This thesis consists of two parts. The first part considers the effect of microwave radiation on magnetotransport in high quality GaAs/AlGaAs heterostructure two dimensional electron systems. The effect of microwave (MW) radiation on electron temperature was studied by investigating the amplitude of the Shubnikov de Haas (SdH) oscillations in a regime where the cyclotron frequency $\omega_{c}$ and the MW angular frequency $\omega$ satisfy $2\omega \leq \omega_{c} \leq 3.5\omega$. The results indicate negligible electron heating under modest MW photoexcitation, in agreement with theoretical predictions. Next, the effect of the polarization direction of the linearly polarized MWs on the MW induced magnetoresistance oscillation amplitude was investigated. The results demonstrate the first indications of polarization dependence of MW induced magnetoresistance oscillations. In the second part, experiments on the magnetotransport of three dimensional highly oriented pyrolytic graphite (HOPG) reveal a non-zero Berry phase for HOPG. Furthermore, a novel phase relation between oscillatory magneto- and Hall- resistances was discovered from the studies of the HOPG specimen.

Abstract In a petrochemical plant, to exert economic efficiency and spacing convenience for transporting fluid or gas, the pipelines used in the plant are often buried along the road. The buried pipelines are usually wrapped in the soil that only the guided wave method is a convenient technique to perform the nondestructive testing for the pipelines. However, the viscosity of soil causes the attenuation of the guided wave during the test, the accuracy and the detection distance will then be affected. Thus, the objectives of this thesis are to study the characteristics, such as the detection distance and the refraction signal, of the T(0,1) guided wave when propagating along pipelines wrapped in the soil at different depths. The thesis would be divided into two parts: experiment and numerical simulation. Four different depths, 0.5, 1.0, 1.5 and 2.0 m, are used in the experiment to evaluate the characteristics of reflected signals and its attenuation. Wavelet transform, which would enhance the capability of distinguishing guided wave defect, is used to improve the attenuation of defected refraction signal caused by soil. In the numerical simulation, this research applies the transient simulation by finite element method to analyze the wave propagation behavior of T(0,1) mode guided wave of buried pipeline, which is incorporated with Two-dimensional Fourier transform for modal identification. The result of experiment shows that the attenuation of the guided wave is caused by the leakage and the viscosity of the soil. The decay rate is proportional to the depth and due to the viscosity of the soil is proportional to the excitation frequency. This phenomenon is more obvious when the pipeline is buried deeper. The reflected signal amplitude of each characteristic would decrease along with the increasing soil depth, but the overall trends did not changed. The result of wavelet transform shows that the capability of distinguishing of the guided wave detection defect of buried pipeline, which attenuation of refraction signal caused by soil would be improved. The result of the numerical simulation indicates that the T(0,1) mode would not cause mode conversion and dispersion due to its propagation through the buried pipeline with different depths of soil. The soil caused leakage of the T(0,1) mode in the form of shear waves. The attenuation rate of guided wave and its detection distance in the study could be the reference of site selection for detection and defect refraction signal determination, which could effectively raise the efficiency of on-site detection.

In this paper, we mainly discuss the transport properties of the two-dimensional gas of a high-mobility GaAs/AlGaAs semiconductor heterostructure in high magnetic fields and low temperatures. We analyzed the measured longitudinal resistivity and Hall resistivity at the five different temperatures. We observed that the classical Hall effect is valid when the magnetic field is less than 0.25 Tesla; and the quantum Hall plateaux appeared obviously when the magnetic field is larger than 1.6 Tesla. We proceeded to analyze the longitudinal resistivity oscillation occurred in the magnetic fields between 0.477 Tesla and 1.483 Tesla. According to the Lifshitz-Kosevich (LK) formula, we can get the two-dimensional electron concentration, effective mass, and quantum scattering time from the quantum magnetoresistivity oscillation measurement. Our results suggested that the applicable range of the LK formula could be broader than the generally-assumed one. In quantum Hall effect regime at high magnetic field, we can calculate the h/e2 value from the quantum Hall plateaux value. In classical Hall effect regime, the three-dimensional electron concentration and classical mobility (classical scattering time) can be obtained. However, we find out that the zero-field Hall resistivity experimental value is not equal to zero, and this is not conformed to the standard theory. We tried to use the magnetic field shift and Hall resistivity shift to solve the problem, and compared both advantages of them. Finally, we observed the plateau-plateau phase transitions of the two-dimensional electron system

