京都大学 / 新制・課程博士 / 博士(工学) / 甲第23196号 / 工博第4840号 / 新制||工||1756(附属図書館) / 京都大学大学院工学研究科材料工学専攻 / (主査)教授 辻 伸泰, 教授 田中 功, 教授 乾 晴行 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Chlorinated ethenes are considered one of the most prevalent sources of groundwater contamination in developed countries. Natural attenuation of chlorinated ethenes is possible through the process of microbial reductive dechlorination. Reductive dechlorination can occur in contaminated aquifers where there are sufficient amounts of organic carbon and reducing redox conditions to support dechlorinating microorganisms. Natural organic carbon (NOC) from dissolved aquifer sediment is thought to be the source of fermentable compounds needed to produce molecular hydrogen that functions as the primary electron donor for reductive dechlorination. Therefore, in an anaerobic aquifer, the production of molecular hydrogen from the fermentation of NOC drives the reductive dechlorination process. The variability and distribution of potential bioavailable organic carbon (PBOC) at a site is relatively unknown and any potential relationships between PBOC and the physical properties of the aquifer sediment have not been evaluated. Exploring relationships between the grain size of aquifer sediment PBOC may help to determine the feasibility of natural attenuation as a long-term remediation strategy at chlorinated ethene-contaminated sites. Because hydraulic conductivity is directly related to aquifer sediment grain size, zones of high hydraulic conductivity may promote greater microbial activity or biodegradation because of the increased availability of PBOC and nutrient flux. To determine potential relationships between PBOC and aquifer sediment grain size, two experiments were performed. PBOC was measured for 106 sediment samples impacted by chlorinated solvent contamination from an anaerobic type II site through a multiple liquid extraction process (Rectanus et al. 2007). Grain size distributions for each of the 106 sediment samples were determined by conducting sieve analyses. The results of both experiments were compared to explore relationships between PBOC and sediment grain size and to evaluate spatial distribution of both in the surficial aquifer. / Master of Science

No / This paper proposes that the changes which occur in composition of the bed load during the transport of mixed-grain-size sediments are largely controlled by the distributions of critical entrainment shear stress for the various size fractions. This hypothesis is examined for a unimodal sediment mixture by calculating these distributions with a discrete particle model and using them in a probabilistic calculation of bed-load composition. The estimates of bed-load composition compare favorably with observations of fractional transport rates made in a laboratory flume for the same sediment, suggesting that the hypothesis is reasonable. The analysis provides additional insight, in terms of grain mechanics, into the processes that determine bed-load composition. These insights strongly suggest that better prediction methods will result from taking account of the variation of threshold within size fractions, something that most previous studies have neglected.

Atlantic Meridional Overturning Circulation (AMOC) is a vital process that transfers heat and nutrients throughout the world's oceans, helping to regulate global climate and support marine ecosystems. The timing and nature of the shift to modern AMOC, and especially to deep-water formation in the North Atlantic, has been a topic of ongoing study, with the Eocene-Oligocene Transition (EOT, ~34 Ma) as a potential focal point of this shift. However, the role played by abrupt EOT cooling and Antarctic glaciation in North Atlantic circulation remains unclear. Improved constraints on Paleogene circulation will provide insight into the sensitivity of AMOC to perturbations in global climate, which is particularly relevant in light of contemporary climate change. To examine deep North Atlantic circulation response to the EOT we obtained grain-size data from the terrigenous fraction of the mud-dominated sediments of the Southeast Newfoundland Ridge contourite drift complex at IODP Site U1411, which is interpreted to have formed under the influence of the Deep Western Boundary Current. We analyzed 195 samples that span 150 m of stratigraphy from 36-26 Ma. The main objective was to use the 'sortable silt' fraction (10-63 µm) to generate a record of relative change in bottom-current intensity. These data are complemented with a record of the abundance and size of lithogenic sand (>63 µm). Here we present the first physical proxy record of abyssal current intensity in the North Atlantic, from late Eocene to mid Oligocene. Invigoration of North Atlantic deep circulation occurred gradually (over Myr timescales), with no significant changes linked temporally to the EOT. We infer that deep circulation in the North Atlantic was not sensitive to the abrupt global cooling and Antarctic glaciation associated with the EOT. Rather, our data suggest that changes in North Atlantic circulation were likely governed by longer-term processes related to the opening of key tectonic gateways, such as the Greenland-Scotland Ridge in the North Atlantic, and the Drake and Tasman Passages in the Southern Ocean. Additionally, we identify a significant mid-Oligocene invigoration of North Atlantic abyssal circulation, which climaxes around 27.9 Ma, and is coeval with a decrease in atmospheric CO2. / Master of Science

