Convergent-Divergent (C-D) nozzles are used in rocket engines to produce thrust as a reaction to the acceleration of hot combustion chamber gases in the opposite direction. To maximize the engine performance at high altitudes, large area ratio, bell-shaped or contoured nozzles are used. At lower altitudes, the exit pressure of these nozzles is lower than the ambient pressure. During this over-expanded condition, the nozzle-internal flow adapts to the ambient pressure through an oblique shock. But the boundary layer inside the divergent portion of the nozzle is unable to withstand the pressure rise associated with the shock, and consequently flow separation is induced. Numerical simulation of separated flows in rocket nozzles is challenging because the existing turbulence models are unable to correctly predict shock-induced flow separation. The present thesis addresses this problem. Axisymmetric, steady-state, Reynolds-Averaged Navier-Stokes (RANS) simulations of a conical nozzle and three sub-scale contoured nozzles were carried out to numerically predict flow separation in over-expanded rocket nozzles at different nozzle pressure ratios (NPR). The conical nozzle is the JPL 45◦-15◦ and the contoured nozzles are the VAC-S1, the DLR-PAR and the VAC-S6-short. The commercial CFD code ANSYS FLUENT 13 was first validated for simulation of separated cold gas flows in the VAC-S1 nozzle. Some modeling issues in the numerical simulations of flow separation in rocket nozzles were determined. It is recognized that compressibility correction, nozzle-lip thickness and upstream-extension of the external domain are the sources of uncertainty, besides turbulence modeling. In high-speed turbulent flows, compressibility is known to affect dissipation rate of turbulence kinetic energy. As a consequence, a reduction in the spreading rate of supersonic mixing layers occurs. Whereas, the standard turbulence models are developed and calibrated for incompressible flows and hence, do not account for this effect. ANSYS FLUENT uses the compressibility correction proposed by Wilcox [1] which modifies the turbulence dissipation terms based on turbulent Mach number. This, as shown in this thesis, may not be appropriate to the prediction of flow separation in rocket nozzles. Simulation results of the standard SST model, with and without the compressibility correction, are compared with the experimental data at NPR=22 for the DLR-PAR nozzle. Compressibility correction is found to cause under-prediction of separation location and hence its use in the prediction of flow separation is not recommended. In the literature, computational domains for the simulation of DLR subscale nozzles have thick nozzle-lips whereas for the VAC subscale nozzles they have no nozzle-lip. Effect of nozzle-lip thickness on flow separation is studied in the DLR-PAR nozzle by varying its nozzle-lip thickness. It is found that nozzle-lip thickness significantly influences both separation location and post-separation pressure recovery by means of the recirculation bubbles formed at the nozzle-lip. Usually, experimental values of free stream turbulence are unknown. So conventionally, to minimize solution dependence on the boundary conditions specified for the ambient flow, the computational domain external to the nozzle is extended in the upstream direction. Its effect on flow separation is studied in the DLR-PAR nozzle through simulations conducted with and without this domain extension. No considerable effect on separation location and pressure recovery is found. The two eddy-viscosity based turbulence models, Spalart-Allmaras (SA) model and Shear Stress Transport (SST) model, are well known to predict separation location better than other eddy-viscosity models, but with moderate success. Their performances, in terms of predicting separation location and post-separation wall pressure distribution, were compared with each other and evaluated against experimental data for the conical and two contoured nozzles. It is found that they fail to predict the separation location correctly, exhibiting sensitivity to the range of NPRs and to the type of nozzle. Depending on NPR, the SST model either under-predicts or over-predicts Free Shock Separation (FSS). Moreover, it also fails to capture Restricted Shock Separation (RSS). With compressibility correction, it under-predicts separation at all NPRs to a greater extent. Even though RSS is captured by using compressibility correction, the transition from FSS to RSS is over-predicted [2]. Early efforts by few researchers to improve predictions of nozzle flow separation by realizability corrections to turbulence models have not been successful, especially in terms of capturing both the separation types. Therefore, causes of turbulence modeling failure in predicting nozzle flow separation correctly were further investigated. It is learnt that limiting of the shear stress inside boundary layer, due to Bradshaw’s assumption, and over-prediction of jet spreading rate are the causes of SST model’s failure in predicting nozzle flow separation correctly. Based on this physical reasoning, values of the a 1 parameter and the two diffusion coefficients σk,2 and σω,2 were empirically modified to match the predicted wall pressure distributions with experimental data of the DLR-PAR and the VAC-S6-short nozzles. The results confirm that accurate prediction of flow separation in rocket nozzles indeed depends on the correct prediction of spreading rate of the supersonic separation-jet. It is demonstrated that accurate RANS simulation of flow separation in rocket nozzles over a wide range of NPRs is feasible by modified values of the diffusion coefficients in turbulence model.

