abstract: Being a remarkably versatile and inexpensive building material, concrete has found tremendous use in development of modern infrastructure and is the most widely used material in the world. Extensive research in the field of concrete has led to the development of a wide array of concretes with applications ranging from building of skyscrapers to paving of highways. These varied applications require special cementitious composites which can satisfy the demand for enhanced functionalities such as high strength, high durability and improved thermal characteristics among others. The current study focuses on the fundamental understanding of such functional composites, from their microstructural design to macro-scale application. More specifically, this study investigates three different categories of functional cementitious composites. First, it discusses the differences between cementitious systems containing interground and blended limestone with and without alumina. The interground systems are found to outperform the blended systems due to differential grinding of limestone. A novel approach to deduce the particle size distribution of limestone and cement in the interground systems is proposed. Secondly, the study delves into the realm of ultra-high performance concrete, a novel material which possesses extremely high compressive-, tensile- and flexural-strength and service life as compared to regular concrete. The study presents a novel first principles-based paradigm to design economical ultra-high performance concretes using locally available materials. In the final part, the study addresses the thermal benefits of a novel type of concrete containing phase change materials. A software package was designed to perform numerical simulations to analyze temperature profiles and thermal stresses in concrete structures containing PCMs. The design of these materials is accompanied by material characterization of cementitious binders. This has been accomplished using techniques that involve measurement of heat evolution (isothermal calorimetry), determination and quantification of reaction products (thermo-gravimetric analysis, x-ray diffraction, micro-indentation, scanning electron microscopy, energy-dispersive x-ray spectroscopy) and evaluation of pore-size distribution (mercury intrusion porosimetry). In addition, macro-scale testing has been carried out to determine compression, flexure and durability response. Numerical simulations have been carried out to understand hydration of cementitious composites, determine optimum particle packing and determine the thermal performance of these composites. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2018

It is important to ensure that vulnerable structures (federal and provincial offices, military structures, embassies, etc) are blast resistant to safeguard life and critical infrastructure. In the wake of recent malicious attacks and accidental explosions, it is becoming increasingly important to ensure that columns in structures are properly detailed to provide the ductility and continuity necessary to prevent progressive collapse. Research has shown that steel fibre reinforced concrete (SFRC) can enhance many of the properties of concrete, including improved post-cracking tensile capacity, enhanced shear resistance, and increased ductility. The enhanced properties of SFRC make it an ideal candidate for use in the blast resistant design of structures. There is limited research on the behaviour of SFRC under high strain rates, including impact and blast loading, and some of this data is conflicting, with some researchers showing that the additional ductility normally evident in SFRC is absent or reduced at high strain loading. On the other hand, other data indicates that SFRC can improve toughness and energy-absorption capacity under extreme loading conditions. This thesis presents the results of experimental research involving tests of scaled reinforced concrete columns exposed to shock wave induced impulsive loads using the University of Ottawa Shock Tube. A total of 13 half-scale steel fibre reinforced concrete columns, 8 with normal strength steel fibre reinforced concrete (SFRC) and 5 with an ultra high performance fibre reinforced concrete (UHPFRC), were constructed and tested under simulated blast pressures. The columns were designed according to CSA A23.3 standards for both seismic and non-seismic regions, using various fibre amounts and types. Each column was exposed to similar shock wave loads in order to provide direct comparisons between seismic and non-seismically detailed columns, amount of steel fibres, type of steel fibres, and type of concrete. The dynamic response of the columns tested in the experimental program is predicted by generating dynamic load-deformation resistance functions for SFRC and UHPFRC columns and using single degree of freedom dynamic analysis software, RCBlast. The analytical results are compared to experimental data, and shown to accurately predict the maximum mid-span displacements of the fibre reinforced concrete columns under shock wave loading.

