Microcalorimetric measurements and contact angle measurements were conducted to study the surface chemistry of powdered minerals. The contact angle measurements were conducted on both flat and powdered talc samples, and the results were used to determine the surface free energy components using Van Oss-Chaudhury-Good (OCG) equation. It was found that the surface hydrophobicity of talc increases with decreasing particle size. At the same time, both the Lifshitz-van der Waals (gSLW) and the Lewis acid-base (gSAB) components (and, hence, the total surface free energy (gS)) decrease with decreasing particle size. The increase in the surface hydrophobicity and the decrease in surface free energy (gS) can be attributed to preferential breakage of the mineral along the basal plane, resulting in the exposure of more basal plane surfaces to the aqueous phase. Heats of immersion measurements were conducted using a flow microcalorimeter on a number of powdered talc samples. The results were then used to calculate the contact angles using a rigorous thermodynamic relation. The measured heat of immersion values in water and calculated contact angles showed that the surface hydrophobicity of talc samples increase with decreasing particle size, which agrees with the direct contact angle measurements. A relationship between advancing water contact angle qa, and the heat of immersion (-DHi) and surface free energies was established. It was found that the value of -DHi decrease as qa increases. The microcalorimetric and direct contact angle measurements showed that acid-base interactions play a crucial role in the interaction between talc and liquid. Using the Van Oss-Chaudhury-Good's surface free energy components model, various talc powders were characterized in terms of their acidic and basic properties. It was found that the magnitude of the Lewis electron donor, gS-, and the Lewis electron acceptor, gS+, components of surface free energy is directly related to the particle size. The gS- of talc surface increased with decreasing particle size, while the gS+ slightly decreased. It was also found that the Lewis electron-donor component on talc surface is much higher than the Lewis electron-acceptor component, suggesting that the basal surface of talc is basic. The heats of adsorption of butanol on various talc samples from n-heptane solution were also determined using a flow microcalorimeter. The heats of adsorption values were used to estimate % hydrophilicity and hydrophobicity and the areal ratios of the various talc samples. In addition, contact angle and heat of butanol adsorption measurements were conducted on a run-of-mine talc sample that has been ground to two different particle size fractions, i.e., d50=12.5 mm and d50=3.0 mm, respectively. The results were used to estimate the surface free energy components at the basal and edge surfaces of talc. It was found that the total surface free energy (gS) at the basal plane surface of talc is much lower than the total surface free energy at the edge surface. The results suggest also that the basal surface of talc is monopolar basic, while the edge surface is monopolar acidic. The results explain why the basicity of talc surface increases with decreasing particle size as shown in the contact angle and microcalorimetric measurements. Furthermore, the effects of the surface free energies of solids during separation from each other by flotation and selective flocculation were studied. In the present work, a kaolin clay sample from east Georgia was used for the beneficiation tests. First, the crude kaolin was subjected to flotation and selective flocculation experiments to remove discoloring impurities (i.e., anatase (TiO2) and iron oxides) and produce high-brightness clay with GE brightness higher than 90%. The results showed that a clay product with +90% brightness could be obtained with recoveries (or yields) higher than 80% using selective flocculation technique. It was also found that a proper control of surface hydrophobicity of anatase is crucially important for a successful flotation and selective flocculation process. Heats of immersion, heats of adsorption and contact angle measurements were conducted on pure anatase surface to determine the changes in the surface free energies as a function of the surfactant dosage (e.g. hydroxamate) used for the surface treatment. The results showed that the magnitude of the contact angle and, hence, the surface free energy and its components on anatase surface varies significantly with the amount of surfactant used for the surface treatment. / Ph. D.