Abstract The diurnal cycle is a dominant mode of sea surface temperature (SST) variability in trop-ical oceans, that influences air-sea interaction and climate processes. Diurnal variability of SST generally ranges from ~0.1 to 2.0◦C and is controlled by atmospheric fluxes of heat and momentum. In the present study, the response of intraseasonal variability (ISV) of SST in the Bay of Bengal (BoB) to diurnal atmospheric forcings, during the summer monsoon of 2007, has been examined using an Ocean General Circulation Model (OGCM). The model is based on the Modular Ocean Model Version 4 (MOM4p0), having a horizontal resolution of 0.25◦ and 40 vertical levels, with a fine resolution of 5 m in the upper 60 m. Numerical experiments were conducted by forcing the model with daily and hourly atmospheric forcings to examine the SST-ISV modulation with the diurnal cycle. Additional experiments were performed to determine the relative role of diurnal cycle in solar radiation and winds on SST and mixed layer depth (MLD). Since salinity, which is decisive in SST variability, varies meridionally in the BoB, two locations were selected for analyses: one in the northern bay at 89◦E, 19◦N where salinity is lower and the other in the southern bay at 90◦E, 8◦N where salinity is higher, as well as observations are available from Research Moored Array for African-Asian-Australian Monsoon Analysis and Prediction (RAMA) buoy for comparision with model simulation. Diurnal atmospheric forcings modify SST-ISV in both southern and northern bay. SST-ISV in the southern bay, is dominantly controlled by the diurnal cycle of insolation, while in the northern bay, diurnal cycle of insolation and winds have comparable contribution. Diurnal cycle enhanced the amplitude of 3 selected intraseasonal events in the southern bay and 3 out of the 6 events in the northern bay, during the study period. In the southern bay, simulated SST variability with hourly forcing was closer to the observations from RAMA, implying that incorporating the diurnal cycle in model forcing rectifies SST-ISV. Moreover, SST obtained with diurnal forcing consists of additional fluctuations at higher frequencies within and in between intraseasonal events; such fluctuations are absent with daily forcing. The diurnal variability of SST is significant during the warming phase of intraseasonal events and reduces during the cooling phase. Diurnal amplitude of SST decreases with depth; depth dependence also being larger during the warming phase. SST-ISV modulation with diurnal forcing results from the diurnal cycle of upper ocean heat fluxes and vertical mixing. Diurnal warming and cooling result in a net gain or loss of heat in the mixed layer after a day’s cycle. When the retention (loss) of heat in the mixed layer increases with diurnal forcing during the warming (cooling) phase of intraseasonal events, the daily mean SST rise (fall) becomes higher, amplifying the intraseasonal warming (cooling). In the southern bay, SST-ISV amplification is mainly controlled by the diurnal variability of MLD, which modifies the heat fluxes. Increased intraseasonal warming with diurnal forcing results from the increase in radiative heating, due to the shoaling of the daytime mixed layer. Amplified intraseasonal cooling is dominantly con-trolled by the strengthening of sub-surface processes, due to the nocturnal deepening of mixed layer and increased temperature gradients below the mixed layer. In the northern bay, SST-ISV modulation with diurnal forcing is not as large as that in the southern bay. The mean increase in SST-ISV amplitudes with diurnal forcing is ~0.16◦C in the southern bay, while it is only ~0.03◦C in the northern bay. Reduced response of SST-ISV to diurnal forcings in the northern bay is related to the weaker diurnal variability of MLD. Salinity stratification limits diurnal variability of mixed layer in the northern bay, unlike in the southern bay. The seasonal (June - September) mean diurnal amplitude of MLD is ~15 m in the southern bay, while it is reduced to ~1.5 m in the northern bay. Diurnal variability of MLD, spanning only a few meters is not sufficient to create large modifications in mixed layer heat fluxes and SST-ISV in the northern bay. The vertical resolution of the model limits the shallowing of mixed layer to 7.5 m, thus restricting the diurnal variability of simulated MLD.

