Reading is considered to be a vital skill for academic success, yet it is seldom taught to or practised with students. Students begin to `read to learn' during primary and secondary schooling. However, at tertiary level the academic demands are much greater than before and involve more extensive reading of conceptually more complex texts. This study investigates the implementation of an intensive reading programme for post-matric English Second Language Science students, based on the assumption that reading improves reading. In addition, this study investigates the effect that reading ability has on academic performance in Science, which relies inter alia, on the ability to read, comprehend and interpret word problems. An intervention group and a control group were used to ascertain the effects of an intensive reading programme and the findings suggest that any reading (intensive or extensive) improves reading and language skills. This in turn impacts on academic performance in Science, if students have an ability in Science to begin with. / Linguistics and Modern Languages / MA - SP APPLIED LINGUISTICS

La conversion photovoltaïque (PV) de l’énergie solaire repose sur la capacité qu’ont certains matériaux à convertir l’énergie des photons en courant électrique. Le développement des systèmes de conversion PV ces trente dernières années a permis des améliorations considérables en terme de coût et de performances dans le domaine des énergies renouvelables.Une cellule multi-jonctions (MJ), à base de matériaux semi-conducteurs III-V, est un empilement de sous-cellules aux gaps décroissants qui permet notamment une plus large utilisation du spectre solaire. Soumettre ces cellules PV à un flux solaire concentré permet d’augmenter significativement la puissance électrique créée par celles-ci, et ainsi d’abaisser substantiellement le coût de l’électricité produite.Le record du monde est actuellement détenu par le partenariat Soitec / Fraunhofer ISE avec un rendement de 46,0 % mesuré sur une cellule quadruple-jonctions en GaInP/GaAs//InGaAsP/InGaAs pour un taux de concentration de 508 X (où 1 X =1 soleil = 1 kW/m²).L’objectif du travail réalisé dans le cadre de cette thèse est de proposer une alternative aux cellules existantes plus simple à mettre en œuvre avec des cellules MJ monolithiques accordées sur substrat de GaSb pour des concentrations solaire de 1 000, soit une irradiance directe de 1 MW/m². Ce type de cellules, du fait de la très bonne complémentarité des gaps des matériaux et ses alignements de bandes favorables, constitue une alternative crédible et originale aux cellules existantes pour une utilisation sous flux solaire fortement concentré.Afin de mieux comprendre la cellule multijonctions III-Sb optimale, les travaux réalisés ont porté sur la fabrication et la caractérisation des trois sous-cellules fabriquées indépendamment. Ces trois échantillons épitaxiés sont l’Al0,9Ga0,1As0,07Sb0,93 (cellule Top), l’Al0,35Ga0,65As0,03Sb0,97 (cellule Middle) et le GaSb (cellule Bottom) ayant comme gaps respectifs 1,6 eV, 1,22 eV et 0,726 eV à 300 K.Le travail présenté dans cette thèse porte sur :- La réalisation et la mise au point de toutes les étapes technologiques nécessaires à la fabrication des cellules (dépôts métalliques, gravure humide et sèche par plasma …).- La caractérisation des métallisations par structure TLM (Transmission Line Method) dont le meilleur résultat obtenu concerne une métallisation tri-couche Cr/Pd/Au (30/30/30 nm) sur substrat GaSb type P.- La caractérisation sous obscurité courant-tension des paramètres électriques des cellules PV à température ambiante et en fonction de la température.- La caractérisation thermique par mesure de la conductivité thermique des matériaux et une cartographie de température de surface en fonction du flux solaire concentré en conditions réelles.- La caractérisation électro-optique par réponse spectrale, à partir de laquelle nous avons calculé le rendement quantique externe qui représente le rapport entre la quantité d’électrons créés et la quantité de photons incidente.- La caractérisation sous illumination à 1 soleil (1 000 W/m²) sous simulateur solaire et en conditions solaire dont nous avons comparé les paramètres électriques.- La caractérisation des cellules sous flux solaire (fortement) concentré au laboratoire PROMES. Les meilleurs rendements obtenus pour les cellules PV Bottom, Middle et Top respectifs de 4,6 % à 40 X (proche de l’état de l’art), 8,2 % à 96 X et 5,4 % à 185 X (première mondiale pour ces matériaux quaternaires).Ce travail a été cofinancé par le Ministère de l’Education et de la Recherche (Allocation ED) et le Labex SOLSTICE.Photovoltaic (PV) solar energy consists on the ability of certain materials to convert the photon energy into electric current. The development of PV conversion systems in the past thirty years has led to considerable improvements in terms of cost and performance in the field of renewable energies. / Photovoltaic (PV) solar energy consists on the ability of certain materials to convert the photon energy into electric current. The development of PV conversion systems in the past thirty