As the introduction of semiconductor¡Bcomputer¡Bnetwork communcation¡Bmulti-media technology¡K¡Ketc. and the development and application of relevant automotive electronics, the car has becoming a high technological product instead of a traditional and machnical conveyance. Based on IC Insights, over 40% of vehicles will be equipped with automotive electronics and the automotive electronics market will reach the scale of US$192 billion in 2010. The scale of market is expected to reach the record of US$400 billion that represented over 50% of vehicles will be equiped with automotive electronics in 2015. The automotive electronics was divided to six functional field including ¡§Powertrain¡¨¡B¡¨Body¡¨¡B¡¨Chassis¡BSecurity¡¨¡B¡¨Safety¡¨ and ¡§Driver information¡¨. According to the research of IEK, ¡§Tire Pressure Monitoring System¡¨ is the most potential product in ¡§Safety¡¨ field for Taiwan manufacturers of IT industry to invest their resource. Based on Strategy Analytics, the global market of Tire Pressure Monitoring System reaches the scale of US$200 million in 2004 and the growth is expected to reach the record of US$1,279 million in 2008 and 63.6% annual compound growth. Quality Function Deployment (QFD) is a systematical tool with customer orientated concept. Adopting QFD method to product design efficiently is able to shorten development time¡Breduce cost and improve quality to satisfy customer¡¦s needs in his or her mind. This research is completed by case study of Tire Pressure Monitoring System (TPMS) which is developed by certain Taiwan company with potentials that is chosen by specialists. In this research we try to collect related information about certain company and explore customer¡¦s real-life needs by conducting questionnaire surveys. Kano¡¦s two-dimensional quality model is applied to identify customer¡¦s critical quality requirements. Quality factor¡Bsub-system/component and process are deployed by the matrix method of QFD to recognize key items for improving product design.

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Amongst the polar organic compounds occurring in unrefined and refined crude oils and the associated polluted production waters, complex mixtures of acids, known historically as naphthenic acids (NAs), have achieved prominence. This is particularly because NAs have been designated a toxicant class of concern in the oil sands process-affected water (OSPW) that has accumulated in vast quantities following exploitation of the oil sands of Northern Alberta, Canada in recent years. However, though there have been calls for NAs to be added to pollutant inventories, at the initiation of the current study, little knowledge existed of the exact composition of refined or unrefined NAs. The overall aim of the current study was therefore to identify individual NAs in refined (commercial) and unrefined (e.g. oil sands process-derived) complex mixtures of acids and then to assess the toxicity of any identified NAs. Individual NAs were tentatively identified by interpretation of the electron ionisation mass spectra of methyl ester derivatives, following comprehensive multidimensional gas chromatography-mass spectrometry (GCxGC-MS). Reference acids were then either purchased, or more commonly, where they were not commercially-available, synthesised, mainly by micro-hydrogenation methods, for co-chromatography and comparison of mass spectra of methyl esters with those of unknowns. The synthetic NAs, purified to >97% were then subjected to toxicological assessments using the Microtox™ assay. In all, 34 compounds were obtained pure enough for testing. Microtox results revealed that the toxicity endpoint (50% Inhibition Concentration, IC50) was between 0.004 and 0.7 mM. Exponential and other correlations were noted between carbon number and toxicity in several of the structural groups of acids assayed, which may be beneficial for predictions of toxicity of non-synthesised acids. Although n-hexanoic acid (IC50 0.7 mM) had the lowest toxicity, adamantane-type acids were the least toxic as a group overall. Conversely, the decahydronaphthalene (decalin)-type acids had the largest range of toxicities (IC50 0.004 to 0.3 mM) and the most toxic acid assayed was 3-decalin-1-yl-propanoic acid. According to USEPA guidelines many individual acids can be said to show low to medium toxicity. Since the acids in commercial and unrefined NAs occur in complex mixtures, an attempt was also made to assess mixture toxicity. Mixtures of individual structural groups of acids (e.g. acyclic isoprenoid acids, n-acids) and a mixture of all 34 acids were assessed. Apart from the adamantane sub-group of acids, all of the mixtures showed toxicities lower than the sum of the parts when calculated using equations for Concentration Addition and Model Deviation Ratios (simply the predicted IC50/Observed IC50). A hypothesis that achievement of a critical micelle concentration is required to produce toxicity was proposed to explain the lower than expected results. Some of the mass spectra of NA present in the commercial and unrefined mixtures were inconsistent with those of any of the alicyclic acids synthesised or purchased. These were hypothesised to be aromatic acids. Fractionation experiments of the NA mixtures using silver ion thin layer chromatography and solid phase extraction (Ag+TLC and Ag+SPE) were carried out in order to provide further evidence for aromatic acids. Ag+TLC allowed separation of a methylated NA mixture from OSPW into three distinct fractions; Ag+SPE resulted in eleven fractions, through the use of a wider range of solvents and differential solvent ratios. Analysis of the fractions by GC-MS revealed that each fraction was largely still made up of unresolved acids (as esters), although one or two fractions revealed some resolved acids. Use of averaged mass spectra and mass chromatography on each fraction revealed further resolved chromatographic peaks and associated interpretable mass spectra. Each of eight of the eleven sub-fractions were examined by GC-MS, in some cases by GCxGC-MS, and all by infrared spectroscopy, ultraviolet visible spectrophotometry and elemental analysis. A number of structures were proposed for the aromatic acids, including those with sulphur-containing moieties. It was noted that far from being minor components, aromatic acids comprised ca.25-40% of the OSPW acid extracts.