Development of modern safety standards for hydrogen storage infrastructure requires fundamental insight into the physics of buoyant gas dispersion into ambient air. Also, from a practical engineering stand-point, flow patterns and dispersion of gas originating from orifices in the side wall of circular pipe or storage tank need to be studied. In this thesis, novel configurations were considered to investigate the evolution of turbulent jets issuing from realistic pipeline geometries. First, the effect of jet densities and Reynolds numbers on vertical jets were investigated, as they emerged from the side wall of a circular pipe, through a round orifice. The resulting jet flow was thus issued through a curved surface from a source whose original velocity components were nearly perpendicular to the direction of the ensuing jets. Particle image velocimetry (PIV) and planar laser-induced fluorescence (PLIF) techniques were employed simultaneously to provide instantaneous and time-averaged flow fields of velocity and concentration. The realistic flow arrangement resulted in an asymmetric flow pattern and a significant deflection from the vertical axis of jets. The deflection was influenced by buoyancy, where heavier gases deflected more than lighter gases. These realistic jets experienced faster velocity decay, and asymmetric jet spreading compared to round jets due to significant turbulent mixing in their near field. In addition to that, horizontal multi-component jets issuing from a round orifice on the side wall of a circular tube were also investigated experimentally by the means of simultaneous velocity and concentration measurements. A range of Reynolds numbers and gas densities were considered to study the effects of buoyancy and asymmetry on the resulting flow structure. The realistic pipeline jets were always exhibited an asymmetry structure and found to deflect about the jet's streamwise axis in the near field. In the far field, the buoyancy dominated much closer to the orifice than expected in the axisymmetric round jet due to the realistic leak geometry along with the pipeline orientation considered in this study. In general, significant differences were found between the centreline trajectory, spreading rate, and velocity decay of conventional horizontal round axisymmetric jets issuing through flat plates and the pipeline leak-representative jets considered in the present study. Finally, the dispersion of turbulent multi-component jets issuing from high-aspect-ratio slots on the side wall of a circular tube were studies experimentally by employing simultaneous PIV and PLIF techniques. Two transversal & longitudinal oblong geometries in respect to the longitudinal axes of the tube , and with an aspect ratio of 10 were considered in this study. Both horizontal and vertical orientations along with broad range of Reynolds numbers and gas densities were considered to investigate the effects of buoyancy and asymmetry on the resulting flow structure. The ensuing jets were found to deflect along the jet streamwise axis, once more, due to the realistic pipeline leak-representative configuration. It was also found that increases in aspect ratio of these realistic jets caused a reduction in the angle of deflection, jet centreline decay rates and the width growth on both velocity and scalar fields compared to their round jets counterparts, most notably in the far field. These findings indicate that conventional jets (those that are issuing through flat surfaces) assumptions are inadequate to predict gas concentration, entrainment rates and, consequently, the extent of the flammability envelope of realistic gas leaks. Thus, extreme caution is required when using conventional jet assumptions to describe the physics of a buoyant jet emitted from realistic geometries. / Graduate

The purpose of this master thesis was to study different content-aware video retargeting techniques, concentrating on a generalization of seam carving for video. Focus have also been put on the possibility to combine different techniques to achieve better retargeting of both multi-shot video and single-shot video. This also involved significant studies of automatic cut detection and different measures of video content. The work resulted in a prototype application for semi-automatic video retargeting, developed in Matlab. Three different retargeting techniques, seam carving, automated pan & scan and subsampling using bi-cubic interpolation, have been implemented in the prototype. The techniques have been evaluated and compared to each other from a content preservation perspective and a perceived quality perspective. / Syftet med examensarbetet har varit att studera tekniker för ändring av bredd/höjd-förhållandet i videosekvenser, där hänsyn tas till innehållet i bilderna. Fokus har lagts på en generalisering av "seam carving" för video och möjligheterna att kombinera olika tekniker för att nå bättre kvalitet både för videosekvenser som består av endast ett, eller flera, klipp. Detta innefattade således också omfattande studier av automatisk klippdetektering och olika mått av videoinnehåll. Arbetet har resulterat i en prototypapplikation utvecklad i Matlab för halvautomatisk förändring av bildförhållande där hänsyn tas till innehållet i sekvenserna. I prototypen finns tre metoder implementerade, "seam carving", automatiserad "pan & scan" och nedsampling med bi-kubisk interpolering. Dessa metoder har utvärderats och jämförts med varandra från ett innehållsbevarande perspektiv och ett kvalitetsperspektiv.

