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Optical studies of InGaN/GaN quantum well structuresDavies, Matthew John January 2014 (has links)
In this thesis I present and discuss the results of optical spectroscopy performed on InGaN/GaN single and multiple quantum well (QW) structures. I report on the optical properties of InGaN/GaN single and multiple QW structures, measured at high excitation power densities. I show a correlation exists between the reduction in PL efficiency at high excitation power densities, the phenomenon so-called ``efficiency-droop'', and a broadening of the PL spectra. I also show a distinct change in recombination dynamics, measured by time-resolved photoluminescence (PL), which occurs at the excitation power densities for which efficiency droop is measured. The broadening of the PL spectra at high excitation power densities is shown to occur due to a rapidly redshifting, short-lived high energy emission band. The high energy emission band is proposed to be due to the recombination of weakly localised/delocalised carriers occurring as a consequence of the progressive saturation of the local potential fluctuations responsible for carrier localisation, at high excitation power densities. I report on the effects of varying threading dislocation (TD) density on the optical properties of InGaN/GaN multiple QW structures. No systematic relationship exists between the room temperature internal quantum efficiency (IQE) and the TD density, in a series of nominally identical InGaN/GaN multiple QWs deposited on GaN templates of varying TD density. I also show the excitation power density dependence of the PL efficiency, at room temperatures, is unaffected for variation in the TD density between 2 x107 and 5 x109 cm-2. The independence of the optical properties to TD density is proposed to be a consequence of the strong carrier localisation, and hence short carrier diffusion lengths. I report on the effects of including an InGaN underlayer on the optical and microstructural properties of InGaN/GaN multiple QW structures. I show an increase in the room temperature IQE occurs for the structure containing the InGaN underlayer, compared to the reference. I show using PL excitation spectroscopy that an additional carrier transfer and recombination process occurs on the high energy side of the PL spectrum associated with the InGaN underlayer. Using PL decay time measurements I show the additional recombination process for carriers excited in the underlayer occurs on a faster timescale than the recombination at the peak of the PL spectrum. The additional contribution to the spectrum from the faster recombination process is proposed as responsible for the increase in room temperature IQE.
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Posouzení vlastností řezné hrany ocelového plechu při tavném a oxidační řezání pevnolátkovým laserem / Evaluation the properties of the cutting edge in fusion and flame cutting by solid state lasersDočekal, Miroslav January 2015 (has links)
The thesis compares oxidation and fusion laser cutting methods in the production of sheet components called Trager consoles. Individual methods of laser cutting are compared in terms of achieved quality and properties of cutting areas. Consequently, the effect of these properties on consecutive technological operations, which are mainly threading and pressing the nuts into components, are evaluated. In the experimental part of the thesis the roughness of cut surfaces was measured and the cuts were classified into quality classes according to the ČSN EN ISO 9013 standard. Metallographic samples were taken in order to measure hardness and determine its course in the direction from the cutting edge into the material. The metallographic samples were further used for capturing detailed images on the microscope and assessing the quality of nuts pressing. Afterwards, the cut moments affecting taps were measured in order to verify the impact of cutting edge properties on threading. These measurements provided sufficient data for comparing the influence of cutting edge properties in individual methods of laser cutting on consecutive operations. Finally, individual methods were compared in terms of production costs. According to all the data and the conclusions reached, fusion method was identified as the most suitable method of laser cutting for components manufacturing.
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Bioinformatický nástroj pro predikci struktury proteinů / Bioinformatics Tool for Protein Structure PredictionPlaga, Michal January 2016 (has links)
The goal of this thesis is test and comparation of the offline tools for prediction of protein structure and creation of metaprediktor, which allows the user to select the appropriate tool, according to given parameters. Testing tool is based on a dataset of proteins, which is based on the SCOP database and it is trying to be as balanced as possible to include proteins from different families and thus could best evaluate individual tools. The results of this thesis are requirements of metaprediktor and also which data and settings can be allowed and processed and how it will be implemented.