The membrane proteins signal peptide peptidase, signal peptide peptidase like and presenilin are intramembrane aspartyl proteases located in the endoplasmic reticulum, plasma membrane and organelle. These membrane proteins are able to catalyze a hydrolytic reaction in a hydrophobic space. The downstream consequences of these reactions impact a variety of cellular functions such as cytokine production, inflammatory responses, embryogenesis, and immune system regulation. Additionally, the aspartyl proteases such as signal peptide peptidase and presenilin, a part of the γ-secretase complex, hydrolyze peptides leading to pathogen maturation and Alzheimer’s disease, respectively. Electron crystallography offers the unique aspect of studying membrane proteins in a near native state. Determining the structures of Haloarcula morismortui and Methanoculleus marisnigri JR1 signal peptide peptidases by electron crystallography may provide insight into how a hydrolysis reaction occurs in a hydrophobic environment and how the protein determines which transmembrane signal peptides to cleave. Additionally, structure determination may help answer questions regarding why human presenilin, part of the γ-secretase complex, incorrectly processes amyloid precursor protein into amyloid-beta peptides leading to Alzheimer’s disease. Such structural data may not only shed light on how amyloid precursor protein is processed but how other proteins are processed by signal peptide peptidase leading to immune responses, cell signaling, and pathogen maturation. In addition, structure-function data may have an impact on pharmaceutical drug designs that targets signal peptide peptidase, signal peptide peptidase like, and/or presenilin. To determine the structure of aspartyl proteases, two archaeal signal peptide peptidases were used for two-dimensional crystallization trials to be able to study their structure by electron crystallography. Haloarcula morismortui and Methanoculleus marisnigri JR1 signal peptide peptidases, both human signal peptide peptidase homologues, were recombinantly over-expressed and purified. During dialysis trials, various lipid-to-protein ratios, sodium chloride concentrations, temperatures, detergents and a variety of other variables were tested. Methanoculleus marisnigri JR1 signal peptide peptidase showed the most promising results in terms of crystallinity. Optimizing dialysis conditions, specifically narrowing the lipid to protein ratio, resulted in two-dimensional crystals. Ordered arrays measuring up to 200 nm x 200 nm were observed. These ordered arrays have been shown to be reproducible amongst multiple batches of purified Methanoculleus marisnigri JR1 signal peptide peptidase. Preliminary projection maps of negatively stained ordered arrays show unit cell dimensions of a = 178 Å, b = 160 Å, γ = 92.0 Å and a = 175 Å, b = 167 Å, γ = 92.0 Å. The monomer measurements are approximately 70 Å by 80 Å. This is the first time a signal peptide peptidase homologue has been crystallized by two-dimensional crystallization.

