[pt] A predição da permeabilidade é uma etapa crítica no fluxo de caracterização e modelagem geológica de reservatórios e essencial para o desenvolvimento de projetos de produção. Estruturas subsísmicas denominadas bandas de deformação (BD) podem diminuir a permeabilidade em até seis ordens de grandeza em relação à rocha matriz de reservatórios areníticos e podem, dessa forma, atuar como barreiras totais ou parciais ao fluxo de fluidos. O presente trabalho pretende contribuir na determinação do comportamento hidráulico de reservatórios propondo um modelo geomecânico analítico para a predição de BD em reservatórios de arenitos. Em termos práticos, o objetivo é prever se em uma determinada porção de um depósito siliciclástico de hidrocarboneto foram atingidas condições para a formação de BD, ou quão próximo se está de uma possível geração dessa feição a fim de se sugerir uma análise da redução de permeabilidade. A proposta se estende na implementação computacional do método e sua aplicação em um estudo de caso de um reservatório arenítico pouco consolidado da margem continental brasileira rico em BD. Os resultados confirmaram a viabilidade do método mostrando que a porção do reservatório analisada atingiu as condições mecânicas para a gênese de BD a partir da idade geológica intitulada de Oligoceno (~ 23 a 35 Ma) para os cenários estabelecidos. / [en] The permeability prediction is a critical step in the flow of geological modeling and reservoir characterization and is essential for the development of production projects. Sub-seismic structures called deformation bands (BD) can reduce permeability up to six orders of magnitude in relation to the host reservoir sandstone and can thus act as total or partial barriers to the fluid flow. The present work intends to contribute in the determination of the hydraulic behavior of reservoirs proposing an analytical geomechanical model for BD s prediction in sandstone reservoirs. In practical terms, the objective is to predict whether the conditions in a given portion of a siliciclastic hydrocarbon deposit have been reached for the localization of BD or how close it is to a possible generation of this feature in order to suggest an analysis of the permeability reduction. The proposal extends to the computational implementation of the method and its application in a case study of a poorly consolidated sandstone reservoir on the brazilian continental margin, rich in BD. The results confirmed the viability of the method by showing that the portion of the analyzed reservoir reached the mechanical conditions for the genesis of BD from the geological age entitled Oligocene (~ 23 to 35 Ma) for the established scenarios.

The purpose of this treatise is not so much to discover heretofore unknown facts through original research; however, certain research is planned to assist in deleting the obvious handicaps one might encounter from using faulty instruments or mouthpieces, but rather to assemble under one cover practical data that may be of value in improving intonation in the band ensemble. Various definitions of terms will be established, purposes determined, opinion and methods of teachers evaluated, conclusions reached, and highlights of other persons’ experiments that may bear upon the subject will be presented.

Topological insulators are electronic materials that behave like an ordinary insulator in their bulk but have robust conducting states on their edge. Besides, in some materials the band structure presents completely flat bands, a special feature leading to strong interactions effects. In this thesis we present a study of the edge states of three particular two-dimensional models presenting flat bands: the honeycomb-Kagome, the $\alpha$--graphyne and a ligand decorated honeycomb-Kagome lattice models. We extend earlier work done on these lattice models by focusing on the topological nature of the edge states involving flat bands. We start by giving a review of the band structure theory and the tight-binding approximation. We then present several main topics in two-dimensional topological insulators such as the notion of topological invariants, the Kane-Mele model and the bulk-edge correspondence. Using these theoretical concepts we study the band structure of these lattices firstly without taking into account the spin and spin-orbit interations. We finally add these interactions to get their bulk band structures as well as the edge states. We observe how these spin-orbit interactions relieve degeneracies and allow for the emergence of edge states of topological nature. Since the lattices studied have an arrangement based on the honeycomb-Kagome lattice, two-dimensional materials having the structures of these lattices can be designed assembling metal ions and organic ligands. Therefore the results obtained could be used as a first hint to create new two-dimensional materials presenting topological properties. / Topologiska isolatorer är elektroniska material som uppför sig som en vanlig isolator i sin bulk men har robusta ledande stater på kanten. Dessutom presenterar bandstrukturen i vissa material helt platta band, en speciell egenskap som leder till starka interaktionseffekter. I denna avhandling presenterar vi en studie av kanttillstånden för tre speciella tvådimensionella modeller som presenterar platta band: bikakan-Kagome, $\alpha$-grafynen och en liganddekorerad honungskaka-Kagome modeller. Vi utökar tidigare arbete med dessa gittermodeller genom att fokusera på den topologiska karaktären hos kanttillstånd som innefattar platta band. Vi börjar med att ge en genomgång av bandstruktursteorin och den tätt bindande approximationen. Vi presenterar sedan flera huvudämnen i tvådimensionella topologiska isolatorer såsom begreppet topologiska invarianter, Kane-Mele modellen och bulk-kant korrespondensen. Med hjälp av dessa teoretiska begrepp studerar vi bandstrukturen för dessa gitter först utan att ta hänsyn till spinnen och spinnsorbital interaktioner. Vi lägger sedan till dessa interaktioner för att få sina bulkbandstrukturer såväl som kanttillstånden. Vi observerar hur dessa spinnsorbital interaktioner lindrar degenerationer och möjliggör uppkomsten av kanttillstånd av topologisk naturen. Eftersom de undersökta gitterna har ett arrangemang baserat på honungskaka-Kagome gitteren, kan tvådimensionella material med strukturerna hos dessa gitter utformas genom att montera metalljoner och organiska ligander. Därför kan de erhållna resultaten användas som en första ledtråd för att skapa nya tvådimensionella material med topologiska egenskaper.