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[en] PARALLEL PROGRAMING IN THE REDIS KEY-VALUE DATASTORE / [pt] PROGRAMAÇÃO PARALELA NO BANCO DE DADOS CHAVE-VALOR REDISJUAREZ DA SILVA BOCHI 12 April 2016 (has links)
[pt] Redis é um banco de dados chave-valor de código livre que dá suporte à
avaliação de scripts Lua, mas sua implementação utiliza apenas uma tarefa
de sistema operacional. Scripts longos são desencorajados porque a avaliação
do código é bloqueante, o que pode causar degradação de desempenho para
os demais usuários. Através da aplicação do modelo de concorrência M:N,
que combina tarefas de nível de sistema operacional com tarefas do nível
de usuário, adicionamos no Redis a capacidade de execução de scripts em
paralelo, permitindo que todos os núcleos do servidor sejam explorados.
Com a utilização de corotinas Lua, implementamos um escalonador capaz
de alocar e suspender a execução de tarefas de nível de usuário nos núcleos
disponíveis sem necessidade de alteração do código dos scripts. Este modelo
permitiu proteger o programador das complexidades naturais do paralelismo
como sincronização no acesso a recursos compartilhados e escalonamento
das tarefas. / [en] Redis is an open source key-value database that supports Lua programming
language scripts, but it s implementation is single threaded. Long running
scripts are discouraged because script evaluation is blocking, which may
cause service levels deterioration. Applying the M:N threading model,
which combines user and operating system threads, we added to Redis the
ability of running scripts in parallel, leveraging all server cores.With the use
of Lua coroutines, we implemented a scheduler able to allocate and suspend
user-level tasks in the available cores without the need of changing scripts
source code. The M:N model allowed us to protect the programmer from the
natural complexities that arise from parallel programming, such as access
to shared resources synchronization and scheduling of tasks into different
operational system threads.
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Millimetre-wave FMCW radar for remote sensing and security applicationsCassidy, Scott L. January 2015 (has links)
This thesis presents a body of work on the theme of millimetre-wave FMCW radar, for the purposes of security screening and remote sensing. First, the development of an optimised software radar signal processor will be outlined. Through use of threading and GPU acceleration, high data processing rates were achieved using standard PC hardware. The flexibility of this approach, compared to specialised hardware (e.g. DSP, FPGA etc…), allowed the processor to be rapidly adapted and has produced a significant performance increase in a number of advanced real-time radar systems. An efficient tracker was developed and was successfully deployed in live trials for the purpose of real-time wave detection in an autonomous boat control system. Automated radar operation and remote data telemetry functions were implemented in a terrain mapping radar to allow continuous monitoring of the Soufrière Hills volcano on the Caribbean island of Montserrat. This work concluded with the installation of the system 3 km from the volcano. Hardware modifications were made to enable coherent measurement in a number of existing radar systems, allowing phase sensitive measurements, including range-Doppler, to be performed. Sensitivity to displacements of less than 200 nm was demonstrated, which is limited by the phase noise of the system. Efficient compensation techniques are presented which correct for quadrature mixer imbalance, FMCW chirp non-linearity, and scanner drive distortions. In collaboration with the Home Office, two radar systems were evaluated for the stand-off detection of concealed objects. Automatic detection capability, based on polarimetric signatures, was developed using data gathered under controlled conditions. Algorithm performance was assessed through blind testing across a statistically significant number of subjects. A detailed analysis is presented, which evaluates the effect of clothing and object type on detection efficiency.
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The modernization of a DOS-basedtime critical solar cell LBICmeasurement system.Hjern, Gunnar January 2019 (has links)
LBIC is a technique for scanning the local quantum efficiency of solar cells. This kind of measurements needs a highly specialized, and time critical controlling software. In 1996 the client, professor Markus Rinio, constructed an LBIC system, and wrote the controlling software as a Turbo-Pascal 7.0 application, running under the MS-DOS 6.22 operating system. By now (2018) both the software and several hardware components are in dire need to be modernized. This thesis thoroughly describes several important aspects of this work, and the considerations needed for a successful result. This includes both very foundational choices about the software architecture, the choice of suitable operating system, the threading model, and the adaptation to new hardware with vastly different behavior. The project also included a new hardware module for position reports and instrument triggering, as well as several adaptations to transform the DOS-based LBIC software into a pleasant modern GUI application.