Goal and Scope of this thesisThe curing process of epoxy resin directly affects the properties of the final polymer, so it is of great interest to develop analytical methods that allows knowing the pathway of the curing processes. There have been numerous research studies about the evolution of the curing and on the quantification of the corresponding kinetic parameters using several techniques such as: Differential Scanning Calorimetry (DSC), Differential Scanning Calorimetry with Temperature Modulation (MTDSC), Thermogravimetric analysis (TGA), Fluorescence, Raman spectroscopy, Nuclear Magnetic Resonance (NMR), High-Resolution Liquid Chromatography (HPLC), Infrared spectroscopy Fourier Transform (FTIR) and Near infrared spectroscopy (NIR). Usually, those studies are done in model reactions due to the fact that is very difficult, and sometimes even impossible, to isolate the intermediate products that are involved in the curing process. In that sense, the goal of the present thesis is to explore the possibilities of the multidimensional correlation spectroscopy for the quantitative monitorization of curing processes by means of infrared spectroscopy and curve resolution methods. The thesis is focused in a complex reaction in which several and side reactions might take place, most or all of them almost at the same time. This main goal is structured in the following items: 1. Analysis of Generalized two-dimensional correlation spectroscopy and Perturbation-correlation mowing-windows two-dimensional correlation spectroscopy as a tool to obtain information about the reaction pathway.2. Analysis of sample-sample two-dimensional correlation spectroscopy as a tool to obtain concentration profiles of the chemical species involved in the curing process.3. Quantitative resolution of the curing process by means of multivariate curve resolution methods - alternating least squares (MCR-ALS) taking into account the information coming from multidimensional correlation spectroscopy analysis. StructureThe thesis is structured in different chapters each one containing the following information.Chapter 1: This chapter presents the background of the thesis, so it is highlighted the interest of the study of resins epoxy. A brief review of the theory of the multidimensional spectroscopy and the chemometrics tools (multivariate curve resolution methods) used is presented focusing on the novelties introduced in the thesis and offering the proper references for the basic concepts already known.Chapter 2: This chapter concerns the experimental work done. It has been included a brief description of the instrumental analytical techniques used to monitor the curing process. Two main curing reactions are described: experimental conditions and scheme of the reaction between the phenylglycidylether (PGE) and -butyrolactone monitored by NIR and of the copolymerization between the diglycidyl ether of bisphenol A (DGEBA) and -valerolactone by FTIR/ATR. Also the conditions of the DGEBA homopolymerization are presented. And finally, the 1H and 13C NMR experimental condition to obtain the spectrum of the final product in the first reaction between PGE and -butyrolactone is described.Chapter 3: This chapter is addressed to the results obtained as a consequence of the studies done. It is articulated in five published works and each one is introduced by a brief description of the main goal and the content of it. The five articles are presented in a sequential order according the main goal of the thesis.Chapter 4: Finally, the thesis ends with a conclusion chapter in which the achieved goals are outlined.As each paper presented in chapter 3, contains its specific conclusion section, in this chapter there are emphasized the thesis conclusions according to the goals formulated in the scope. In that sense the first and general conclusion is that Multidimensional correlation spectroscopy and multivariate curve resolution method are useful spectroscopic and chemometric methods to quantitative monitoring a curing process using infrared spectroscopy.Concretely it can be also stated that: - Generalized and perturbation-correlation moving-windows two-dimensional correlation spectroscopy, are valuable methods to obtain information about the reaction pathway in the case studied which is representative of a curing process.- Sample-sample two-dimensional correlation spectroscopy is very useful method to obtain concentration profiles of the chemical species involved in the curing process.- And finally, MCR-ALS is a very useful method for the quantitative resolution of the curing process. / El proceso de curado la resina epoxi afecta directamente las propiedades finales del polímero, por lo que es de gran interés para el desarrollo de métodos de análisis que permite conocer la vía de los procesos de polimerización. Por lo general, esos estudios se hacen en reacciones modelo, debido al hecho, que es muy difícil, a veces o incluso imposible, aislar los productos intermedios que intervienen en el proceso de curado. En ese sentido, el objetivo de la tesis es explorar las posibilidades de la espectroscopia de correlación multidimensional para la monitorización cuantitativa de los procesos de curado por medio de espectroscopia infrarrojo y métodos de resolución de la curva. La tesis se centra en una reacción compleja en la que varias reacciones secundarias y puede tener lugar, la mayoría o la totalidad de ellos casi al mismo tiempo.Las conclusiones de la tesis de acuerdo a los objetivos son formulados en el ámbito de aplicación, métodos espectroscópicos y quimiométricos. En ese sentido, la primera conclusión general y es que la espectroscopia de correlación multidimensional y método de resolución de curva multivariante son útiles para el seguimiento de un proceso de curado mediante espectroscopía de infrarrojo.Concretamente, puede ser también señaló que: - La espectroscopia generalizada de correlación bidimensional y espectroscopia de correlación de la perturbación por ventana móvil, son métodos valiosos para obtener información sobre el camino de reacción en el caso estudiado, que es representativa de un proceso de curado.- La espectroscopia de correlación bidimensional muestra-muestra es un metodo útil para obtener perfiles de concentración de las especies químicas involucradas en el proceso de curado.- Por último, MCR-ALS es un método muy útil para la resolución cuantitativa del proceso de curado.

