The main purpose of this thesis is the modification of the original flange gasket of the VVER1000 pressurizer manhole. Then the construction and function of the pressurizer itself is described, together with detailed calculations of the original and new modified gasket to meet the ČSN EN 1591 standard together with a description of the legislation that has to be followed in the calculations. The comparisons of both gasket types together with main conclusions are placed in the last section of this thesis.

This thesis deals with the replacement of the lid gasket of the primary collector of the steam generator VVER 1000. Original sealing by nickel rings is replaced by kammprofile gasket with expanded graphite layers. The thesis compare the properties of both types of gaskets and the new and the original configuration of flange joint which have been calculated according to EN 1591. The results are compared and conclusions arising therefrom are presented. The work includes results of FEM analysis of the new configuration of the flange joint. There is also a description of the main components of the nuclear power plants VVER 1000 primary circuit in the introductory part which focused on the construction and operation of the steam generator and its primary collector.

The aim of this thesis is to address issues concerning the sealing of the lid for the primary collector within the steam generator (SG) of the nuclear power plant VVER 440. These steam generators are sealed in the original design by nickel rings. Modifying the existing method of sealing by a new type of sealing material, primarily from expanded graphite, can significantly reduce the pressure in the sealing surface and also stress in bolts and flanged joints. The new solution of sealing between the joint of collector and the lid should extend the life of joints and thus the nuclear and technical safety. The text is divided into the theoretical and computational part. A principle of the SG, the SG design, and a description of the joint and lid are mentioned in the theoretical part. The computational part shows calculations of the new joint, the original one, and comparison of both solutions in terms of technical and nuclear safety. The work contains drawing of the new joint.

The electronic structure of the zero-gap two-dimensional graphene has a charge neutrality point exactly at the Fermi level that limits the practical application of this material. There are several ways to modify the Fermi-level-region of graphene, e.g. adsorption of graphene on different substrates or different molecules on its surface. In all cases the so-called dispersion or van der Waals interactions can play a crucial role in the mechanism, which describes the modification of electronic structure of graphene. The adsorption of water on graphene is not very accurately reproduced in the standard density functional theory (DFT) calculations and highly-accurate quantum-chemical treatments are required. A possibility to apply wavefunction-based methods to extended systems is the use of local correlation schemes. The adsorption energies obtained in the present work by means of CCSD(T) are much higher in magnitude than the values calculated with standard DFT functional although they agree that physisorption is observed. The obtained results are compared with the values available in the literature for binding of water on the graphene-like substrates. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

Multifunctional batteries with enhanced safety performance have received considerable attention for their applications at extreme conditions. However, few batteries can endure a mix‐up of battery polarity during charging, a common wrong operation of rechargeable batteries. Herein, a polarity‐switchable battery based on the switchable intercalation feature of graphite is demonstrated. The unique redox‐amphoteric intercalation behavior of graphite allows a reversible switching of graphite between anode and cathode, thus enabling polarity‐switchable symmetric graphite batteries. The large potential gap between anion and cation intercalation delivers a high midpoint device voltage (≈average voltage) of ≈4.5 V. Further, both the graphite anode and cathode are kinetically activated during the polarity switching. Consequently, polarity‐switchable symmetric graphite batteries exhibit a remarkable cycling stability (96% capacity retention after 500 cycles), a high power density of 8.66 kW kg−1, and a high energy density of 227 Wh kg−1 (calculated based on the total weight of active materials in both anode and cathode), which are superior to other symmetric batteries and recently reported dual‐graphite or dual‐carbon batteries. This work will inspire the development of new multifunctional energy‐storage devices based on novel materials and electrolyte systems.

This work is focused on segregation processes in the matrix of spheroidal graphite cast iron with different silicon and nickel content during heat treatment. The aim of this work is to trace the redistribution of the elements of interest during homogenization annealing with different dwell time by comparison of the effective distribution coefficients. Comparison of some specific properties and description of structure development of spheroidal graphite cast iron matrix from initial state to the state after ferritization and homogenization annealing is included in this work.

This doctoral thesis deals with the comparison of different methods of alloying elements’ concentration measurement based on energy dispersive spectroscopy and also with the suitability of particular methods of quantitative assessment of heterogeneity of the spheroidal graphite cast iron matrix. The segregation curves construction, distribution coefficient and heterogeneity index formulation is also discussed. The notion “normalized distribution coefficient” is introduced newly. The goal of the thesis, which is to be achieved by means of evaluation of large experimental data sets, is the evaluation of applicability of homogenization annealing of spheroidal graphite cast iron with the aim to eliminate segregation of silicon, and mainly nickel, as pearlite- and carbide-forming agent at the border of an eutectic cell. The result is an optimized homogenization annealing schedule maximizing the suppression of silicon and nickel segregation while taking into account the minimization of financial expenses and risk of grain coarsening.