Die mikromechanische Gleichspannungswandlung basierend auf verschiebungsabhängigen Kapazitäten stellt eine Alternative zu etablierten rein elektronischen Wandlern für den Spezialfall der kapazitiven oder piezoelektrischen Verbraucher dar. Durch ihre kleine Bauform und den Verzicht auf Induktivitäten bietet sie den Vorteil der On-Chip-MEMS- und CMOS-Integration und ermöglicht die Bereitstellung hoher elektrischer Gleichspannungen aus den verfügbaren Grundspannungen der Elektronik (z. B. 3, 5 bzw. 12 V). Von hohen Polarisationsspannungen profitieren nicht nur kapazitive Sensoren und Aktoren, sondern auch piezoelektrische Messverfahren. Diese Arbeit stellt eine umfangreiche Übersicht und Bewertung der möglichen Bauformen mikromechanischer Gleichspannungswandler sowie die konkrete Umsetzung, Charakterisierung und Modellbildung eines resonant arbeitenden Wandlers vor. Es wird auf Besonderheiten und Probleme im Entwurf eingegangen und ausgehend von den Ergebnissen ein Konzeptentwurf für einen optimierten resonanten Gleichspannungswandler erarbeitet.:1 Einleitung 2 Theoretische Grundlagen 3 Ausführungsvarianten von MEMS-DC/DC-Wandlern 4 Designstudie und Umsetzung des resonanten Funktionsprinzips 5 Zusammenfassung und Ausblick / Micromechanical DC/DC conversion based on variable capacitances is an alternative to established electronic voltage converters, which does not require bulky inductors and is suitable for capacitive and piezoelectric loads. The converters are capable of boosting up the polarization voltage from CMOS and electronic levels (3, 5, 12 V), which is beneficial not only for capacitive sensors and actuators but also for piezoelectric sensing. Advantages of this method are the on-chip- and CMOS-integrability. This thesis introduces a comprehensive overview and evaluation of possible designs as well as the practical application, characterization and modeling of a resonant micromechanical DC/DC converter. Innovative claims include a test board for the characterization of resonant DC/DC converters and a SPICE behavioral model of the device, considering parasitic effects. Characteristics and problems of the design are discussed and the results are used to demonstrate an optimized conceptual design of a resonant DC/DC converter.:1 Einleitung 2 Theoretische Grundlagen 3 Ausführungsvarianten von MEMS-DC/DC-Wandlern 4 Designstudie und Umsetzung des resonanten Funktionsprinzips 5 Zusammenfassung und Ausblick

Drag polars for three Micro Air Vehicles (MAVs) were measured at Reynolds numbers of 70,000, 50,000, 30,000, and 10,000 and compared to predictions generated using the classical approach. The MAVs tested had different configurations and aspect ratios varying from 1.2 to 1.6 and ratios of wetted surface area to planform area from 2.6 to 3.9. A force balance was used to measure the lift and drag on the MAVs at angles of attack ranging from -5 degrees (or -10 degrees) to 10 degrees. The force balance allowed the MAVs to rotate in the pitching axis. The MAV angle of attack was set using an elevator installed on the MAV and controlled using a standard radio control used by RC plane enthusiasts. Uncertainty analysis performed on the data showed the uncertainty for high Reynolds numbers was dominated by velocity uncertainty, and uncertainty for the lower Reynolds numbers was dominated by uncertainty in the force measurements. Agreement between measured and predicted drag polars was good with the measured drag never being more than two times the predicted drag. For the majority of the tests, the drag coefficients followed the expected Reynolds number trend: increasing with decreasing Reynolds number.

Treemaps are a popular space-filling visualization of hierarchical data that maps an attribute of a datum, or a data aggregate, to a proportional amount of area. Assuming a rectangular treemap consisting of nested rectangles (also called tiles), there are multiple possible valid tiling arrangements. A common criterion for optimization is aspect ratio. Nevertheless, treemaps usually consist of multiple rectangles, so the aspect ratios need be aggregated. The basic definition of aspect ratio (width divided by height) cannot be meaningfully aggregated. Given this, a definition of aspect ratio that does not differentiate height from width was suggested. This definition allows for meaningful aggregation, but only as long as there are no large differences in the data distribution, and the target aspect ratio is 1:1. Originally, a target aspect ratio of 1:1 was deemed to be axiomatically ideal. Currently, perceptual studies have found an aspect ratio of 1:1 to lead to the largest area estimation error. However, with any other target this definition of aspect ratio cannot be meaningfully aggregated. This thesis suggests a correction that can be applied to the current metric and would allow it to be meaningfully aggregated even when there are large value differences in the data. Furthermore, both the uncorrected and corrected metrics can be generalized for any target (i.e. targets other than 1:1). Another issue with current evaluation techniques is that algorithm fitness is evaluated through Monte Carlo trials. In this method, synthetic data is generated and then aggregated to generate a single final result. However, tiling algorithm performance is dependant on data distribution, so a single aggregateresult cannot generalize overall performance. The alternative suggested in this thesis is visual cluster analysis, which should hold more general predictive power.All of the above is put into practice with an experiment. In the experiment, a new family of tiling algorithms, based on criteria derived from the results of the perceptual tests in literature,is compared to the most popular tiling algorithm, Squarify. The results confirm that there are indeed vast but consistent value fluctuations for different normal distributions. At least for a target aspect ratio of 1.5, the new proposed algorithms are shown to perform better than Squarify for most use cases in terms of aspect ratio.

