing feedback control using integrated piezoresistive sensing. Integrated piezoresistive sensing is an effective way to produce small, reliable, accurate, and economical on-chip sensors to monitor compliant MEMS devices. A piezoresistive flexure model is presented that accurately models the piezoresistive response of long, thin flexures even under complex loading conditions. The model facilitates the design of compliant piezoresistive MEMS devices, which output an electrical signal that directly relates to the device's motion. The piezoresistive flexure model is used to design a self-sensing long displacement MEMS device. Motion is achieved through contact-aided compliant rolling elements that connect the output shaft to kinematic ground. Self-sensing is achieved though integrated piezoresistive sensing. An example device is tested that demonstrates 700 micrometers of displacement with a sensing resolution of 2 micrometers. The piezoresistive microdisplacement transducer (PMT) is a structure that uses integrated piezoresistive sensing to monitor the output displacement of a thermomechanical inplane microacutator (TIM). Using the PMT as a feedback sensor for closed-loop control of the TIM reduced the system's response time from 500~$mu$s to 190~$mu$s, while maintaining a positioning accuracy of $pm$29~nm. Feedback control of the TIM also increased its robustness and reliability by allowing the system to maintain its performance after it had been significantly damaged.

<p>Obtaining full-field \emph{dynamic} material state awareness would have profound and wide-ranging implications across many fields and disciplines. For example, achieving dynamic state awareness in soft tissues could lead to the early detection of pathophysiological conditions. Applications in geology and seismology could enhance the accuracy of locating mineral and hydrocarbon resources for extraction or unstable subsurface formations. Ensuring safe interaction at the human-machine interfaces in soft robotic applications is another example. And as a final representative example, knowing real-time material dynamics in safety-critical structures and infrastructure can mitigate catastrophic failures. Because many materials (e.g., carbon fiber-reinforced polymers composites, ceramic matrix composites, biological tissues, cementitious and geological materials, and nanocomposites) exhibit coupling between their mechanical state and electrical transport characteristics, self-sensing via the piezoresistive effect is a potential gateway to these capabilities. While piezoresistivity has been mostly explored in static and quasi-static conditions, using piezoresistivity to achieve dynamic material state awareness is comparatively unstudied. Herein lies the significant gap in the state of the art: the piezoresistive effect has yet to be studied for in-situ dynamic sensing.</p> <p><br></p> <p>In this thesis, the gap in the state of the art is addressed by studying the piezoresistive effect of carbon nanocomposites subject to high-rate and transient elastic loading. Nanocomposites were chosen merely as a representative self-sensing material in this study because of their ease of manufacturability and our good understanding of their electro-mechanical coupling. Slender rods were manufactured using epoxy, modified with a small weight fraction of nanofillers such as carbon black (CB), carbon nanofibers (CNFs), and multi-walled carbon nanotubes (MWCNTs), and subject to loading states such as steady-state vibration at structural frequencies ($10^2-10^4$ Hz), controlled wave packet excitation, and high-strain rate impact loading in a split-Hopkinson pressure bar. This work discovers foundational principles for dynamic material state awareness through piezoresistivity. </p> <p><br></p> <p>Three major scholarly contributions are made in this dissertation. First, an investigation was pursued to establish dynamic, high-strain rate sensing. This investigation clearly demonstrated the ability of piezoresistivity to accurately track rapid and spatially-varying deformation for strain rates up to $10^2$ s$^{-1}$. Second, piezoresistivity was used to detect steady-state vibrations common at structural frequencies. Utilizing simple signal processing techniques, it was possible to extract the excitation frequency embedded into the collected electrical measurements. The third contribution examined the dynamic piezoresistive effect through an array of surface-mounted electrodes on CNF/epoxy rods subject to highly-controlled wave packet excitation. Electrode-spacing adjustments were found to induce artificial signal filtering by containing larger portions of the injected wave packets. The strain state in the rod was found after employing an inverse conductivity-to-mechanics model, thereby demonstrating the possibility of deducing actual in-situ strains via this technique. A digital twin in ABAQUS was constructed, and an elastodynamic simulation was conducted using identical dynamic loading, the results of which showed very good agreement with the piezo-inverted strains. </p> <p><br></p> <p>This work creates the first intellectual pathway to full-field dynamic embedded sensing. This work has far-reaching potential applications in many fields, as numerous materials exhibit self-sensing characteristics through deformation-dependent changes to electrical properties. Therefore, \emph{piezoresistive elastodynamics} has the incredible potential to be applied not just in structural applications but in other potentially innovated applications where measuring dynamic behavior through self-sensing materials is possible.  </p>