The load-carrying and energy-dissipation capacities of ultra-high-performance concrete (UHPC) under dynamic loading are evaluated in relation to microstructure composition at strain rates on the order of 10⁵ s⁻¹ and pressures of up to 10 GPa. Analysis focuses on deformation and failure mechanisms at the mesostructural level. A cohesive finite element framework that allows explicit account of constituent phases, interfaces, and fracture is used. The model resolves essential deformation and failure mechanisms in addition to providing a phenomenological account of the effects of the phase transformation. Four modes of energy dissipation are tracked, including pressure-sensitive inelastic deformation, damage through the development of distributed cracks, interfacial friction, and energy released through phase transformation of the quartz silica constituent. Simulations are carried out over a range of volume fractions of constituent phases to quantify trends that can be used to design materials for more damage-resistant structures. Calculations show that the volume fractions of the constituents have more influence on the energy-dissipation capacity than on the load-carrying capacity, that inelastic deformation is the source of over 70% of the energy dissipation, and that the presence of porosity changes the role of fibers in the dissipation process. The results also show that the phase transformation has a significant effect on the load-carrying and energy-dissipation capacities of UHPC for the conditions studied. Although transformation accounts for less than 2% of the total energy dissipation, the phase transformation leads to a twofold increase in the crack density and yields nearly an 18% increase to the overall energy dissipation. Microstructure-behavior relations are established to facilitate materials design and tailoring for target-specific applications.

Der vorliegende Bericht beschreibt das Verhalten von ultrahochfestem Beton unter zweiaxialer Druckbeanspruchung. Bisher wurden ein Feinkornbeton und zwei Grobkornbetone mit unterschiedlichen Faserzusätzen untersucht. Die Zylinderdruckfestigkeiten nach 28 Tagen betragen rund 150, 160 und 170 N/mm². Besonders bei dem Feinkornbeton wurde eine überwiegend horizontale Ausrichtung der Stahlfasern festgestellt, die zu einer Anisotropie im Materialverhalten führte. Zusammenfassend muss festgestellt werden, dass die zweiaxiale Druckfestigkeit von UHPC nur geringfügig größer ist als die einaxiale. Für die Mischungen mit 2,5 Vol.-% Fasergehalt übersteigt die Festigkeit bei einem Spannungsverhältnis von Spannung 1 zu Spannung 2 gleich Eins die einaxiale Festigkeit um 7 bzw. 10 %. Bei dem Beton mit 0,9 Vol.-% Fasergehalt lag diese zweiaxiale Festigkeit sogar geringfügig unter der einaxialen. Bei der Bemessung von UHPC dürfen somit die vom Normalbeton bekannten Festigkeitssteigerungen unter mehraxialer Druckbelastung, wie sie z.B. bei reinen Druckknoten von Stabwerkmodellen angesetzt werden, nicht verwendet werden! Für die Beschreibung der Bruchkurve kann nach jetzigem Erkenntnisstand das Bruchkriterium nach OTTOSEN als eine gute Näherung empfohlen werden. Die Versuche haben gezeigt, dass sich UHPC in vielen, zum Teil sicherheitsrelevanten Bereichen anders verhält als Normalbeton. Für eine umfassende Beschreibung des Tragverhaltens sind weitere Versuche unter dreiaxiale Druckbelastung und kombinierter Druck-Zug-Belastung notwendig.

O objetivo de colaborar com o equacionamento da problemática do crescimento populacional por meio de uma proposta viável economicamente, e com vantagens tecnológicas com vistas à durabilidade para a armazenagem de gêneros alimentícios em baixas temperaturas motivou o desenvolvimento desta pesquisa, na qual se propõe o uso do concreto como material alternativo para a construção de sistemas de guarda e conservação de alimentos. A partir de um adequado método de dosagem e da tecnologia desenvolvida pelo grupo de pesquisadores do Laboratório de Materiais Avançados à Base de Cimento, foram elaborados dois concretos diferenciados pela incorporação ou não de ar. A durabilidade do concreto para ambientes com baixas temperaturas tem sido relacionada a um sistema de vazios de ar com volume de 6 '+ OU -' 1 % e adequado espaçamento entre as bolhas de ar. O desempenho desses concretos em ambientes com baixas temperaturas foi avaliado acondicionando-os em uma câmara fria com temperatura de - 35 ± 2 graus Celsius. A sanidade dos corpos-de-prova foi monitorada por meio de ensaios não destrutivos (i.e. determinação da freqüência natural). O período de exposição foi de trinta e cinco dias, sendo que após o sétimo dia ocorreu a estabilização dos valores da freqüência natural dos corpos-de-prova. Os dois tipos de concretos ensaiados - com ar incorporado e sem ar incorporado - mostraram-se resistentes nestas condições de ensaio. Os resultados obtidos demonstram que os concretos, de acordo com o método utilizado, atendem a todos os