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Transmission electron microscopy studies of GaN/gamma-LiAlO 2 heterostructuresLiu, Tian-Yu 15 June 2005 (has links)
Die vorliegende Arbeit beschaeftigt sich mit dem strukturellen Aufbau von (1-100) M-plane GaN, das mit plasmaunterstuetzter Molekularstrahlepitaxie auf gamma-LiAlO2(100) Substraten gewachsen wurde. Die heteroepitaktische Ausrichtung einerseits, sowie die Mikrostruktur und die Erzeugungsmechanismen der Defekte andererseits, wurde mit der Transmissionselektronenemikroskopie (TEM) systematisch untersucht. Das gamma-LiAlO2 Substrat reagiert heftig im Mikroskop unter Bestrahlung mit hochenergetischen Elektronen. Waehrend dieser Strahlenschaedigung verliert das Material seine urspruengliche kristalline Struktur und vollzieht eine Phasentransformation, die anhand einer Serie von Feinbereichsbeugungsdiagrammen nachgewiesen werden konnte. Die atomare Grenzflaechenstruktur zwischen epitaktisch gewachsenem alpha-GaN(1-100) und tetragonalem gamma-LiAlO2 Substrat ist mittels HRTEM untersucht worden. Die neuartige Epitaxiebeziehung ist mit Elektronenbeugung bestaetigt worden und lautet folgendermassen: (1-100)GaN liegt parallel zu (100)gamma-LiAlO2 und [11-20]GaN ist parallel zu [001]gamma-LiAlO2. Die Realstruktur der M-plane GaN Schichten, die auf (100)gamma-LiAlO2 gewachsen werden, unterscheidet sich erheblich von der in C-plane Orientierung hergestellten Epischichten. Ausfuehrliche TEM Untersuchungen zeigen, dass die M-plane Schichten vor allem intrinsische (I1 und I2) und extrinsische (E) Stapelfehler in der Basalebene enthalten. Der vorherrschende I2 Stapelfehler besitzt keine Komponente des Verschiebungsvektors senkrecht zur Ebene und ist damit nicht geeignet, epitaktische Dehnung entlang der [11-20] Richtung abzubauen. Darueberhinaus ist eine komplexe Grenze in der (10-10) Prismen- flaeche entdeckt worden, die zur Grenzflaeche geneigt verlaeuft. Die Defekte in den M-plane GaN Epischichten werden waehrend der anfaenglichen Keimbildungsphase erzeugt. Atomare Stufen entlang der [001] Richtung auf dem LiAlO2 Substrat fuehren zur Bildung von Stapelfehlern vom Typ I2. / In this work the structure of (1-100)M-plane GaN epitaxially grown on gamma-LiAlO2(100) by using plasmaassisted molecular beam epitaxy (PAMBE) is studied. The heteroepitaxial alignment and the microstructure of M-plane GaN as well as the defect formation in the layer are systematically investigated by using transmission electron microscopy (TEM). The gamma-LiALO2 substrate reacts under irradiation of high-energy electrons in the TEM (200-300 keV).The material looses its original crystalline structure during this process undergoing irradiation damage followed by a phase transformation as it is verified by a series of selected area diffraction patterns taken under constant electron dose. The result is a structural phase transformation from the tetragonal gamma to the trigonal alpha phase. The atomic interface structure of epitaxially grown hexagonal alpha-GaN(1-100) layers on tetragonal gamma-LiAlO2 (100) substrates is investigated by means of HRTEM. The novel epitaxial orientation relationship verified by electron diffraction is given by (1-100)GaN parallel to (100)gamma-LiAlO2 and [11-20]GaN parallel to [001]gamma-LiAlO2. The defect structure of M-plane GaN epilayers grown on gamma-LiAlO2(100) substrates is different to that of C-plane GaN. Our detailed TEM studies reveal that the M-plane layers mainly contain intrinsic I1 and I2 and extrinsic E basal plane stacking faults. The dominant I2 stacking fault has no out-of-plane displacement vector component and is thus not qualified for epitaxial strain relief along the [11-20] axis. Beyond this, a complex type of planar defect is detected in the (10-10) prism plane which is inclined with respect to the interface. The study of nucleation samples shows that the surface morphology is directly correlated to the generation of the dominant planar defects. Atomic steps along the [001] direction in the gamma-LiAlO2 substrate result in the formation of basal plane stacking faults I2.