One of the most important factors that influences a stream's hydraulic and ecological health is the streambed's sediment size distribution. This distribution affects streambed stability, sediment transport rates, and flood levels by defining the roughness of the stream channel. Adverse effects on water quality and wildlife can be expected when excessive fine sediments enter a stream. Many chemicals and toxic materials are transported through streams by binding to fine sediments. Increases in fine sediments also seriously impact the survival of fish species present in the stream. Fine sediments fill tiny spaces between larger particles thereby denying fish embryos the necessary fresh water to survive. Reforestation, constructed wetlands, and slope stabilization are a few management practices typically utilized to reduce the amount of sediment entering a stream. To effectively gauge the success of these techniques, the sediment size distribution of the stream must be monitored. Gravel bed streams are typically stratified vertically, in terms of particle size, in three layers, with each layer having its own distinct grain size distribution. The top two layers of the stream bed, the pavement and subpavement, are the most significant in determining the characteristics of the stream. These top two layers are only as thick as the largest particle size contained within each layer. This vertical stratification by particle size makes it difficult to characterize the grain size distribution of the surface layer. The traditional bulk or volume sampling procedure removes a specified volume of material from the stream bed. However, if the bed exhibits vertical stratification, the volume sample will mix different populations, resulting in inaccurate sample results. To obtain accurate results for the pavement size distribution, a surface oriented sampling technique must be employed. The most common types of surface oriented sampling are grid and areal sampling. Due to limitations in the sampling techniques, grid samples typically truncate the sample at the finer grain sizes, while areal samples typically truncate the sample at the coarser grain sizes. When combined with an analysis technique, either frequency-by-number or frequency-by-weight, the sample results can be represented in terms of a cumulative grain size distribution. However, the results of different sampling and analysis procedures can lead to biased results, which are not equivalent to traditional volume sampling results. Different conversions, dependent on both the sampling and analysis technique, are employed to remove the bias from surface sample results. The topic of the present study is to determine the accuracy of sediment samples obtained by the different sampling techniques. Knowing the accuracy of a sample is imperative if the sample results are to be meaningful. Different methods are discussed for placing confidence intervals on grid sample results based on statistical distributions. The binomial distribution and its approximation with the normal distribution have been suggested for these confidence intervals in previous studies. In this study, the use of the multinomial distribution for these confidence intervals is also explored. The multinomial distribution seems to best represent the grid sampling process. Based on analyses of the different distributions, recommendations are made. Additionally, figures are given to estimate the grid sample size necessary to achieve a required accuracy for each distribution. This type of sample size determination figure is extremely useful when preparing for grid sampling in the field. Accuracy and sample size determination for areal and volume samples present difficulties not encountered with grid sampling. The variability in number of particles contained in the sample coupled with the wide range of particle sizes present make direct statistical analysis impossible. Limited studies have been reported on the necessary volume to sample for gravel deposits. The majority of these studies make recommendations based on empirical results that may not be applicable to different size distributions. Even fewer studies have been published that address the issue of areal sample size. However, using grid sample results as a basis, a technique is presented to estimate the necessary sizes for areal and volume samples. These areal and volume sample sizes are designed to match the accuracy of the original grid sample for a specified grain size percentile of interest. Obtaining grid and areal results with the same accuracy can be useful when considering hybrid samples. A hybrid sample represents a combination of grid and areal sample results that give a final grain size distribution curve that is not truncated. Laboratory experiments were performed on synthetic stream beds to test these theories. The synthetic stream beds were created using both glass beads and natural sediments. Reducing sampling errors and obtaining accurate samples in the field are also briefly discussed. Additionally, recommendations are also made for using the most efficient sampling technique to achieve the required accuracy. / Master of Science