The strain and damage sensing abilities of randomly oriented multi-walled carbon nanotubes (MWCNTs) dispersed in the polymer binder of energetic composites were experimentally investigated. Ammonium perchlorate (AP) crystals served as the inert energetic and atomized aluminum as the metallic fuel, both of which were combined to create a representative fuel-oxidizer filler often used for aerospace propulsive applications. MWCNTs were dispersed within an elastomer binder of polydimethylsiloxane (PDMS), and hybrid energetics were fabricated from it, with matrix material comprised of the identified fillers. The nanocomposites were characterized based on their stress-strain response under monotonic uniaxial compression to failure, allowing for the assessment of effects of MWCNTs and aluminum powder on average compressive elastic modulus, peak stress, and strain to failure. The piezoresistive response was measured as the change in impedance with applied monotonic strain in both the mesoscopic and microscopic strain regimes of mechanical loading for each material system, as well as under ten cycles of applied compressive loading within those same strain regimes. Gauge factors were calculated to quantify the magnitude of strain and damage sensing in MWCNT-enhanced material systems. Electrical response of single-cycle thermal loading was explored with epoxy in place of the elastomer binder of the previously discussed studies. Piezoresistive response due to microscale damage from thermal expansion was observed exclusively in material systems enhanced by MWCNTs. The results discussed herein validate structural health monitoring (SHM) applications for embedded carbon nanotube sensing networks in polymer-based energetics under unprecedented cyclic loads. / Master of Science / The ability to characterize both deformation and damage in real time within materials of high energetic content, such as solid rocket propellant, is of great interest in experimental mechanics. Common energetic ammonium perchlorate, in the fonn of crystal particles, was embedded in polymer binders (ie PDMS and epoxy) and investigated under a variety of me­chanical and thermal loads. Carbon nanotubes, conductive tube-shaped molecular structures of carbon atoms, have been demonstrated in prior proofs of concept to induce substantial electrical response change when dispersed in composites which are experiencing strain. With the introduction of carbon nanotubes in the energetic composites investigated herein, the electrical response of the material systems was measured as a change in impedance with applied strain. Elastomer-bonded energel.ks were t.esl.ed under monotonic compression and cyclic compression, and expanded exploration was done on these material systems with the additional particulate of aluminum powder, allowing for varied particulate sizes and conductivity enhancement of the overall composite. The magnitude of the resulting piezoresistive change due to strain and microscale damage was observed to increase dramatically in material systems enhanced by MWCNT networks. Local heating was used to explore thermal loading on epoxy-bonded energetic material systems, and sensing of permanent damage to the­ material through its CNT network was proven through a permanent change in the electrical response which was exclusive to the CNT-enhanced material systems. These results demon­strate valid structural health monitoring (SHM) applications for embedded carbon nanotube sensing networks in particulate energetic composites, under a variety of load cases.

The study of self-sensing cementitious materials is a constantly expanding topic of study in the materials and civil engineering fields and refers to the creation and utilization of cement-based materials (including cement paste, cement mortar, and concrete) that are capable of sensing (i.e. measuring) stress and strain states without the use of embedded or attached sensors. With the inclusion of electrically conductive fillers, cementitious materials can become truly self-sensing. Previous researchers have provided only qualitative studies of self-sensing material stress-electrical response. The overall goal of this research was to modify and apply previously developed predictive models on cylinder compression test data in order to provide a means to quantify stress-strain behavior from electrical response. The Vipulanandan and Mohammed (2015) stress-resistivity model was selected and modified to predict the stress state, up to yield, of cement cylinders enhanced with nanoscale iron(III) oxide (nanoFe2O3) particles based on three mix design parameters: nanoFe2O3 content, water-cement ratio, and curing time. With the addition of a nonlinear model, parameter values were obtained and compiled for each combination of nanoFe2O3 content and water-cement ratio for the 28-day cured cylinders. This research provides a procedure and lays the framework for future expansion of the predictive model.

