Many techniques have been developed over the years in first world countries for the estimation of flood hydrographs from small catchments for application in design, management and operations of water related issues. However, relatively little attention has been directed towards the transfer and adaptation of such techniques to developing countries in which major hydrological decisions are crucially needed, but in which a scarcity of quality hydrological data often occurs. As a result, hydrologists and engineers in developing countries are frequently unable to alleviate the problems that extreme rainfall events can create through destructive flood flows or, alternatively, they do not possess the appropriate tools with which to design economically viable hydraulic structures. Eritrea is a typical example of a developing country which faces difficulties in regard to the adaptation of an appropriate design flood estimation technique for application on small catchments. As a result, the need has arisen to adapt a relatively simple and robust design flood model that can aid hydrologists and engineers in making economic and safe designs of hydraulic structures in small catchments. One objective of this study was, therefore, to review approaches to hydrological modelling and design flood estimation techniques on small catchments, in order to identify the barriers regarding their adaptation, as well as to assist in the selection of an appropriate technique for application, in Eritrea. The southern African adaptation of the SCS (i.e. Soil Conservation Service) design hydrograph technique, which has become a standard method for design flood estimation from small catchments in that region, was selected for application on small catchments in Eritrea for several reasons. It relies on the determination of a simple catchment response index in the form of an initial Curve Number (CN), which reflects both the abstraction characteristics and the non-linear stormflow responses of the catchment from a discrete rainfall event. Many studies on the use of SCS-based hydrological models have identified that adjustment of the initial CN to a catchment's antecedent soil moisture (ASM) to be crucial, as the ASM has been found to be one of the most sensitive parameters for accurate estimates of design flood volumes and peak discharges. In hydrologically heterogeneous regions like Eritrea, the hypothesis was postulated that simulations using a suitable soil water budgeting procedure for CN adjustment would lead to improved estimates of design flood volumes and peak discharges when compared with adjustments using the conventional SCS antecedent moisture conditions (SCS-AMC) method. The primary objective of this dissertation was to develop a surrogate methodology for the soil water budgeting procedure of CN adjustment, because any direct applications of soil water budgeting techniques are impractical in most parts of Eritrea owing to a scarcity of adequate and quality controlled hydrological information. It was furthermore hypothesised that within reasonably similar climatic regions, median changes in soil moisture storage from the socalled "initial" catchment soil moisture conditions, i.e. LIS, were likely to be similar, while between different climatic regions median LISs were likely to be different. Additionally, it was postulated that climatic regions may be represented by a standard climate classification system. Based on the above hypotheses, the Koppen climate classification, which can be derived from mean monthly rainfall and temperature information, was first applied to the 712 relatively homogeneous hydrological response zones which had previously been identified in southern Africa. A high degree of homogeneity of median values of LIS, derived by the daily time step ACRU soil moisture budgeting model, was observed for zones occurring within each individual Koppen climate class (KCC) - this after a homogeneity test had been performed to check if zones falling in a specific KCC had similar values of median LIS. Further assessment within each KCC found in southern Africa then showed that a strong relationship existed between LIS and Mean Annual Precipitation (MAP). This relationship was, however, different between KCCs. By developing regression equations, good simulations of median LIS from MAP were observed in each KCC, illustrating the potential application of the Koppen climate classification system as an indicator of regional median LIS, when only very basic monthly climatological information is available. The next critical task undertaken was to test whether the estimate of median LIS from MAP by regression equation for a specific Koppen climate class identified in southern Africa would remain similar for an identical Koppen climatic region in Eritrea. As already mentioned, LIS may be determined from daily time step hydrological soil moisture budget models such as ACRU model. The performance of the ACRU stormflow modelling approach was, therefore, first