In recent years, application of confluent jets for design of ventilation supply devices has been studied. Similarly, numerus studies have been made on the potential and application of variable air volume (VAV) in order to reduce the energy demand of ventilation systems. This study investigates the combination of supply devices based on confluent jets and VAV, both in terms of the nearfield flow behavior of the device and the impact on thermal comfort, indoor air quality and energy efficiency on a classroom-level space when the airflow rate is varied. The method used in this study is an experimental field study where the confluent jets-based supply devices were compared to the previously installed displacement ventilation. The field study evaluated the energy efficiency, thermal comfort and indoor air quality of the two systems. In the case of the confluent jets supply devices, airflow rate was varied in order to see what impact the variation had on the performance of the system for each airflow rate. Furthermore, the confluent jets supply devices were investigated both experimentally and numerically in a well insulated test room to get high resolution data on the particular flow characteristics for this type of supply device when the airflow rate is varied. The results from the field study show nearly uniform distribution of the local mean age of air in the occupied zone, even in the cases of relatively low airflow rates. The airflow rates have no significant effect on the degree of mixing. The thermal comfort in the classroom was increased when the airflow rate was adapted to the heat load compared to the displacement system. The results lead to the conclusion that the combination of supply devices based on confluent jets can reduce energy usage in the school while maintaining indoor air quality and increasing the thermal comfort in the occupied zone. The results from the experimental and numerical study show that the flow pattern and velocity in each nozzle is directly dependent on the total airflow rate. However, the flow pattern does not vary between the three different airflow rates. The numerical investigation shows that velocity profiles for each nozzle have the same pattern regardless of the airflow rate, but the magnitude of the velocity profile increases as the airflow increases. Thus, a supply device of this kind could be used for variable air volume and produce confluent jets for different airflow rates. The results from both studies show that the airflow rate does not affect the distribution of the airflow on both near-field and room level. The distribution of air is nearly uniform in the case of the near-field results and the room-level measurement shows a completely uniform degree of mixing and air quality in the occupied zone for each airflow rate. This means that there is potential for combining these two schemes for designing air distribution systems with high energy efficiency and high thermal comfort and indoor air quality. / Under senare tid har applikation av Confluent jets för design av tilluftsdon studerats. Många studier har även utförts över potentialen av att applicera variabelt luftflöde (VAV) för att minska energianvändningen i ventilationssystem. Denna studie undersöker möjligheten att kombinera Confluent jets-don med VAV, både med avseende på den lokala flödesbilden och dess påverkan på termisk komfort, luftkvalitet och energieffektivitet i en klassrumsmiljö där luftflödes varieras. Denna studie baseras dels på en experimentell fältstudie där tilluftsdon baserade på Confluents jets jämfördes med befintliga deplacerande tilluftsdon. Fältstudien utvärderade energieffektiviteten, den termiska komforten och luftkvaliteten för båda typerna av tillluftsdon. Confluent jets-donen testades under varierat luftflöde för att se påverkan av flödesvariationen på ventilationens prestation under de olika flödena. Utöver fältstudien testades Confluent jets-donen experimentellt och numeriskt i ett välisolerat test-rum för få den detaljerade flödeskarakteristiken för den här typen tilluftsdon vid varierat luftflöde. Resultaten från fältstudien visar på en jämn fördelning av den lokala luftsmedelåldern i vistelsezonen, även för fallen med relativt låga luftflöden. Luftflöden har ingen signifikant effekt på omblandningen. Den termiska komforten i klassrummet ökade när luftflödet anpassades efter värmelasten jämfört med de deplacerande donen. Slutsatsen från fältstudien är att kombinationen av VAV och Confluent jets-don kan användas för att minska energianvändningen på skolan och bevara luftkvaliteten och den termiska