Polymer bonded explosives (PBXs) are composites comprised of energetic crystals with a very high energy density surrounded by a polymer binder. The formation of hotspots within polymer bonded explosives can lead to the thermal decomposition and initiation of the energetic material. A frictional heating model is applied at the mesoscale to assess the potential for the formation of hotspots under low velocity impact loadings. Monitoring of the formation and growth of damage at the mesoscale is considered through the inclusion of a piezoresistive carbon nanotube network within the energetic binder providing embedded strain and damage sensing. A coupled multiphysics thermo-electro-mechanical peridynamics framework is developed to perform computational simulations on an energetic material microstructure subject to these low velocity impact loads. With increase in impact energy, the model predicts larger amounts of sensing and damage thereby supporting the use of carbon nanotubes to assess damage growth and subsequent formation of hotspots. The framework is also applied to assess the combined effects of thermal loading due to prescribed hotspots with inertial effects due to low velocity impact loading. It has been found that the present model is able to detect the presence of hotspot dominated regions within the energetic material through the piezoresistive sensing mechanism. The influence of prescribed hotspots on the thermo-electro-mechanical response of the energetic material under a combination of thermal and inertial loading was observed to dominate the lower velocity impact response via thermal shock damage. In contrast, the higher velocity impact energies demonstrated an inertially dominated damage response. Quantifying the piezoresistive effect derived from embedding carbon nanotubes in polymers remains a challenge since these nanocomposites exhibit significant variation in their electro-mechanical properties depending upon factors such as CNT volume fraction, CNT dispersion, CNT alignment and properties of the polymer. Of interest is electrical percolation where the electrical conductivity of the CNT/polymer nanocomposite increases through orders of magnitude with increase in CNT volume fraction. Estimates and distributions for the electrical conductivity and piezoresistive coefficients of the CNT/polymer nanocomposite are obtained and analyzed with increasing CNT volume fraction and varying barrier potential, which is a parameter that controls the extent of electron tunneling. The effect of CNT alignment is analyzed by comparing the electro-mechanical properties in the alignment direction versus the transverse direction for different orientation conditions. Estimates of piezoresistive coefficients are converted into gage factors and compared with experimental sources in literature. The methodology for this work uses automated scripts which are used in conjunction with high performance computing to generate several 5 μm ×5 μm realizations for different CNT volume fractions. These realizations are then analyzed using finite elements to obtain volume averaged effective values, which are then subsequently used to generate measures of central tendency (estimated mean) and variability (standard deviation, coefficient of variation, skewness and kurtosis) in a descriptive statistical analysis. / Doctor of Philosophy / Carbon nanotubes or CNTs belong to a class of novel materials known as nanomaterials which are materials with length scales on the order of nanometers. CNTs have been widely studied due to their unique mechanical, electrical and thermal properties in comparison to traditional materials such as metals or plastics. Often times, research and applications concerning the use of CNTs involves embedding the CNTs as a filler within a larger composite material system. In the present work, CNTs are considered to be embedded within a polymer. It is known that the electrical properties of such a CNT/polymer composite change in response to the application of a mechanical force. This change in electrical properties is caused due to the presence of CNTs and is used as a means of sensing the mechanical state of the composite, i.e. real time structural monitoring. The extent of the change in electrical properties, also known as sensing, depends upon a number of different factors such as the amount of CNTs used per unit volume of the polymer, how well dispersed or clumped together the CNTs are within the polymer and the type of polymer material used, among other factors. A statistical analysis is performed with several case studies where these factors are varied and the resulting change in the sensing response is monitored. Several important conclusions were made from the statistical analysis with some of the results providing new insights into the sensing behavior of CNT/polymer composites. For example, it was found that a key parameter known as barrier potential, which directly influences the extent of sensing achieved through a mechanism known as electrical tunneling, needs to be several orders of magnitude lower than previously reported values to accurately capture the sensing effects. Key metrics quantifying the extent of sensing from the analysis were found to be in agreement with previously reported experimental results. The significance of such a statistical study lies in the fact that CNT embedded composites are increasingly being proposed and used for sensing applications. The use of CNT embedded polymers to encase explosive crystalline grains such as HMX or RDX is one such example. These explosive grains are used in a number of different civil and military applications such as fuel rocket propellants, industry explosives, military munitions etc. The grains possess extremely high energy densities and are susceptible to undergo violent chemical reaction if a trigger is provided through thermal or mechanical means. As such, the monitoring of the structural state of these explosives is crucial for their safe handling and processing. In this work, the sensing response of a composite material comprising of explosive grains surrounded by polymer material containing CNTs is studied in response to different types of mechanical loads, ranging from mild stimuli to impact. It was found that the sensing mechanism was capable of tracking mechanical damage as well as the resulting temperature increases interior to the composite. In addition to its application to safety and preventative measures, the use of CNTs in this context also provided insight into the mechanisms related to the sudden release of energy in these explosive grains which is of significant interest since this is an active area of research as well.