requisitos para os quais foram projetados / The aim to collaborate with the set out of the world population increase problem, using a feasible and economical proposal, with technology advantages, destined to store foodstuff in low temperatures, motivated the development of this research, that suggests concrete as an alternative material to storage and conservation foodstuff system construction. Starting from the concrete design with an adequate method, and based on the technology developed by worker group of Laboratory of Advanced Cement Based Materials, were designed two kinds of concrete: with and without incorporated air. The durability of concrete in low temperatures environment were related to air voids system with 6 '+ OU -' 1% of air content, and to adequate spacing between air voids. The concrete behaviour in low temperatures environment was evaluated placing the specimens in a cold chamber, whose temperatures were about -35 '+ OU -' 2 Celsius degrees. The integrity of the specimens was evaluated by non-destructive method (determination of natural frequency). The exposure period of the specimens was thirty five days, but at seventh day the natural frequencies values were stabilized. Both kind of concrete were resistant in this condition. The obtained results show that concretes, in conformity to the used methodology, performed all requirement for that were designed

O concreto de elevado desempenho (CED) é aquele que atende aos requisitos de durabilidade e de resistência mecânica da construção, produzido a partir de materiais selecionados, com equipamentos eficientes e procedimentos controlados. Desenvolveu-se, assim, um estudo experimental, tendo como objetivo principal analisar e estabelecer correlações a partir de propriedades mecânicas e de durabilidade com a microestrutura da matriz. Para tanto, considera-se: a) emprego de agregados da região de São Carlos SP, analisando as suas características fundamentais; b) o emprego de cimentos Portland CP II E 32, CP V ARI Plus e CP V ARI RS em conformidade com ABNT, estabelecendo uma sinergia com os outros materiais envolvidos; c) o estabelecimento de dosagens buscando uma maior compacidade; d) a relação entre os constituintes, correlacionando-os com as formas produtivas e características de aplicações; e) o acompanhamento do desenvolvimento da hidratação e da microestrutura das composições estabelecidas e da influência adição da sílica ativa na matriz como um todo. A análise da microestrutura fundamentou-se em ensaios de poro simetria por intrusão de mercúrio, poro simetria por adsorção de gás nitrogênio, microscopia eletrônica de varredura, termogravimetria e difração de raio-X. Os resultados indicam que a sílica ativa tem forte influência na qualidade dos concretos de alto desempenho, principalmente quando em associação com escória de alto fomo, indicando a possibilidade de se produzir concretos duráveis. Da mesma forma, os resultados mecânicos sugerem excelentes perspectivas na produção do CED, com altas resistências à compressão, na faixa de até 110MPa, à tração na flexão da ordem de 10MPa e resistência à abrasão cerca de 40% superior a dos concretos convencionais. / High performance concrete (HPC) is concrete that meets the requisites of hardness and mechanical strength of construction applications, and is produced with selected materiaIs, efficient equipment and controlled procedures. An experimental study was carried out with the main purpose of analyzing and establishing correlations based on mechanical properties and durability of the matrix\'s microstructure. To this end, the following factors were taken into consideration: a) the use of aggregates available in the region of São Carlos, SP, analyzing their fundamental characteristics; b) the use of Portland CP II E 32, CP V AR! Plus and CP V AR! RS cements according to the ABNT code, establishing a synergy with the other materiais involved; c) the establishment of dosages in the search for greater compactness; d) the relation among the constituents, correlating them with the forms of production and characteristics of application; e) follow-up of the development of hydration and of the microstructures of the compositions established, and the influence of the addition of active silica in the matrix as a whole. The microstructural analysis was based on tests of porosity by mercury intrusion, porosity by adsorption of nitrogen gas, scanning electron microscopy, thermogravimetry and X-ray diffraction. The results indicate that active silica exerts a strong influence on the quality of high performance concretes, particularly when associated with slag, indicating the possibility of producing durable concretes. Similarly, the mechanical findings suggest excellent prospects for HPC production, with high compressive strength in the range of up to 110MPa, flexural strength in the order of 10MPa, and abrasive strength approximately 40% superior to that of conventional concretes.