years has led to considerable improvements in terms of cost and performance in the field of renewable energies.A multi-junction (MJ) cell, based on III-V semiconductor materials, is a stack of sub-cells with decreasing gaps which notably allows wider use of the solar spectrum. Exposing these PV cells to a concentrated solar flux can significantly increase the electrical power generated, and therefore substantially lower the cost of electricity yielded.The world record is currently held by the partnership Soitec / Fraunhofer ISE with an efficiency of 46.0 % measured on a four-junction cell GaInP/GaAs//InGaAsP/InGaAs for a concentration ratio of 508 X (where 1 X = 1 sun = 1 kW/m²).The objective of the work in this thesis is to propose an alternative to existing cells, easier to implement with monolithic MJ cells grown on a GaSb substrate for solar concentrations of 1 000, which corresponds to a direct irradiance of 1 MW/m². This type of cell, due to the good complementary of the material gaps and its favorable band alignments, is a realistic and original alternative to existing cells for use under highly concentrated solar flux.To better understand the optimal multijunction III-Sb cell, the work carried out consisted on the manufacturing and characterization of the three sub-cells independently.These three epitaxial samples are Al0,9Ga0,1As0,07Sb0,93 (Top cell), the Al0,35Ga0,65As0,03Sb0,97 (Middle cell) and GaSb (Bottom cell) having as respective gaps 1.6 eV, 1.22 eV and 0.726 eV at 300 K.The work presented in this thesis is:- The establishment of all the technological steps required to manufacture the cells (metal deposition, wet and dry plasma etching ...).- The characterization of metallization by TLM structure (Transmission Line Method) with the best result being a three-layer metallization Cr/Pd/Au (30/30/30 nm) on a GaSb P-type substrate.- The characterization under dark of current-voltage electrical parameters of PV cells at room temperature and in function of the temperature.- The thermal characterization by measuring the thermal conductivity of the materials and a surface temperature mapping in function of the concentrated solar flux in realistic conditions.- The electro-optical characterization by spectral response, from which we calculated the external quantum efficiency which is the ratio between the amount of electrons created and the amount of incident photons.- The characterization under 1 sun illumination (1 000 W/m²) in a solar simulator and in realistic conditions of which we compared the electrical parameters.- The characterization of solar cells under (highly) concentrated solar flux in the PROMES laboratory.The best efficiencies for Bottom, Middle and Top PV cells respectively are 4.6 % for 40 X (close to the state of the art), 8.2 % for 96 X and 5.4 % for 185 X (world first for these quaternary materials).This work was cofounded by the Ministry of Education and Research (ED Research grant) and Labex SOLSTICE.

Cette étude porte sur la mise en forme des matériaux composites renforcés par des fibres ou des mèches de fibres courtes tels que les SMC ou les BMC. Un travail expérimental a dans un premier temps été réalisé à l’échelle macroscopique. Ce travail a permis de mettre au point un rhéomètre de compression lubrifiée ainsi que des méthodes d’essais et de dépouillement. Ceci permet de mieux caractériser la rhéologie des compounds SMC et BMC en traitant les problématiques de leur compressibilité et des frottements éventuels entre les parois du rhéomètre et la matière déformée. Un travail numérique a ensuite permis de simuler la mise en forme d’un BMC après l’identification des paramètres d’un modèle rhéologique simple à partir des données expérimentales obtenues sur le rhéomètre. Enfin, un travail expérimental à l’échelle microscopique a permis d’une part de caractériser finement les microstuctures de SMC modèles à partir de microtomographies à rayons X, et d’autre part de caractériser et de modéliser par le biais d’essais d’extraction de fibres les interactions entre les mèches formant le renfort fibreux de ces matériaux. / This study focuses on the processing of composite materials reinforced with short fibres or fibres bundles such as SMC or BMC. Firstly, an experimental work was carried-out at the macroscopic scale. This work led to the development of a lubricated compression rheometer and associated analysis methods to better characterize the rheology of SMC and BMC compounds, by accounting for the compressibility of compounds and the possible friction between the rheometer wall and the flowing composite. Numerical simulation was then achieved in order to simulate the forming of a BMC. For that purpose, the constitutive parameters of a simple tensorial rheological model were determined from experimental data obtained with the rheometer. Finally, an experimental work at the microscopic level allowed (i) the microstuctures of SMC models from X-ray microtomography micrographs and (ii) fibre pull-out experiment to be characterized, and the interaction mechanisms between the fiber bundles forming the fiber reinforcement of these materials to be modelled.