The current state of the art in structural health monitoring is primarily reliant on sensing deformation of structures at discrete locations using sensors and detecting damage using techniques such as X-ray, microCT, acoustic emission, impedance methods etc., primarily employed at specified intervals of service life. There is a need to develop materials and structures with self-sensing capabilities such that deformation and damage state can be identified in-situ real time. In the current work, the inherent deformation and damage sensing capabilities of carbon nanotube (CNT) based nanocomposites are explored starting from the nanoscale electron hopping mechanism to effective macroscale piezoresistive response through finite elements based computational micromechanics techniques. The evolution of nanoscale conductive electron hopping pathways which leads to nanocomposite piezoresistivity is studied in detail along with its evolution under applied deformations. The nanoscale piezoresistive response is used to evaluate macroscale nanocomposite response by using analytical micromechanics methods. The effective piezoresistive response, obtained in terms of macroscale effective gauge factors, is shown to predict the experimentally obtained gauge factors published in the literature within reasonable tolerance. In addition, the effect of imperfect interface between the CNTs and the polymer matrix on the mechanical and piezoresistive properties is studied using coupled electromechanical cohesive zone modeling. It is observed that the interfacial separation and damage at the nanoscale leads to a larger nanocomposite irreversible piezoresistive response under monotonic and cyclic loading because of interfacial damage accumulation. As a sample application, the CNT-polymer nanocomposites are used as a binding medium for polycrystalline energetic materials where the nanocomposite binder piezoresistivity is exploited to provide inherent deformation and damage sensing. The nanocomposite binder medium is modeled using electromechanical cohesive zones with properties obtained through the Mori-Tanaka method allowing for different local CNT volume fractions and orientations. Finally, the traditional implementation of Material Point Method (MPM) is extended for composite problems with large deformation (e.g. large strain nanocomposite sensors with elastomer matrix) allowing for interfacial discontinuities appropriately. Overall, the current work evaluates nanocomposite piezoresistivity using a multiscale modeling framework and emphasizes through a sample application that nanocomposite piezoresistivity can be exploited for inherent sensing in materials. / Ph. D.

Παρατηρείται ότι, το ΙΑΜ έχει ήδη εδρεώσει τη θέση του ανάμεσα στα δομικά υλικά. Όμως για να μπορεί να χαρακτηριστεί ως πολυλειτουργικό υλικό, θα πρέπει να παρέχει και άλλες λειτουργίες μη δομικής φύσεως. Η διατριβή αυτή, επικεντρώθηκε στην ανίχνευση βλάβης σε στοιχεία ΙΑΜ μέσω διηλεκτρικών μετρήσεων και πιο συγκεκριμένα μέσω της μεταβολής της ηλεκτρικής αντίστασης στα στοιχεία αυτά. Τα αποτελέσματα των πειραματικών δοκιμών θα χρησιμοποιηθούν ώστε να θέσουν τις βάσεις για κατάλληλους συντελεστές συσχέτισης μεταξύ της εξέλιξης της βλάβης και της πιεζοαντίστασης σε στοιχεία ΙΑΜ. / This thesis presents the preliminary results of an ongoing experimental program aiming at assessing the piezoresistivity of carbon textile reinforced concrete dumbbell specimens under monotonic tensile loading, along the direction of loading. During testing both longitudinal strain and longitudinal electrical resistivity were recorded; electrical resistivity measurements were realized using a high-precision multimeter. The results of this experimental campaign may be used for setting the ground for establishing appropriate correlation factors between damage progression and piezoresistivity properties for TRC elements.