komforten i vistelsezonen. Resultaten från den experimental och numeriska studien visar luftflödet och lufthastigheten i varje enskild dysa är direkt beroende på det totala luftflödet genom donet. Dock är flödesfördelningen mellan dysorna oberoende av de tre olika luftflödena. Den numeriska undersökningen visar att flödesprofilen för varje dysa är konstant trots att flödet varieras, men amplituden för varje profil ökar med en höjning av luftflödet. Det betyder att tilluftsdon av den här typen kan användas med VAV för att producera Confluent jets för olika luftflöden. Resultaten från båda studierna visar att luftflöde inte påverkar fördelningen av luften vare sig längs luftdonen eller på rumsnivå. Fördelningen av luften är nästan helt jämn längs donen och på rumsnivå är omblandningen och luftkvalitet den samma för varje luftflöde. Det betyder att det finns potential för att kombinera det här två teknikerna för att designa luftdistribueringssystem med hög energieffektivitet och hög termisk komfort med god luftkvalitet.

Este trabalho avalia a importância relativa dosmodos dinâmicos na composição da estrutura vertical do fluxo geostrófico e de suas anomalias em relação à média, com o objetivo de fornecer uma descrição das formas de estratificação predominantes na coluna de água e de identificar prováveis regiões de ocorrência de ondas de Rossby planetárias (OR) dos diversos modos dinâmicos. Raios de deformação internos são estimados para avaliar a possibilidade de interações não-lineares entre OR e as alterações da estratificação local forçadas por sua própria passagem. A análise proposta baseia-se em dados de densidade estimados a partir de perfis verticais de salinidade climatológicos aliados a perfis sintéticos de temperatura. Estes últimos são extrapolados verticalmente a partir de dados orbitais da temperatura da superfície do mar (TSM) e da anomalia da altura da superfície livre (h), segundo um método de reconstrução estatística desenvolvido para este estudo. O primeiro modo baroclínico é dominante tanto no fluxo total quanto em suas anomalias, respondendo em média por 30% da estrutura vertical de velocidade, sendo que este valor descresce aproximadamente por uma razão de três em modos superiores. O segundo modo é significativo ou mesmo dominante em algumas regiões, particularmente em latitudes próximas ao equador. O terceiro é evidente em algumas áreas localizadas, mas não assume papéis importantes em escala de bacia. O modo 0 responde por frações de 6 a 9%, mas é provável que estes resultados sejam subestimados pela metodologia aplicada. Anomalias verticais relacionadas ao primeiro modo coincidem com regiões onde OR longas do primeiro modo tem maior expressão, enquanto o segundo modo parece ser um marcador de OR curtas e ondas de instabilidade tropical. Fenômenos transientes associados ao terceiro modo são observados em áreas restritas dos três oceanos. A magnitude das variações dos raios internos em resposta à fenômenos transientes em algumas regiões implicam em variações significativas na velocidade de fase teórica de OR longas lineares, um indício de que efeitos não-lineares podem ser importantes. Por fim, amplificações da importância do modo barotrópico sobre feições topográficas significativas sugere a existência de mecanismos de transferência de energia entre modos dinâmicos induzidas pela interação com a batimetria. / This study evaluates the relative importance of the dynamical modes in the composition of the geostrophic flow and of its anomalies from the long-term average, respectively seeking to determine the dominant vertical stratification structures of the water column and to identify regions where planetary Rossby waves (RW) of different dynamical modes may most likely occur. The baroclinic Rossby radii of deformation are estimated to evaluate the possibility of nonlinear interactions between RWand changes of the local stratification forced by the wave\'s passing. This analysis is based on density data estimated from climatological salinity profiles and synthetic temperature profiles. The latter are vertically extrapolated for sea surface temperature (SST) and sea surface height anomaly (h) satellite data, using a statistical reconstruction method developed in this study. The first baroclinic mode dominates both the total geostrophic flow and its anomalies, accounting for 30% of the velocity\'s vertical structure on average, where this value decreases approximately by a factor of 3 in subsequent baroclinic orders. The second mode is significant or even dominant in some areas, particularly near the equator. The third