The effect of Laves phase (Fe2Nb) formation on the Charpy impact toughness of the ferritic stainless steel type AISI 441 was investigated. The steel exhibits good toughness after solution treatment at 850°C, but above and below this treatment temperature the impact toughness decreases sharply. With heat treatment below 850°C the presence of the Laves phase on grain boundaries and dislocations plays a significant role in embrittlement of the steel whereas above that temperature, an increase in the grain size from grain growth plays a major role in the impact embrittlement of this alloy. The toughness results agree with the phase equilibrium calculations made using Thermo–Calc® whereby it was observed that a decrease in the Laves phase volume fraction with increasing temperature corresponds to an increase in the impact toughness of the steel. Annealing above 900°C where no Laves phase exists, grain growth is found which similarly has a very negative influence on the steel’s impact properties. Where both a large grain size as well as Laves phase is present, it appears that the grain size may be the dominant embrittlement mechanism. Both the Laves phase and grain growth, therefore, have a significant influence on the impact properties of the steel, while the Laves phase’s precipitation behaviour has also been investigated with reference to the plant’s manufacturing process, particularly the cooling rate after a solution treatment. The microstructural analysis of the grain size shows that there is a steady increase in grain size up to about 950°C, but between 950°C and 1000°C there is a sudden and rapid 60 % increase in the grain size. The TEM analysis of the sample that was annealed at 900°C shows that the Laves phase had already completely dissolved and cannot, therefore, be responsible for “unpinning of grain boundaries” at temperatures of 900°C and higher where this “sudden” increase in grain size was found. The most plausible explanation appears to be one of Nb solute drag that loses its effectiveness within this temperature range, but this probably requires some further study to fully prove this effect. During isothermal annealing within the temperature range of 600 to 850°C, the time – temperature – precipitation (TTP) diagram for the Laves phase as determined from the transformation kinetic curves, shows two classical C noses on the transformation curves. The first one occurring at the higher temperatures of about 750 to 825°C and the second one at much lower temperatures, estimated to possibly be in the range of about 650 to 675°C. The transmission electron microscopy (TEM) analyses show that there are two independent nucleation mechanisms that are occurring within these two temperature ranges. At lower temperatures of about 600°C, the pertaining nucleation mechanism is on dislocations and as the temperature is increased to above 750°C, grain boundary nucleation becomes more dominant. Also, the morphology of the particles and the mis-orientation with the matrix changes with temperature. At lower temperatures the particles are more needle-like in shape, but as the temperature is increased the shape becomes more spheroidal. The effect of the steel’s composition on the Laves phase transformation kinetics shows that by lowering the Nb content in these type 441 stainless steels, had no significance effect on the kinetics on precipitation of the Laves phase. However, a Mo addition and a larger grain size of the steel, retard the formation of the Laves phase, although the optimum values of both parameters still need further quantification. The calculation made for the transformation kinetics of the Laves phase, using the number density of nucleation sites No and the interfacial energy, as the fitting parameters in this work, demonstrated a reasonable agreement with experimental results. / Thesis (PhD)--University of Pretoria, 2010. / Materials Science and Metallurgical Engineering / unrestricted

No description available.

Thesis (MScEng (Civil Engineering))--University of Stellenbosch, 2009. / ENGLISH ABSTRACT: Calculation of longshore sediment transport rates is a typical part of coastal engineering work. One of the important inputs to such calculations is the sediment grain size. A single, representative grain size is typically required. The inter-tidal beach is the most convenient and common area from which grain size data can be obtained. Yet only a fraction of the longshore transport occurs at the beach, with the bulk of the transport occurring in the surf zone, where sampling is difficult. Sediment transport calculations can be improved if the representative grains size is also characteristic of this area. A better understanding how the grain size in the longshore transport zone compares to the beach grain size is required. A review of relevant literature indicates that limited attention has been given to quantifying the grain size in the longshore transport zone. No previous investigations were found that tried to link the longshore transport zone grain size to that found on the beach. A comprehensive analysis of beach and longshore transport zone grain sizes was therefore undertaken and is described in this thesis. Beach grain sizes were compared to those in the longshore transport zone for three different locations around the world: Published grains size information, together with detailed wave and profile data, was obtained from the US Army Field Research Facility at Duck; a second data set was obtained from measurements done at Bogenfels in Namibia; a third dataset was compiled from sampling undertaken by the author in Table Bay, South Africa. A total of 189 samples were collected at four sampling lines in Table Bay between September 2005 and September 2006. Samples were collected across the entire profile from the primary dune to a water depth of 10 m. Samples were collected by grab in the offshore, and by swimming and diving in the surf zone. The location of the four Table Bay sampling lines was chosen so as to obtain data from beaches with different wave and grain size characteristics. Together with the