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Webový server pro predikci 3D struktury proteinu / Web Server for Protein Structure PredictionVotroubek, Lukáš January 2013 (has links)
This work deals with proteins, especially with their structure and kinds of tertiary, or 3D, structure prediction. Tertiary structure prediction is very important for function prediction of this vitally important substance. Bioinformatics do this prediction much more effective and faster, because classical methods of structure prediction directly from molecule are very expensive and slow. On the other hand they are much more exact. Objective of this thesis is to describe tertiary structure prediction methods, describe used tools and possibility of automatic communication with them. Next objective is describe implementation of server, that will serve to protein engineers for more effective finding of information about tertiary structure from more servers without requesting each of them separately. Results of testing will be described in this work too.
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Interference Analysis and Resource Management in Server Processors: from HPC to Cloud ComputingPons Escat, Lucía 01 September 2023 (has links)
[ES] Una de las principales preocupaciones de los centros de datos actuales es maximizar la utilización de los servidores. En cada servidor se ejecutan simultáneamente varias aplicaciones para aumentar la eficiencia de los recursos. Sin embargo, las prestaciones dependen en gran medida de la proporción de recursos que recibe cada aplicación. El mayor número de núcleos (y de aplicaciones ejecutándose) con cada nueva generación de procesadores hace que crezca la preocupación por la interferencia en los recursos compartidos. Esta tesis se centra en mitigar la interferencia cuando diferentes aplicaciones se consolidan en un mismo procesador desde dos perspectivas: computación de alto rendimiento (HPC) y computación en la nube.
En el contexto de HPC, esta tesis propone políticas de gestión para dos de los recursos más críticos: la caché de último nivel (LLC) y los núcleos del procesador. La LLC desempeña un papel clave en las prestaciones de los procesadores actuales al reducir considerablemente el número de accesos de alta latencia a memoria principal. Se proponen estrategias de particionado de la LLC tanto para cachés inclusivas como no inclusivas, ambos diseños presentes en los procesadores para servidores actuales. Para los esquemas, se detectan nuevos comportamientos problemáticos y se asigna un mayor espacio de caché a las aplicaciones que hacen mejor uso de este. En cuanto a los núcleos del procesador, muchas aplicaciones paralelas (como aplicaciones de grafos) no escalan bien con un mayor número de núcleos. Además, el planificador de Linux aplica una estrategia de tiempo compartido que no ofrece buenas prestaciones cuando se ejecutan aplicaciones de grafo. Para maximizar la utilización del sistema, esta tesis propone ejecutar múltiples aplicaciones de grafo en el mismo procesador, asignando a cada una el número óptimo de núcleos (y adaptando el número de hilos creados) dinámicamente.
En cuanto a la computación en la nube, esta tesis aborda tres grandes retos: la compleja infraestructura de estos sistemas, las características de sus aplicaciones y el impacto de la interferencia entre máquinas virtuales (MV). Primero, esta tesis presenta la plataforma experimental desarrollada con los principales componentes de un sistema en la nube. Luego, se presenta un amplio estudio de caracterización sobre un conjunto de aplicaciones de latencia crítica representativas con el fin de identificar los puntos que los proveedores de servicios en la nube deben tener en cuenta para mejorar el rendimiento y la utilización de los recursos. Por último, se realiza una propuesta que permite detectar y estimar dinámicamente la interferencia entre MV. El enfoque usa métricas que pueden monitorizarse fácilmente en la nube pública, ya que las MV deben tratarse como "cajas negras". Toda la investigación descrita se lleva a cabo respetando las restricciones y cumpliendo los requisitos para ser aplicable en entornos de producción de nube pública.