Made available in DSpace on 2016-06-02T19:52:00Z (GMT). No. of bitstreams: 1 5215.pdf: 2573740 bytes, checksum: b0159c517597ec5097315a913808cb47 (MD5) Previous issue date: 2012-10-05 / Financiadora de Estudos e Projetos / Brazil is the largest producer and exporter of the world market of frozen concentrated orange juice (FCOJ), and the State of São Paulo stands out as the largest producer and exporter of that commodity in Brazil. In recent years, the State of Paraná has increased its production and export of FCOJ. Through the survey of secondary data and interviews with key players, this study identified and evaluated the main critical aspects of the competitiveness of the agri-food chain of FCOJ in Paraná. Through the rapid appraisal method (method of quick research) were possible to evaluate 11 drivers of competitiveness, focusing on the links of agricultural production and processing of that chain. A total of 24 interviews were conducted, using questionnaires and interviews screenplays. It was possible to identify which are the drivers of competitiveness, considered in the context of this research, which are considered favorable, neutral and unfavorable for the competitiveness of the links of agricultural production and processing of the agri-food chain of FCOJ in Paraná. From these analyses it was also possible to verify that none of the drivers of competitiveness, considered in this dissertation, was regarded as very favorable or very unfavorable for the competitiveness of the link of agricultural production of that chain. From these analyses it was also possible to verify that none of the drivers of competitiveness, considered in this dissertation, was regarded as very favorable for the competitiveness of the link of processing of that chain, and only a driver of competitiveness, of the set of drivers considered in this dissertation, was regarded as very unfavorable for the competitiveness of the link of processing. The analyses allowed to point out proposals for public policies and private strategies to enhance the competitiveness. In a general context, it was possible to conclude that the links of agricultural production and processing of the agri-food chain of FCOJ in Paraná have a great potential to continue to expand in Paraná. The citriculture in Paraná has a great potential to expand because it has a good technology, a good production capacity and productivity and a sufficient amount of available agricultural land to extend the exploration of the citriculture in Paraná, in addition, the economic agents that act in the citriculture in Paraná have contracts for the supply of orange to the economic organizations that have manufacturing plants that produce FCOJ in Paraná, so these contracts ensure the sale of the most part of the Paraná s orange production, which is good for the citrus growers who act in Paraná. The processor sector of orange also has a great potential to expand in Paraná because it has agro-industrial technologies of good level and a good production capacity, in addition to be able to expand without great difficulties its manufacturing capacity of FCOJ, moreover, the existence of contracts for orange supply between economic organizations who act in processing and citrus growers in Paraná, secures the supply of oranges, considered of good quality, for the producing plants of FCOJ installed in Paraná. / O Brasil é o maior produtor e exportador do mercado mundial de suco de laranja concentrado congelado (SLCC), sendo que o Estado de São Paulo destaca-se como o maior produtor e exportador nacional dessa commodity. Nos últimos anos, o Estado do Paraná tem aumentado a sua produção e exportação de SLCC. Por meio de levantamento de dados secundários e de entrevistas com agentes-chaves, identificou-se e avaliou-se os principais aspectos críticos da competitividade da cadeia agroindustrial de SLCC no Paraná. Por meio do método rapid appraisal (método de pesquisa rápida) foi possível avaliar 11 direcionadores de competitividade, com foco nos elos de produção agrícola e de processamento dessa cadeia. Um total de 24 entrevistas foram realizadas, utilizando-se de questionários e roteiros de entrevistas. Foi possível identificar quais são os direcionadores de competitividade, considerados no âmbito desta pesquisa, que são considerados favoráveis, neutros e desfavoráveis para a competitividade dos elos de produção agrícola e de processamento da cadeia agroindustrial