mode is evident in some localized regions, but can be ignored at basin-scales. The barotropic mode accounts for 6 to 9% fractions on average, however these values are probably underestimated by the used methods. Vertical anomalies related to the first baroclinic mode coincide with regions where long RWs answers for a significant fraction of local variance, while the second mode highlights zones where short RWs and tropical instability waves are reported. Transient phenomena related with the third mode are observed in comparatively small areas on all three oceans. The magnitude of the baroclinic radii\'s variations in response of the transient variability results in significant changes of the theorethical phase speed for long linear RWs, an evidence that nonlinear effects may be important. Lastly, the greater significance of the barotropic mode over proeminent bottom features suggests the existence of energy transfer mechanisms between dynamical modes triggered by the interaction with the bathymetry.

Este trabalho avalia a importância relativa dosmodos dinâmicos na composição da estrutura vertical do fluxo geostrófico e de suas anomalias em relação à média, com o objetivo de fornecer uma descrição das formas de estratificação predominantes na coluna de água e de identificar prováveis regiões de ocorrência de ondas de Rossby planetárias (OR) dos diversos modos dinâmicos. Raios de deformação internos são estimados para avaliar a possibilidade de interações não-lineares entre OR e as alterações da estratificação local forçadas por sua própria passagem. A análise proposta baseia-se em dados de densidade estimados a partir de perfis verticais de salinidade climatológicos aliados a perfis sintéticos de temperatura. Estes últimos são extrapolados verticalmente a partir de dados orbitais da temperatura da superfície do mar (TSM) e da anomalia da altura da superfície livre (h), segundo um método de reconstrução estatística desenvolvido para este estudo. O primeiro modo baroclínico é dominante tanto no fluxo total quanto em suas anomalias, respondendo em média por 30% da estrutura vertical de velocidade, sendo que este valor descresce aproximadamente por uma razão de três em modos superiores. O segundo modo é significativo ou mesmo dominante em algumas regiões, particularmente em latitudes próximas ao equador. O terceiro é evidente em algumas áreas localizadas, mas não assume papéis importantes em escala de bacia. O modo 0 responde por frações de 6 a 9%, mas é provável que estes resultados sejam subestimados pela metodologia aplicada. Anomalias verticais relacionadas ao primeiro modo coincidem com regiões onde OR longas do primeiro modo tem maior expressão, enquanto o segundo modo parece ser um marcador de OR curtas e ondas de instabilidade tropical. Fenômenos transientes associados ao terceiro modo são observados em áreas restritas dos três oceanos. A magnitude das variações dos raios internos em resposta à fenômenos transientes em algumas regiões implicam em variações significativas na velocidade de fase teórica de OR longas lineares, um indício de que efeitos não-lineares podem ser importantes. Por fim, amplificações da importância do modo barotrópico sobre feições topográficas significativas sugere a existência de mecanismos de transferência de energia entre modos dinâmicos induzidas pela interação com a batimetria. / This study evaluates the relative importance of the dynamical modes in the composition of the geostrophic flow and of its anomalies from the long-term average, respectively seeking to determine the dominant vertical stratification structures of the water column and to identify regions where planetary Rossby waves (RW) of different dynamical modes may most likely occur. The baroclinic Rossby radii of deformation are estimated to evaluate the possibility of nonlinear interactions between RWand changes of the local stratification forced by the wave\'s passing. This analysis is based on density data estimated from climatological salinity profiles and synthetic temperature profiles. The latter are vertically extrapolated for sea surface temperature (SST) and sea surface height anomaly (h) satellite data, using a statistical reconstruction method developed in this study. The first baroclinic mode dominates both the total geostrophic flow and its anomalies, accounting for 30% of the velocity\'s vertical structure on average, where this value decreases approximately by a factor of 3 in subsequent baroclinic orders. The second mode is significant or even dominant in some areas, particularly near the equator. The third mode is