verified on an Eritrean gauged research catchment, viz. the Afdeyu, in order to have confidence in the use of values of LIS generated by it. A SCS-ACRU stormflow modelling approach was then tested on the same catchment by using the new approach of CN adjustment, termed the ACRU-Koppen method, and results were compared against stormflow volumes obtained using the SCS-AMC classes and the Hawkins' soil water budgeting procedures for CN adjustment, as well as when CNs remain unadjusted. Despite the relatively limited level of information on climate, soils and land use for the Afdeyu research catchment, the ACRU model simulated both daily and monthly flows well. By comparing the outputs generated from the SCS model when using the different methods of CN adjustment, the ACRU-Koppen method displayed better levels of performances than either of the other two SCS-based methods. A further statistical comparison was made among the ACRU, the SCS adjusted by ACRU-Koppen, the SCS adjusted by AMC classes and the unadjusted SCS models for the five highest stormflows produced from the five highest daily rainfall amounts of each year on the Afdeyu catchment. The ACRU model produced highly acceptable statistics from stormflow simulations on the Afdeyu catchment when compared to the SCS-based estimates. In comparing results from the ACRU-Koppen method to those from the SCS-AMC and unadjusted CN methods it was found that, statistically, the ACRU-Koppen performed much better than either of the other two SCS based methods. On the strength of these results the following conclusions were drawn: • Changes in soil moisture storage from so-called "initial" catchment soil moisture conditions, i.e. L1S, are similar in similar climatic regions; and • Using the ACRU-Koppen method ofCN adjustment, the SCS-SA model can, therefore, be adapted for application in Eritrea, for which Koppen climates can be produced from monthly rainfall and temperature maps. Finally, future research needs for improvements in the SCS-ACRU-Koppen (SAK) approach in light of data availability and the estimation ofL1S were identified. From the findings of this research and South African experiences, a first version of a "SCSEritrea" user manual based on the SAK modelling approach has been produced to facilitate its use throughout Eritrea. This user manual, although not an integral part of this dissertation, is presented in its entirety as an Appendix. A first Version of the SCS-Eritrea software is also included. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2004.

The present work is a contribution to description and understanding of the distribution and movement of water in swelling soils. In order to investigate the moisture distribution in swelling soils a detailed knowledge of volume change properties, flow characteristics and total potential of water in the soil is essential. Therefore, a possible volume change mechanism is first described by dividing the swelling soils into four categories and volume change of a swelling soil is measured under different overburden pressures. The measured and calculated (from volume change data) overburden potential components are used to check the validity of the derivation of a load factor, ∝. Moisture diffusivity in swelling soil under different overburden pressures is measured using Gardner's (1956) outflow method. Behaviour of equilibrium moisture profiles in swelling soils is theoretically explained, solving the differential equation by considering the physical variation of individual soil properties with moisture content and overburden pressure. Using the measured volume change data and moisture potentials under various overburden pressures, the behaviour of possible moisture profiles are described at equilibrium and under steady vertical flows in swelling soils. It is shown that high overburden pressures lead to soil water behaviour quite different from any previously reported.

The intensification of biofuel production causes negative impacts on soil quality, thus the soil requires adequate assessment to ascertain its quality status, however site-specific nature of results in literature requires independent soil property measurement and assessment depending on specific agroecosystem and management goals. Therefore, the main objective of this study was to investigate seasonal pattern of soil quality, soil water and thermal regimes and performance of sugarcane and tung crops at the experimental station of Soils Department, Federal University of Santa Maria, Santa Maria, RS, Brazil. The sugarcane experiment (three seasons) was established in 2010 under no-tillage; no-tillage + compaction; conventional tillage and chiseling treatments in a randomized complete block design with three replications. In years 2011 and 2012, there was no soil disturbance; however residue mulching was imposed, giving split-plot design. The tung-based cropping system (two seasons, 2012-2014) was a randomized complete block design experiment with four replications. The treatments