paranaense de SLCC. A partir dessas análises também foi possível verificar que nenhum dos direcionadores de competitividade, considerados nesta dissertação, foi considerado como muito favorável ou muito desfavorável para a competitividade do elo de produção rural da cadeia agroindustrial paranaense de SLCC. A partir dessas análises também foi possível verificar que nenhum dos direcionadores de competitividade, considerados nesta dissertação, foi considerado como muito favorável para a competitividade do elo de processamento da cadeia de SLCC no Paraná, e somente um direcionador de competitividade, do conjunto de direcionadores considerados nesta dissertação, foi considerado como muito desfavorável para o desempenho competitivo do elo de processamento. As análises permitiram apontar propostas de políticas públicas e estratégias privadas que possam aumentar a competitividade. Em um contexto geral, pode-se concluir que os elos de produção rural e de processamento da cadeia agroindustrial de SLCC no Paraná têm um grande potencial para continuar a se expandir no território paranaense. A citricultura, no Paraná, tem um grande potencial para se expandir porque ela dispõe de boa tecnologia, de boa capacidade de produção e produtividade e de quantidade de terra agrícola disponível considerada como suficiente para ampliar a exploração da atividade citrícola no estado, além disso, os agentes econômicos que atuam na citricultura paranaense possuem contratos de fornecimento de laranja com as organizações econômicas que possuem usinas produtoras de SLCC instaladas no Paraná, assim, esses contratos asseguram a comercialização da maior parte da produção paranaense de laranja, o que é algo bom para os citricultores que atuam no Paraná. Já o setor processador de laranja também tem um grande potencial para se expandir no Paraná porque ele dispõe de tecnologias agroindustriais de bom nível e de boa capacidade de produção, além de ter condições de ampliar, sem maiores dificuldades, a sua capacidade de fabricação de SLCC, além disso, a existência de contratos de suprimento de laranja entre as organizações econômicas que atuam no processamento citrícola e os citricultores, no Estado do Paraná, assegura o abastecimento de laranja, considerada de boa qualidade, para as usinas produtoras de SLCC instaladas no Paraná.

Submitted by Fabio Sobreira Campos da Costa (fabio.sobreira@ufpe.br) on 2016-08-19T12:20:36Z No. of bitstreams: 2 license_rdf: 1232 bytes, checksum: 66e71c371cc565284e70f40736c94386 (MD5) TESE N 127 - PROTEN DEN UFPE - VERONICA AZEVEDO.pdf: 11747677 bytes, checksum: a2779760a6f763a69e1f529900e5dfdf (MD5) / Made available in DSpace on 2016-08-19T12:20:36Z (GMT). No. of bitstreams: 2 license_rdf: 1232 bytes, checksum: 66e71c371cc565284e70f40736c94386 (MD5) TESE N 127 - PROTEN DEN UFPE - VERONICA AZEVEDO.pdf: 11747677 bytes, checksum: a2779760a6f763a69e1f529900e5dfdf (MD5) Previous issue date: 2016-01-29 / CAPEs / Notadamente nos últimos anos, a geração de eletricidade a partir de fontes renováveis de energia tem mostrado contínuo aumento que está relacionado, sobretudo, às preocupações com as variações climáticas, à dependência dos combustíveis fósseis e à necessidade de suprir a geração de energia elétrica com recursos que produzam menos impactos ao meio ambiente. A capacidade instalada da energia renovável no mundo, que foi de 800GW em 2004, alcançou 1.712GW em 2014 e a participação na matriz energética global também aumentou, atingindo o percentual de 22,8% em 2014. O Brasil possui uma matriz energética predominantemente renovável. Somente em 2014, aproximadamente 74,6% da eletricidade gerada procedeu das fontes renováveis de energia. O percentual restante (25,4%) proveio dos combustíveis fósseis e das fontes nucleares. Mas, muito embora o País possua uma matriz energética tipicamente renovável, nota-se que o principal sistema de geração é o aproveitamento hidráulico, que é bem vulnerável às variações climáticas globais e pode apresentar, em função disso, redução de sua capacidade instalada em longo prazo. Visando contribuir para a diversificação da matriz energética brasileira, esta pesquisa apresenta dois métodos distintos e macroespaciais para auxiliar a seleção de áreas potenciais para a inserção de usinas solares termoelétricas: o Método baseado no Processo Analítico Hierárquico, que trata o problema da localização sob uma organização hierárquica de critérios, como pressupõe os