evident in some localized regions, but can be ignored at basin-scales. The barotropic mode accounts for 6 to 9% fractions on average, however these values are probably underestimated by the used methods. Vertical anomalies related to the first baroclinic mode coincide with regions where long RWs answers for a significant fraction of local variance, while the second mode highlights zones where short RWs and tropical instability waves are reported. Transient phenomena related with the third mode are observed in comparatively small areas on all three oceans. The magnitude of the baroclinic radii\'s variations in response of the transient variability results in significant changes of the theorethical phase speed for long linear RWs, an evidence that nonlinear effects may be important. Lastly, the greater significance of the barotropic mode over proeminent bottom features suggests the existence of energy transfer mechanisms between dynamical modes triggered by the interaction with the bathymetry.

In first part of the study we discuss impact of dynamical core in simulation of tropical rainfall. Over years many new dynamical cores have been developed for atmospheric models to increase efficiency and reduce numerical errors. CAM3.1 gives an opportunity to study the impact of the dynamical core on simulations with its three dynamical cores namely Eulerian spectral(EUL) , Semilagrangian dynamics(SLD) and Finite volume(FV) coupled to a single parametrization package. A past study has compared dynamical cores of CAM3 in terms on tracer transport and has showed advantages using FV in terms of tracer transport. In this study we compare the dynamical cores in climate simulations and at their optimal configuration, which is the intended use of the model. The model is forced with AMIP type SST and rainfall over seasonal, interannual scales is compared. The significant differences in simulation of seasonal mean exist over tropics and over monsoon regions with observations and among dynamical cores. The differences among EUL and SLD, which use spectral transform methods are lesser compared that of with FV clearly indicating role of numerics in differences. There exist major errors in simulation of seasonal cycle in all dynamical cores and errors in simulation of seasonal means over many regions are associated with errors in simulation of seasonal cycle such as over south china sea. Seasonal cycle in FV is weaker compared to SLD and EUL. The dynamical cores exhibit different interannual variability of rainfall over Indian monsoon region, the period of maximum power corresponding to a dynamical core differs substantially with another. From this study there seems no superiority associated with FV dynamical core over all climate scales as seen in tracer transport. The next part of the study deals with impact of diurnal ocean atmosphere coupling in an AGCM,CAM3.1. Due to relatively low magnitude of diurnal cycle of SST and lack of SST observations over diurnal scales current atmospheric models are forced with SSTs of periods grater than a day. CAM 3.1 standalone model is forced with monthly SSTs but the interpolation is linear to every time step between any two months and this linear interpolation implies a linear diurnal and intraseasonal variation of SST which is not true in nature. To test the sensitivity of CAM3.1 to coupling of SST on diurnal scales, we prescribed over tropics(20S20N) a diurnal cycle of SST over daily mean interpolated SST of different magnitudes and phase comparable to observations. This idea of using a diurnal cycle of SST retaining seasonal mean SST in an atmospheric model is novel and provides an interesting frame work to test sensitivity of model to interpolations used in coupling of boundary conditions. Our analysis shows a high impact of using diurnal cycle of SST on simulation of mean rainfall over tropics. The impact in a case where diurnal cycle of SST is fixed and retained to daily mean SST implies that changes associated with a coupled model are to some extent due to change in representation of diurnal cycle of SST. A decrease of excess rainfall over western coast of Bay of Bengal and an increase of rainfall over northern bay of Bengal in such case is similar to the improvement due to coupling atmospheric model to a slab ocean model. This also implies that problems with current AMIP models in simulation of seasonal mean Indian monsoon rainfall could be due to erroneous representation of diurnal cycle of SST in models over this region where the diurnal cycle of SST is high in observations. The high spatial variability of the impact in various cases over tropics implies that a similar spatial variation of diurnal cycle could be important for accurate simulation of rainfall over tropics. Preliminary analysis shows that impact on rainfall was due to changes in moisture convergence. We also hypothesized that diurnal cycle of SST could trigger convection over regions such as northern Bay of Bengal and rainfall convergence feedback sustains it. The impact was also found on simulation of internal interannual variability of rainfall