En resumen, esta tesis aborda la contención en los principales recursos compartidos del sistema en el contexto de la consolidación de servidores. Los resultados experimentales muestran importantes ganancias sobre Linux. En los procesadores con LLC inclusiva, el tiempo de ejecución (TT) se reduce en más de un 40%, mientras que se mejora el IPC más de un 3%. Con una LLC no inclusiva, la equidad y el TT mejoran en un 44% y un 24%, respectivamente, al mismo tiempo que se mejora el rendimiento hasta un 3,5%. Al distribuir los núcleos del procesador de forma eficiente, se alcanza una equidad casi perfecta (94%), y el TT se reduce hasta un 80%. En entornos de computación en la nube, la degradación del rendimiento puede estimarse con un error de un 5% en la predicción global. Todas las propuestas presentadas han sido diseñadas para ser aplicadas en procesadores comerciales sin requerir ninguna información previa, tomando las decisiones dinámicamente con datos recogidos de los contadores de prestaciones. / [CAT] Una de les principals preocupacions dels centres de dades actuals és maximitzar la utilització dels servidors. A cada servidor s'executen simultàniament diverses aplicacions per augmentar l'eficiència dels recursos. Tot i això, el rendiment depèn en gran mesura de la proporció de recursos que rep cada aplicació. El nombre creixent de nuclis (i aplicacions executant-se) amb cada nova generació de processadors fa que creixca la preocupació per l'efecte causat per les interferències en els recursos compartits. Aquesta tesi se centra a mitigar la interferència en els recursos compartits quan diferents aplicacions es consoliden en un mateix processador des de dues perspectives: computació d'alt rendiment (HPC) i computació al núvol.
En el context d'HPC, aquesta tesi proposa polítiques de gestió per a dos dels recursos més crítics: la memòria cau d'últim nivell (LLC) i els nuclis del processador. La LLC exerceix un paper clau a les prestacions del sistema en els processadors actuals reduint considerablement el nombre d'accessos d'alta latència a la memòria principal. Es proposen estratègies de particionament de la LLC tant per a caus inclusives com no inclusives, ambdós dissenys presents en els processadors actuals. Per als dos esquemes, se detecten nous comportaments problemàtics i s'assigna un major espai de memòria cau a les aplicacions que en fan un millor ús. Pel que fa als nuclis del processador, moltes aplicacions paral·leles (com les aplicacions de graf) no escalen bé a mesura que s'incrementa el nombre de nuclis. A més, el planificador de Linux aplica una estratègia de temps compartit que no ofereix bones prestacions quan s'executen aplicacions de graf. Per maximitzar la utilització del sistema, aquesta tesi proposa executar múltiples aplicacions de grafs al mateix processador, assignant a cadascuna el nombre òptim de nuclis (i adaptant el nombre de fils creats) dinàmicament.
Pel que fa a la computació al núvol, aquesta tesi aborda tres grans reptes: la complexa infraestructura d'aquests sistemes, les característiques de les seues aplicacions i l'impacte de la interferència entre màquines virtuals (MV). En primer lloc, aquesta tesi presenta la plataforma experimental desenvolupada amb els principals components d'un sistema al núvol. Després, es presenta un ampli estudi de caracterització sobre un conjunt d'aplicacions de latència crítica representatives per identificar els punts que els proveïdors de serveis al núvol han de tenir en compte per millorar el rendiment i la utilització dels recursos. Finalment, es fa una proposta que de manera dinàmica permet detectar i estimar la interferència entre MV. L'enfocament es basa en mètriques que es poden monitoritzar fàcilment al núvol públic, ja que les MV han de tractar-se com a "caixes negres". Tota la investigació descrita es duu a terme respectant les restriccions i complint els requisits per ser aplicable en entorns de producció al núvol públic.
