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Active research of SMAs has shown that its Seebeck coefficient is sensitive to its martensitic phase transformation and has the potential to determine the SMAs state of transformation. The combination of Shape Memory Alloys, which have a positive Seebeck coefficient, and Constantan which has a negative Seebeck coefficient (-35 mV/K) results in a thermocouple capable of measuring temperature. The work presented in this thesis is based on the development and design of this sensor. This sensor is used to study the hysteretic behaviour of SMAs. Although Shape Memory Alloys (SMAs) exhibit a myriad of nonlinearities, SMAs show two major types of nonlinear hysteresis. During cyclic loading of the SMAs, it is observed that one type of hysteretic behavior depends on the rate of heating the SMAs, whilst the variation of maximum temperature of an SMA in each cycle results in the other hysteretic behavior. This later hysteretic behavior gives rise to major and minor nonlinear loops of SMAs. The present work analyzes the nonlinearities of hysteretic envelopes which gives the different maximum temperatures reached for each hysteretic cycle with respect to stress and strain of the SMA. This work then models this behavior using Adaptive Neuro Fuzzy Inference System (ANFIS) and compares it to experimental results. The nonlinear learning and adaptation of ANFIS architecture makes it suitable to model the temperature path hysteresis of SMAs. / Master of Science

This thesis aims to provide a comprehensive reference on the effective integration of shape memory alloys into architectural design and design. Despite growing interest in SMAs for kinetic structures and adaptive facades, there is currently a fragmented understanding of how to leverage their unique properties in the built environment. Designers lack consolidated resources that map the capacities and limitations of different SMA materials and configurations with respect to functional objectives, manufacturing constraints, and performance goals. My research will gather dispersed knowledge across materials science, mechanics, and fabrication processes relevant to architectural SMAs. After conducting extensive research and different stages of prototyping, a final responsive wall piece will be designed and built that interacts with users responding to different stimuli including touch, sound, or distance. The outcome of this research on the integration of shape memory alloys (SMAs) into architectural design and construction can contribute significantly to designers and the field of architecture in several ways • Unlocking new design possibilities: • Facilitating interdisciplinary collaboration• Developing design guidelines and tools • Advancing responsive architecture• Inspiring future research and innovation / Master of Architecture / This thesis explores how new materials called Shape Memory Alloys (SMAs) can be used to make buildings more dynamic and responsive to their environment. SMAs are special because they can change shape when heated and return to their original form when cooled, much like magic metal. The research shows how SMAs can be used in architecture to create structures that move and adapt in response to changes in their surroundings. For example, building facades made with SMAs can automatically adjust to control sunlight and temperature, making buildings more energy-efficient and comfortable for people inside. A significant part of this study is a project where SMAs are used to create a wall that reacts to touch and other stimuli, bringing the wall to life in a way that interacts with people nearby. This work aims to inspire architects and designers to think beyond static structures and consider how buildings can become more interactive and environmentally friendly. Overall, this research opens up exciting possibilities for the future of building design, making our living and working spaces smarter and more in tune with our needs and the natural world.

NiTi based shape memory alloys (SMA) cover most of the commercially produced shape memory devices and components. The reversible martensitic transformation between the phases B2 (austenite) and B19′ (martensite) is responsible for the shape memory effect in these alloys. The amount of strain which can be regained after a permanent deformation through thermal activation, known as the recoverable strain, is a strong function of crystallographic texture and microstructure. Texture influences the activation of a specific martensite variant during stress induced martensitic (SIM) transformation and also the re-orientation of twinned variants during further deformation. The variant selection decides the amount of recoverable strain. Since the NiTi based shape memory alloys inevitably undergo thermo-mechanical processing in the course of component design, the consequent evolution of texture and microstructure regulate the shape memory behavior. The present thesis is aimed to address this issue in some NiTi alloys that are technologically important for different applications, namely a binary Ni-rich NiTi alloy, a copper containing NiTi alloy and a hafnium containing NiTi alloy. The Ni rich NiTi alloy displays pseudoelastic behavior that can be used for couplings, the NiTiCu alloy provides a controlled thermal hysteresis suitable for actuator applications and the NiTiHf alloy can be used for high temperature applications. The first Chapter of the thesis provides a detailed overview