The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. The experimental apparatus, procedures and results obtained in this thesis on scaled-down experiments of SST Early and Late Feed simulated solutions were adapted and reproduced under hot-cell with actual wastes by our partners at Hanford. To prepare the application of the pretreatment process to pilot scale process, several varation to the feed solutions were investigated including the presence of carboxylates and amines organics compounds and solids particles. Results of the study showed that 4 organics species presented complications to the process (NTA, HEDTA, EDTA and sodium citrate) while the other species (Formate, acetate, glycolate and IDA) and solids particles did not in the conditions of the stored wastes. In this thesis, the kinetics of the crystalline species formed at the condition of the early feed certification run (66 °C and 25 g/h evaporation) were determined along with the effect of the operating temperature and evaporation rate on these kinetics. On one hand, the study of evaporation rate values ranging from 25g/h to 75g/h showed that an increase in evaporation rate increased the specific nucleation while decreasing the specific growth rate. On the other hand, experiments on operating temperature ranging from 35 °C to 75 °C displayed that the nucleation rate of all species increased with temperature at the exception of sodium carbonate monohydrate and burkeite crystals, and that the growth rate of all species increased with temperature at the exception of sodium nitrate. Furthermore, sulfate based crystals such as trisodium fluoride sulfate were only roduced at 45 °C and 75 °C. A simple steady state MSMPR population balance model was developed expressing the total population density function as the sum of the specific population density functions. The specific semi-batch crystallization kinetics were implemented in this model.

Bakalauro baigiamajame darbe nagrinėjama savitarna lyginant ją su tradicine paslauga prekybos centruose Lietuvoje bei naujos paslaugos įtaka jos vartotojams. Teorinėje dalyje pateikta savitarnos esmė ir bendrosios jos savybės, savitarnos valdymo veiksnių analizė (naudojimosi savitarna lemiami veiksniai, savitarnos priėmino veiksniai), aptarti savitarnos technologijos tinkamumo kriterijai bei savitarnos reikšmė aptarnaujant klientus. Darbo problema. Stiprėjanti konkurencija paslaugų sektoriuje skatina paslaugų įmones ieškoti naujų verslo technologinių sprendimų, kurti naujas paslaugų technologijas, kurias taikant paslaugos teikiamos efektyviau. Savitarnos technologijos taikymas aptarnaujant vartotojus yra efektyvesnis negu individualizuotas, tačiau nevisos savitarnos paslaugos prigyja. Savitarnos pripažinimas iš vartotojų pusės yra susijęs su pasitikėjimu paslaugos teikėju, todėl yra svarbu nustatyti veiksnius darančius įtaką vartotojų suvokimui apie pačią paslaugą ir nustatyti savitarnos mašinų reikalingumą Lietuvos prekybos centruose. / This bachelor final paper analyses self-service comparison to traditional service of shopping centers in Lithuania and the input of self-service technology on service users. Theoretic chapter provides the analysis of the essence and general properties of self-service as well as analysis of the self-service operate factors (the use of self-service determinant factors and self-service adoption factors), discussion of the eligibility criteria for self-service technology and self-service importance for customer needs. Work problem. Increasing competition in the services sector encourages service companies of finding new technological solutions for their business and create new technology based services for more efficiency. Self-service technology for customer servicing is more effective than individualized but not all self-service naturalize. Self-service recognition from the consumer side is related to the trust of the service provider, so it is important to identify the factors influencing consumer’s perceptions of service and the need for self-checkout alternative in shopping centers of Lithuania.