En resum, aquesta tesi aborda la contenció en els principals recursos compartits del sistema en el context de la consolidació de servidors. Els resultats experimentals mostren que s'obtenen importants guanys sobre Linux. En els processadors amb una LLC inclusiva, el temps d'execució (TT) es redueix en més d'un 40%, mentres que es millora l'IPC en més d'un 3%. En una LLC no inclusiva, l'equitat i el TT es milloren en un 44% i un 24%, respectivament, al mateix temps que s'obté una millora del rendiment de fins a un 3,5%. Distribuint els nuclis del processador de manera eficient es pot obtindre una equitat quasi perfecta (94%), i el TT pot reduir-se fins a un 80%. En entorns de computació al núvol, la degradació del rendiment pot estimar-se amb un error de predicció global d'un 5%. Totes les propostes presentades en aquesta tesi han sigut dissenyades per a ser aplicades en processadors de servidors comercials sense requerir cap informació prèvia, prenent decisions dinàmicament amb dades recollides dels comptadors de prestacions. / [EN] One of the main concerns of today's data centers is to maximize server utilization. In each server processor, multiple applications are executed concurrently, increasing resource efficiency. However, performance and fairness highly depend on the share of resources that each application receives, leading to performance unpredictability. The rising number of cores (and running applications) with every new generation of processors is leading to a growing concern for interference at the shared resources. This thesis focuses on addressing resource interference when different applications are consolidated on the same server processor from two main perspectives: high-performance computing (HPC) and cloud computing.
In the context of HPC, resource management approaches are proposed to reduce inter-application interference at two major critical resources: the last level cache (LLC) and the processor cores. The LLC plays a key role in the system performance of current multi-cores by reducing the number of long-latency main memory accesses. LLC partitioning approaches are proposed for both inclusive and non-inclusive LLCs, as both designs are present in current server processors. In both cases, newly problematic LLC behaviors are identified and efficiently detected, granting a larger cache share to those applications that use best the LLC space. As for processor cores, many parallel applications, like graph applications, do not scale well with an increasing number of cores. Moreover, the default Linux time-sharing scheduler performs poorly when running graph applications, which process vast amounts of data. To maximize system utilization, this thesis proposes to co-locate multiple graph applications on the same server processor by assigning the optimal number of cores to each one, dynamically adapting the number of threads spawned by the running applications.
When studying the impact of system-shared resources on cloud computing, this thesis addresses three major challenges: the complex infrastructure of cloud systems, the nature of cloud applications, and the impact of inter-VM interference. Firstly, this thesis presents the experimental platform developed to perform representative cloud studies with the main cloud system components (hardware and software). Secondly, an extensive characterization study is presented on a set of representative latency-critical workloads which must meet strict quality of service (QoS) requirements. The aim of the studies is to outline issues cloud providers should consider to improve performance and resource utilization. Finally, we propose an online approach that detects and accurately estimates inter-VM interference when co-locating multiple latency-critical VMs. The approach relies on metrics that can be easily monitored in the public cloud as VMs are handled as ``black boxes''. The research described above is carried out following the restrictions and requirements to be applicable to public cloud production systems.
In summary, this thesis addresses contention in the main system shared resources in the context of server consolidation, both in HPC and cloud computing. Experimental results show that important gains are obtained over the Linux OS scheduler by reducing interference. In inclusive LLCs, turnaround time (TT) is reduced by over 40% while improving IPC by more than 3%. In non-inclusive LLCs, fairness and TT are improved by 44% and 24%, respectively, while improving performance by up to 3.5%. By distributing core resources efficiently, almost perfect fairness can be obtained (94%), and TT can be reduced by up to 80%. In cloud computing, performance degradation due to resource contention can be estimated with an overall prediction error of 5%. All the approaches proposed in this thesis have been designed to be applied in commercial server processors without requiring any prior information, making decisions dynamically with data collected from hardware performance counters. / Pons Escat, L. (2023). Interference Analysis and Resource Management in Server Processors: from HPC to Cloud Computing [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/195840
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Beyond conventional c-plane GaN-based light emitting diodes: A systematic exploration of LEDs on semi-polar orientationsMonavarian, Morteza 01 January 2016 (has links)
Despite enormous efforts and investments, the efficiency of InGaN-based green and yellow-green light emitters remains relatively low, and that limits progress in developing full color display, laser diodes, and bright light sources for general lighting. The low efficiency of light emitting devices in the green-to-yellow spectral range, also known as the “Green Gap”, is considered a global concern in the LED industry. The polar c-plane orientation of GaN, which is the mainstay in the LED industry, suffers from polarization-induced separation of electrons and hole wavefunctions (also known as the “quantum confined Stark effect”) and low indium incorporation efficiency that are the two main factors that contribute to the Green Gap phenomenon. One possible approach that holds promise for a new generation of green and yellow light emitting devices with higher efficiency is the deployment of nonpolar and semi-polar crystallographic orientations of GaN to eliminate or mitigate polarization fields. In theory, the use of other GaN planes for light emitters could also enhance the efficiency of indium incorporation compared to c-plane.