of the existing knowledge related to evolution of microstructure and texture during processing, the transformation texture and its role on the shape memory behavior in NiTi alloys. The second chapter includes the experimental procedure followed to generate different textures, namely unidirectional and cross rolling with and without a subsequent annealing and also the details of the techniques used to characterize the structure, microstructure, texture and mechanical properties. The evolution of texture during thermo-mechanical processing of a Ni rich NiTi alloy and its impact on shape memory behavior is addressed in Chapter 3. The two modes of rolling employed at higher temperature led to the formation of different textures. The texture of unidirectionally rolled samples was characterized by a strong <111>||ND fiber, while a strong Goss {100}<110> component along with <111>||ND fiber was observed in the texture of the cross rolled samples. Annealing of the unidirectionally rolled samples generated a strong <100>||ND fiber, and a weak <111>||ND fiber was observed for the cross rolled samples. Microtexture analyses indicated that dynamically recrystallized grains had significantly different texture compared to the statically annealed material. One of the salient features of this study is the analysis of different twin boundaries with coincident site lattice (CSL) relations that has been observed in the hot rolled material. The origin of these twins has been attributed to deformation. The evolution of twin boundaries with CSL relation has strong influence on texture formation. A few of the important texture components have been found to have CSL relation amongst them. The origin of different texture components were found using intra-grain misorientation parameters. In-situ transformation studies in a scanning electron microscope have confirmed the formation of different types of twins at very low amount of strain in the Ni rich NiTi alloy. A Schmid factor based criterion was used to identify the activation of a particular variant. Trace analysis of the surface relief due to SIM transformation was utilized to confirm the theoretically predicted variant. Schmid criterion has been found to be valid in all the cases. Modulus variation with temperature and strain was studied using dynamical mechanical analysis. Microstructural changes during thermal and thermo-mechanical cycling revealed higher orientation gradient along grain boundaries compared to grain interior. The compatibility condition at the grain boundaries were attributed to higher misorientation development. Misorientation development during cycling loading process is also found to be a strong function of texture. Processing condition and texture has a strong influence on the recoverable strain. Particularly, the strength of <111>||ND fiber is influential in deciding the recoverable strain. Study of microstructure and texture evolution in the TiNiCu SMA and subsequent study on its impact on recoverable strain is presented in Chapter 4. Convincing evidences for the mechanisms operating during different dynamic restoration processes have been presented through microstructural investigation. Texture analysis of the austenite phase showed the formation of <111>||ND fiber. Despite the weakening of texture at larger strain, strength of certain deformation texture components like S {123}<634> and Cu {112}<111> increased, which suggested that texture evolution in TiNiCu alloy deviates from the texture of binary NiTi at large strains. Transformation texture analysis was carried out through electron back scattered diffraction technique, using an in-situ heating stage. The analysis of the results showed predominant activation of <011> type II as well as {11 1 } type I twins. A comparison of martensite and austenite pole figures indicated strong variant selection during phase transformation. Like the binary NiTi alloy, cross rolling of TiNiCu alloy also showed ample changes in the texture of martensite phase through the formation of different texture components. Annealing of both unidirectionally and cross rolled samples led to the weakening of texture. The change in volume fraction of Ti2NiCu precipitates, resulting from different processing conditions, influenced the transformation temperature. In this case also, texture and large intra-grain misorientation governed the recoverable strain. Chapter 5 is dedicated to the study of high temperature NiTiHf alloy. X-ray diffraction and differential scanning calorimetric studies confirmed a two step martensitic transformation, a B19` monoclinic and rhombohedral R-phase martensite in the studied alloy (Ni49.4Ti38.6Hf12). Microstructural investigations showed the formation of dendritic (Ti,Hf)2Ni precipitates along the grain boundary. Evolution of R-phase martensite was always observed along with (Ti,Hf)2Ni precipitates, irrespective of the processing condition. Dissolution of (Ti,Hf)2Ni precipitates by solution treatment suppressed the R phase formation. Strong texture of R-phase martensite confirmed variant selection during martensitic transformation. On the contrary, texture of B19` martensite was always weak, suggesting no preference for variant selection. Rolled material with a relatively strong texture exhibited higher recoverable strain compared to annealed material. Finally, all the significant outcomes of the present investigation are summarized in Chapter 6. Based on the conclusions, suggestions for future work have been mentioned.