were: tung-crambe-sunflower/soybean + inorganic fertilizer; tung-crambe-sunflower/soybean + organic manure; tung-oats-peanut; and sole tung (control). Crambe and oats were planted in winter while sunflower (1st year)/soybean (2nd year) and peanut were planted in summer. Disturbed and undisturbed (using cores of known volume) soil samples were collected from soil layers 0-10, 10-20, 20-40 and 40-60 cm in sugarcane, and 0-10, 10-20, 20-40, 40-60 and 60-80 cm in tung for the laboratory determination of soil quality indicators. There was field monitoring of soil water retention, matric potential and soil temperature and agronomic parameters measured include sugarcane yield and tung plant height. Minimum data set for soil quality assessment was made using principal component analysis and soil quality index was obtained using weighted additive method. The temporal patterns of soil water storage and temperature were evaluated using algorithms for time series data. Except for Ma in 0-10 cm layer of tillage plots, both tillage and residue mulching did not significantly affect (p<0.05) the soil quality indicators, overall soil quality, water retention and sugarcane yield. The degree of compaction was not enough to limit sugarcane growth. Residue retention significantly influenced temporal processes of soil temperature and state-time analysis was better than classical regression of time series analysis of soil water storage and temperature. Cropping system did not significantly influence (p<0.05) soil quality indicators, overall SQI and tung plant height, but significant influenced soil water retention. For the two experiments, there was no discernible trend in the seasonal values of soil hydro-physical variables and crop response. / A intensificação da produção de biocombustíveis pode prejudicar a qualidade do solo. Portanto, para evitar a degradação do solo é necessário monitorar periodicamente os atributos mais afetados pela atividade agrícola. Assim, o objetivo deste estudo foi investigar o padrão sazonal da qualidade, da água e regimes térmicos do solo, bem como o desempenho das culturas da cana-de-açúcar e do tungue na estação experimental do Departamento de Solos da Universidade Federal de Santa Maria, Santa Maria, RS, Brasil. Para isso foram avaliados dois experimentos. O experimento de cana-de-açúcar (três anos de cultivo) foi implantado em 2010 e os tratamentos foram: plantio direto; plantio direto com compactação adicional; preparo convencional e; escarificado, distribuídos em um delineamento de blocos casualizados com três repetições. Nos anos de 2011 e 2012, não houve revolvimento do solo, mas foi adicionada cobertura vegetal morta, designando um esquema de parcelas subdivididas. Para o sistema de cultivo do tungue (dois anos de cultivo, 2012-2014) foi utilizado um experimento de blocos ao acaso com quatro repetições. Os tratamentos foram: tungue-crambe-girassol / soja com fertilizantes inorgânicos; tungue-crambe-girassol / soja com adubação orgânica; tungue-aveia-amendoim; e tungue (controle). Crambe e aveia foram plantadas no inverno, enquanto girassol (1° ano) / soja (2º ano) e amendoim foram plantados no verão. Amostras de solo com estrutura alterada e preservada foram coletadas (usando cilindros com 57 mm de diâmetro e 40 mm de altura) nas camadas de 0-10, 10-20, 20-40 e 40-60 cm na cana-de-açúcar, e de 0-10, 10-20, 20-40, 40-60 e 60-80 cm no tungue para a determinação laboratorial dos indicadores de qualidade do solo. Houve o monitoramento á campo da temperatura, umidade potencial matricial da água no solo e parâmetros agronômicos incluindo a produtividade da cana-de-açúcar e altura da planta de tungue. Um conjunto mínimo de dados para a avaliação da qualidade do solo foi obtido através da análise de componentes principais e o índice de qualidade do solo foi obtido pelo método aditivo ponderado. Os padrões temporais de armazenamento de água do solo e a temperatura do solo foram avaliados utilizando algoritmos para dados de séries temporais. Exceto para a macroporosidade, na camada de 0-10 cm dos tratamentos com preparo do solo, o preparo e a cobertura de palha não afetaram significativamente (p <0,05) os indicadores de qualidade do solo, o índice de qualidade do solo, a retenção de água ou a produtividade de cana-de-açúcar. O grau de compactação não foi suficiente para limitar o crescimento da cana-de-açúcar. A permanência da palha na superfície influenciou significativamente os processos temporais de temperatura do solo e a análise temporal foi melhor do que a análise de regressão clássica para a análise das séries temporais de armazenamento de água e temperatura do solo. O sistema de cultivo não influenciou significativamente (p<0,05) os indicadores de qualidade do solo, o índice de qualidade do solo e a altura da planta, mas influenciou significativamente a retenção de água do solo. Nos dois experimentos, não houve nenhuma tendência clara nos valores sazonais de variáveis físico-hídricas do solo e na resposta da cultura.