Submitted by Geyciane Santos (geyciane_thamires@hotmail.com) on 2015-09-30T15:03:49Z No. of bitstreams: 1 Dissertação - Luciano Moreira de Sousa Neto.pdf: 29845322 bytes, checksum: d7781fb07ffa9fee00b00aa4bd8a416f (MD5) / Approved for entry into archive by Divisão de Documentação/BC Biblioteca Central (ddbc@ufam.edu.br) on 2015-09-30T18:57:55Z (GMT) No. of bitstreams: 1 Dissertação - Luciano Moreira de Sousa Neto.pdf: 29845322 bytes, checksum: d7781fb07ffa9fee00b00aa4bd8a416f (MD5) / Approved for entry into archive by Divisão de Documentação/BC Biblioteca Central (ddbc@ufam.edu.br) on 2015-09-30T19:01:17Z (GMT) No. of bitstreams: 1 Dissertação - Luciano Moreira de Sousa Neto.pdf: 29845322 bytes, checksum: d7781fb07ffa9fee00b00aa4bd8a416f (MD5) / Made available in DSpace on 2015-09-30T19:01:17Z (GMT). No. of bitstreams: 1 Dissertação - Luciano Moreira de Sousa Neto.pdf: 29845322 bytes, checksum: d7781fb07ffa9fee00b00aa4bd8a416f (MD5) Previous issue date: 2014-03-21 / Não Informada / High performance concrete, in addition to high strength, has lower permeability and higher durability. The self-compacting concrete reduces the need for densification and scattering and facilitates concreting of slender pieces. The combination of these two concrete on one allows the linking of the qualities of both. In the construction industry, concrete production has potential to reuse some kinds of residues. In this work, the residue of industrial glass was used as mineral additive in the combined production of high performance concrete and self-compacting concrete. The residue of industrial glass, after the grinding process, was added to the concrete with the aim to evaluate its properties in fresh and hardened state. It was possible to evaluate and compare the performance of industrial waste glass with silica fume. Following the experimental program, the materials were characterized and Marsh Funnel tests and minicone of Kantro were performed with the superplasticizer MC-PowerFlow 1102. The optimum dosage of superplasticizer was evaluated in fresh concrete tests. Concrete were produced and characterized in fresh and hardened states. For characterization of concrete in the fresh state, the following tests were used: slump flow, T500, L box, funnel method V and segregation column method. For characterization of concrete in the hardened state, the following tests were performed: axial compression tests, traction by diametrical compression, static modulus of elasticity and water absorption by immersion. Concrete with the addition of waste ground glass hit resistance close to 67 MPa at 90 days, while the concrete with addition of silica fume hit resistance close to 88 MPa at the same age. As the concrete produced with addition of industrial waste glass obtained swift technical skills of high performance concrete and selfcompacting concrete, the results of this research were considered satisfactory. / O concreto de alto desempenho, além de alta resistência, tem baixa permeabilidade e maior durabilidade. O concreto autoadensável reduz a necessidade de adensamento e espalhamento e facilita a concretagem de peças esbeltas. A combinação desses dois concretos em um só permite a junção das qualidades de ambos. Na indústria da construção civil, a produção de concreto é um celeiro potencial para reutilizar alguns tipos de resíduos. Neste trabalho, o resíduo de vidro industrial foi usado como aditivo mineral na produção combinada de concreto de alto desempenho e autoadensável. O resíduo de vidro industrial, após o processo de moagem, foi adicionado ao concreto, com o objetivo de avaliar as suas propriedades no estado fresco e endurecido. Foi possível avaliar e comparar o desempenho do resíduo de vidro industrial com a sílica ativa. Seguindo o programa experimental, os materiais foram caracterizados e ensaios de funil de Marsh e minicone de Kantro foram realizados com o superplastificante MC-PowerFlow 1102. A dosagem ótima do superplastificante foi avaliada em ensaios de concreto fresco. Os concretos foram produzidos e caracterizados nos estados fresco e endurecido. Para a caracterização do concreto no estado fresco, foram realizados os seguintes ensaios: slump flow, T500, caixa L, método de funil V e método da coluna de segregação. Para a caracterização do concreto no estado endurecido, foram realizados os seguintes ensaios: ensaio de compressão axial, tração por compressão diametral, determinação do módulo de compressão estático de elasticidade e determinação de absorção de água por imersão. O concreto com a adição de resíduo de vidro moído atingiu resistência próxima de 67 MPa aos 90 dias, enquanto o concreto com a adição de sílica ativa atingiu resistência próxima de 88 MPa na mesma idade. Como o concreto produzido com adição de resíduos de vidro industrial obteve qualidades técnicas de concreto de alto desempenho e de concreto autoadensável, os resultados desta pesquisa foram considerados satisfatórios.