No description available.

No / Raman spectroscopy was evaluated as a non-destructive analytical tool for the characterisation of white substances in burials. In addition, Fourier transform Raman spectroscopy was used to assess the conversion of hydrated lime into calcium carbonate. Fourteen samples of white substances from archaeological and forensic sites were analysed and characterised. The results show that not all white residues in burials are lime. Lime can easily be mistaken for other building materials (gypsum), for minerals (brushite) or degraded metal (cerussite). This study highlights the need for chemical analysis of white residues when encountered in burials. Analytical information derived from Raman spectra of white substances can further assist in the interpretation of the taphonomic processes of burials and their funerary context. Copyright (c) 2014 John Wiley & Sons, Ltd.

L'objectif de cette thèse est l'étude de la déformation, à l'échelle microscopique, de la phase MAX Ti2AlN, synthétisée par métallurgie des poudres. Ce travail se divise en trois parties : une première dans laquelle l'accent a été mis sur l'hystérèse mécanique des phases MAX via des essais cyclés, en nanoindentation sphérique et compression ex-situ de micro-piliers, sur des grains d'orientations différentes déterminées par l'EBSD. Dans la deuxième nous nous sommes intéressés à la déformation de micropiliers via des essais de compression cyclés in-situ couplés à la micro-diffraction Laue. L'objectif a été d'analyser les taches diffraction au cours de la déformation du pilier afin de mettre en évidence les mécanismes de déformation élémentaires mis en jeu et d'observer les structures finales via des images MEB post-mortem des piliers. Enfin, une dernière dans laquelle l'objectif a été l'étude des mécanismes de déformation en température à l'échelle microscopique via des essais de nano-indentation allant jusqu'à 800°C. La caractérisation des lignes de glissement en surface et des configurations microstructurales sous l'empreinte a été réalisée par AFM et MET respectivement. Toutes les données recueillies par ces divers essais aux petites échelles, ont permis d'affiner notre compréhension des mécanismes de déformation du monocristal de phase MAX, notamment vis à vis des modèles usuellement proposés dans la littérature. / The thesis's goal is to study the deformation, at microscopic scale, of the MAX phase Ti2AlN synthesized by powder metallurgy. This work is divided into three parts: in the first part, the interest has been put on the hysteretic behavior of the MAX phases via cyclic mechanical solicitations, during spherical indentation tests and ex-situ compression of micro-pillars, on differently orientated grains beforehand determined by EBSD. In the second part, we were interested into the micro-pillar's deformation via insitu cyclic compression tests coupled with Laue micro-diffraction. The goal was to analyse the evolution diffraction lines during the pillar's deformation in order to highlight the elementary deformation mechanisms and to observe the finale structures via the post-mortem SEM imaging of the pillars. Finally, a last part was devoted to study the deformation mechanisms in temperature at microscopic scale via nano-indentation tests up to 800°C. The characterization of the slip lines on the surface has been revealed by AFM and that of t he microstructural configurations (dislocations) under the indent has been done by TEM. All data collected by these various tests at the small scales have refined our understanding of the deformation mechanisms of crystal MAX phase, particularly with respect to the models usually proposed in the literature.