axiomas do Método AHP; e o Método do Custo de Produção de Eletricidade, que define os locais aptos em função do custo nivelado da eletricidade (LCOE – Levelised Cost of Electricity). Ambas as metodologias foram aplicadas para Pernambuco, localizado na região Nordeste do Brasil, e considerou a implantação de usinas de coletores parabólicos de 80MWe, tipo SEGS, operando somente em modo solar, sem armazenadores térmicos. Com base nas análises realizadas, confirmou-se que Pernambuco apresenta grande potencial para a implantação de usinas solares, principalmente no Sertão Pernambucano, onde foram encontrados os ambientes mais favoráveis à instalação. Na aplicação do Método AHP, por exemplo, o Sertão apresentou alto potencial de instalação em todos os cenários avaliados, inclusive no cenário Ponto de Partida, onde os pesos não foram considerados. No Método do Custo de Produção de Eletricidade, o Sertão também mostrou alto potencial de instalação uma vez que os custos de geração de energia elétrica encontrados foram os menores do estado (da ordem de R$ 337,16/MWh). Este custo é elevado quando comparado com o preço da eletricidade gerada pela fonte hidráulica no país (R$ 182,09/MWh), por exemplo, mas estão em conformidade quanto ao esperado para sua inserção no mercado brasileiro. De modo geral, as abordagens apresentadas se mostraram muito consistentes e revelaram um potencial bastante promissor para o desenvolvimento da tecnologia em Pernambuco. Este potencial deverá ser avaliado detalhadamente e incluir a medição local da radiação solar por pelo menos cinco anos. / Notably in recent years, the generation of electricity using energy from renewable resources has presented continuous increase, which is due to, especially, the concerns about climate changes, the dependency in fossil fuel and the necessity of production of electric energy with resources to decrease the negative impacts in the environmental. The global renewable power generation capacity, which presented 800GW on the beginning of 2004, reaching an estimated 1,712GW at year’s end 2014, and the renewable electricity global production in 2014 presented 22.8%. Brazil has a mainly renewable energy matrix. In 2014, 74.6% of the electricity produced came from renewable sources of energy. The remaining percentage comes from fossil fuels and nuclear sources (25.4%). Although it shows a remarkably renewable character, it is notable that the main source of generation of electricity is the water source, which is susceptible the climate changes, and should present the reduction in your capacity installed in a long term. As a way of contributing to diversify the energy matrix Brazilian, this work presents two different methodologies macro spatial for the selection of the best sites for insertion of solar thermal power plants: the methodologies based on analytic hierarchy process (AHP) where the selection the best site was based on means of the hierarchical organization of criteria according to axioms of the AHP method; and the method based on cost of electricity generation where the best site were selected according to Levelised Cost of Electricity (LCOE). Both studies were made in Pernambuco, located in Northeastern Region of Brazil and considered the implementation of a parabolic trough solar power plant, of 80MWe, operating exclusively in solar mode, without thermal stores. The analyzes performed confirmed that the Pernambuco presents great potential for the installation of solar thermal power plants, especially, in the Sertão Pernambucano where the best sites were located. In the methodologies AHP, for example, this region presented great potential for the installation in all scenarios analyzed, including the Ponto de Partida scenarios where weights are not used. In the method based on cost of electricity, the Sertão presented great potential also. In this region it is possible to find electric energy generation costs by MWh of the order of R$ 337.16. This costs are still high when comparing the cost of generation of the hydraulic source (R$ 182.09/MWh) in Brazil, although, they comply as to expected for its insertion in the Brazilian Market. The methodologies used demonstrated very consistent and identified a promising potential for solar thermal power generation in Pernambuco. This potential should be analyzed in details and include the local measurement of the incident direct normal solar irradiation for at least five years.