Le comportement des alliages à mémoire de forme (AMF) et des alliages à mémoire de forme magnétiques (AMFM) est régi par les mécanismes de transformation martensitique à l'échelle de la microstructure, à l'origine de leurs propriétés remarquables (mémoire de forme, superélasticité, grandes déformations associées à la réorientation martensitique sous champ magnétique). Les mécanismes de transformation et de réorientation martensitique peuvent être induits par des sollicitations thermiques, magnétiques et / ou mécaniques et de manière couplée. La mise au point d'outils de conception fiables nécessite une meilleure prédictibilité du comportement réel des alliages à mémoire de forme sous sollicitations thermo - magnéto - mécaniques complexes.Le choix d'une modélisation multiaxiale et multi échelle est pertinent. Le modèle reporté présente une formulation unifiée, permettant de simuler aussi bien le comportement des AMF que celui des AMFM.Parallèlement au développement de ce modèle, une étude expérimentale est nécessaire afin d'une part d'identifier les propriétés intrinsèques des matériaux étudiés, et d'autre part de valider les estimations de la modélisation. A cette fin, des mesures de fractions volumiques de phase par diffraction des rayons X in situ ont été entreprises lors de sollicitations thermiques (cycles de chauffage-refroidissement), mécaniques (traction, compression, essais biaxiaux) et magnétiques (champ magnétique unidirectionnel). L'exploitation des résultats de diffractométrie permet une analyse quantitative des fractions volumiques des phases en présence. Celles-ci sont comparées aux estimations du modèle à des fins de validation. / The behavior of shape memory alloys (SMA) and magnetic shape memory alloys (MSMA) is governed by the martensitic transformation mechanisms at the scale of the microstructure. This transformation is at the origin of their remarkable properties (memory effect, superelasticity, large deformations associated with the martensitic reorientation under magnetic field). The martensitic transformation and reorientation mechanisms can be induced by thermal, magnetic and / or mechanical stresses and in a coupled manner. The development of reliable design tools requires a better predictability of the actual behavior of shape memory alloys under complex thermal-magneto-mechanical loading.The choice of multiaxial and multiscale modeling is relevant. The model proposed in this work presents a unified formulation, making possible to simulate both the behavior of SMA and MSMA.In parallel with the development of this model, an experimental study is necessary in order to identify the intrinsic properties of the materials studied and to validate the estimates of the modeling. For this purpose, measurements of phase fractions by in-situ X-ray diffraction were carried out during thermal (heating-cooling cycles), mechanical (tensile, compressive, biaxial) and magnetic (unidirectional magnetic field) loadings. The diffraction patterns allow a quantitative estimation of the volume fractions of the phases. These are compared to model estimates for validation purposes.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The successful design, implementation and testing of a feedback control system for tab-deflection control of a shape memory alloy (SMA) based control surface actuator is presented. The research is performed as part of the Control Surfaces in Confined Spaces (CoSICS) research project conducted at Stellenbosch University. The research group investigates ways to provide control surface actuation in size-restricted spaces in commercial aircraft such as the Airbus A320 and A330. This is achieved by investigating the concept of trailing edge tabs to reduce the required torque load, resulting in reduced actuator requirements enabling the use of smaller actuators. This thesis contributes to the project by investigating the possibility of using SMA-based actuators in reduced hinge moment requirement applications. An SMA-based tab actuator demonstrator design is presented. Mathematical models are derived for the SMA material, thermodynamics and actuator geometry. The models are combined to formulate an SMA-based control surface actuator model. The model is utilised in four tracking feedback controller designs; two based on linear and two based on non-linear control techniques. The manufactured prototype is presented along with the incorporated hardware for controller implementation. System identification follows and validates the three mathematical models. Practical verification of the model and two of the controllers is conducted. The unimplemented controllers are implemented through a validated model simulation. Controller evaluation, based on the dynamic controller performance, is conducted. The results validate the concept of using an SMA actuator for tab-deflection control and indicate important limitations for the intended application. / AFRIKAANSE OPSOMMING: Die tesis behels die ontwerp, implementering en toetsing van ’n terugvoer beheerstelsel vir hulpvlak defleksie beheer van ’n vorm-geheue allooi (SMA) gebaseerde aktueerder. Die navorsing vorm deel van die Beheervlakke in Begrensde Ruimtes (CoSICS) navorsingsprojek by Stellenbosch Universiteit. Die CoSICS navorsing behels ’n ondersoek na beheervlak aktueering in beknopte spasies in kommersiële vliegtuie soos die Airbus A320 en A330. Die probleem word aangespreek deur ’n ondersoek na aerodinamiese hulpvlakke wat ’n vermindering in skarnier moment tot gevolg het en sodoende die aktueerder vereistes verminder. Hierdie tesis dra by tot die projek deur die moontlikheid van die gebruik van SMAgebaseerde aktueerders in verminderde skarnier moment vereiste toepassings te ondersoek. ‘n SMA gebaseerde hulpvlak demonstrasie aktueerder ontwerp word voorgelê. Wiskundige modelle vir die SMA materiaal, termodinamika en prototipe geometrie is geformuleer en gekombineer om ‘n SMA gebaseerde beheervlak aktueerder model te ontwikkel. Die model word in vier beheerder ontwerpe toegepas. Twee ontwerpe is op liniëre en twee op nie-liniëre beheer tegnieke gebaseer. Die prototipe en nodige hardeware vir beheerder implementasie is voorgedra. Stelsel identifikasie is toegepas en verifieer die drie wiskundige modelle. Praktiese verifikasie van die model en twee beheerders is gedoen. Die ongeïmplementeerde beheerders is deur die geverifieerde aktueerder model gesimuleer. ‘n Beheerder evaluasie gebaseer op die dinamiese beheerder gedrag word toegepas. Die evaluasie beklemtoon kritiese aspekte en beperkinge in verband met SMA aktueering. Die resultate regverdig die gebruik van ‘n SMA aktueerder vir hulpvlak defleksie beheer en beklemtoon belangrike beperkinge ten opsigte van die voorgestelde toepassing.