<p>Рад је окренут ка анализи мел-фреквенцијских кепстралних коефицијената као обележја говорника која се користе при аутоматском препознавању говорника. Испитан је утицај промене облика чујних критичних опсега као и модификације енергије у њима на тачност препознавања говорника. Такође испитане су и неке трансформације ради умањења временске променљивости модела истих говорника.</p> / <p>Rad je okrenut ka analizi mel-frekvencijskih kepstralnih koeficijenata kao obeležja govornika koja se koriste pri automatskom prepoznavanju govornika. Ispitan je uticaj promene oblika čujnih kritičnih opsega kao i modifikacije energije u njima na tačnost prepoznavanja govornika. Takođe ispitane su i neke transformacije radi umanjenja vremenske promenljivosti modela istih govornika.</p> / <p>The work is oriented towards the analysis of mel-frequency cepstral<br />coefficients as speaker features used in automatic speaker recognition. The<br />influence of the shape of auditory critical bands as well as the proposed<br />energy modification inside them is tested. Also, some transformations for<br />reducing of time variability of models of the same speakers are proposed.</p>

Diferentes métodos geoestatísticos são apresentados como a melhor solução para diferentes contextos de acordo com a natureza dos dados a serem analisados. Alguns dos métodos de estimativa mais populares incluem a krigagem ordinária e a krigagem ordinária lognormal, esta ultima requerendo a transformação dos dados originais para uma distribuição gaussiana. No entanto, esses métodos apresentam limitações, sendo uma das mais discutidas o efeito de suavização apresentado pelas estimativas obtidas. Alguns algoritmos recentes foram propostos como meios de se corrigir este efeito, e são avaliados neste trabalho para a sua eficiência, assim como alguns algoritmos para a transformada reversa dos valores convertidos na krigagem ordinária lognormal. Outra abordagem para o problema é por meio do grupo de métodos denominado de simulação estocástica, alguns dos mais populares sendo a simulação gaussiana seqüencial e a simulação por bandas rotativas, que apesar de não apresentar o efeito de suavização da krigagem, não possuem a precisão local característica dos métodos de estimativa. Este trabalho busca avaliar a eficiência dos diferentes métodos de estimativa (krigagem ordinária, krigagem ordinária lognormal, assim como suas estimativas corrigidas) e simulação (simulação seqüencial gaussiana e simulação por bandas rotativas) para diferentes cenários de dados. Vinte e sete conjuntos de dados exaustivos (em grid 50x50) foram amostrados em 90 pontos por meio da amostragem aleatória simples. Estes conjuntos de dados partiam de uma distribuição gaussiana (Log1) e tinham seus coeficientes de variação progressivamente aumentados até se chegar a uma distribuição altamente assimétrica (Log27). Semivariogramas amostrais foram computados e modelados para os processos geoestatísticos de estimativa e simulação. As estimativas ou realizações resultantes foram então comparadas com os dados exaustivos originais de maneira a se avaliar quão bem esses dados originais eram reproduzidos. Isto foi feito pela comparação de parâmetros estatísticos dos dados originais com os dos dados reconstruídos, assim como por meio de análise gráfica. Resultados demonstraram que o método que apresentou melhores resultados foi a krigagem ordinária lognormal, estes ainda melhores quando aplicada a transformação reversa de Yamamoto, com grande melhora principalmente nos resultados para os dados altamente assimétricos. A krigagem ordinária apresentou sérias limitações na reprodução da cauda inferior dos conjuntos de dados mais assimétricos, apresentando para estes resultados piores que as estimativas não corrigidas. Ambos os métodos de simulação utilizados apresentaram uma baixa correlação como os dados exaustivos, seus resultados também cada vez menos representativos de acordo com o aumento do coeficiente de variação, apesar de apresentar a vantagem de fornecer diferentes cenários para tomada de decisões. / Different geostatistical methods present themselves as the optimal solution to different realities according to the characteristics displayed by the data in analysis. Some of the most popular estimation methods include ordinary kriging and lognormal ordinary kriging, this last one involving the transformation of data from their original space to a Gaussian distribution. However, these methods present some limitations, one of the most prominent ones being the smoothing effect observed in the resulting estimates. Some recent algorithms have been proposed as a way to correct this effect, and are tested in this work for their effectiveness, as well as some methods for the backtransformation of the lognormal converted values. Another approach to the problem is by means of the group of methods known as stochastic simulation, some of the most popular ones being the sequential Gaussian simulation and turning bands simulation, which although do not present the smoothing effect, lack the local accuracy characteristic of the estimation methods. This work seeks to assess the effectiveness of the different estimation (ordinary kriging, lognormal ordinary kriging, and their corrected estimates) and simulation (sequential Gaussian simulation and turning bands simulation) methods for different scenarios. Twenty seven exhaustive data sets (in a 50x50 grid) have been sampled at 90 points based on simple random sampling. These data sets started from a Gaussian distribution (Log1) and had their variation coefficients increased progressively, up to a highly asymmetrical distribution (Log27). Experimental semivariograms have been computed and modeled for geostatistical estimation and simulation processes. The resulting estimates or realizations were then compared to the original exhaustive data in order to assess how well these reproduced the original data. This was done by comparing statistical parameters of the original data and the ones of the reconstructed data, as well as graphically. Results showed that the method that presented the best correlation with the exhaustive data was lognormal ordinary kriging, even better when the backtransformation technique by Yamamoto is applied, which much improved the results for the more asymmetrical data sets. Ordinary kriging and its correction had some severe limitations in reproducing the lower tail of the more asymmetrical data sets, with worst results than those for the uncorrected estimates. Both simulation methods used presented a very small degree of correlation to the exhaustive data, their results also progressively less representative as the variation coefficient grew, even though it has the advantage of presenting several scenarios for decision making.