Darbe analizuojamos dvimačių ir trimačių objektų geometrinės transformacijos. Yra sistemų, kurios pateikia priemones demonstruoti ir atlikti užduotis. Yra galimybė sukurti ir transformuoti figūrą. Bet tokiose sistemose nėra galimybės atlikti kontrolinę užduotį, kurią vėliau galima peržiūrėti ir spręsti apie studento žinias. Analizuojamose sistemose nėra galimybės išsaugoti užduotį. Kuriama sistema turi galimybę sukurti, įtraukti ir išsaugoti naują užduotį. Sistema skirta dviejų tipų vartotojams - paprasti vartotojai ir administratoriai. Paprastas vartotojas gali mokintis transformacijų valdymo ir atlikti kontrolinę užduotį. Administratorius be šių galimybių dar gali kurti naujas užduotis ir valdyti duomenų bazę. / I am analysing the system for two-dimentional and three-dimentional objects transformation in this work. There is the system that serves the purpose to demonstrate and control exercised worksheets. Available systems allows to create and transform the shape. But there is no condition of worksheet, that after accomplished, we could conclude about students‘ knowledge. There is no possibility to save created worksheet in the analysed systems, so there is no chance to resume its data base. My demonstrated system has the tools for creating, saving and including new worksheet to the data base. There are two types of users using the system – ordinary user and administrating user. Administrator has all privilege to control the program. Ordinary user can study or make worksheet.

Darbe analizuojama diskrečioji Le Gall transformacija (DLGT) yra viena iš bangelių transformacijų, kurios naudojamos skaitmeninių vaizdų glaudinime. Vaizdų glaudinimas ypač svarbus, kai kalbama apie vaizdų siuntimą mažo pralaidumo kompiuteriniu kanalu. Šiai problemai spręsti pasitelkiama diskrečioji Le Gall transformacija, bei didelis dėmesys darbe skirtas vaizdo fragmento DLGT spektrui. Šio spektro radimui sukurtas ir realizuotas naujas algoritmas − greitoji procedūra. Palyginamosios analizės metu įrodyta, kad sukurta greitoji procedūra randa vaizdo fragmento DLGT spektrą daugiau nei 50 kartų greičiau nei tiesiogiai taikant DLGT vaizdo fragmentui. Darbo pradžioje aptariamos pagrindinės bangelių ir jų transformacijų savybės. Šių savybių svarba iliustruojama pateiktais pavyzdžiais ir sąsajomis su taikymu praktikoje. Viena iš svarbesnių aptariamų savybių būtų transformacijos lokalizavimas erdvėje. Nors DLGT pilnai netenkina šios savybės, tačiau darbe apžvelgtas dekoreliacijos metodas leidžia išspręsti šią problemą. Be to, pateikiami išsamūs DLGT algoritmai vienmačiams ir dvimačiams vaizdams. Šių algoritmų dėka buvo sukurta programinė įranga, padedanti analizuoti DLGT. Galiausiai darbo pabaigoje pateikiama sukurtos programinės įrangos instrukcija. / In this paper the main attention is dedicated to discrete Le Gall transformation (DLGT), the family of discrete wavelets transformations, which usage in the image compression is quite popular. Image compression is very important when it comes to low bandwidth network and computer channels. To deal with this problem the discrete Le Gall wavelets are brought up and focused on the image fragment DLGT spectrum. For calculation of this spectrum the new fast procedure is suggested and realized. In comparative analysis the fast procedure is proved to work more than 50 times faster than applying DLGT direct to image fragment. In the beginning of this paper the main concepts of wavelets and their transformations are analyzed. An importance of these properties is illustrated by examples and applications in practice. One of the most important properties is localization in space. Even though DLGT does not fully meet this property decorrelation technique, introduced in paper, benefits in solving localization problem. Moreover, DLGT algorithms are proposed for one-dimensional and 2-dimensional images. According to these algorithms the new program was created, which is dedicated for image analysis. Finally, in the end of paper the instructions of program are presented.