We report the fabrication of Ni2.7Mn0.9Ga0.4/InGaAs bilayers on GaAs (001)/InGaAs substrates by molecular beam epitaxy. To form freestanding microtubes the bilayers have been released from the substrate by strain engineering. Microtubes with up to three windings have been successfully realized by tailoring the size and strain of the bilayer. The structure and magnetic properties of both, the initial films and the rolled-up microtubes, are investigated by electron microscopy, X-ray techniques and magnetization measurements. A tetragonal lattice with c/a = 2.03 (film) and c/a = 2.01 (tube) is identified for the Ni2.7Mn0.9Ga0.4 alloy. Furthermore, a significant influence of the cylindrical geometry and strain relaxation induced by roll-up on the magnetic properties of the tube is found. / Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

The modeling, analysis and experimental verification of a two-degree-of-freedom typical aeroelastic section with superelastic shape memory alloy springs are presented. The focus is to investigate the effects of the phase transformation of the shape memory alloy springs on the flutter and post-flutter behaviors of the typical section. The shape memory alloy phase transformation kinetics is described by a modified version of well-known phenomenological models. The shape memory alloy spring model is based on classical spring design (with the pure shear assumption) and modified to account for the nonlinear effects of phase transformation. The cross-section of the shape memory alloy wire is represented by a linear radial distribution of shear strain and nonlinear radial distributions of shear stress and martensitic fraction. The equations of motion of a linear typical section are modified to include the shape memory alloy springs. A linear unsteady aerodynamic model is employed to determine the aerodynamic loads. The proposed model is cast into state-space representation and solved with a Runge-Kutta method. It is numerically and experimentally shown that the phase transformation of shape memory alloy springs can be effectively exploited to enhance the aeroelastic behavior of a typical section by replacing unstable flutter oscillations by stable oscillations of acceptable amplitudes over a range of airflow speeds, providing a useful method of passive aeroelastic control. Since the modified aeroelastic behavior is attractive for wind energy harvesting purposes, electromechanical coupling is also modeled in the plunge degree-of-freedom along with a resistive load in the electrical domain for electrical power estimation. The exploitation of the shape memory alloy phase transformation is more attractive for airfoil-based wind energy harvesting performance than the use of typical concentrated nonlinearities (e.g., hardening steel) in terms of enhanced electrical power output. / A modelagem, análise e verificação experimental de uma seção típica aeroelástica com dois graus de liberdade e molas com memória de forma superelásticas são apresentadas. O foco é investigar os efeitos da histerese pseudoelástica das molas com memória de forma nos comportamentos de flutter e pós-flutter da seção típica. A cinética das transformações de fase nas molas com memória de forma é descrita por uma versão modificada de modelos fenomenológicos amplamente conhecidos. O modelo de molas helicoidais com memória de forma é baseado em teoria clássica de molas (com a hipótese de cisalhamento puro) e modificado para representar os efeitos não lineares de transformação de fase. A seção transversal do fio da mola com memória de forma é representada por uma distribuição radial e linear de deformações de cisalhamento e por distribuições radiais e não lineares de tensões cisalhantes e de frações martensíticas. As equações de movimento de uma seção típica linear são modificadas para incluir as molas com memória de forma. Um modelo aerodinâmico linear não estacionário é utilizado para se determinar as cargas aerodinâmicas. O modelo proposto é representado em espaço de estados e resolvido com um método Runge-Kutta. Mostra-se, numérica e experimentalmente, que a histerese pseudoelástica de molas com memória de forma pode ser efetivamente explorada para melhorar o comportamento aeroelástico de uma seção típica ao transformar oscilações instáveis de flutter em oscilações estáveis e de amplitudes aceitáveis em uma faixa de velocidades do escoamento, provendo um método útil de controle aeroelástico passivo. Como o comportamento aeroelástico modificado (pela histerese pseudoelástica) é atrativo para a coleta de energia do escoamento, um acoplamento eletromecânico é modelado no grau de liberdade de deslocamento linear, juntamente com uma carga resistiva no domínio elétrico do problema para se estimar a potência elétrica gerada. A exploração da histerese pseudoelástica das molas com memória de forma é mais atrativa para a performance da coleta aeroelástica de energia do que o uso de não linearidades concentradas típicas (como o enrijecimento não linear do aço) em termos de melhoria na potência elétrica gerada.