The Swedish truck industry is forced to find new material solutions to achieve lighter engines with increased strength. Customers and new environmental regulations demand both higher specific power and more environmentally friendly trucks, and this places a rising pressure on the manufactures. This demand could be met by increasing the peak pressure in the cylinders. Consequently, a more efficient combustion is obtained and the exhaust lowered. This however exposes the engine to higher loads and material physical properties must therefore be enhanced. Today, alloyed gray iron is the predominantly used engine material. This material cannot meet the requirements of tomorrow’s engines. Compacted Graphite Iron has good potential to be the replacement; it opens new design opportunities with its superior strength, which can lead to smaller, more efficient engines and additional power. The question is: how will manufacturing be affected? The main goal of this thesis is to identify and investigate the main factors’ effect and their individual contributions on CGI machining.  When the relationship between the fundamental features; machinability, material microstructure, and material physical properties, are revealed, then the CGI material can be optimized, both regarding the manufacturing process and design requirements. The basic understanding is developed mainly through experimental analysis. No attempt has been made to optimize the material to be used as engine material in this thesis. The thesis demonstrates the importance of having good casting process control. It also illustrates the microstructural properties’ effects on CGI machinability, and what new aspects of machining must be taken into account, compared to gray iron. / QC 20101105 / OPTIMA CGI

No description available.

Um estudo sistemático a respeito da utilização de padrão interno em determinações multielementares por espectrometria de absorção atômica (ETAAS) foi desenvolvido. O objetivo principal do presente trabalho foi verificar a possibilidade de melhorar a precisão e a exatidão dos resultados analíticos, que são obtidos na análise de fluidos biológicos. O pré-tratamento dessas amostras foi simplificado e reduzido a uma única etapa de diluição com surfactante (Triton X-100) e ácido (HNO3). Conseqüentemente, a complexidade da solução diluída de amostra, a ser introduzida no tubo de grafite, apresenta uma elevada quantidade de concomitantes que podem provocar interferências químicas. A seleção preliminar dos elementos a serem testados como padrão interno considerou a semelhança de parâmetros físico-químicos relacionados com o processo de atomização. Desta forma, Ag, Bi, In e Tl foram testados como padrão interno para a determinação simultânea de Cd/Pb em sangue e urina, enquanto Bi, Ge, In, Sb, Sn e Te foram os elementos selecionados para a determinação de Mn/Ni/Se em soro sangüíneo. A melhoria da qualidade dos resultados analíticos obtidos na determinação simultânea de Cd e Pb em sangue foi observada quando Ag foi utilizada como padrão interno, na presença de NH4H2PO4 como modificador químico. Verificou-se uma melhoria na exatidão dos resultados obtidos para Cd e Pb, após a correção com padrão interno. Por outro lado, os resultados obtidos na análise de urina não foram corrigidos por nenhum dos elementos testados. Os melhores resultados para a determinação simultânea de Mn, Ni e Se foram obtidos com a utilização de Bi, Sn e Te como padrão interno. Entretanto, verificou-se que a correção de todos os resultados não seria viável com o uso de um único padrão interno. O melhor desempenho nos testes realizados na presença de soro sangüíneo foi obtido com Bi, que melhorou discretamente a precisão dos resultados obtidos para Se. Desta forma, a padronização interna visando a determinação simultânea de Mn, Ni e Se não foi eficiente. A padronização interna em ETAAS, com a finalidade de melhorar a precisão e a exatidão dos resultados analíticos, é uma estratégia tão complexa, quanto os efeitos interferentes que se pretende corrigir: são necessários mais estudos para compreender melhor como a utilização de uma condição de compromisso afeta os processos de atomização, bem como mais informações a respeito das interferências físicas e químicas causadas por amostras complexas, analisadas por ETAAS após uma simples etapa de diluição. Deve-se considerar com especial atenção o modificador químico e as temperaturas das etapas de pirólise e de atomização empregadas, que são parâmetros críticos para o desempenho de um elemento como padrão interno. / A systematic study involving the use of internal standard for multielement determinations by electrothermal atomic absorption spectrometry was developed. The main objective of this work was evaluate the possibility of improving precision and accuracy of the analytical results for biological fluids. The sample pre-treatment was reduced to a single dilution step with surfactant (Triton X-100) and acid (HNO3), increasing the amount of concomitant introduced into the atomizer. The preliminary selection of the elements to be tested as internal standard considered the resemblance of physico-chemical parameters related with the atomization process. Thus, Ag, Bi, In and Tl were tested as internal standard for the simultaneous determination of Cd/Pb in blood and urine, and Bi, Ge, In, Sb, Sn and Te were the selected elements for the determination of Mn/Ni/Se in blood serum. The correction of the results obtained for the simultaneous determination of Cd and Pb in blood was achieved when Ag was used as internal standard, in presence of NH4H2PO4 as chemical modifier. An improvement for the accuracy of the results was observed for both analytes after their correction with the internal standard. On the other hand, the results obtained for the urine analysis were not corrected by using the tested elements. The best results for the simultaneous determination of Mn, Ni and Se were observed when Bi, Sn and Te were used as internal standard. However, the correction for the results for all analytes was not possible by using only one internal standard. The best performance in presence of the serum was obtained for Bi, which improves slightly the precision for the Se results. Thus, the internal standardization for the simultaneous determination of Mn, Ni and Se was not efficient. The internal standardization in ETAAS, aiming the improvement of precision and accuracy of the analytical results, is a strategy as complex as the interference effects to be corrected: more studies are required in order to better understand how the adoption of a compromised condition disturbs the atomization processes, as well as to get more information about the physical and chemical interference caused by complex samples, analyzed by ETAAS after a single dilution step. The chemical modifier and the selected temperatures for the pyrolysis and atomization steps are critical parameters for the performace of an internal standard and they should be carefully considered.