The present work was accomplished in a slope with a pedological system composed of Red Argisol/Gleysol, in a pasture area located in an unit of agricultural production in the municipal district of Santa Maria - RS. It aimed at the characterization morphologic and the physic-hydrical and the discretization of the variability of the loss of soil of the slope. Thirteen aligned profiles were selected in a toposequency, of a total of 57, reconstituted by the polls method. After description the approach of the pedologic system in the thirteen profiles, considering the vertical and lateral succession of the verified horizons, the samples were collected for the chemical and physical-hydrical determinations in laboratory (texture, densities, porosities, retention hydrical and availability of water, saturated hydraulic conductivity and permeability to the air), in three sampling orientations. Furthermore, the soil losses were estimated through the coupling of the Universal Equation of Loss of the Soil - RUSLE, in SIG atmosphere. In the toposequency, three profiles were classified as Gleysol and the others as Red Argisol. Argisols and Gleysols presented variated chemical and physical limitations, producing strong use limitation. The horizons Bt in Argissolos are found in different depths in the studied profiles, implicating different behaviors, depending on the thickness of the horizons upper (suprajacente) The physical-hydrical dynamics of the system is marked by a different behavior among the surface (loam) and the subsurface (clayer), and it should be understood, considering the group of the horizons of each profile, to predict the physical-hydrical behavior of the soil. The saturated hydraulic conductivity of the soil presented a variation along the horizons of the soil profiles in different positions of the landscape, with great differences among the values observed in surface in relation to the ones of the subsurface, identifying the existence of a lateral flow of water in the soil, mainly in the portion of the hillside and its space variation in a topographical sequence. In the podzolic cover, the blockade of vertical drainage occurs in the top of the horizon Bt, generating a more humid zone above. The smallest retention of water in all the profiles occured in the loam horizons, Ap and A1, in all the tensions, while in the deepest horizons, Bt1 and Bt2, there was a larger retention as a consequence of the decrease of the sand tenor and increase of the clay tenor. The transition horizons, AB and BA, presented an intermediate behavior. The available water in the soil for the plants was influenced directly by the texture, which increased with the increment of the sand fraction and it decreases with the increase of the clay fraction. With the drier of the soil the permeability to the air tends to increase due to the drainage of the water of the pores which start to conduct air, being highly dependent of the macroporosity. The animal trampling and the preparation operations promoted an increase of the soil density, resulting in the reduction of the total porosity and of the macroporosity and consequently an increase in the microporosity in the horizons Ap and A1, which suffer the direct effects of the anthropic activity. The methodology application that engagement RUSLE in atmosphere SIG, allowed the discretization of the space variability of the factors that determine the losses, as well as the soil losses in a slope of the Central Depression of RS. / O presente trabalho foi realizado em uma vertente com sistema pedológico composto de Argissolo/Gleissolo, em área de pastagem, localizada em uma unidade de produção agropecuária, no município de Santa Maria RS. Objetivou-se, a caracterização morfológica e físico-hídrica e a discretização da variabilidade das perdas de solo da vertente. Foram selecionados treze perfis alinhados em uma topossequência, de um total de 57, descritos pelo método de tradagem. Após abordagem morfológica do sistema pedológico nos treze perfis, considerando a sucessão vertical e lateral, dos horizontes constatados, procederam-se as coletas de amostras para as determinações químicas e análise granulométricas, e em três orientações de amostragem as determinações físicohídricas (densidades, porosidades, retenção hídrica, condutividade hidráulica do solo saturado e permeabilidade ao ar). Além disso, foi estimada as perdas de solo através do acoplamento da Equação Universal de Perda do Solo RUSLE, em ambiente SIG. Na topossequência, três perfis foram classificados como Gleissolo e os demais como Argissolo Vermelho. Os Gleissolos apresentaram limitações variadas decorrentes do excesso de água e os Argissolos limitações químicas e físicas. O horizonte Bt nos Argissolos, encontra-se em profundidades variadas nos perfis estudados, implicando