Recently, the supercritical carbon dioxide (s-CO2) Brayton cycle has been identified as a promising candidate for solar-thermal energy conversion due to its potentially high thermal efficiency (50%, for turbine inlet temperatures of ~ 1000 K). Realization of such a system requires development of solar receivers which can raise the temperature of s-CO2 by over 200 K, to a receiver outlet temperature of 1000 K. Volumetric receivers are an attractive alternative to tubular receivers due to their geometry, functionality and reduced thermal losses. A concept of a ceramic pressurized volumetric receiver for s-CO2 has been developed in this work. Computational Fluid Dynamics (CFD) analysis along with a Discrete Ordinate method (DOM) radiation heat transfer model has been carried out, and the results for temperature distribution in the receiver and the resulting thermal efficiency are presented. Issues regarding material selection for the absorber structure, window, coating, receiver body and insulation are also addressed. A modular small scale prototype with 0.5 kWth solar heat input has been designed. The design of a small scale s-CO2 loop for testing this receiver module is also presented in this work. There is a lot of ongoing investigation for design and simulation of different configurations of heat exchangers and solar receivers using s-CO2 as the working fluid, in which wall temperatures up to 1000 K are encountered. While CO2 is considered to be transparent as far as solar radiation spectrum is concerned, there may be considerable absorption of radiation in the longer wavelength range associated with radiation emission from the heated cavity walls and tubes inside the receivers. An attempt has been made, in this study, to include radiation modelling to capture the effect of absorption bands of s-CO2 and the radiative heat transfer among the equipment surfaces. As a case study, a numerical study has been performed to evaluate the contribution of radiative heat transfer as compared to convection and conduction, for s-CO2 flow through a circular pipe. The intent is to provide a guideline for future research to determine the conditions for which radiation heat transfer modelling inside the pipe can be significant, and what errors can be expected otherwise. The effect of parameters such as Reynolds number, pipe diameter, length to diameter ratio, wall emissivity and total wall heat flux has been studied. The effect of radiation modelling on wall temperatures attained for certain amount of heat flux to be transferred to s-CO2 is also studied. The resulting temperature distribution, in turn, affects the estimation of heat loss to the environment

Ce travail est consacré à l’étude des propriétés de systèmes à base de tensioactifs non ioniques hydrogéné et fluoré dans le but de préparer des matériaux poreux silicatés. L’effet de la solubilisation d’hexadécane ou de décane dans des micelles de C12H25CO(OC2H4)9OCH3 conduit à la formation de silices mésoporeuses à plus larges pores, tandis qu’aucun effet de gonflement n’est observé avec l’ajout de cyclohexane. Lorsque les matériaux sont préparés avec des micelles de C8F17C2H4(OC2H4)9OH, l’ajout de perflorooctylbromure (PFOBr) augmente la taille des mésopores. Par ailleurs, l’incorporation de grandes quantités de PFOBr ou de perfluorodécaline conduit à la formation de macropores. Avec C7F15C2H4(OC2H4)8OH, l’incorporation de (C4F9CH)2 permet d’élargir les mésopores et de créer un réseau de macropores, tandis que l’ajout de PFOBr ne conduit ni à la formation de mésopore, ni à la formation de macropore. Les résultats mettent en évidence que la formation de matériaux macroporeux à partir d’émulsions hydrogénées ou fluorées est favorisée avec les systèmes qui présentent des valeurs de PIT (Température d’Inversion de Phase) élevées. Pour finir, l’effet de l’addition de différents alcools dans le système à base de C8F17C2H4(OC2H4)9OH a été étudié. La