Splitter plates are passive flow control devices for reducing drag and suppressing vortex shedding from bluff bodies. Most studies of splitter plates involve the flow around an “infinite” circular cylinder, however, in the present study the flow around a surface-mounted finite-height circular cylinder, with a wake-mounted splitter plate, was studied experimentally in a low-speed wind tunnel using a force balance and single-component hot-wire anemometry. Four circular cylinders of aspect ratios AR = 9, 7, 5 and 3 were tested for a Reynolds number range of Re = 1.9×10^4 to 8.2×10^4. The splitter plates had lengths, relative to the cylinder diameter, of L/D = 1, 1.5, 2, 3, 5 and 7, thicknesses ranging from T/D = 0.10 and 0.15, and were the same height as the cylinder being tested. The cylinders were partially immersed in a flat-plate turbulent boundary layer, where the range of boundary layer thickness relative to the cylinder diameter was δ/D = 1.4 to 1.5. Measurements were made of the mean drag force coefficient, the Strouhal number at the mid-height position, and the Strouhal number and power spectra along the cylinder height. For all four finite circular cylinders, the splitter plates were effective at reducing the magnitude of the Strouhal number, and weakening or even suppressing vortex shedding, depending on the specific combination of AR and L/D. Compared to the case of an infinite circular cylinder, the splitter plate is less effective at reducing the mean drag force coefficient of a finite circular cylinder. The largest drag reduction was obtained for the cylinder of AR = 9 and splitter plates of L/D = 1 to 3, while negligible drag reduction occurred for the shorter cylinders.

Plasmonic properties and the related novel applications are studied on various types of metallic nano-structures in one, two, or three dimensions. For 1D nanostructure, the motion of free electrons in a metal-film with nanoscale thickness is confined in its normal dimension and free in the other two. Describing the free-electron motion at metal-dielectric surfaces, surface plasmon polariton (SPP) is an elementary excitation of such motions and is well known. When further perforated with periodic array of holes, periodicity will introduce degeneracy, incur energy-level splitting, and facilitate the coupling between free-space photon and SPP. We applied this concept to achieve a plasmonic perfect absorber. The experimentally observed reflection dip splitting is qualitatively explained by a perturbation theory based on the above concept. If confined in 2D, the nanostructures become nanowires that intrigue a broad range of research interests. We performed various studies on the resonance and propagation of metal nanowires with different materials, cross-sectional shapes and form factors, in passive or active medium, in support of corresponding experimental works. Finite- Difference Time-Domain (FDTD) simulations show that simulated results agrees well with experiments and makes fundamental mode analysis possible. Confined in 3D, the electron motions in a single metal nanoparticle (NP) leads to localized surface plasmon resonance (LSPR) that enables another novel and important application: plasmon-heating. By exciting the LSPR of a gold particle embedded in liquid, the excited plasmon will decay into heat in the particle and will heat up the surrounding liquid eventually. With sufficient exciting optical intensity, the heat transfer from NP to liquid will undergo an explosive process and make a vapor envelop: nanobubble. We characterized the size, pressure and temperature of the nanobubble by a simple model relying on Mie calculations and continuous medium assumption. A novel effective medium method is also developed to replace the role of Mie calculations. The characterized temperature is in excellent agreement with that by Raman scattering. If fabricated in an ordered cluster, NPs exhibit double-resonance features and the double Fano-resonant structure is demonstrated to most enhance the four-wave mixing efficiency.