comportamentos distintos, dependendo da espessura do (s) horizontes (s) suprajacente (s). A dinâmica físico-hídrica do sistema, caracteriza-se por um comportamento distinto entre a superfície (textura média) e a subsuperfície (textura argilosa) devendo ser compreendida, considerando o conjunto dos horizontes de cada perfil, para predizer o comportamento físico-hídrico do solo. A condutividade hidráulica do solo apresentou variação ao longo dos horizontes dos perfis de solo em diferentes posições da paisagem, ocorrendo grandes diferenças entre os valores observados em superfície em relação a subsuperfície, identificando-se a existência de fluxo lateral de água no solo, principalmente, na porção da encosta e a sua variação espacial em uma sequência topográfica. Na cobertura argissólica, o bloqueio de drenagem vertical ocorre no topo do horizonte Bt, originando acima deste uma zona mais úmida. A menor retenção de água em todos os perfis ocorreu nos horizontes com textura média, Ap e A1, em todas as tensões, enquanto que nos horizontes mais profundos, Bt1 e Bt2, houve maior retenção, como consequência da diminuição do teor de areia e aumento do teor de argila. Os horizontes de transição, AB e BA, apresentaram um comportamento intermediário. A água disponível no solo para as plantas foi influenciada diretamente pela granulometria, aumentando nos horizontes com maior percentual de areia e diminuindo com o aumento da fração argila. Com o secamento do solo a permeabilidade ao ar tende a aumentar devido à drenagem da água dos poros os quais passam a conduzir maior quantidade de ar, sendo altamente dependente dos macroporos. O pisoteio animal e as operações de preparo promoveram aumento da densidade do solo, resultando na redução da porosidade total e da macroporosidade e consequentemente um aumento na microporosidade nos horizontes Ap e A1, os quais sofrem os efeitos diretos das atividades antrópicas. A aplicação de metodologia que acopla a RUSLE em ambiente SIG, permitiu a discretização da variabilidade espacial dos fatores que influenciam as perdas, bem como as perdas de solo de uma vertente da Depressão Central do RS.

Made available in DSpace on 2014-07-29T16:24:18Z (GMT). No. of bitstreams: 1 Dissertacao Rogerio Gomes Pereira.pdf: 1311913 bytes, checksum: 594d4803b27bb1b817ac16d754681cbb (MD5) Previous issue date: 2011-02-14 / The average national rice yield was 11,3 million tones, with a harvested area of about 2,7 million hectares (IBGE 2010). Part of this comes from upland production systems in savannas that have high acidity, low fertility, with low phosphorus and potassium levels, low cation exchange capacity and high aluminum saturation. Upland rice in the Brazilian savannas (Cerrados) experiences multiple abiotic stresses and is characterized by high levels of uncertainty caused by rainfall variability. The increasing consumption of plant biomass to generate energy has produced products and by-products with high potential for agricultural use. Among these products is charcoal, that, due to its physical-chemical and molecular properties, have beneficial effects for the physical, chemical and biological soil characteristics. The objective of this work was to investigate the effect of charcoal on soil chemical properties and on the development of upland rice, and on the transpiration rate response of upland rice as an alternative to decrease the effect of drought on its growth and development. Two pot experiments were carried out using a random split-plot experimental design. The main treatments (plots) were water stress (WS) and no-water stress (NWS) and the sub treatments (subplots) were different biochar doses, 0% or control (T1), 6% (T2), 12% (T3) and 24% (T4) in growing medium (sand). The plastic pots were randomized within the sub plots with six replications. The total transpirable soil water (TTSW), the p factor, defined as the average fraction of TTSW that can be depleted from the root zone before reduction in transpiration occurs and the normalized transpiration rate (NTR) were determined. Charcoal significantly increased dry matter accumulation and leaf area of rice plants in both experiments and positively affected the chemical and physical soil properties such as water retention and nitrate availability to the plants. Biochar addition increased TTSW, p factor and reduced NTR. Consequently, biochar addition was able to change the moisture threshold (p factor) of the growing medium, up to a maximum concentration of 12%, hence delaying the point where transpiration declines and affects yield. / A safra nacional de arroz foi de 11,3 milhões de toneladas, com uma área colhida de aproximadamente 2,7 milhões hectares (IBGE 2010). Parte desta produção é cultivada em sistema de sequeiro sob solos de cerrados que é caracterizado por apresentar elevada