This thesis deals with the near-field of confluent jets, which can be of interest in many engineering applications such as design of a ventilation supply device. The physical effect of interaction between multiple closely spaced jets is studied using experimental and numerical methods. The primary aim of this study is to explore a better understanding of flow and turbulence behavior of multiple interacting jets. The main goal is to gain an insight into the confluence of jets occurring in the near-field of multiple interacting jets. The array of multiple interacting jets is studied when they are placed on a flat and a curved surface. To obtain the boundary conditions at the nozzle exits of the confluent jets on a curved surface, the results of numerical prediction of a cylindrical air supply device using two turbulence models (realizable 𝑘 − 𝜖 and Reynolds stress model) are validated with hot-wire anemometry (HWA) near different nozzles discharge in the array. A single round jet is then studied to find the appropriate turbulence models for the prediction of the three-dimensional flow field and to gain an understanding of the effect of the boundary conditions predicted at the nozzle inlet. In comparison with HWA measurements, the turbulence models with low Reynolds correction (𝑘 − 𝜖 and shear stress transport [SST] 𝑘 − 𝜔) give reasonable flow predictions for the single round jet with the prescribed inlet boundary conditions, while the transition models (𝑘 − 𝑘l − 𝜔𝜔 and transition SST 𝑘 − 𝜔) are unable to predict the flow in the turbulent region. The results of numerical prediction (low Reynolds SST 𝑘 − 𝜔 model) using the prescribed inlet boundary conditions agree well with the HWA measurement in the nearfield of confluent jets on a curved surface, except in the merging region. Instantaneous velocity measurements are performed by laser Doppler anemometry (LDA) and particle image velocimetry (PIV) in two different configurations, a single row of parallel coplanar jets and an inline array of jets on a flat surface. The results of LDA and PIV are compared, which exhibit good agreement except near the nozzle exits. The streamwise velocity profile of the jets in the initial region shows a saddle back shape with attenuated turbulence in the core region and two off-centered narrow peaks. When confluent jets issue from an array of closely spaced nozzles, they may converge, merge, and combine after a certain distance downstream of the nozzle edge. The deflection plays a salient role for the multiple interacting jets (except in the single row configuration), where all the jets are converged towards the center of the array. The jet position, such as central, side and corner jets, significantly influences the development features of the jets, such as velocity decay and lateral displacement. The flow field of confluent jets exhibits asymmetrical distributions of Reynolds stresses around the axis of the jets and highly anisotropic turbulence. The velocity decays slower in the combined regio  of confluent jets than a single jet. Using the response surface methodology, the correlations between characteristic points (merging and combined points) and the statistically significant terms of the three design factors (inlet velocity, spacing between the nozzles and diameter of the nozzles) are determined for the single row of coplanar parallel jets. The computational parametric study of the single row configuration shows that spacing has the greatest impact on the near-field characteristics.

The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. In this thesis, experimental apparatus, procedures and results are given on scaled-down experiments of SST Early Feed for hot-cell adaptation along with operating parameters and crystallization mechanism studies on early feed multi-solute crystallization. Moreover, guidance is given regarding future steps towards adapting the technology to multi-salt crystallization kinetic parameter estimates and modeling. Crystallization, Evaporative Fractional Crystallization, Nuclear Waste Pretreatment, Cesium Removal, Hanford, SST Early and Late feed, Multi-solute, Multi-salts, Simulant Testing