In this thesis, I present a systematic exploration of the suitable GaN orientation for future lighting technologies. First, in order to lay the groundwork for further studies, it is important to discuss the analysis of processes limiting LED efficiency and some novel designs of active regions to overcome these limitations. Afterwards, the choice of nonpolar orientations as an alternative is discussed. For nonpolar orientation, the (1-100)-oriented (m-plane) structures on patterned Si (112) and freestanding m-GaN are studied. The semi-polar orientations having substantially reduced polarization field are found to be more promising for light-emitting diodes (LEDs) owing to high indium incorporation efficiency predicted by theoretical studies. Thus, the semi-polar orientations are given close attention as alternatives for future LED technology.
One of the obstacles impeding the development of this technology is the lack of suitable substrates for high quality materials having semi-polar and nonpolar orientations. Even though the growth of free-standing GaN substrates (homoepitaxy) could produce material of reasonable quality, the native nonpolar and semi-polar substrates are very expensive and small in size. On the other hand, GaN growth of semi-polar and nonpolar orientations on inexpensive, large-size foreign substrates (heteroepitaxy), including silicon (Si) and sapphire (Al2O3), usually leads to high density of extended defects (dislocations and stacking faults). Therefore, it is imperative to explore approaches that allow the reduction of defect density in the semi-polar GaN layers grown on foreign substrates.
In the presented work, I develop a cost-effective preparation technique of high performance light emitting structures (GaN-on-Si, and GaN-on-Sapphire technologies). Based on theoretical calculations predicting the maximum indium incorporation efficiency at θ ~ 62º (θ being the tilt angle of the orientation with respect to c-plane), I investigate (11-22) and (1-101) semi-polar orientations featured by θ = 58º and θ = 62º, respectively, as promising candidates for green emitters. The (11-22)-oriented GaN layers are grown on planar m-plane sapphire, while the semi-polar (1-101) GaN are grown on patterned Si (001).
The in-situ epitaxial lateral overgrowth techniques using SiNx nanoporous interlayers are utilized to improve the crystal quality of the layers. The data indicates the improvement of photoluminescence intensity by a factor of 5, as well as the improvement carrier lifetime by up to 85% by employing the in-situ ELO technique. The electronic and optoelectronic properties of these nonpolar and semi-polar planes include excitonic recombination dynamics, optical anisotropy, exciton localization, indium incorporation efficiency, defect-related optical activities, and some challenges associated with these new technologies are discussed. A polarized emission from GaN quantum wells (with a degree of polarization close to 58%) with low non-radiative components is demonstrated for semi-polar (1-101) structure grown on patterned Si (001). We also demonstrated that indium incorporation efficiency is around 20% higher for the semi-polar (11-22) InGaN quantum wells compared to its c-plane counterpart. The spatially resolved cathodoluminescence spectroscopy demonstrates the uniform distribution of indium in the growth plane. The uniformity of indium is also supported by the relatively low exciton localization energy of Eloc = 7meV at 15 K for these semi-polar (11-22) InGaN quantum wells compared to several other literature reports on c-plane. The excitons are observed to undergo radiative recombination in the quantum wells in basal-plane stacking faults at room temperature. The wurtzite/zincblende electronic band-alignment of BSFs is proven to be of type II using the time-resolved differential transmission (TRDT) method. The knowledge of band alignment and degree of carrier localization in BSFs are extremely important for evaluating their effects on device properties. Future research for better understanding and potential developments of the semi-polar LEDs is pointed out at the end.
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