A incorporação de resíduos industriais ao concreto, tais como as pozolanas, é uma das soluções para o aproveitamento de subprodutos poluentes estando em acordo com os princípios da sustentabilidade. É objetivo do trabalho discutir e analisar a viabilidade da aplicação de um resíduo das termoelétricas da indústria de beneficiamento do arroz, a cinza da casca de arroz (CCA), como adição mineral em concretos duráveis. Com 88% de sílica em sua composição, a CCA tem grande potencial de utilização em concretos porque possibilita o aumento da resistência à compressão pelas suas características de alta pozolanicidade e grande finura. Misturas de argamassas padrão contendo 0, 5, 10 e 15% de CCA moídas apenas industrialmente e com moagem adicional de 1 hora, foram confeccionadas a fim de se avaliar o comportamento do aglomerante (CPV - ARI PLUS + CCA) em relação à resistência mecânica. Concretos com traços 1:3,5, 1:5 e 1:6,5, relação água-aglomerante igual a 0,45 e 15% de CCA foram ensaiados à compressão. Os ensaios mostraram que a CCA é predominantemente cristalina e tem alta pozolanicidade. Quanto às argamassas padrão e aos concretos, os resultados mostraram que a utilização da CCA em compósitos à base de cimento é viável, além de ser ecologicamente correta. / Industrial residues, such as pozzolan, can be incorporated in concretes as a solution for polluter refuses, according to sustainable principles. The objective of this work it is to discuss and analyze the use of rice thermoeletrical industry residue, the rice rusk ash (RHA), as mineral addition in durable concretes. The RHA can be used to increase the compression strength of concretes once it has high pozzolanicity and thinness, composed by 88% of silica. It was created mixtures of standard mortars containing 0, 5 10 and 15% of industrial grounded RHA and also with one hour of additional grind. The idea of those mixtures was to evaluate the mechanical strength of the agglomerate (pure Portland cement + RHA). Compression tests in poor, normal and rich concretes with water/agglomerate ratio of 0,45 and 15% of RHA were set too. The tests indicated that the RHA is predominant crystalline and it is a high pozzolanicity material. All the analyses showed that the material has suitable and competitive characteristics for application as agglomerate component.

Pour les poutres et les dalles ne comportant pas d'armatures de cisaillement, la résistance à l'effort tranchant ou au poinçonnement est souvent un critère important de dimensionnement. Ce type de rupture est caractérisé par un comportement fragile pouvant conduire à l'effondrement partiel voir total de la structure. Malgré de nombreuse recherche dans ce domaine, la résistance à l'effort tranchant et au poinçonnement des structure en béton armé ou précontraint demeure un phénomène complexe et dont l'approche normative est souvent empirique est simplifiée. La capacité des bétons renforcés de fibres métalliques à réduire voir à remplacer totalement les armatures de cisaillement des structures en béton armé et précontraint a été mis en évidence par plusieurs études expérimentales. Cependant, et malgré ses nombreux atouts, l'application à l'échelle industrielle des bétons de fibres est restée marginal, principalement due au manques d'un cadre normatif cohérent et reconnu. Les processus fixes d'une usine de préfabrication d'éléments en béton offre des possibilités optimales pour utiliser des matériaux cimentaires à hautes performances tel que les bétons autoplaçant, les bétons à hautes résistances, etc. Du point de vue de l'auteur, l'utilisation de bétons à hautes performances renforcés de fibres métalliques est le pas de développement et d'optimisation pour cette industrie. Les Bétons Fibrés à Hautes Performances (BFHP) reprennent une matrice similaire aux Bétons à Hautes Performances (BHP) auxquels est ajouté une certaine quantité de fibres métalliques conférant au matériau un comportement au niveau de la structure exploitable dans le dimensionnement. Les BFHP présentent un ratio résistances/coûts intéressant ainsi qu'une alternative au Béton Fibré Ultra-Performants (BFUP). L'objectif principal de ce travail est d'analyser le comportement au cisaillement et au poinçonnement d'éléments de structures en BFHP et en BFUP sans armatures de cisaillement et proposé des recommandations et des règles de dimensionnement adaptées aux ingénieurs de la pratique (…) / For members and flat