acidez e baixa fertilidade natural, com baixos teores de fósforo, potássio, capacidade de troca catiônica e elevada saturação por alumínio. O arroz de terras altas cultivado no Brasil Central (Cerrados) experimenta múltiplos estresses abióticos e sua produtividade é caracterizada pela incerteza devido à variabilidade na precipitação. O crescente consumo de biomassa vegetal para a geração de energia tem disponibilizado subprodutos com alto potencial para o uso agrícola. Dentre esses subprodutos, destaca-se o carvão vegetal, que devido as suas características físico-químicas e moleculares, tem-se mostrado benéfico para as propriedades físicas, químicas e biológicas do solo. O objetivo deste estudo foi analisar os efeitos de diferentes doses de carvão vegetal de eucalipto na produção de matéria seca na cultura do arroz de terras altas e nas características físico-químicas e hídricas em substrato areia, e na resposta da taxa de transpiração do arroz de terras altas como uma alternativa para minimizar os efeitos da seca no seu desenvolvimento e crescimento. Dois experimentos em vasos foram realizados por meio do delineamento em parcela sub-dividida. A parcela principal foi constituída pelo tratamento deficiência hídrica (WS) e não deficiência hídrica (NWS) e as sub-parcelas pelas diferentes doses de carvão; 0% (controle, T1), 6% (T2), 12% (T3) e 24% (T4) adicionadas no substrato (areia). Os vasos foram inteiramente casualizados nas sub-parcelas com seis repetições por dose de carvão. A quantidade de água transpirável no solo (TTSW), o fator de depleção (p), definido como a fração de água disponível no solo que pode ser retirada da zona radicular antes de ocorrer a redução da taxa de transpiração, e a taxa de transpiração normalizada (NTR) foram determinadas. A adição de carvão ao substrato proporcionou um aumento significativo na produção de matéria seca e área foliar das plantas de arroz em ambos os experimentos. Nos tratamentos T2, T3 e T4, a adição de carvão vegetal alterou significativamente as características químicas e físico-hídricas do solo, aumentando a retenção de água e a disponibilidade de nitrato para as plantas. A adição de carvão aumentou a TTSW, o fator p e reduziu a NTR. Conseqüentemente, o carvão foi responsável por modificar o fator p, até uma concentração máxima de 12% e retardar o ponto no qual o declínio da transpiração afeta o rendimento.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.

Cette thèse concerne la caractérisation expérimentale d’un sable limoneux provenant du barrage de Livet – Gavet (38) dans le cadre du projet ANR TerreDurable avec plusieurs objectifs : 1- Caractériser au travers d’essais de laboratoire le comportement hydromécanique d’un sable fin limoneux (sol A1 dans la classification GTR) en fonction de son état de saturation. Lors de cette étude, un accent particulier est porté sur la caractérisation de ce comportement dans le domaine proche de la saturation. 2- Interpréter le comportement hydrique du matériau sur chemin de drainage – imbibition en relation avec l’analyse de sa microstructure. 3- Fournir d’un point de vue général une base de données et d’analyses exhaustive permettant le développement et la calibration de modèles de comportement des sols fins proches de la saturation, en particulier en considérant des chemins de chargement hydromécanique complexes. Pour l’ensemble de cette étude, le matériau est considéré sous deux états : soit à l’état de pâte (matériau normalement consolidé) préparée à une teneur en eau proche de la limite de liquidité, soit sous forme compactée (matériau sur-consolidé) à différentes énergies de compactage et différentes teneurs en eau initiales. / This thesis concerns the experimental characterization of a silty sand from the Livet - Gavet dam (38) as part of the ANR TerreDurable project, for following objectives: 1- Through laboratory tests, characterize the hydro-mechanical behaviour of a fine silty sand (Type A1 in the GTR classification) according to its saturation state. In this study, particular emphasis is placed on the characterization of this behaviour in the near-saturated domain. 2- Interpret the water behaviour of material on the drainage - imbibition cycles, in relation to the analysis of its microstructure. 3- From a general point of view, provide a comprehensive database and analysis allowing the development and calibration of models of near-saturated fine soil's behaviour, in particular, by considering complex hydro-mechanical loading paths. For all tests in this study, the material is considered in two states: either in the state of paste (normally consolidated material) prepared at water content close to the limit of liquidity, or in compacted state (over consolidated material) at different compaction energies and different initial water contents.