détermination des paramètres structuraux de la phase cristal liquide hexagonal, indique que les alcools à courte ou moyenne chaîne jouent le rôle de solvant, tandis que le fluoro-octanol joue celui d’un co-tensioactif. L’addition d’alcools courts provoque la destruction progressive des micelles qui perturbe le mécanisme d’auto-assemblage et les matériaux obtenus présentent des structures vermiformes / This work deals with the study of the properties of nonionic hydrogenated and fluorinated surfactant based systems which are related to the synthesis of porous silica. The effect of the solubilization of low fraction of hexadecane or decane in the micelles of C12H25CO(OC2H4)9OCH3 leads to the formation of large mesoporous silica, whereas no swelling effect was noted with cyclohexane. When the materials are templated by fluorinated micelles of C8F17C2H4(OC2H4)9OH, large pore mesoporous materials are obtained with perfluorooctyl bromide (PFOBr). Both PFOBr and perfluorodecalin give rise to macropores at high oil concentrations. With C7F15C2H4(OC2H4)8OH, the fluorocarbon (C4F9CH)2 is not only an effective expander to enlarge the pore size of mesoporous materials, but also very favourable for the design of macropore network. On the contrary, with PFOBr, there is neither mesopore nor macropore. Therefore, both hydrogenated and fluorinated systems obey to the same rule: the formation of macroporous materials template by emulsions is favoured with systems which exhibit a high value of the PIT. Lastly, alcohols used as additives in the C8F17C2H4(OC2H4)9OH -water system to tune the characteristics of the recovered materials. The structural parameters of the hexagonal liquid crystal show the short and medium alcohols behaved like solvent, while the long chain and fluorinated octanol acted as co-surfactant. The short alcohols provoke a micelle breaking effect. Thus, the self-assembly mechanism is disturbed and wormhole-like structures are recovered

Die Charakterisierung von Dispersionen hat das Ziel, die Zusammensetzung und den Zustand von partikelhaltigen Stoffgemischen zu erfassen. Vor allem der Zustand der dispersen Phase (Partikel), der wiederum von der Größe und der Konzentration der Partikel bestimmt wird, ist in diesem Zusammenhang von besonderer Bedeutung. Neben optischen Verfahren, wie der Laserbeugung oder der Lichtstreuung, ist die Anwendung von akustischen Methoden vor allem dann sinnvoll, wenn die zu untersuchenden dispersen Stoffgemische opak und optische Methoden nur noch eingeschränkt (nach Verdünnung) anwendbar sind. Derartige Dispersionen weisen oftmals eine hohe Partikelkonzentration auf. Die Erfassung und Auswertung von Ultraschallechosignalen aus konzentrierten Dispersionen stellt einen neuartigen Ansatz innerhalb der akustischen Partikelmesstechnik dar. Im Rahmen der vorliegenden Arbeit wurden theoretische und experimentelle Untersuchungen zum Ultraschallrückstreuverhalten von konzentrierten Dispersionen im unteren Megahertzbereich durchgeführt. Die messtechnische Erfassung der von der Dispersion reflektierten Schallanteile stellte eine besondere Herausforderung dar. Vor allem bei Partikeln, die klein gegenüber der Wellenlänge des Schalls sind oder einen geringen akustischen Kontrast gegenüber der kontinuierlichen Phase aufweisen, ist ein entsprechend schwaches Echosignal zu erwarten. Im Ergebnis der durchgeführten Untersuchungen zeigt sich eine hohe Sensitivität des akustischen Rückstreuverhaltens gegenüber der Zusammensatzung der Dispersion. Vor allem in konzentrierten Dispersionen kann die Messung direkt, d. h. ohne vorherige Verdünnung durchgeführt werden. Dieser Umstand prädestiniert das entwickelte Messverfahren für den Einsatz innerhalb der prozessnahen Charakterisierung von Partikelsystemen, beispielsweise bei Nasszerkleinerungs- oder Kristallisationsprozessen. Bei derartigen Prozessen ist eine Probenahme und Probenaufbereitung nicht oder nur eingeschränkt möglich.