Duck and Bogenfels data, data from six different beaches was therefore available for study. A settling tube was used to determine the grain sizes. Verification of the settling tube analyses against conventional sieving indicated a good comparison. However, the settling tube proved unsuitable for processing of samples with coarse to very coarse material, for which sieving was conducted instead. The grain size at the mid-tide level has been used to characterise the beach. The limits of the longshore transport zone were defined by calculating the cross-shore distribution of longshore transport with the Unibest model. Simpler methods, such as the depth of closure, either overestimated or underestimated it, depending on which wave condition was used in the depth of closure formula. It was found that the beaches with steeper mid-tide beach slopes, such as Bogenfels and northern Table Bay, had coarser median grain sizes than more gently sloping beaches such as found in the south of Table Bay. On energetic beaches, the mid-tide beach grain sizes were significantly coarser than those in the surf zone, by more than twice. At less exposed locations, such as Duck and the central Table Bay beaches, this difference was less. At sheltered locations, such as the southern sampling lines in Table Bay, the mid-tide beach grain sizes are virtually the same as those found in the surf zone. The surf similarity parameter was used to compare the characteristics of the different sites. This parameter was defined using the average wave height seaward of breaking, and the mid-tide beach slope. The ratio between the longshore transport zone grain size and the mid-tide beach grain size was found to be similar to the inverse of the surf similarity parameter for the six beaches that were studied. These findings have led to an improved understanding of the grain size in the longshore transport zone and allow a better characterisation of the representative grain size to use for sediment transport calculations. / AFRIKAANSE OPSOMMING: In kusingenieurswese word langstrandse sedimentvervoer (langsvervoer) gereeld bereken. Belangrike invoer vir sulke berekeninge is die verteenwordigende korrelgrootte van die sand. Die sandkorrelgrootte van die benatte strand is die maklikste om te bepaal, al vind net ‘n klein gedeelte van die langsvervoer op die benatte strand plaas. Die grootste gedeelte van die langsvervoer kom in die brandersone voor, waar dit moeilik is om monsters te neem. Sedimentvervoerberekeninge kan verbeter word as die korrelgrootte ook hierdie sone verteenwoordig. Dit is dus van belang om te verstaan hoe die korrelgrootte van die benatte strand met die gemiddelde korrelgrootte oor die algehele langsvervoersone vergelyk. ‘n Literatuursoektog dui aan dat min aandag al gegee is aan hoe die korrelgrootte op die benatte strand met dié in die langsvervoersone vergelyk. ‘n Ontleding van sandkorrelgroottes op die benatte strand en in die langsvervoersone is dus onderneem en word in die tesis uiteengesit. Strandkorrelgroottes word met dié in die langsvervoersone vergelyk vir drie verskillende gebiede in die wereld : (1) Gepubliseerde data oor korrelgroottes, sowel as strandhellings en golwe, is van die Field Research Facility by Duck in die VSA verkry ; (2) ‘n tweede stel data is van opmetings by Bogenfels in Namibie verkry; (3) die derde stel data is saamgestel deur die skrywer tydens opmetings in Tafelbaai, Suid-Afrika. ‘n Totaal van 189 monsters is tussen September 2005 en September 2006 by vier verskillende opmetingslyne in Tafelbaai geneem. Monsters is geneem van die duin tot in 10 m waterdiepte. In dieper water is grypmonsters geneem, terwyl dié in the brandersone verkry is deur te duik. Die posisie van die vier Tafelbaaise opmetingslyne is gekies om strande met verskillende golftoestande en korrelgroottes te dek. Tesame met die data van Duck en Bogenfels is dus ses datastelle vir ontleding beskikbaar. ‘n Valbuis is gebruik om die korrelgroottes te bepaal. Die valbuismetode het goed met gewone sifresultate vergelyk, behalwe vir monsters met baie growwe korrels. Hiervoor is sifwerk gebruik. Die korrelgrootte van die benatte strand is gebruik om die strand te karakteriseer. Die grense van die langsvervoersone is bepaal deur die dwarsstrandse verdeling van die langsvervoer met die Unibest-model te bereken. Eenvoudiger metodes, soos die berekening van die sluitingsdiepte, het minder betroubare resultate gelewer. Daar is gevind dat steiler benatte strande, soos Bogenfels en Noord-Tafelbaai se strande, groter gemiddelde korrelgroottes as platter benatte strande, soos dié in suidelike Tafelbaai, het. Op blootgestelde strande is die benatte strand se korrelgrootte tot meer as twee keer groter as dié in die brandersone. By gedeeltelik beskutte strande, soos Duck en Sentraal- Tafelbaai se strande, was die verskil minder. Op beskutte strande, soos die Suid-Tafelbaai se strande, is gevind dat die benatte strand se korrelgrootte amper dieselfde as dié in die brandersone is. Die brandergelyksoortigheidsfaktor is gebruik om die verskillende strande te vergelyk. Die golfhoogtes net buite die branderlyn en die benatte strandhelling is gebruik om die veranderlike te bereken. Daar is gevind dat by die ses strande wat ondersoek is, die verhouding van die korrelgrootte in die langsvervoersone en dié van die benatte strand ongeveer gelyk aan die omgekeerde brandergelyksoortigheidsfaktor is. Die bevindings het tot ‘n beter begrip van die wisseling van die korrelgroottes in die langsvervoersone gelei. Gevolglik kan ‘n akkurater verteenwoordigende sandkorrelgrootte bepaal word.