slabs without shear reinforcement, the shear and punching shear strength are often the determining design criteria. These failure modes are characterized by a fragile behaviour implying possible partial or total collapse of the structure. Despite extensive research in this field, shear and punching shear in reinforced and prestressed concrete structures, remain complex phenomena so much that the current approach is often empirical or simplified. The ability of Steel Fibre Reinforced Concrete (SFRC) to reduce shear reinforcement in reinforced and prestressed concrete members and slabs,or even eliminate it, is supported by several experimental studies. However its practical application remains marginal mainly due to the lack of standard, procedures and rules adapted to its performance. The stationary processes in precast industry offer optimal possibilities for using high performance cementitious materials such as Self Compacting Concrete (SCC) and High Strength Concrete (HSC). For the author, the combination of High Performance Concrete and steel fibres is the following step in the development and the optimization of this industry. The High Performance Fibre Reinforced Concrete (HPFRC) stands between conventional SFRC and Ultra-High Performance Fibre Reinforced Concrete (UHPFRC). The HPFRC exhibiting a good strength/cost ratio is, thus, an alternative of UHPFRC for precast elements. The principal aim of this work was to analyse the shear and punching shear behaviour of HPFRC and UHPFRC structures without transversal reinforcement and to propose recommendations and design models adapted for practitioners. Several experimental studies on structural elements, i.e. beams and slabs, were undertaken for this purpose. Firstly, an original experimental campaign was performed on pre-tensioned members in HPFRC. A total number of six shear-critical beams of a 3.6 m span each, and two full scale beams of a 12 m span each, were tested in order to evaluate the shear and flexural strength. The principal parameter between the specimens was the fibres (…)

At an average age of 42 years, 10% of the nation’s over 607,000 bridges are posted for load restrictions, with an additional 15% considered structurally deficient or functionally obsolete. While there are major concerns with decks in 75% of structurally deficient bridges, often weight and geometry of the deck further limit the load rating and functionality of the bridge. Traditional deck systems and construction methods usually lead to prolonged periods of traffic delays, limiting options for transportation agencies to replace or widen a bridge, especially in urban areas. The purpose of this study was to develop a new generation of ultra-lightweight super shallow solid deck systems to replace open grid steel decks on movable bridges and as well serve as a viable alternative in bridge deck replacements across the country. The study has led to a lightweight low-profile asymmetric waffle deck made with advanced materials. The asymmetry comes from the arrangement of primary and secondary ribs, respectively perpendicular and parallel to the direction of traffic. The waffle deck is made with ultrahigh performance concrete (UHPC) reinforced with either high-strength steel (HSS) or carbon fiber reinforced polymer (CFRP) reinforcement. With this combination, the deck weight was limited to below 21 psf and its overall depth to only 4 inch, while still meeting the strength and ductility demands for 4 ft. typical stringer spacing. It was further envisioned that the ultra-high strength of UHPC is best matched with the high strength of HSS or CFRP reinforcement for an efficient system and the ductile behavior of UHPC can help mask the linear elastic response of CFRP reinforcement and result in an overall ductile system. The issues of consideration from the design and constructability perspectives have included strength and stiffness, bond and development length for the reinforcement, punching shear and panel action. A series of experiments were conducted to help address these issues. Additionally full-size panels were made for testing under heavy vehicle simulator (HVS) at the accelerated pavement testing (APT) facility in Gainesville. Detailed finite element analyses were also carried out to help guide the design of this new generation of bridge decks. The research has confirmed the superior performance of the new deck system and its feasibility.