Dans le contexte énergétique qui se profile, la production d’électricité par voie solaire thermodynamique s’avère une solution prometteuse, que ce soit pour des considérations économiques, d’échelle de production ou environnementales. Une voie d’amélioration du rendement des centrales solaires à tour consiste à utiliser des cycles thermodynamiques à haut rendement type cycles combinés. Cela nécessite de pouvoir fournir un fluide de travail pressurisé à très haute température (10bar et 1000°C minimum). Ce manuscrit présente les travaux menés afin de développer et de viabiliser un concept d’absorbeur solaire surfacique modulaire en céramique (carbure de silicium) capable de répondre à ces exigences. Le choix du carbure de silicium s’est imposé pour sa résistance aux hautes températures et aux problèmes d’oxydation. Cependant, l’utilisation d’une céramique comme matériau implique un risque de casse des modules. Les céramiques sont en effet fragiles lorsqu’elles sont soumises à des contraintes de traction. C’est la connaissance et la maitrise de ce risque qui fait l’objet de cette étude. L’approche adoptée combine le développement d’outils numériques et d’études expérimentales réalisées sur le site de la centrale solaire Thémis (Targassonne, 66, France). La méthodologie desimulation développée permet de prédire le comportement thermique et le comportement mécanique de l’absorbeur. Ceci permet de réduire les risques encourus par l’absorbeur et d’en connaitre les performances. Cette méthodologie a été éprouvée à l’aide des résultats expérimentaux. / For the future, using thermodynamical solar power plant seems to be a good solution to ensure electrical production. Solar tower plants are able to produce electricity in significant amount, are environmentally friendly and economically competitive. One way to increase the yield of these plants is using high efficiency thermodynamical cycles, like combined cycle. That requires to providing a working fluid at high temperature and high pressure (10bar and 1000°C at least). This PHD thesis presents the works performed to develop and enhance a concept of modular plate solar ceramic absorber that can ensure the required air production. We chose the silicon carbide as material due to its resistance to high temperatures and oxidation problems. The drawback is ceramic modules are weak to traction stresses. The study focuses on the knowledge and the control of this phenomenon. This work combines the developments of numerical tools and experimental studies performed at Thémis power plant (Targassonne, 66, FRANCE). The numerical method permits simulations to predict the thermal behavior and the mechanical behavior of a solar module absorber. It allows the reduction of the mechanical stresses undergone by solar receiver and the prediction of its performances. This methodology was tested using experimental results.

Cette thèse concerne l’étude de l’influence de la formulation sur le comportement rhéologique des émulsions inverses très concentrées. Nous avons utilisé une démarche originale consistant à positionner le module élastique (G’) de ces émulions sur une carte bidimensionnelle formulation-composition, afin d’étudier, en particulier, l’effet de la formulation dite optimale. Deux effets nets sont liés à celle-ci: les émulsions préparées à HLB=10, c’est-à-dire à proximité de la valeur optimale (HLB=10,5), présentent des valeurs de G’ nettement plus faibles que les autres formulations, tandis qu’à une distance particulière (HLB=7,7), les valeurs de G’ sont toujours plus élevées comparativement aux autres formulations. Cette valeur particulière de HLB correspond aussi à une stabilité maximale de la dispersion et à une taille moyenne des gouttes minimale. Les émulsions très concentrées étant généralement opaques et fragiles, l’analyse du transport stationnaire incohérent de lumière polarisée, qui ne nécessite pas de dilution, a été utilisée comme méthode alternative aux techniques classiques pour déterminer l’épaisseur moyenne du film interfacial (h). La taille moyenne des gouttes (R) a pu ensuite être déterminée à partir d’un modèle géométrique qui relie R à l’épaisseur moyenne du film interfacial (h), à la fraction volumique de phase dispersée (f) et à un facteur géométrique moyen (f9) tenant compte du caractère polyédrique des gouttes. Ainsi, une expression modifiée du modèle proposé par Mougel et al. (2006) a été établie pour modéliser le module élastique (G’) en le reliant à la taille moyenne de gouttes (R), la tension interfaciale (s) et la fraction volumique de phase dispersée (f) / This thesis deals with the study of the influence of formulation on the rheological behavior of highly concentrated reverse emulsions. We used an original approach consisting in representing the elastic modulus (G’) of these emulsions on a formulation-composition bidimensional map to study, in particular, the effect of the so-called optimum formulation. Two major effects are observed in relation to this one: emulsions prepared at HLB=10, i.e. at the proximity of optimum value (HLB=10.5) present values of G’ remarkably lower than those at other formulations, while at a certain distance (HLB=7.7) the values of G’ are higher in comparison to others formulations. This last particular HLB matches with the occurrence of a maximum stability and a minimum drop size of dispersion. Highly concentrated emulsions being generally opaque and fragile, the analysis of incoherent polarized steady light transport, that does not imply any dilution, has been used as an alternative method to classical techniques to determine the average film thickness (h). The average drop size (R) has then to be determined from a geometrical model linking it to the average film thickness (h), to the dispersed phase volume fraction (f) and to a geometrical factor (f9) that takes into account the polyhedral shape of the drops. Hence, a modified expression of the model proposed by Mougel et al. (2006) has been established to model the elastic modulus (G’) by relating it to the average drop size (R), the interfacial tension (s) and the dispersed phase volume fraction (f)