L'élaboration de nouveaux alliages maintient un fort intérêt pour le phénomène d’instabilité plastique, ou l'effet Portevin-Le Chatelier (PLC), provoqué par l'interaction des dislocations avec des atomes de soluté. Par ailleurs, l'effet PLC attire l'intérêt comme un exemple remarquable d'auto-organisation dans les systèmes dynamiques. Il est associé à des motifs complexes de séries de chutes de contrainte liées à la nucléation et au mouvement des bandes de déformation dans le matériau déformé, et nécessite une compréhension de l'auto-organisation des dislocations. La déformation plastique des alliages Al-Mg est sujette à l'instabilité dans une large gamme de conditions expérimentales. Pour cette raison, les alliages Al-Mg binaires ont longtemps servi d'objets modèles pour l'étude de l'effet PLC. En même temps, l'utilisation pratique des alliages binaires Al-Mg est limitée en raison d’une faible résistance mécanique. Une amélioration significative de leurs propriétés peut être atteinte en ajoutant des solutés supplémentaires, conduisant en particulier à la formation de précipités. En outre, une forte réduction de la taille de grains du polycristal pourrait être une technique clé pour produire des matériaux à haute résistance et ténacité. Cependant, il existe très peu d'information, souvent contradictoire, sur l'instabilité PLC dans les alliages Al-Mg à grains fins et contenant des précipités. Le but de l'étude de cette thèse a été d'étudier les caractéristiques spécifiques de l'effet PLC dans les alliages à base AlMg, avec et sans nanoparticules, à gros grains et à grains fins, ces derniers obtenus par une méthode de déformation plastique sévère. Grâce à l’application de méthodes d’extensométrie locale, notamment de la technique de corrélation d’images, ces études ont révélé une persistance non habituelle de la propagation des bandes de déformation dans les alliages comprenant des précipités et/ou des grains fins. Ce mode dynamique est observé dans un large intervalle de vitesses de déformation, tandis qu’il n’apparait qu’à haute vitesse dans des alliages modèles AlMg. Par ailleurs, l’analyse des distributions statistiques des amplitudes des chutes de contrainte a révélé une tendance vers une statistique en loi puissance, caractéristique du mode de propagation. Ce phénomène est attribué à une modification du couplage spatial entre les dislocations, due à la concentration de contraintes internes. La combinaison de ces études avec l’analyse de l’émission acoustique a mis en évidence une influence de la microstructure sur la compétition entre un facteur aléatoire et la synchronisation des dislocations. Enfin, l’étude par corrélation d’images a permis d’observer une interrelation entre l’instabilité PLC et la formation de la striction. / The elaboration of new alloys sustains a strong interest to the phenomenon of unstable plastic flow, or the Portevin–Le Chatelier (PLC) effect, caused by interaction of dislocations with solute atoms. Moreover, this effect attracts interest as a rich example of self-organization in dynamical systems. It is associated with complex patterns of stress serrations related to nucleation and motion of deformation bands in the deforming material, and requires understanding of self-organization of dislocations. Plastic deformation of Al-Mg alloys is prone to instability in a wide range of experimental conditions. For this reason, binary Al-Mg alloys served for a long time as model objects for investigation of the PLC effect. At the same time, the practical use of binary Al-Mg alloys is limited because of their low strength. A significant improvement of their properties can be achieved by additional alloying, in particular, leading to precipitation. Further, extensive grain refinement could be a key technique used to produce tough and high- strength materials. However, there exists very limited and often contradictory information on the PLC instability in fine-grained Al-Mg alloys containing precipitates. The objective of the present thesis was to investigate specific features of the PLC effect in AlMg-based alloys with and without nanoscale particles, both in coarse-grained and fine-grained states, the latter obtained by severe plastic deformation. Using local extensometry methods, particularly the image correlation technique, these studies revealed an unusual persistence of the propagation of deformation bands in alloys with precipitates and/or fine grains. This dynamic mode is observed in a wide range of strain rates, whereas it only appears at high strain rate in model Al-Mg alloys. Moreover, the analysis of statistical distributions of stress drop amplitudes revealed a tendency to power law statistics characteristic of the propagation mode. This phenomenon was attributed to a modification of the spatial coupling between dislocations due to the concentration of internal stresses. The combination of these studies with the acoustic emission analysis uncovered an influence of the microstructure on the competition between a random factor and the dislocation synchronization. Finally, the study by the image correlation made it possible to observe an interrelation between the PLC instability and the neck formation.