L’objectif de cette thèse est de développer un cylindre instrumenté pour mesurer sa déflexion dans les applications médicales. Deux types de matériaux sont utilisés pour le cylindre : l'acier inoxydable et le NiTi. Des microjauges sont réparties le long du cylindre pour mesurer en temps réel sa déformation, permettant ainsi de guider le cylindre à sa destination envisagée dans un geste chirurgical. Plusieurs approches pour la mesure de déformation sont présentées et comparées, et la mesure de déformation par les microjauges piézorésistives semiconductrices intégrées sur le cylindre paraît la méthode optimale en tenant compte de la sensibilité, la compatibilité biomédicale et la faisabilité en microfabrication. Des analyses théoriques et par méthode d'éléments finis sont effectués pour analyser le comportement mécanique du cylindre en flexion mais aussi pour positionner et dimensionner les microjauges piézorésistives sur le cylindre. Un premier prototype a été réalisé et caractérisé pour vérifier la fonctionnalité de notre système.La réalisation des microjauges sur les cylindres se déroule par la microfabrication en salle blanche. Le germanium est utilisé comme le matériau piézorésistif. A cause de la spécificité géométrique des cylindres en tant que le substrat de la microfabrication, de nombreuses modifications sont apportées au procédé de fabrication 'standard' pour le dépôt et l'usinage des matériaux en surface du substrat métallique courbe. Le résultat de microfabrication est présenté, ainsi que l'analyse et les améliorations éventuelles du procédé actuel. / The objective of this assertation is to develop an instrumented cylinder in order to measure its deflection status in medical applications. The cylinders are made of two types of materials: stainless steel and NiTi. The microgauges are distributed along the cylinder to measure its real-time surface strain, thus allowing the cylinder to be guided to its planned destination during a surgical operation.Several approaches for strain measurement are presented and compared, and strain measurement with semiconductor piezoresistive microgauges integrated on the cylinder appears to be the optimal method considering the sensitivity, biomedical compatibility and feasibility in microfabrication.Theoretical analysis and finite element method analysis are carried out in order to analyze the mechanical behavior of the deflected cylinder and to determine the optimal position and size of the piezoresistive microgauges on the cylinder. A first prototype was developed and characterized to verify the functionality of our system.The microgauges are implemented on thin cylinders by microfabrication in cleanroom. Germanium is used as the piezoresistive material. Due to the curved geometry of metal cylinders as the substrate for microfabrication, several ajustments are made to the standard process of material deposition and surface machining. The analysis of experimental results, as well as the possible upgrades of the current process, are discussed.

Multifunctional polymer fibers with strain and liquid sensing capabilities were fabricated and characterized. The Hansen Solubility Parameters (HSPs) were used as a tool for selecting a suitable polymer to employ as matrix for the sensing material before fiber fabrication. The addition of conductive carbon particles to a polymer matrix provides it with sensing capabilities, such as against tensile strain and the presence of liquids as it was evaluated in this work. Multiwall carbon nanotubes (MWCNTs, MW) as well as a mixture of carbon black (CB) and MWCNTs in weight concentration of 1:1 were used as conductive fillers. The route followed to achieve electrically conductive polymer fibers necessary for sensing evaluations was a combined process of melt-mixing and subsequent melt-spinning. Melt-mixing and melt-spinning are processing techniques widely used in the polymer industry that could enable the up-scaling of the fibers developed in this work. Additionally to single component fibers, bi-component (BICO) fibers consisting of a polycarbonate (PC)+CB+MW sheath and a neat PC core were also fabricated, characterized and their performance was compared to the single component fibers. The state of dispersion of the carbon nanoparticles (CNPs) as well as tensile behavior, electrical resistivity, strain and liquid sensing properties of the composite fibers were evaluated. Finally a specific fiber composition with potential to be used as sensing material for mechanical strain and liquid exposition was proposed to be tested under two real situations (strain monitoring of a rigid structure and leakage detection of a chemical substance). Sensing fibers as the developed in this work have many potential applications such as real-time deformation and structural health monitoring and early cracking detection of any kind of structure. On the other hand, fibers able to sense the presence of liquids can perceive the leakage of chemicals that are hazardous to life. Moreover, this technology can also be applied in smart clothing manufacture by combining sensing fibers with flexible woven electronics.