Le biome boréal, emmagasinant d’importantes quantités de carbone en son sol et recouvrant une majorité du territoire alaskien, fennoscandien et russe, contribue grandement au système climatique. Toutefois, les variabilités climatiques et les propriétés de l’écosystème, notamment en ce qui a trait à la présence ou l’absence de pergélisol, complexifient la quantification de la variabilité des bilans de carbone du biome boréal, au sein duquel se retrouvent des écosystèmes forestiers, lentiques et de zones humides. Ces bilans de carbone sont grandement influencés par le début et la fin de la saison de croissance photosynthétique, étant à leur tour dépendants de plusieurs variables environnementales telles que la température de l’air et du sol, le contenu du sol en eau, les stades de développement de la végétation, etc. Cette recherche vise à quantifier l’impact de ces variabilités environnementales sur la variabilité des moments où se produisent le début et la fin de la saison de croissance photosynthétique, en distinguant les forêts boréales avec et sans pergélisol. La saison de croissance photosynthétique est caractérisée à partir de la productivité primaire brute dérivée de mesures covariance des turbulences provenant de 40 sites-années d’observation à travers la forêt boréale nord-américaine où l’épinette noire est l’espèce d’arbre dominante. Les variables environnementales considérées étaient les températures de l’air et du sol, les stades de développement de la végétation, le couvert nival, le rayonnement photosynthétiquement actif et le contenu du sol en eau. Le cadre statistique choisi incluait le calcul des coefficients de corrélations de Pearson, l’analyse des points communs et la modélisation par équations structurelles. Les résultats de cette étude montrent que la variabilité du début de la saison de croissance dans les sites sans pergélisol est contrôlée directement par la variabilité annuelle des stades de développement de la végétation ainsi que par le moment où survient le dégel du sol. Ce résultat souligne ainsi l’importance de l’accès à l’eau liquide du sol afin que la végétation initie la photosynthèse. Aucune variable environnementale ne pouvait significativement expliquer le contrôle du début de la photosynthèse au sein des sites avec pergélisol. À l’automne, le contenu du sol en eau ainsi que le début du couvert nival influencent directement la variabilité de la fin de la saison de croissance photosynthétique. Il est alors montré que la disponibilité de l’eau peut mener à une cessation plus hâtive de la photosynthèse à l’automne. L’effet de l’apparition du couvert nival est quant à lui opposé dans les sites avec et sans pergélisol. Son retard dans les sites sans pergélisol témoigne d’une température de l’air suffisamment élevée pour que les précipitations tombent sous forme liquide, prolongeant ainsi les activités photosynthétiques. Son retard dans les sites avec pergélisol signifie plutôt des précipitations neigeuses moindres, retardant ainsi l’apparition d’une couche isolante pour le sol, qui aurait pu allonger la saison de croissance photosynthétique. Cette étude contribue à clarifier les processus contrôlant le début et la fin de la saison de croissance photosynthétique et aidera à améliorer la compréhension des effets des changements climatiques sur la force du puits de carbone de la forêt boréale nord-américaine. / The boreal forest, storing large amounts of carbon in its soil and covering a majority of the Alaskan, Canadian, Fennoscandian and Russian territory, is an integral part of the climate system. However, climatic variability and ecosystem properties, particularly with regards to the presence or absence of permafrost, limits our understanding of the carbon balance variability in the boreal biome, which comprises forest, lake and wetland ecosystems. The boreal carbon sink-source strength is greatly influenced by phenological events, including the start and end of the photosynthetic growing season, which are themselves dependent on several environmental variables such as air and soil temperature, soil water content, vegetation development stages, etc. This research aims to provide new insights on the influence of environmental variability on the variability in the timing of the photosynthetic growing season, by broadly distinguishing between boreal forests with and without permafrost. The photosynthetic growing season is characterized using gross primary productivity derived from eddy covariance measurements of net ecosystem carbon dioxide exchange. Data from 40 black spruce- dominated site-years of observation across the North American boreal forest are used. The considered environmental predictors were air and soil temperatures, vegetation development stages, snow cover, photosynthetically active radiation and soil water content. The statistical framework included the calculation of Pearson correlation