Neste trabalho, foram desenvolvidas antenas têxteis de micro-ondas para aplicação em sistemas vestíveis, operando nas bandas ISM de 2,45 GHz e 5,8 GHz. Foram compiladas informações sobre o estado da arte em antenas têxteis, sendo realizado um estudo sobre antenas planares de micro-ondas e técnicas de alimentação das mesmas. Foi feita uma prospecção dos processos de fabricação de antenas têxteis de micro-ondas, definindo-se o processo e materiais têxteis usados na construção das antenas desenvolvidas. Procedeu-se à caracterização do tecido usado como substrato das antenas determinando-se suas características eletromagnéticas, utilizadas no projeto das antenas. Foram desenvolvidas antenas de microfita com plaqueta retangular e alimentação por sonda coaxial, para banda ISM de 2,45 GHz. Investigou-se o efeito da espessura do substrato da antena, tendo-se obtido experimentalmente larguras de banda de 4,8% e 6,0% para substratos com 0,7 mm e 1,4 mm de espessura, respectivamente. Foi proposta uma antena de microfita alimentada via acoplamento por proximidade que integra um transformador de um quarto de comprimento de onda ao circuito de alimentação, resultando em alargamento de banda da antena. Essa configuração foi utilizada no projeto de quatro antenas, que demonstraram experimentalmente larguras de banda de 11,2%, 13,4%, 17,0% e 24,0%. Uma configuração de antena têxtil empregando cavidade de um quarto de modo foi proposta para operação em banda dupla, sendo a tecnologia de guia de ondas integrado ao substrato - SIW, empregada em sua fabricação. Foi desenvolvido um procedimento de projeto para essa antena, o qual foi aplicado ao projeto de uma antena de banda dupla para as faixas ISM e 2,45 GHz e 5,8 GHz. Os resultados experimentais demostraram operação em banda dupla, com largura da banda inferior de 9,3%, e largura da banda superior de 9,2%. A antena de cavidade de quarto de modo apresentou as vantagens de maior ganho e menores dimensões relativamente às antenas têxteis de microfita desenvolvidas. De forma geral, os resultados experimentais dos protótipos construídos apresentaram boa concordância com os resultados fornecidos por simulação, demonstrando que as configurações de antenas propostas atenderam a seus objetivos, e a efetividade dos procedimentos de projeto adotado. / In this work, textile microwave antennas for use in wearable systems operating at 2.45 GHz and 5.8 GHz ISM bands were developed. Information on the state of art in textile antennas were compiled, and a study on microwave planar antennas and feeding techniques was performed. Processes for manufacturing textile microwave antennas were presented, and the fabrication process and textile materials used in this work were defined. The electromagnetic characteristics of the fabric used as antenna substrate were experimentally obtained, and used in the antenna design. Microstrip antennas using rectangular patch and coaxial probe feed were designed to operate at the 2.45 GHz ISM band. The effect of the antenna substrate thickness on the antenna characteristics was investigated, and experimental bandwidths of 4,8% and 6% were demonstrated for antennas with 0.7 mm and 1.4 mm thick substrates, respectively. A microstrip antenna fed by proximity coupling, including a quarter wavelength transformer at the feeding circuit, was proposed, resulting in the widening of the antenna bandwidth. This configuration was used to design four antennas, which experimentally demonstrated bandwidths of 11.2%, 13.4%, 17.0% and 24.0%. A textile antenna configuration employing a fourth mode cavity was proposed for dual band operation. Substrate integrated waveguide technology - SIW, was used for the antenna manufacturing. A design procedure was developed for this antenna, which has been applied to the design of a dual band antenna for the 2.45 GHz and 5.8 GHz ISM bands. The experimental results of this antenna demonstrated dual band operation, with 9.3% bandwidth at the lower band and 9.2% bandwidth at the higher band. The quarter mode cavity antenna presented the advantages of increased gain and smaller area than the designed textile microstrip antennas. In general, the experimental results of the fabricated prototypes exhibited good agreement with the results provided by simulation, demonstrating that the textile antenna configurations proposed met their expected performance and validating the design procedures adopted.