<p dir="ltr">The demand and utilization of fiber-reinforced composites are increasing in various sectors, including aerospace, civil engineering, and automotive industries. Non-destructive methods are necessary for monitoring fiber-reinforced composites due to their complex and often visually undetectable failure modes. An emerging method for monitoring composite structures is through the integration of self-sensing capabilities. Self-sensing in nanocomposites can be achieved through nanofiller modifications, which involve introducing an adequate amount of nanofillers into the matrix, such as carbon nanotubes (CNTs) and carbon nanofillers (CNFs). These fillers form an electrically well-connected network that allows the electrical current to travel through conductive pathways. The disruption of connectivity of these pathways, caused by mechanical deformations or damages, results in a change in the overall conductivity of the material, thereby enabling intrinsic self-sensing.</p><p dir="ltr">Currently, the majority of predictive modeling attempts in the field of self-sensing nanocomposites have been dedicated to microscale piezoresistivity. There has been a lack of research conducted on the modeling of strain-induced resistivity changes in macroscale fiber-matrix material systems. As a matter of fact, no analytical macroscale model that addresses the impact of continuous fiber reinforcement in nanocomposites has been presented in the literature. This gap is significant because it is impossible to make meaningful structural condition predictions without models relating observed resistivity changes to the mechanical condition of the composite. Accordingly, this dissertation presents a set of three research contributions. The overall objective of these contributions is to address this knowledge gap by developing and validating an analytical model. In addition to advancing our theoretical understanding, this model provides a practical methodology for predicting the piezoresistive properties of continuous fiber-reinforced composites with integrated nanofillers.</p><p dir="ltr">To bridge the above-mentioned research gap, three scholarly contributions are presented in this dissertation. The first contribution proposes an analytical model that aims to predict the variations in resistivity within a material system comprising a nanofiller-modified polymer and continuous fiber reinforcement, specifically in response to axial strain. The fundamental principle underlying our methodology involves the novel use of the concentric cylindrical assembly (CCA) homogenization technique to model piezoresistivity. The initial step involves the establishment of a domain consisting of concentric cylinders that represent a continuous reinforcing fiber phase wrapped around by a nanofiller-modified matrix phase. Subsequently, the system undergoes homogenization to facilitate the prediction of changes in the axial and transverse resistivity of the concentric cylinder as a consequence of longitudinal deformations. The second contribution investigates the effect of radial deformations on piezoresistivity. Here, we demonstrate yet another novel application of the CCA homogenization technique to determine piezoresistivity. This contribution concludes by presenting closed-form analytical relations that describe changes in axial and transverse resistivity as functions of externally applied radial strain. The third contribution involves computationally analyzing piezoresistivity in fiber-reinforced laminae by using three-dimensional representative volume elements (RVE) with a CNF/epoxy matrix. By comparing the single-fiber-based analytical model with the computational model, we can investigate the impact of interactions between multiple adjacent fibers on the piezoresistive properties of the material. The study revealed that the differences between the single-fiber CCA analytical model and the computational model are quite small, particularly for composites with low- to moderate-fiber volume fractions that undergo relatively minor deformations. This means that the analytical methods herein derived can be used to make accurate predictions without resorting to much more laborious computational methods.</p><p dir="ltr">In summary, the impact of this dissertation work lies in the development of novel analytical closed-form nonlinear piezoresistive relations. These relations relate the electrical conductivity/resistivity changes induced by axial or lateral mechanical deformations in directions parallel and perpendicular to the reinforcing continuous fibers within fiber-reinforced nanocomposites and are validated against in-depth computational analyses. Therefore, these models provide an important and first-ever bridge between simply observing electrical changes in a self-sensing fiber-reinforced composite and relating such observations to the mechanical state of the material.</p>