Η λεπτομερής ιζηματολογική ανάλυση των αποθέσεων της τομής Μακρυλιά, έδειξε την ύπαρξη τουλάχιστον 5 κύκλων ιζηματογένεσης με αυξανόμενο προς τα πάνω κοκκομετρικό μέγεθος που αναπτύχτηκαν σε ένα περιβάλλον υφαλοκρηπίδας. Η κύρια λιθολογία είναι αμμούχος πηλός και τα ιζήματα μεταφέρθηκαν ως ομογενές αιώρημα. Το ποσοστό του ανθρακικού ασβεστίου είναι χαμηλό και τείνει αυξανόμενο προς τα πιο αδρομερή κλάσματα. Το ποσοστό του οργανικού υλικού έδειξε την παρουσία αρκετών δειγμάτων με αυξημένο οργανικό υλικό προτείνοντας την ύπαρξη εν δυνάμει μητρικών πετρωμάτων για την γένεση υδρογονανθράκων. Η σχέση μεταξύ του ανθρακικού ασβεστίου και οργανικού υλικού είναι κύρια αρνητική προτείνοντας ανοξικές συνθήκες. Η βιοστρωματογραφική ανάλυση έδειξε Πλειοκαινική ηλικία των ιζημάτων που αποτέθηκαν σε εναλλασσόμενες οξικές – ανοξικές συνθήκες. Από τα παραπάνω αποτελέσματα και περνώντας υπόψη τα υπάρχοντα αποτελέσματα των ιζημάτων που περιβάλλουν την περιοχή μελέτης φαίνεται πως οι μελετηθείσες αποθέσεις συγκεντρώθηκαν σε μια ρηχή με ήσυχα νερά ενδο-ορεινή λεκάνη στα περιθώρια της κύριας λεκάνης της Ιεράπετρας. / Detailed sedimentological analysis, in Makrylia cross-section deposits, showed at least five coarsening-upward cycles developed in a shelf environment. The main lithology is sandy silt and sediments transported as homogenous suspension in a low energy environment that deposited in a shallow water basin. Calcium carbonate (CaCO3) is low and tends to increase to the coarse-grained clasts. Organic carbon (TOC) ratio showed the presence of many high content samples in TOC suggesting potential hydrocarbon source rocks. There is mostly a negative relation between CaCO3 and TOC introducing generally anoxic conditions. Biostratigraphy analysis showed a Pliocene age for the studied deposits in alternating conditions with oxic- anoxic events. According to the above results and taking into account previous results from the surrounding sediments it seems that studied deposits accumulated in a shallow, low energy, intra-mountain basin at the margins of the main Ierapetra basin.

<p>The physical properties of the coarse fraction of the till (0.4 to 20 cm) and the surface boulders have been studied at two different sites in Sweden. The research work included: development of a new image analysis software for 3D size and shape measurements of particles; lithological analysis on multiple size fractions in till and magnetic susceptibility survey on coarse till clasts, surface boulders and local bedrock.</p><p>The new 3D image analysis method provides an enormous amount of size and shape data for each particle in the coarse fraction (2 to 20 cm) in till. The method is suitable for field study, cost effective and the software is executable in Matlab. The field imaging method together with the image analysis software give non subjective results of size and shape of coarse particles and makes it feasible and easy to study representative sample size, which is one tonne for testing clasts of size up to 20 cm.</p><p>The lithological analysis of the multiple size fraction of the till clasts has been investigated on six different size fractions of the till (0.4 to 20 cm); the result of the different samples from the two sites shows that this method can potentially be used as a stratigraphic tool in the areas where there is no unique indicator lithologies.</p><p>The magnetic susceptibility has been made on the surface boulders, the 6-20 cm till fraction and on insitu bedrock outcrops near to the study sites. The method has good potential for determining stratigraphic relationships between different till units as well as for determining the provenance ofcoarse clasts and surface boulders.</p>