coefficients, commonality analyses and structural equation modeling. This study shows that the variability in the start of the growing season in permafrost-free sites is directly controlled by the variability in vegetation development stage as well as by the thawing of seasonally frozen ground. This result thus emphasizes the importance of access to liquid soil water for the vegetation to initiate photosynthesis. No environmental variable could significantly explain photosynthesis recovery in sites with permafrost. In fall, the soil water content as well as the start of snow cover directly influence the variability in the end of the photosynthetic growing season. These results suggest that the availability of water can limit photosynthesis in the fall. The effect of snow cover is opposite in sites with and without permafrost. A delay in the appearance of continuous snow cover in sites without permafrost indicates that the air temperature is high enough for precipitation to fall in liquid form and for photosynthesis to continue. In contrast, its delay in sites with permafrost indicates less snowfall, thus delaying the appearance of an insulating layer for the soil, which could have lengthened the photosynthetic growing season. This study sheds light on the controls of the annual variation of the timing of the photosynthetic growing season and will help understanding of the effects of climate change on the strength of the North American boreal forest carbon sink.

Dynamic soil water repellency is an important soil phenomenon in the vadose zone as it is now recognised that most soils in the world are likely to express some degree of reduced wettability and/or long term hydrophobicity. Fractional wettability and contact angles are, however, rarely discussed or quantified for natural systems. This is particularly the case in the presence of dynamic contact angles. Soil water repellency remains a persistent impediment and challenge to accurate conceptual and numerical models of flow and storage in the vadose zone. This dissertation addresses the opportunity and pressing need for contributions that develop better quantifiable definitions, descriptions, and understanding of soil water repellency. Using materials collected from post wildfire sites, this work employs water and ethanol to identify, isolate, and quantify contact angle dynamics and fractional wettability effects during infiltration. Varied concentrations of water and ethanol solutions were applied to soils and observed through X-ray microtomography, tension infiltration experiments, and moisture content measurements in the laboratory and field. Several analyses from lab and field investigations showed that applications of ethanol and specifically, water-ethanol aqueous solutions provide unique additional insights into proportions of media that remain non-wettable and how those proportions affect overall hydrologic processes, which are not readily observable through water infiltrations alone. Observations include the wetting up of microporous structures, reduced storage, and changes in unsaturated hydraulic conductivities. Challenges which develop as a consequence of variable fluid properties including changes to operational pore assemblages, slow down of wetting fronts, and non-uniqueness relative to infiltration responses are addressed. Important insights and contributions were developed through this approach and water-ethanol mixtures are valuable tools for developing greater quantification and mechanistic data to better inform our models and understanding of dynamic soil water repellency. / Dissertation / Doctor of Philosophy (PhD) / Quantifying fluid behaviours in soils is important for a host of environmental, social, and economic reasons. Over the last 25+ years, one soil phenomenon has garnered increased attention because it interferes with our ability to carry out this work. Soils that are or become water repellent develop all over the world and where hydrophobic or non-wetting substances can enter soil and remain in pore spaces or as coatings on particles. To assist in the tracking and management of its complex effects on water storage and infiltration, the goals of this work were to develop fundamental insights into the manifestation and effects of this variable soil property on key hydrologic properties and processes. This work tests a new conceptual model for understanding these systems through both field and laboratory work and using a number of different technologies. These include X-ray microtomography (μXCT), tension infiltrometry, and more regularly applied techniques which are sensitive to changes in repellency. The works shows how combining fractional wettability and contact angle dynamics generates a stereoscopic conceptual framework which facilitates increased capacity for quantifying and understanding of soil systems expressing dynamic soil water repellency.